Rate Of Depletion Research Articles

FLASH radiotherapy sparing effect on the circulating lymphocytes in pencil beam scanning proton therapy: impact of hypofractionation and dose rate

Purpose. The sparing effect of ultra-high dose rate (FLASH) radiotherapy has been reported, but its potential to mitigate depletion of circulating blood and lymphocytes (CL) has not been investigated in pencil-beam scanning-based (PBS) proton therapy, which could potentially reduce the risk of radiation-induced lymphopenia. Material and methods. A time-dependent framework was used to score the dose to the CL during the course of radiotherapy. For brain patients, cerebral vasculatures were semi-automatic segmented from 3T MR-angiography data. A dynamic beam delivery system was developed capable of simulating spatially varying instantaneous dose rates of PBS treatment plans, and which is based on realistic beam delivery parameters that are available clinically. We simulated single and different hypofractionated PBS intensity modulated proton therapy (IMPT) FLASH schemes using 600 nA beam current along with conventionally fractionated IMPT treatment plan at 2 nA beam current. The dosimetric impact of treatment schemes on CL was quantified, and we also evaluated the depletion in subsets of CL based on their radiosensitivity. Results. The proton FLASH sparing effect on CL was observed. In single-fraction PBS FLASH, just 1.5% of peripheral blood was irradiated, whereas hypofractionated FLASH irradiated 7.3% of peripheral blood. In contrast, conventional fractionated IMPT exposed 42.4% of peripheral blood to radiation. PBS FLASH reduced the depletion rate of CL by 69.2% when compared to conventional fractionated IMPT. Conclusion. Our dosimetric blood flow model provides quantitative measures of the PBS FLASH sparing effect on the CL in radiotherapy for brain cancer. FLASH Single treatment fraction offers superior CL sparing when compared to hypofractionated FLASH and conventional IMPT, supporting assumptions about reducing risks of lymphopenia compared to proton therapy at conventional dose rates. The results also indicate that faster conformal FLASH delivery, such as passive patient-specific energy modulation, may further enhance the sparing of the immune system.

Effect of hormone-induced plasma membrane phosphatidylinositol 4,5-bisphosphate depletion on receptor endocytosis suggests the importance of local regulation in phosphoinositide signaling

Phosphatidylinositol 4,5-bisphosphate (PIP2) has been shown to be critical for the endocytosis of G protein-coupled receptors (GPCRs). We have previously demonstrated that depletion of PIP2 by chemically induced plasma membrane (PM) recruitment of a 5-phosphatase domain prevents the internalization of the β2 adrenergic receptor (β2AR) from the PM to early endosomes. In this study, we tested the effect of hormone-induced PM PIP2 depletion on β2AR internalization using type-1 angiotensin receptor (AT1R) or M3 muscarinic acetylcholine receptor (M3R). We followed the endocytic route of β2ARs in HEK 293T cells using bioluminescence resonance energy transfer between the receptor and endosome marker Rab5. To compare the effect of lipid depletion by different means, we created and tested an AT1R fusion protein that is capable of both recruitment-based and hormone-induced depletion methods. The rate of PM PIP2 depletion was measured using a biosensor based on the PH domain of phospholipase Cδ1. As expected, β2AR internalization was inhibited when PIP2 depletion was evoked by recruiting 5-phosphatase to PM-anchored AT1R. A similar inhibition occurred when wild-type AT1R was activated by adding angiotensin II. However, stimulation of the desensitization/internalization-impaired mutant AT1R (TSTS/4A) caused very little inhibition of β2AR internalization, despite the higher rate of measurable PIP2 depletion. Interestingly, inhibition of PIP2 resynthesis with the selective PI4KA inhibitor GSK-A1 had little effect on the change in PH-domain-measured PM PIP2 levels but did significantly decrease β2AR internalization upon either AT1R or M3R activation, indicating the importance of a locally synthetized phosphoinositide pool in the regulation of this process.

Depletion rates of O2-naphthenic acids from oil sands process-affected water in wetland microcosms.

