Depleted Mantle Research Articles

Compositional and geochronological signatures of metamafic dykes from the Sangsang peridotites, South Tibet: Evidence for magma-starved forearc rifting during Neo-Tethyan subduction re-initiation

In this study we present new mineral chemistry, whole-rock geochemical and zircon U–Pb geochronological data for 12 metamafic dykes in the mantle sequence of the Sangsang ophiolite in South Tibet (China). Modal analyses of these dykes gave averages of ~40%–65% plagioclase and ~35%–60% amphibole and small amounts of (igneous) clinopyroxene, epidote and opaque minerals. This mineral assemblage resembles that of typical orthoamphibolites. Nevertheless, due to the absence of foliation the investigated rocks are described as metamafic lithologies. These rocks have primitive mantle (PM)-normalized multi-element patterns with negative Nb and Ta anomalies as well as weak, negative Ti anomalies. In addition, they have initial 87Sr/86Sr ratios [(87Sr/86Sr)i] of 0.702844–0.703581, initial 143Nd/144Nd ratios [(143Nd/144Nd)i] of 0.512891–0.512959 and high εNd(t) values (+7.9 to +9.3). Uranium-Pb ages of magmatic zircons separated from the investigated metamafic dykes indicate that the parental melts of their protoliths intruded the Sangsang mantle at ~119.0–118.5 ​Ma.The metamorphic mineral assemblages recognized in the investigated dykes are suggestive of a retrograde metamorphic process, from (epidote-)amphibolite facies (~470–610 ​°C, ~1.9–4.3 ​kbar) and to prehnite-pumpellyite facies (≤280 ​°C, ≤ 3 ​kbar), active within a rift-produced oceanic lithosphere. Microtextural and geochemical data suggest that the protoliths of the dykes were most likely massive gabbros. Compositional data show that the parental magmas of the gabbroic protoliths were generated by melting of a depleted mantle (DM) source that had been weakly modified by fluids emanating from a subducted oceanic lithospheric slab. The age of the gabbroic protoliths is slightly younger than the existing ages for ophiolites from the central Yarlung-Zangbo Suture Zone (YZSZ) in the literature (~129–123 ​Ma). We, therefore, suggest that the gabbroic protoliths of the Sangsang metamafic dykes were formed in an incipient forearc setting during Neo-Tethyan subduction re-initiation (Aptian). Our tectonomagmatic model provides insights into the igneous accretion and post-solidification evolution of the oceanic lithosphere in South Tibet.

Mineral chemistry, geochemistry, Raman spectroscopy and geotectonic significance of Neoproterozoic ophiolitic peridotites and pyroxenites from Kab Amiri district, central Eastern Desert, Egypt

The small gold mining Kab Amiri district ultramafic ophiolitic section (central Eastern Desert) comprises highly serpentinized peridotites (serpentinites) and few pyroxenites. It lies within a region of Neoproterozoic ophiolitic rocks and associated derivatives. The chromian spinel textural and chemical compositional features suggest transitional greenschist-amphibolite up to lower amphibolite facies metamorphism and indicates that they represent highly-depleted mantle residues. The presence of the Si-Ob-Si antisymmetric ν1(A1), symmetric ν2(A1) bands and the hydroxyl group (OH) modes are conclusive for the discrimination of antigorite. Furthermore, the speculation of serpentines as antigorite can also be indicated from the hydroxyl group modes. The Kab Amiri ophiolite suite (central Eastern Desert) represents fragments of oceanic lithosphere that are developed in forearc setting in a supra-subduction zone (SSZ) environment. Thus the low TiO2 contents, the enrichment in LILE and LREE and the Nb depletion reflect the remelting of a highly depleted mantle source and suggest their formation in a SSZ environment (i.e forearc).

Depletion ages and factors of MORB mantle sources

Sr-Nd-Hf-Pb isotopes show that the depleted MORB mantle (DMM) is not homogeneous. The heterogeneity is attributed to different ages of depletion and/or various degrees of depletion for a given domain of DMM, as well as multiple depletion events, metasomatism, and mixing between DMM and other mantle components. A mid-ocean ridge basalt, in principle, should contain information about the depletion history of its mantle sources. Here we develop a model to extract the model depletion age and the composition of a MORB mantle source prior to MORB production using Sr-Nd isotopes or Sr-Hf isotopes in a MORB. The complexities of multiple depletion events, mixing, metasomatism, and enrichment are not addressed in this contribution. The model is based on two assumptions: (i) Isotope evolution in a MORB mantle follows a two-stage evolution model, the first stage in the primitive mantle from the beginning of the solar system to the time of mantle depletion at age Td, and the second stage in the depleted mantle from age Td to the present day. That is, there is only one single depletion event. The depletion age and degree of depletion of a given mantle source are to be determined. (ii) The trace element composition of a depleted mantle source corresponding to the given MORB can be related to a reference DMM by a log-linear relation with the compatibility index CoI (Zhang, 2014). Applying the two assumptions to the available and large MORB database (Gale et al., 2013), we calculate the global distribution of sub-ridge mantle age and composition. The results show: (i) Mean or reference MORB mantle composition of Salters and Stracke (2004) is close to the average depleted MORB mantle composition, whereas that of Workman and Hart (2005) is significantly more depleted than the average depleted MORB mantle. (ii) Model ages for sub-ridge mantle depletion are mostly between 0.8 to 3.0 Ga. (iii) There are large-scale patterns in depletion ages for sub-ridge mantle regions. For example, beneath Mid-Atlantic Ridge, mantle depletion ages are young (0.8 to 2.1 Ga) north of 30°N, older (1.6 to 4.5 Ga) between 25°N to 35°S), and mixed (0.6-4.4 Ga) south of 35°S. The Pacific sub-ridge mantle has a narrow range of model depletion ages of 1.6 to 3.0 Ga, with a mean of 2.3 Ga. Indian sub-ridge mantle has a younger mean depletion age of 1.7 Ga. These large-scale patterns reveal history of mantle depletion, mantle convection, and possible mixing between older and younger depleted mantles.