Treatment wetland microcosms were constructed to evaluate the fate of O2-naphthenic acids in microcosm reactors containing OSPW only (i.e., natural attenuation), OSPW with peat soil (sorption and microbial degradation), and cattail microcosm reactors (plant-mediated uptake and biotransformation). Depletion in OSPW occurs by mechanisms of natural attenuation, sorption and microbial degradation, and plant-mediated uptake and biotransformation. The average rate of depletion for O2-naphthenic acids was 0.005 (SD 0.010) per day in OSPW only, 0.029 (SD 0.013) per day in OSPW with peat soil, and 0.043 (SD 0.013) per day in cattail microcosm reactors. Slow rates of depletion from OSPW by natural attenuation highlight the need to develop effective remediation strategies for OSPW, and the increase in rates of depletion for cattail microcosm reactors highlights the importance of wetland vegetation in supporting naphthenic acid removal from OSPW. Reactors containing OSPW with peat soil showed the greatest increase in rates of O2-naphthenic acid depletion for lower molecular weight congeners compared to reactors with OSPW only. Cattail microcosm reactors showed the greatest increase in the rates of O2-naphthenic acid depletion for higher molecular weight congeners compared to reactors with OSPW and peat soil.

Effects of alcohols as sacrificial reagents on a copper-doped sodium dititanate nanosheets/graphene oxide photocatalyst in CO2 photoreduction.

Carbon dioxide (CO2) photoreduction is an intriguing approach that converts CO2 into high-value substances with the assistance of a photocatalyst. Key to effective photoreduction is to promote the interaction of photo-induced holes and a sacrificial reagent (SCR), separating the holes from photoelectrons and enhancing the rate of the subsequent product generation. Methanol, ethanol, isopropanol, and water SCRs were tested for their ability to assist a copper-doped sodium dititanate nanosheets/graphene oxide heterostructure (CTGN) in CO2 photoreduction. The CTGN photocatalyst was suspended in a CO2-saturated aqueous solution with the assigned SCR while illuminated by a mercury lamp. Product samples from the gas and liquid phases were analyzed for targeted product compositions. Methanol SCR exhibited the best performance in facilitating CO2 photoreduction, producing ethanol as the main product at a total carbon consumption (TCC) of 6544 μmol gcat -1. The remarkable performance of methanol is attributed to the high diffusivity and excellent stability of the hydroxymethyl radical that developed during the photoreduction. The kinetics studies revealed the first and second order for the CO2 depletion and product generation rates, respectively, for the alcohol SCRs.

Pregled proizvodnje biodizela transesterifikacijom esterifikovanog ulja Carica Papaia (CSO)

As a result of global urbanization and modernization, the use of petroleum (fossil fuel) is on the increase and there are growing concerns among stakeholders in the oil and gas industry over the depletion rate of petroleum reserves and its rising cost. The conversion of readily available sources of biomass to produce different types of biofuels to address the future energy crisis is one of the preferred attractive choices. Biodiesel is generally produced by the transesterification reaction of vegetable oils, waste vegetable oil or animal fats in the presence of a suitable catalyst. The choice of biodiesel as a preferred renewable source of energy was based on its biodegradability, non-toxic, lower emissions, sulphur free, low levels of polycyclic aromatic hydrocarbons (PAHs) and their nitrated compounds. This alternative source of energy is environmentally friendly and could be used in the existing diesel engines with little or no modifications. This will reduce the world's dependence on fossil fuels that are non-renewable with the attendant environmental benefits to mankind. However, the use of these edible vegetable oils will put pressure on the food uses of such oil which will result to fuel-food crisis in the future. This impending crisis can be readily averted by exploring non-edible crops/agricultural waste biomass that can be grown or harnessed domestically and capable of producing oils as valuable raw materials for the emerging industry. A free fatty acid (FFA) lower than 3% is necessary to carry out the base catalysed reaction to end. For biodiesel production, the higher the acid value of the oil, the lesser the conversion efficiency hence the need for esterification process. Papaya seed contains 27.3% to 28.3% protein, 28.2% to 30.7% lipids, and 19.1% to 22.6% crude fibers, it is not economically used. The majority of seeds are produced as residues and discarded as agricultural waste during fruit processing, generating environmental issues. Oil is abundant in papaya seeds (13.9% to 40.0%), which is rich in monounsaturated fatty acids and beneficial phytochemicals as tocopherol, carotene, and phenolics. This provides information on how to reduce pollution and make waste seeds lucrative. As a result, the CPSO is receiving an increasing amount of attention.

Vacuum-ultraviolet irradiation of pyridine:acetylene ices relevant to Titan astrochemistry.

Nitrogen-containing polycyclic aromatic hydrocarbons (NPAHs) are important molecules for astrochemistry and prebiotic chemistry, as their occurrence spans from interstellar molecular clouds to planetary systems. Their formation has been previously explored in gas phase experiments, but the role of solid-state chemical reactions in their formation under cryogenic conditions remains elusive. Here, we explore the formation of NPAHs through vacuum ultraviolet (VUV) irradiation of pyridine:acetylene ices in amorphous and co-crystalline phases, with the aim to simulate conditions relevant to the interstellar medium and Titan's atmosphere. Our results show that the synthesis of ethynylpyridines from VUV-irradiated pyridine:acetylene amorphous ices is achievable at 18 K. In the co-crystal phase, photolysis at 110 K leads to the formation of NPAHs such as quinolizinium+ and precursors, reflecting a dynamical system under our conditions. In contrast, irradiation at 90 K under stable conditions did not produce volatile photoproducts. These results suggest that such chemical processes can occur in Titan's atmosphere and potentially in its stratosphere, where the co-condensation of these molecules can form composite ices. Concurrently, the formation of stable co-crystals can influence the depletion rates of pyridine, which suggests that these structures can be preserved and potentially delivered to Titan's surface. Our findings provide insights into the molecular diversity and chemical evolution of organic matter on Titan, crucial for future space exploration missions, such as the Dragonfly mission, which may uncover higher-order organics derived from pyridine precursors on Titan's surface.

Kinetics of dehydrogenation of n-heptane over GaPt supported catalytically active liquid metal solutions (SCALMS).

The concept of Supported Catalytically Active Liquid Metal Solutions (SCALMS) was explored for the catalytic dehydrogenation of n-heptane. For this purpose, a GaPt on alumina (Ga84Pt/Al2O3) was compared with a Pt on alumina catalyst at different reaction temperatures and feed compositions. While the observed activation energies with both catalysts for the overall n-heptane depletion rate were similar with both catalysts, the SCALMS systems provides a lower activation energy for the desired dehydrogenation path and significantly higher activation energies for the undesired aromatization and cracking reaction. Thus, the SCALMS catalyst under investigation shows technically interesting features, in particular at high temperature operation. The partial pressure variation revealed an effective reaction order of around 0.7 for n-heptane for both catalysts, while the effective order for hydrogen was 0.35 for Pt/Al2O3 and almost zero for SCALMS.

Source area morphometry and high depletion rate of landslides may indicate their coseismic origin

Ancient coseismic landslides indicate prehistoric earthquakes and may also be a measure of their intensity. Their identification in the landscape remains, however, challenging. We used field geologic observations of source areas of recent rainfall-induced and earthquake-induced landslides to define a morphometric index that can distinguish between these two types of triggers. Morphometries of 129 landslides from tropical, subtropical and temperate zones developed in a variety of bedrock types were described by using the following parameters: i) depletion index (Id), i.e. the ratio between the length of the depleted part and the length of the source area; ii) relative slope height (Hrel) and iii) source area angle (φS), i.e. the angle between the top of the line connecting the scarp top with the toe of the source area and the horizontal plane. They were obtained using globally available digital elevation models and satellite images. Their combination into an Index of Potential Trigger (IPT) successfully distinguished between the two types of landslide triggers with an overall accuracy of 87%. The rainfall-induced landslides had a significantly lower average IPT value of 0.01 as compared with 0.37 for the coseismic landslides. The index of potential trigger may be a useful and readily implemented morphometric tool for preliminary identification of prehistoric coseismic landslides recorded in the current topography.

The Metallogenic Characteristics and Specific Genesis of the Dongchuan Copper Deposit in Yunnan Province

With the rapid development of the social economy and the continuous deepening of urbanization construction, society has entered a new development process, which has played a good promoting role in the development of various social industries. In this context of comprehensive social development, the demand for mineral resources is constantly increasing, which has also subtly accelerated the depletion rate of mineral resources. As a large-scale mineral resource area, the Dongchuan copper deposit in Yunnan needs to further clarify its internal mineralization characteristics and genetic mechanisms in order to achieve reasonable exploration and development, and accelerate the smooth development of various mineral activities in the future. Therefore, the article first clarifies the genetic mechanism of the Dongchuan copper deposit in Yunnan; On this basis, the main mineralization characteristics of the Dongchuantong deposit in Yunnan are clarified.