Initial 87Sr/86Sr as a sensitive tracer of Archaean crust-mantle evolution: Constraints from igneous and sedimentary rocks in the western Dharwar Craton, India

Among the rocky planets of the solar system only the Earth has “granitic” continental crust. The timing and processes involved in the formation of Earth’s first extensive crust is still enigmatic. The chemical and isotope compositions of ancient crustal rocks preserve a record of their genesis. The Rb-Sr system proves to be an efficient proxy for the reconstruction of crust-mantle evolution since it can bring together information from seawater as preserved in chemical sedimentary rocks and information from magmatic rocks that can trace the time and extent of crust formation and concomitant mantle depletion during the Archaean eon. The Dharwar Craton in India preserves a suite of metamorphosed igneous and sedimentary rocks that record its early crustal evolution. To overcome the susceptibility for resetting and the difficulty in determining initial 87Sr/86Sr, the minerals barite and apatite are used to obtain precise and accurate 87Sr/86Sr, because these minerals preferentially incorporate Sr and exclude Rb and preserve the initial Sr isotope compositions at the time of their formation. Initial 87Sr/86Sr of apatite were obtained in situ using Laser Ablation Multi-Collector Inductively Coupled Plasma Mass Spectrometry. The robustness and only minor dispersion of the isotope ratios demonstrate the capability of matrix apatites in preserving initial Sr ratios. The least radiogenic value is used as the best estimate for the initial 87Sr/86Sr. The 87Sr/86Sr ratios of apatite from igneous rocks that formed from 3.5 Ga to 2.6 Ga constrain the Rb/Sr of the source over the whole time-span. A comparison of the Sr isotopes between seawater-derived barite and initial Sr isotope ratios in apatite from igneous rocks reveals that significant mafic to intermediate crust had formed by 3.2 Ga. Studying the entire Archaean time window, a dominantly mafic crust was the main source for the granitoid rocks in the Dharwar Craton from 3.5 to 3.1 Ga, whereas the rocks from 2.9 to 2.7 Ga were extracted dominantly from the depleted mantle.

The Late Jurassic Zedong ophiolite: A remnant of subduction initiation within the Yarlung Zangbo Suture Zone (southern Tibet) and its tectonic implications

The Zedong ophiolite is the largest ophiolite massif east of Dazhuqu in the Yarlung Zangbo Suture Zone in the southern Tibetan Plateau. However, its age, geodynamic setting and relationship to the Xigaze ophiolite remain controversial. New zircon U–Pb ages, whole-rock geochemical and Nd–Pb isotopic data from ophiolitic units provide constraints on the geodynamic and tectonic evolution of the Zedong ophiolite. U–Pb zircon geochronology of dolerite lavas and late gabbro–diabase dikes yield weighted mean ages of 153.9 ± 2.5 Ma and 149.2 ± 5.1 Ma, respectively. Strong positive εNd(t) and positive Δ7/4Pb and Δ8/4Pb values indicate derivation from a highly depleted mantle source with an isotopic composition similar to that of the Indian MORB-type mantle. The geochemistry of ophiolitic lavas and early dikes are analogous to typical island arc tholeiites whereas late dikes are similar to boninites. The geochemistry of these rock types suggests multi-stage partial melting of the mantle and gradually enhanced subduction influences to the mantle source through time. Combined with the MORB-like 162.9 ± 2.8 Ma Luobusha ophiolitic lavas, we suggest that the Luobusha lavas, Zedong lavas and early dikes originated in an infant proto-arc setting whereas late dikes in the Zedong ophiolite originated in a forearc setting. Together, they represent a Neo-Tethyan subduction initiation sequence. The Late Jurassic intra-oceanic proto-arc to forearc setting of the Zedong ophiolite contrasts with the continental margin forearc setting for the Xigaze ophiolite, which suggests a laterally complex geodynamic setting for ophiolites along the Yarlung Zangbo Suture Zone.