Determination of regions prone to sand production and the linkage to fluid flow rates by integrating rock strength parameters and microphotographs in the southern onshore basin, India

One of the main challenges for healthy hydrocarbon yields from the production wells is the sand production, and its control assumes significant importance for successful production operations. The prime objective remains to control the sand production without compromising on the fluid flow rates. Sand production is conventionally associated with diverse heterogeneous formations, especially poorly consolidated formations. Scrutinizing fluid flow rates at different orientations of perforations is a valuable analysis in controlling the sand production. This study was conducted to examine the case of sand production in a few development wells from Malleshwaram field of the Krishna Godavari (KG) basin in south India and provide alternatives to arrest this sand production. The influence of oriented perforations on fluid flow rates to minimize sanding tendencies was examined. Sand grain diameter was estimated using the distribution plots of the grain sizes obtained from the photomicrographs, and the average value of the grain size was estimated around 100 μm. The fluid flow model was simulated for actual scenario in the hydrocarbon bearing Nandigama formation using finite element modeling (FEM). Sanding tendencies in these formations were studied at varying depletion rates. Critical draw down pressure (CDDP), which is a function of both critical bottom hole pressure and reservoir pore pressure, for well 1 and well 2 is estimated as 4650 Psi and 3400 Psi, respectively, at 0% depletion. CDDP was used to estimate the onset of sanding, and the flow rate for horizontal perforation was calculated as 0.024548 m3\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${\\mathrm{m}}^{3}$$\\end{document}/sec. Strength parameters, namely the unconfined compressive strength (UCS) and cohesion, were also investigated in all the wells to decipher the formation strength and a possible linkage to sanding. These results present a completely fresh analysis of the sanding potential and the related parameters responsible for it in these formations. Fluid flow rates for the producing reservoir are studied at different set of oriented and sized perforations. It was observed that a hiked flow rate in horizontal perforations maintains the production in a safe and no-sanding zone. This study provides vital information and a workflow for similar heterogeneous complex formations for designing the well completions, augmenting economic production and reinforcing future reservoir management.

Examining soil nutrient balances and stocks under different land use and management practices in contrasting agroecological environments

AbstractAgricultural sustainability and land degradation can be monitored through studying soil nutrient dynamics. This study was conducted to investigate the balance and stocks of nitrogen (N) and phosphorus (P) under major land use types and land management (LM) practices in three contrasting agroecological environments in Ethiopia. We employed a nutrient monitoring approach and assessed soil N and P inputs and outputs at watershed and plot scales. Field data were collected from 72 sites representative of the major land uses of the three watersheds for the watershed scale analysis. In addition to the watershed data, 16 experimental runoff plots were established and the response of nutrient balances to improved LM practices for the major land uses, including cropland with three treatments (control, farmyard manure [FYM] and soil bund), grazing land with three treatments (control, exclosure and FYM + exclosure) and bushland with two treatments (control and exclosure). Nutrient balances, flows and stocks varied significantly among agroecological settings, land‐use types and LM practices. Severe and negative N balances were found in all agroecological environments, with midland (−70.8) > highland (−61.7) > lowland (−50.3 kg ha−1 yr−1), whereas slightly positive P balances were found in all agro‐ecosystems. As a result, the midland (4.2% yr−1) and highland (2.1% yr−1) sites had greater N depletion rates than the lowland site (1.0% yr−1). Our results also demonstrated that applied LM practices improved N balances: by 32%–40% in cropland through FYM and mineral fertilizer, by 7%–18% in grazing land via FYM and exclosure, and by 6%–36% in degraded bushland via exclosure, implying that, implementing FYM and mineral fertilizer for cropland and implementing FYM with exclosure on non‐croplands can reverse nutrient depletion in the study sites and in other areas having similar agroecological conditions.

Physiological impact of heat stress and their alleviation measures in agriculture: A review

Abiotic stresses are becoming more prevalent in modern agriculture as a result of shifting climate scenarios. Elevated temperature stress is one of the most important abiotic stresses to address since it has detrimental consequences for plant physiology, molecular structure, and phenology. The morphological impact occurs in the form of reduced germination, poor emergence, poor seedling vigor, abnormal seedling. Heat stress also results in the closure of stomata, reduced leaf size and consequent increase in stomatal density. One of the major physiological impacts of heat stress is on the fluidity of the membrane structure of the plant cell. Heat stress leads to increased fluidity of the thylakoid membrane and disruption of metabolic functions, which either deliver or accept electrons from PSII and, thus, cause dislodging of PSII from thylakoid membrane. The respiration generally increases in the temperature range of 0-35/ 40⁰C, reaches plateau at 40-50⁰C and decreases beyond 50⁰C due to damage to the respiratory mechanism. Elevated temperature directly impacts the cellular water content and indirectly through the increased water depletion rate from the soil. In order to design the appropriate corrective actions, it is crucial to research all the factors leading to heat stress thoroughly. The traditional agronomic and breeding interventions are crucial, but the rising food demand and the intensifying heat stress call for some cutting-edge biotechnological interventions, such as transgenics, genome editing, and CRISPR/cas9, to induce genome-level heat tolerance. The present review deals in detail with each of the previously listed aspects.

Soil-Matric-Potential-Based Irrigation Scheduling to Increase Yield and Water Productivity of Okra

A field experiment was conducted on okra (Abelmoschus esculentus L.) for assessing the sustainability of yield with optimum irrigation schedule based on soil moisture depletion. Four irrigation treatments: Irrigation at I1:20%, I2:30%, I3:40% and I4:50% of soil moisture depletion rate in main plots and three fertilizer treatments: Fertigation at F1:100%, F2:80% and F3:60% of recommended NPK (100:25:40 kg/ha) in subplots were tested. Soil matric potential was recorded continuously using electronic tensiometers. The soil moisture characteristics curve was derived for various soil matric potential value sand the soil water content. The irrigation controller triggered solenoid valves for irrigation when soil moisture depletion reached a prespecified level in each treatment. Soil moisture depletion values were significantly predicted based on a regression model calibrated for each treatment over the crop growing period. The model gave minimum prediction error (PE) for I1, followed by I2, I3 and I4, respectively. Plant growth and yield parameters were significantly influenced by the soil moisture availability under each treatment. It is recommended that irrigation be scheduled at 20% soil moisture depletion rate together with 100% NPK fertilizer application for attaining sustainable yield of okra (12.3 t/ha), apart from maximum WUE (3.5 kg/m3) and plant growth parameters under semiarid inceptisols.

A New Highly Parameterized Linear Inversion of Water Table Change and Groundwater Depletion Rate Tested With the High Plains Aquifer, U.S.A.

AbstractUnderstanding groundwater resource dynamics is limited by the sparsity of observations of water levels, pumping rates, and hydraulic properties relative to their spatiotemporal heterogeneity. To address some of this complexity, we proposed a new highly parameterized linear inverse method to quantify water table change and groundwater depletion rate in unconfined aquifers that does not require initial or boundary conditions. The method requires linearization, and we tested the performance of six proposed water table functions with three coordinate systems with synthetic models, finding that water table functions by the dimensionless method achieve the lowest errors. Our inverted water table changes and depletion rates remained stable and accurate with head measurement error of 5%. However, inversions became less accurate when head observations contained large temporal gaps. Next, we applied the inversion for water table changes and depletion rates in the Texas High Plains Aquifer (HPA) and the HPA during 2000–2015. To address sparse water levels and uncertain hydraulic conductivity measurements, two modifications were made to improve data constraints for inversion: (a) calculating winter‐time water levels for wells with >1 head observation by linear interpolation and (b) using hydraulic conductivity geostatistical realizations. The inverted water table change and depletion rate expected mean values and uncertainties were reasonable compared to the known pumping records of the Texas HPA. With relatively minor data curation, the new inverse method can quantify spatiotemporally continuous water table change, depletion rates, and their uncertainty for heterogeneous aquifers with temporally sparse and noisy water level observations.