Mesozoic Northward Subduction Along the SE Asian Continental Margin Inferred from Magmatic Records in the South China Sea

During the Mesozoic, Southeast (SE) Asia (including South China and the South China Sea (SCS)) was located in a transitional area between the Tethyan and Pacific geotectonic regimes. However, it is unclear whether geodynamic processes in the SE Asian continental margin were controlled by Tethyan or paleo-Pacific Ocean subduction. Herein, we report ~124 Ma adakitic granodiorites and Nb-enriched basalts from the Xiaozhenzhu Seamount of the SCS. Granodiorites have relatively high Sr/Y (34.7–37.0) and (La/Yb)N (13.8–15.7) ratios, as well as low Y (9.67–9.90 μg/g) and Yb (0.93–0.94 μg/g) concentrations, typical of adakites. Their Sr/Y and (La/Yb)N values coupled with their relatively low initial 87Sr/86Sr ratios (0.70541–0.70551), relatively high K2O contents (3.31–3.38 wt%), high Th/La ratios (0.33–0.40), negative εNd(t) values (−3.62 to −3.52), and their variable zircon εHf(t) values (−3.8 to +5.2) indicate that these rocks were formed by melting of subducted oceanic crust and sediments. The Nb-enriched basalts show enrichment in high field strength elements (HFSE) and have εNd(t) values of +2.90 to +2.93, as well as relatively low initial 87Sr/86Sr ratios of 0.70341–0.70343, demonstrating that they were derived from a depleted-mantle (DM) source metasomatized by silicate magmas originating from melting of a subducted oceanic lithospheric slab. By combining our findings with data from other Late Mesozoic arc-related magmatic rocks and adakites from the broader study area, we propose a geotectonic model involving subduction of young oceanic lithosphere during the Late Jurassic and northward subduction of the proto-South China Sea (PSCS) along the SE Asian continental margin during the Early Cretaceous. This conceptual model better explains the two-period Mesozoic magmatism, commonly reported for the SE Asian continental margin.

Extensive crustal extraction in Earth’s early history inferred from molybdenum isotopes

Estimates of the volume of the earliest crust based on zircon ages and radiogenic isotopes remain equivocal. Stable isotope systems, such as molybdenum, have the potential to provide further constraints but remain underused due to the lack of complementarity between mantle and crustal reservoirs. Here we present molybdenum isotope data for Archaean komatiites and Phanerozoic komatiites and picrites and demonstrate that their mantle sources all possess subchondritic signatures complementary to the superchondritic continental crust. These results confirm that the present-day degree of mantle depletion was achieved by 3.5 billion years ago and that Earth has been in a steady state with respect to molybdenum recycling. Mass balance modelling shows that this early mantle depletion requires the extraction of a far greater volume of mafic-dominated protocrust than previously thought, more than twice the volume of the continental crust today, implying rapid crustal growth and destruction in the first billion years of Earth’s history.

Pacific Lithosphere Evolution Inferred from Aitutaki Mantle Xenoliths

Abstract Highly siderophile element (HSE: Os, Ir, Ru, Pt, Pd, Re), major and trace element abundances, and 187Re–187Os systematics are reported for xenoliths and lavas from Aitutaki (Cook Islands), to investigate the composition of Pacific lithosphere. The xenolith suite comprises spinel-bearing lherzolites, dunite, and harzburgite, along with olivine websterite and pyroxenite. The xenoliths are hosted within nephelinite and alkali basalt volcanic rocks (187Os/188Os ∼0·1363 ± 13; 2SD; ΣHSE = 3–4 ppb). The volcanic host rocks are low-degree (2–5%) partial melts from the garnet stability field and an enriched mantle (EM) source. Pyroxenites have similar HSE abundances and Os isotope compositions (Al2O3 = 5·7–8·3 wt %; ΣHSE = 2–4 ppb; 187Os/187Os = 0·1263–0·1469) to the lavas. The pyroxenite and olivine websterite xenoliths directly formed from—or experienced extensive melt–rock interaction with—melts similar in composition to the volcanic rocks that host the xenoliths. Conversely, the Aitutaki lherzolites, harzburgites and dunites are similar in composition to abyssal peridotites with respect to their 187Os/188Os ratios (0·1264 ± 82), total HSE abundances (ΣHSE = 8–28 ppb) and major element abundances, forsterite contents (Fo89·9±1·2), and estimated extents of melt depletion (<10 to >15%). These peridotites are interpreted to sample relatively shallow Pacific mantle lithosphere that experienced limited melt–rock reaction and melting during ridge processes at ∼90 Ma. A survey of maximum time of rhenium depletion ages of Pacific mantle lithosphere from the Cook (Aitutaki ∼1·5 Ga), Austral (Tubuai’i ∼1·8 Ga), Samoan (Savai’i ∼1·5 Ga) and Hawaiian (Oa’hu ∼2 Ga) island groups shows that Mesoproterozoic to Neoproterozoic depletion ages are preserved in the xenolith suites. The variable timing and extent of mantle depletion preserved by the peridotites is, in some instances, superimposed by extensive and recent melt depletion as well as melt refertilization. Collectively, Pacific Ocean island mantle xenolith suites have similar distributions and variations of 187Os/188Os and HSE abundances to global abyssal peridotites. These observations indicate that Pacific mantle lithosphere is typical of oceanic lithosphere in general, and that this lithosphere is composed of peridotites that have experienced both recent melt depletion at ridges and prior and sometimes extensive melt depletion across several Wilson cycles spanning periods in excess of two billion years.

The crust-mantle evolution of the Anabar tectonic province in the Siberian Craton: Coupled or decoupled?

To clarify the tectonic-thermal evolution of the Anabar tectonic province in the central Siberian Craton, we performed an isotope-geochemical study of 20 xenoliths from the Udachnaya, Zarnitsa, and Komsomolskaya kimberlite pipes to represent different crustal levels. Most mafic granulites have Proterozoic Nd model ages and geochemical characteristics close to those of intraplate basalts, whereas some mafic and intermediate granulites with Archean model ages exhibit geochemical features of supra-subduction ophiolitic basalts. Analysis of U-Pb ages and hafnium isotopic composition of zircon indicates that the main tectonic-thermal events modified the crust at 2.7 and 1.9–1.8 Ga, which is consistent with ages of mantle depletion events from previous studies. All zircons have Archean Hf model ages (TDMC3.6-3.2 Ga). Overall, thermal events with ages of 2.9–2.8, 2.7, 2.4, 1.97 and 1.8 Ga have remarkable influence on the studied zircons. Tectono-thermal events at 2.4 1.97, 1.9 and 1.8 Ga with no addition of juvenile material are recorded by zircons from xenoliths of mafic and intermediate granulites and metadiorites. A compilation of isotope-geochemical data demonstrates that instead of age-stratified, the crust of the Anabar tectonic province consists of variably reworked Paleoarchean rocks and juvenile Proterozoic rocks at all crustal levels. Hence the crust and mantle of the Siberian Craton has been coupled since the Paleoarchean.

Impact of Mafic Underplating and Mantle Depletion on Subsequent Rifting: A Numerical Modeling Study

AbstractOrogenesis in the Variscan belt of Western Europe was followed by a major magmatic event during the Permian that formed a mafic lower crust by crystallizing pyroxenite and gabbros from mantle‐derived melts at the base of the continental crust. Partial melting of the asthenosphere left a significantly depleted mantle that was progressively incorporated into the subcontinental lithospheric mantle as the orogenic domain cooled. The potential impact of such large‐scale thermal and lithologic layering has never been taken into account in the study of the Alpine Tethys and North Atlantic rift systems that developed subsequently in Western Europe. Here we investigate via numerical modeling how a mafic heterogeneity within the lowermost part of a quartzo‐feldspathic continental crust and/or a zone of depleted mantle within the lithospheric mantle beneath a former orogenic domain could have influenced subsequent rifting. Our numerical modeling results indicate that, in a thermally equilibrated lithosphere, a mafic body within the lower continental crust or a zone of shallow depleted mantle prevents rifting of overlying weaknesses (e.g., faults and suture zones). We propose that the regional mafic lower crust beneath the Variscan orogenic domain may explain why the Tethyan and southern North‐Atlantic rift systems did not localize at former suture zones of the Western European orogenic lithosphere.

A 4 Ga record of granitic heat production: Implications for geodynamic evolution and crustal composition of the early Earth

The radiogenic heat produced by granites has a significant influence on the thermal state of the crust due to both their relatively high heat production with respect to most rock types and high abundance. However, the variations in present day heat production with age are generally based on relatively few measurements that are poorly distributed geographically. In this study, we construct a global model for the heat production of granitic rocks for the past 4 Ga using 13,400 geochemical analyses. We observe a nearly monotonic increase in radiogenic heat production from 4.0 to 2.0 Ga, which mirrors a shift from more TTG-like calcic to more alkalic compositions. This shift towards high-heat-producing granites post-2.0 Ga is often attributed to enrichment related to reworking and/or erosion. However, there is a strong correlation between granitic heat production with that of similarly-aged basalts and gabbros, which suggests a dominant mantle-level component to granite generation rather than crustal reworking. Secular cooling and mantle depletion may affect heat production, but the signal is complex and cannot easily explain the heat production with age profile. The most likely mechanism to describe the observed heat production–age pattern is one of selective preservation as a consequence of thermal stability. High heat producing terranes that were not stable during the Archean become increasingly stable towards the present. This selective preservation model has significant implications for the growth and composition of the continental crust. Ferroan, alkalic and felsic compositions were less thermally stable in the Archean due to their generally higher heat production and thus may have been more common in the early Earth than assumed by most compositional models. The temporal heat production model determined in this study can be used to improve geotherm models, particularly within ancient terranes.