Sulfate consumption during the hydration of Alite and its influence by SCMs

AbstractSCMs with a large specific surface area, such as calcined clays or fine limestone powder, can significantly accelerate the occurrence of the aluminate heat flow peak during the early hydration of blended cements. These systems therefore require a higher amount of sulfate. While this effect has been drawn back to the sulfate incorporation into C‐S‐H, which is formed more rapidly due to the filler effect, it has been recently shown that in systems with high amounts of metakaolin, the sulfate balance is influenced by further mechanisms. This study provides new results on the influence of aluminum‐rich and aluminum‐free SCMs on the early hydration of alite in presence of calcium sulfate. A synthesized alite was blended with 5 wt% of anhydrite and its hydration was investigated by isothermal calorimetry and in‐situ XRD at a w/b ratio of 0.5. It was shown that the formed C‐S‐H is able to take up the calcium and sulfate ions, indicated by a depletion of the solid anhydrite after approximately 20 hours. This process is significantly accelerated by incorporating 30 wt% of a fine limestone filler. The addition of metakaolin leads to an acceleration of the alite hydration compared to the reference as well, but to a significantly lower extend compared to the limestone. However, this system requires a lower degree of alite reaction to reach sulfate depletion. This indicates that in metakaolin‐rich systems, the sulfate demand is influenced by further effects. The results from in‐situ‐XRD reveal that significant ettringite formation is taking place in the metakaolin‐blended system already during the first hours of hydration. Correlations between the degree of alite hydration and the rate of sulfate depletion provide new insights into the mechanisms affecting the sulfate balance and early hydration of blended cements.

Inter‐Basin Water Transfer Effectively Compensates for Regional Unsustainable Water Use

AbstractGlobally, a persistent decline of freshwater availability has been identified over a number of intensively irrigated agricultural regions. Large‐scale inter‐basin water transfer (IBWT) has been suggested as a key tool for stabilizing regional terrestrial water storage (TWS). However, IBWT projects are prohibitively expensive, and their large‐scale cost effectiveness remains unclear. Here we quantify the IBWT impacts on TWS trends in the North China Plain (NCP), a global hotspot for TWS depletion and IBWT. Based on in‐situ observations, remote sensing, and water balance principles, we provide a framework to disentangle complex climate and anthropogenic impacts on NCP TWS. Results show that the NCP TWS depletion rate was significantly attenuated in 2015–2021, which is primarily attributable to recently enhanced IBWT. Otherwise, the average NCP TWS would currently be 94.9 ± 4.9 mm (or 12.2 ± 0.6 km3) lower. However, the positive effect of IBWT is partly offset by increased crop water consumption (−24.1 ± 5.2 mm or −3.1 ± 0.7 km3). IBWT and agricultural management (i.e., reducing crop density) are both necessary for stabilizing future NCP TWS. Otherwise, a TWS declining trend exceeding 100 mm/year may occur under elevated CO2 conditions. As such, this study verifies the feasibility and effectiveness of IBWT for mitigating regional water shortages, as well as the crucial role of agricultural management in stabilizing regional TWS.

Present and future groundwater depletion rates in Wadi Zabid, Tihama Coastal Plain, Yemen

Present and future groundwater depletion rates in Wadi Zabid, Tihama Coastal Plain, Yemen

Vegetation Health and Forest Canopy Density Monitoring in The Sundarban Region Using Remote Sensing and GIS

The present study explores vegetation health and forest canopy density in the Sundarbans region using Landsat-8 images. This work analyzes changes in vegetation health using two vegetation indices, the Normalized Difference Vegetation Index (NDVI) and Forest Canopy Density (FCD) values of the Sundarbans, from 2014 to 2020. NDVI, comprising two bands, Red and Near-infrared (NIR), shows a declining trend during the period. Two NDVI land cover classification maps for 2014 and 2020 are produced, and the interest area is divided into five classes: Scanty, Low, Medium, and Densely Vegetated Regions and Water Bodies. A single-band linear gradient pseudo-color is used to assess the land cover difference between 2020 and 2014, showing marked changes in densely vegetative areas. The NDVI difference marks the coastal regions with a higher depletion rate of vegetation than the regions away from the seacoasts. FCD has been taken to compare the results of NDVI with it. FCD consists of another four models: AVI (advanced vegetative index), BI (Bare soil index), SSI (scaled shadow index), and TI (thermal index). FCD is also called crown cover or canopy coverage, which refers to the portion of an area in the field covered by the crown of trees. 2014 and 2015 FCD maps are produced with a single band linear gradient pseudocolor with five land cover classifications: bare soil, Bare Soil, Shrubs, Low, Medium, and Highly vegetated regions. Both maps bear a significant resemblance to NDVI land classification maps. Further, the FCD values of the two maps are scaled between 1 and 100, and the area of each class is calculated. To check the veracity of the NDVI and FCD analysis, a Deep Neural Network (DNN) model has been developed to classify each year’s image taken from Google Earth Engine (GEE). It classifies each year’s image with 99% accuracy. The calculation of the area of each class emphasizes the rapid decline of densely wooded vegetation. Almost 80% of the highly forested zone has been diminished and has become part of the medium-forested region. Area inflation in medium-forested regions corroborates the same. The study also analyzes the migration of vegetation density, i.e., where and how many areas are unchanged, growing, or deforested.