Post-spreading Basalts from the Nanyue Seamount: Implications for the Involvement of Crustal- and Plume-Type Components in the Genesis of the South China Sea Mantle

Fresh samples of basalts were collected by dredging from the Nanyue intraplate seamount in the Southwest sub-basin of the South China Sea (SCS). These are alkali basalts displaying right-sloping, chondrite-normalized rare earth element (REE) profiles. The investigated basalts are characterized by low Os content (60.37–85.13 ppt) and radiogenic 187Os/188Os ratios (~0.19 to 0.21). Furthermore, 40Ar/39Ar dating of the Nanyue basalts showed they formed during the Tortonian (~8.3 Ma) and, thus, are products of (Late Cenozoic) post-spreading volcanism. The Sr–Nd–Pb–Hf isotopic compositions of the Nanyue basalts indicate that their parental melts were derived from an upper mantle reservoir possessing the so-called Dupal isotopic anomaly. Semiquantitative isotopic modeling demonstrates that the isotopic compositions of the Nanyue basalts can be reproduced by mixing three components: the average Pacific midocean ridge basalt (MORB), the lower continental crust (LCC), and the average Hainan ocean island basalt (OIB). Our preferred hypothesis for the genesis of the Nanyue basalts is that their parental magmas were produced from an originally depleted mantle (DM) source that was much affected by the activity of the Hainan plume. Initially, the Hainan diapir caused a thermal perturbation in the upper mantle under the present-day Southwest sub-basin of the SCS that led to erosion of the overlying LCC. Eventually, the resultant suboceanic lithospheric mantle (SOLM) interacted with OIB-type components derived from the nearby Hainan plume. Collectively, these processes contributed crustal- and plume-type components to the upper mantle underlying the Southwest sub-basin of the SCS. This implies that the Dupal isotopic signature in the upper mantle beneath the SCS was an artifact of in situ geological processes rather than a feature inherited from a Southern Hemispheric, upper mantle source.

Mafic whole-rock geochemistry and neodymium isotopes, Green Mountain and Rowe/Prospect Rock slices, Vermont Appalachians

Mafic rocks containing sodic-calcic amphibole in the Green Mountain slice (GMS) and Rowe/Prospect Rock slice (R/PRS), Vermont Appalachians were originally subalkaline basalts emplaced as melts during Neoproterozoic rifting of Rodinia that led to the formation of the Iapetus Ocean basin. Relatively high degrees of partial melting of asthenosphere that was highly depleted in incompatible elements produced R/PRS magma(s), which may have been contaminated locally by continental crust and/or fluids. Trace element chemistry suggests that mafic bodies from different locations in the R/PRS may be fractionated magmatic equivalents. Mafic rocks in the GMS formed from magmas produced by relatively low degrees of partial melting of mantle that was relatively enriched in incompatible elements compared to depleted mantle. These enriched melts may have been derived from a plume and/or enriched lithospheric components, potentially continental crust, embedded in depleted upper mantle. A depleted mantle signature preserved locally in the GMS probably reflects increasing asthenospheric input during crustal thinning, opposed to crustal or fluid contamination. Whole-rock minor and trace element data from the GMS and R/PRS are distinct from analyses of glaucophane schist from the Tillotson Peak Complex in northern Vermont, which may be exhumed Iapetan ocean floor. Exhumed mafic rocks in the GMS and R/PRS were formed as lower plate melts prior to relatively high pressure subduction zone metamorphism, providing evidence for subduction of the Laurentian margin, not subduction erosion. Low pressure greenschist facies mafic rocks that occur structurally between the GMS and R/PRS were sourced from depleted or highly depleted mantle in a supra-subduction zone environment, potentially a forearc or backarc basin; an ophiolitic origin is equivocal. Geochemical and isotopic data and interpretations are compatible with rift-related tectonomagmatic models for the peri-Laurentian realm of the northern Appalachians.

Magmatic evolution of the Cerro Maricunga gold porphyry-epithermal system, Maricunga belt, N-Chile

The Cerro Maricunga gold project is located in the Maricunga gold belt in northern Chile, within the remnant edifice of the Tertiary Ojo de Maricunga volcano. The gold mineralization is hosted within a 23‒15 Ma old complex system of interwoven porphyry intrusions, flows, dikes and diverse breccia types, all forming part of a large diatreme system. In particular, phreatomagmatic and phreatic processes contributed to the formation of the synmineral diatreme complex. The rocks are calc-alkaline (daci)andesites and very rare dacites of the medium-K series with a high-K tendency and a conspicuous “adakitic” signature. Rare-earth element patterns reflect formation during a period of distinctly thickened continental crust with retention of heavy rare-earth elements by a garnet-bearing residue at a depth of ≥45 km. U-Pb zircon ages show a wide spectrum from Proterozoic, over Permian and Triassic ages to Paleocene, Oligocene, early and mid-Miocene ages. The Phanerozoic zircon ages indicate the assimilation of country rocks, whereas the Proterozoic age reflects the presence of a lower crustal Neoproterozoic basement that is also suggested by εNd values of −3.9 to −3.1 for bulk rock, i.e. mantle depletion model ages around 1 Ga. The last magmatic activity at the Ojo de Maricunga volcano was at ∼14.9 Ma. Stable isotope data on hydrothermal barite and supergene acanthite and gypsum (δ34Sacanthite: −0.6 to −0.4; δ34Ssulfate: 0.2 to 4.6; δ18Osulfate: 9.2 to 13.8) indicate an igneous origin of sulfur and arid conditions during mineral formation. The emplacement of the diatreme complex took place during the adjustment of the Chilean flat slab setting in a time of increased crustal thickness. Although the rocks at Ojo de Maricunga show a pronounced adakite-like signature, they formed in a common MASH zone or a deep hot zone within the lower crust. Gold mineralization took place at ∼17.9 Ma (Re-Os on molybdenite), syngenetic with diatreme formation and emplacement of hydrous magma. The thickening of continental crust was more advanced in the northern part of the Maricunga belt in the early to mid-Miocene than previously assumed, and then shifted south where several younger gold porphyries formed.

Genesis of the Singhbhum Craton, eastern India; implications for Archean crust-mantle evolution of the Earth

The Singhbhum Craton in eastern India, one of the four major Archean cratons of the Indian Shield, is underlain by Paleoarchean granitoids (trondhjemite-tonalite-granodiorite i.e. TTGs, and potassic granites) that are encircled by greenstone belts rich in banded iron formation known as Iron Ore Group. This study presents whole rock major-trace element geochemistry, Sr and Nd isotopes, K-feldspar common Pb isotopes, along with in-situ zircon U–Pb ages and Hf isotope data from the granitoids and the greenstone volcanic rocks to characterize their source(s) and to constrain the evolution of the Paleoarchean continental crust. Zircon U–Pb ages show that these granitoids were emplaced during two magmatic episodes at ca. 3.47–3.44 Ga and 3.36–3.28 Ga. The greenstone volcanic rocks in the eastern part of the craton are basalts and basaltic andesites with rare komatiites, whereas those in the western part are basaltic-andesites and andesites. Whole rock Sm–Nd isotope regression lines for volcanic rocks from the eastern (including komatiites) and western regions yield ages of 3746 ± 340 Ma (MSWD = 169) and 2961 ± 420 Ma (MSWD = 3.3), respectively. The major and trace element data show that the volcanic rocks of the eastern and western greenstone belts had a different petrogenesis. The granitoids are highly evolved with SiO2 contents up to 76 wt%. The major and trace element data indicate that the granitoids of the Singhbhum Craton were derived by partial melting of a mafic crust at variable depths (ca. 10–15 kbar). The isotopic compositions of Pb measured on leached K-feldspars from the granitoids show undepleted mantle-like characteristics and negate the possible involvement of much older evolved crust in the formation of these rocks. The whole rock initial Nd isotopic compositions (εNdi = −0.3 to +2.2) and zircon in-situ initial Hf isotopic compositions (εHfi = −0.3 to +2.0) of the granitoids calculated using zircon crystallization ages indicate that they were derived from a near-chondritic reservoir. These data suggest that only a limited volume of continental crust formed prior to ca. 3.5 Ga, and major crust extraction from the mantle started at ca. 3.5 Ga. Using this time as the start of major crustal growth and concomitant mantle depletion, Nd and Hf mantle depletion histories are proposed for the Singhbhum Craton that can be described by the equations εNdt = −2.85 × (tGa) + 10, and εHft = −4.68 × (tGa) + 16.4. These curves do not change the model ages for young rocks, but they make a significant difference for the Archean rocks.

The Neoproterozoic Upper Ruvubu alkaline plutonic complex (Burundi) revisited: Large-scale syntectonic emplacement, magmatic differentiation and late-stage circulations of fluids

The Upper Ruvubu Alkaline Plutonic Complex (URAPC) in Burundi consists of three separate intrusions, each with a specific emplacement age and petrological composition. Three main units are recognized: an outer unit with silica-saturated plutonic rocks (from gabbro to granite), an inner unit with silica-undersaturated plutonic rocks (feldspathoidal syenite with subordinate feldspathoidal monzonite and ijolite) and a carbonatitic body in the subsoil, known by drilling. The URAPC is quite large in size (∼24 km long and up to 10 km wide). It is considered to have been intruded syntectonically in an overall extensional context, thanks to the kilometric shear zones that accommodated its emplacement. Radiometric ages from literature range from 748 to 705 Ma and point to structurally-controlled magmatic differentiation followed by long-lived circulations of late-stage fluids postdating the emplacement of a part of the undersaturated rocks and the carbonatites. In the north-western part of the outer unit, gabbro likely has been emplaced at a deeper structural level than the granite, which represents a more apical structural level of emplacement.This petrological, geochemical and isotopic (Sr-Nd-Hf) study concentrates on the processes that generated the URAPC: (i) fractional crystallization, evidenced by the chemical evolution trends of the major and trace elements, and by marked P, Ti and Ba anomalies in the trace element patterns; (ii) crustal assimilation/contamination, as shown by the wide range of Nd isotope compositions and the general increase of the Sr isotope ratios with increasing SiO2 contents, and (iii) late-magmatic/hydrothermal alteration inducing an increase of the Sr isotope composition without changing significantly the Nd isotope composition.The isotopic data are consistent with an asthenospheric mantle source, though less depleted than the Depleted Mantle (DM), contaminated by the Subcontinental Lithospheric Mantle (SCLM). The silicate and carbonate magmatic series are cogenetic. The outer unit is clearly more contaminated than the inner unit, whereas the carbonatitic body could have evolved by liquid immiscibility.The URAPC lies within East Africa’s Western Rift Valley, which is marked by 23 alkaline plutonic complexes. Their emplacement has been ascribed to reactivation of Proterozoic lithospheric weakness zones resulting from the breakup of the Neoproterozoic supercontinent Rodinia supercontinent.