Experimental Study on the Control Mechanism of Non-Equilibrium Retrograde Condensation in Buried Hill Fractured Condensate Gas Reservoirs

During the depletion development of condensate gas reservoirs, when the formation pressure drops below the dew point pressure, the condensate oil and natural gas systems are in the non-equilibrium state of foggy retrograde condensation. The rational use of the non-equilibrium phase characteristics of the foggy retrograde condensation phenomenon during the development process will be beneficial to the recovery of condensate oil and natural gas. In order to clarify the retrograde condensation control mechanism during the non-equilibrium depletion development of condensate gas reservoirs, the phase characteristics of a condensate oil and gas system were studied by constant composition expansion and constant volume depletion experiments. Then, on the basis of a long core depletion experiment and chromatographic analysis experiment, the influence of different pressure drop speeds, fluid properties, and reservoir physical properties on the control effect of non-equilibrium retrograde condensation after the coupling of the fluid retrograde condensation and reservoir core is analyzed. The results show that during the pressure decline process, the condensate oil and gas system will produce a strong foggy retrograde condensation phenomenon, with the saturation of the retrograde condensate increasing and then decreasing. The cumulative recovery of the condensate oil and natural gas, as well as the mass fraction of the heavy components in the condensate oil, increase with the increase in the depletion rate. Different fluid properties and reservoir physical properties have a great influence on the cumulative recovery degree of the condensate oil, and have little influence on the recovery degree of the natural gas. This work has a certain guiding role for the stable production and enhanced recovery of fractured condensate gas reservoirs in subsurface structures of metamorphic rocks.

Surface tension and evaporation behavior of liquid fuel droplets at transcritical conditions: Towards bridging the gap between molecular dynamics and continuum simulations

The phase transition from subcritical to supercritical conditions, referred to as transcritical behavior, significantly impacts the evaporation and fuel–air mixing in high-pressure liquid-fuel propulsion systems. Transcritical behavior is characterized as a transition from classical two-phase evaporation to a single-phase gas-like diffusion regime as surface tension and latent heat of vaporization reduce. However, the interfacial behavior represented by the surface tension coefficient and evaporation rate during this transition which are crucial inputs for Computational Fluid Dynamics (CFD) simulations of practical transcritical fuel spray is still missing. This study aims at developing new evaporation rate and surface tension models for transcritical n-dodecane droplets using molecular dynamics (MD) simulations irrespective of the droplet size. As MD simulations are primarily limited to the nanoscale, the new models can bridge the gap between MD and continuum simulations and enable the direct application of these findings to microscopic droplets. A new characteristic timescale, i.e., “undroplet time,” is defined which marks the transition from classical two-phase evaporation to single-phase gas-like diffusion behavior. The undroplet time indicates the onset of droplet core disintegration and penetration of nitrogen molecules into the droplet, which occurs after the vanishment of the surface tension. By normalizing the time with respect to the undroplet time, the rate of surface tension decay, evaporation rate, and the rate of droplet mass depletion become independent of the droplet size. Calculation of pairwise correlation coefficients for the entire MD results shows that both surface tension coefficient and evaporation rate are strongly correlated with the background temperature, while pressure and droplet size play a less significant role past the critical point. Therefore, new models for surface tension coefficient and evaporation rate spanning from sub- to supercritical conditions are developed as a function of background pressure and temperature, which can be used in continuum simulations. The identified phase change behavior based on the undroplet time shows a good agreement with the phase change regime maps obtained using microscale experiments and nanoscale MD predictions.