Major, trace element, and SrNd isotopic geochemistry of Cenozoic basalts in Central‐North and East Mongolia: Petrogenesis and tectonic implication

This paper presents new major element, trace element, and SrNd isotope data of Cenozoic basalts in volcanic provinces Hovsgol, Taatsiin Gol, and Dariganga‐Abaga in Northern, Central, and Eastern Mongolia, respectively, to explore the petrogenesis of the basalts and their geodynamic setting. Cenozoic volcanic rocks in Mongolia are dominated by basalts, belonging to alkaline and tholeiitic series, and are characterized by ocean island basalts (OIB)‐like major and trace element signature, such as enrichment of light REE relative to heavy REE and enrichment in both large‐ion lithophile elements (LILE) and high‐field‐strength elements (HFSE) with positive NbTa anomalies in primitive mantle‐normalized spider diagram. On the other hand, the Central‐North Mongolian basalts are higher in SiO2 and Al2O3 but lower in MgO, CaO, and TiO2 than East Mongolian basalts and display positive K anomaly, which is in contrast to the negative K anomaly of the latter. Despite the evolved nature of the Central‐North Mongolian basalts, the roles of crustal contamination and fractional crystallization, or assimilation coupled with fractional crystallization (AFC), are insignificant in the genesis of the basalt; instead, both the mantle heterogeneity and melting condition have significant contributions to the compositional variations of the basalts. Importantly, the SrNd isotopic signatures suggest that the mantle sources are characterized by mixing of two isotopic components, a depleted mantle (DM) and an enriched mantle (EM). Although, the EM component is variable, which can be ascribed to metasomatized subcontinent lithosphere (SCLM) and altered recycled oceanic crust (ROC) for the mantle sources of the Central‐North and East Mongolian basalts, respectively. Taking these results together with published age and high‐resolution tomographic data, we propose that all Cenozoic volcanism in Mongolia is related to shallow mantle (asthenosphere) upwelling stemming from the mantle transitional zone (MTZ), but the triggering causes for the mantle upwellings are different. The mantle upwelling related to generation of the Central‐North Mongolian basalts was likely triggered by a far‐field effect of the Indo‐Asian collision, which might have caused the avalanched/subducted materials of the Mongol‐Okhotsk and/or the Central Asian orogenic belt (CAOB) that sink into and stagnated within the MTZ. The mantle upwelling related to the formation of the East Mongolian basalts, which are located at the westernmost of the big mantle wedge constructed by the subducting and stagnant Pacific slab, was induced directly by the westward subduction of the Pacific Plate beneath East Asia.

Eclogites as palaeodynamic archives: Evidence for warm (not hot) and depleted (but heterogeneous) Archaean ambient mantle

Some high-Mg eclogite xenoliths, entrained by kimberlites from the mantle lithospheres of ancient continental cores, and rare orogenic eclogites and ophiolites, exhumed or obducted during the closure of palaeo-ocean basins, have elemental and isotopic compositions indicative of protoliths that formed as little-differentiated melts erupted in ancient ocean floors. Despite metamorphism and, in part, partial melt loss, these samples of ancient mid-ocean ridge basalt and picrite retain a memory of the chemical and physical state of their protoliths' ambient convecting mantle sources. Published data show that, when filtered to exclude specimens with cumulate protoliths or showing evidence for later enrichment (metasomatism), the samples lack Y or Al2O3 depletion relative to TiO2 and MgO. This indicates melt segregation of the protolith predominantly from a garnet-free peridotite source and implies intersection of the solidus at low pressures (≤3 GPa).Given the dependence of melt composition and volume on source composition (assumed to be similar to modern depleted mantle) and mantle potential temperature (TP), we calculate moderate average melt fractions F (∼0.22 ± 0.01) from the Ti contents of the least differentiated samples in three sample suites with 2.6 to 2.9 Ga ages. This converts to TP of ∼1410 ± 10°C assuming a final pressure of melting of 0.5 GPa, melt productivity of 10%/GPa and mantle adiabat of 0.4°C/km, and using a mantle solidus parameterisation. Though model-dependent, the results are in agreement with recent work advocating moderate Archaean mantle TP. Estimates drop to F=0.19 and TP=1380°C at 1.9 Ga and F=0.12 and TP=1310 at 0.6 Ga, corresponding to a decrease in TP of only ∼100°C over the last 3 Ga. A less depleted mantle source yields higher F and TP, but the above estimates are in better agreement with qualitative evidence from Al2O3 and Y, and with Nd–Hf and Sr isotope compositions of orogenic eclogite and granulite suites and mantle eclogites, respectively, which indicate that portions of the Meso- to Neoarchaean mantle were depleted. Moderate TP supports early plate strengthening and a possible transition to plate tectonics in the Mesoarchaean if not earlier. Moreover, moderate temperatures in Archaean subduction zones may have facilitated deep recycling of volatiles that would otherwise have been lost from subducting slabs at shallow depths.

Chromium spinel in Late Quaternary volcanic rocks from Kamchatka: Implications for spatial compositional variability of subarc mantle and its oxidation state

The Kamchatka volcanic arc (Russia) is one of best-studied, but most complex tectonic margins on Earth, with an extensive geologic history extending back to the Late Cretaceous. Unlike many other subduction zones, primitive basalts with Mg# > 65 are abundant in Kamchatka, thereby allowing characterization of the mantle source through compositional analyses of near-liquidus minerals in the rocks. In this paper, we present a comprehensive dataset on the composition of Cr-spinel inclusions in olivine for all main Late Quaternary volcanic zones in Kamchatka, comprising 1604 analyses of spinel inclusions and their host-olivine in 104 samples from 30 volcanic complexes (single volcanoes and volcanic fields). The studied rocks are basalts, basaltic andesites and high-Mg andesites, which cover the whole compositional range of the primitive Late Quaternary volcanic rocks in Kamchatka. The spinel composition shows large variability. Spinel inclusions with the lowest Cr# and Fe3+/Fe2+ ratios were found in basalts from Sredinny Range and Northern Kamchatka, whereas the most Cr-rich and oxidized spinel inclusions occur in basalts and high-Mg andesites from the Central Kamchatka Depression. Intermediate Cr-spinel compositions characterize the Eastern Volcanic Belt of Kamchatka. The compositions of olivine-spinel pairs were used to quantify the oxidation state of parental Kamchatka magmas and the degree of partial mantle melting. The redox conditions recorded in spinel compositions range from ΔQFM = +0.7 to +3.7. ΔQFM for spinel from the Sredinny Range and Northern Kamchatka correlates with a number of whole-rock proxies for the involvement of slab-derived components (e.g., La/Nb and Ba/La), which suggests a coupling between mantle oxidation state and slab-derived fluid/melt metasomatism. These correlations were not observed in frontal Kamchatka volcanoes with the highest estimated ΔQFM, which possibly indicates buffering of the mantle oxidation state by sulfur. The estimated degrees of partial mantle melting range from 8 to >20% for Kamchatka volcanoes. Spinel from the Central Kamchatka Depression has the highest Cr# and could crystallize from magmas generated from the most depleted sources. In contrast to the Eastern Volcanic Belt, spinel Cr# and the inferred degrees of melting in the Central Kamchatka Depression do not correlate with spinel TiO2 content. The apparent decoupling between the proxies of mantle depletion in the CKD spinel is interpreted to reflect refertilization of the CKD mantle by oxidized Ti-rich slab- or mantle lithosphere-derived melts near the northern edge of the subducting Pacific Plate. This study demonstrates that the composition of Cr-spinel in volcanic rocks in combination with bulk-rock compositions can be a powerful tool to map regional variations of the mantle source depletion, oxidation state, and involvement of various slab-derived components in island-arc magmatism.

Diamondiferous Paleoproterozoic mantle roots beneath Arctic Canada: A study of mantle xenoliths from Parry Peninsula and Central Victoria Island

While the mantle roots directly beneath Archean cratons have been relatively well studied because of their economic importance, much less is known about the genesis, age, composition and thickness of the mantle lithosphere beneath the regions that surround the cratons. Despite this knowledge gap, it is fundamentally important to establish the nature of relationships between this circum-cratonic mantle and that beneath the cratons, including the diamond potential of circum-cratonic regions. Here we present mineral and bulk elemental and isotopic compositions for kimberlite-borne mantle xenoliths from the Parry Peninsula and Central Victoria Island, Arctic Canada. These xenoliths provide key windows into the lithospheric mantle underpinning regions to the North and Northwest of the Archean Slave craton, where the presence of cratonic material has been proposed. The mantle xenolith data are supplemented by mineral concentrate data obtained during diamond exploration. The mineral and whole rock chemistry of peridotites from both localities is indistinguishable from that of typical cratonic mantle lithosphere. The cool mantle paleogeotherms defined by mineral thermobarometry reveal that the lithospheric mantle beneath the Parry Peninsula and Central Victoria Island terranes extended well into the diamond stability field at the time of kimberlite eruption, and this is consistent with the recovery of diamonds from both kimberlite fields. Bulk xenolith Se and Te contents, and highly siderophile element (including Os, Ir, Pt, Pd and Re) abundance systematics, plus corresponding depletion ages derived from Re-Os isotope data suggest that the mantle beneath these parts of Arctic Canada formed in the Paleoproterozoic Era, at ∼2 Ga, rather than in the Archean. The presence of a diamondiferous Paleoproterozoic mantle root is part of the growing body of global evidence for diamond generation in mantle roots that stabilized well after the Archean. In the context of regional tectonics, we interpret the highly depleted mantle compositions beneath both studied regions as formed by mantle melting associated with hydrous metasomatism in the major Paleoproterozoic Wopmay-Great Bear-Hottah arc systems. These ∼2 Ga arc systems were subsequently accreted along the margin of the Slave craton to form a craton-like thick lithosphere with diamond potential thereby demonstrating the importance of subduction accretion in building up Earth’s long-lived continental terranes.