Dependence Of Current Density Research Articles

Lattice Boltzmann Model Investigation of Simultaneous Imbibition/Evaporation in PEMFC Cathodic Catalyst Layer Using Reconstructed 3D Image Data from Transmission Electron Microscopy

Proton Exchange Membrane Fuel Cells (PEMFCs) are widely used and significant attention is directed towards optimizing of the cathode catalyst layer. The critical focus revolves around refining the multi-phase boundary of the electrically conducting carbon support, the ion-conducting ionomer, the catalyst particles as well as the pore space that can be either occupied by oxygen (feedstock) or water (product). Challenges related to mass transport limitations of oxygen towards these multiple-phase boundaries, also denoted as active sites, persist, especially when liquid water increasingly saturates the pore space (Fig. 1). Furthermore, the evaporated water additionally hinders oxygen transport in the gas phase1,2. This study focuses on the investigation of pore-scale transport mechanisms inside of the cathodic catalyst layer, taking into account the counter-current diffusion of oxygen and water vapor in the gas phase as well as the generation of liquid water that increasingly saturates the void space. For this purpose, a multi-phase and multi-component pore scale Lattice Boltzmann model (LBM), coupled to two-phase reaction, was implemented. The LBM is tailored based on previous works3,4, including the localized generation of water at constant current densities, the imbibition of the pore structure with water counter-currently to the diffusion of oxygen, and the simultaneous evaporation of water. An actual 3D cathode catalyst layer from a commercial membrane electrode assembly, reconstructed from transmission electron microscopy (TEM) image data, was employed. It was imaged using a source voltage of 200kV and a current of 2 nA. The scanned sample had an approximate total volume of 500 × 500 × 100 nm3. From this, a 3D domain of 138 × 138 × 58 nm3 was reconstructed for this study. A 2D cross-section of the reconstructed image is exemplarily shown in Fig. 1. The in-silico study of water and oxygen transport through the catalyst layer elaborates the relationship between the rates of water invasion and evaporation in dependence of current density and catalyst layer structure. The critical conditions for water flooding are evaluated for different process conditions. Fig. 1 Schematic representation of the cathode catalyst layer: The ionomer is represented in white; the carbon for electron connectivity is represented in gray; pore space for oxygen and water transport in yellow; the black circles represent the active sites, i.e., Pt-particles located at the multi-phase boundary of ionomer, carbon and oxygen-filled pores; the red circles represent the inactive sites, that have no connection to ion and/or oxygen transport pathways. References A. Suzuki et al., Int. J. Hydrogen Energy, 36, 2221–2229 (2011) https://www.sciencedirect.com/science/article/pii/S0360319910022913.M. El Hannach, M. Prat, and J. Pauchet, Int. J. Hydrogen Energy, 37, 18996–19006 (2012) https://www.sciencedirect.com/science/article/pii/S0360319912022069.S. Bhaskaran et al., Dry. Technol., 40, 735–747 (2022) https://doi.org/10.1080/07373937.2021.1898417.S. Bhaskaran et al., Int. J. Hydrogen Energy, 47, 31551–31565 (2022) https://www.sciencedirect.com/science/article/pii/S0360319922030932. Figure 1

Impact of Spontaneous Orientational Polarization on Triplet-Triplet Upconversion-Based Blue Organic Light-Emitting Diodes.

The spontaneous orientation polarization (SOP) of a permanent dipole moment of the molecule induces a giant surface potential (GSP) in an organic semiconductor film, and GSP is expected to be a crucial parameter for understanding the operational mechanism of organic light-emitting diodes (OLEDs). This study demonstrates that the voltage-dependent migration of a carrier recombination zone induced by a polar electron transporting layer (ETL) having a positive SOP causes a decline in the overall performance of the OLED in triplet-triplet upconversion (TTU) based on OLEDs. Specifically, the TTU efficiency in an OLED with 2,2',2″-(1,3,5-benzinetriyl)-tris(1-phenyl-1-H-benzimidazole) (TPBi) as the ETL decreased by 20% due to the reduction of electrically generated triplet exciton density. This decrease resulted in a lower external electroluminescence (EL) quantum efficiency (EQE) of 5.4% at 1 mA cm-2, while the OLED with a nonpolar ETL resulted in an EQE of around 8.1% at 1 mA cm-2. We confirmed a shift in the recombination zone from the current density dependence of the EL spectra in the OLEDs. Our results indicate that the fixed carrier recombination zone near a hole transport layer and an emitting layer (HTL/EML) strongly enhanced the TTU process, while the polar EML/ETL interface induced the migration of the recombination zone depending on voltage, resulting in the decrease of triplet exciton density.

Cell size induced bias of current density in hypertrophic cardiomyocytes

ABSTRACT Alterations in ion channel expression and function known as “electrical remodeling” contribute to the development of hypertrophy and to the emergence of arrhythmias and sudden cardiac death. However, comparing current density values – an electrophysiological parameter commonly utilized to assess ion channel function – between normal and hypertrophied cells may be flawed when current amplitude does not scale with cell size. Even more, common routines to study equally sized cells or to discard measurements when large currents do not allow proper voltage-clamp control may introduce a selection bias and thereby confound direct comparison. To test a possible dependence of current density on cell size and shape, we employed whole-cell patch-clamp recording of voltage-gated sodium and calcium currents in Langendorff-isolated ventricular cardiomyocytes and Purkinje myocytes, as well as in cardiomyocytes derived from trans-aortic constriction operated mice. Here, we describe a distinct inverse relationship between voltage-gated sodium and calcium current densities and cell capacitance both in normal and hypertrophied cells. This inverse relationship was well fit by an exponential function and may be due to physiological adaptations that do not scale proportionally with cell size or may be explained by a selection bias. Our study emphasizes the need to consider cell size bias when comparing current densities in cardiomyocytes of different sizes, particularly in hypertrophic cells. Conventional comparisons based solely on mean current density may be inadequate for groups with unequal cell size or non-proportional current amplitude and cell size scaling.

Fe(Se,Te) Thin Films Deposited through Pulsed Laser Ablation from Spark Plasma Sintered Targets.

Iron-based superconductors are under study for their potential for high-field applications due to their excellent superconducting properties such as low structural anisotropy, large upper critical fields and low field dependence of the critical current density. Between them, Fe(Se,Te) is simple to be synthesized and can be fabricated as a coated conductor through laser ablation on simple metallic templates. In order to make all the steps simple and fast, we have applied the spark plasma sintering technique to synthesize bulk Fe(Se,Te) to obtain quite dense polycrystals in a very short time. The resulting polycrystals are very well connected and show excellent superconducting properties, with a critical temperature onset of about 16 K. In addition, when used as targets for pulsed laser ablation, good thin films are obtained with a critical current density above 105 A cm-2 up to 16 T.

Effect of peak discharge current on the ion current density on the substrate in the short-pulse HiPIMS

The bombardment of the substrate with accelerated ions from the plasma during the magnetron sputtering process is an effective way of controlling the energy transfer to the coating. One of the ways to increase the ion flux on the substrate is to change the parameters of the discharge power supply pulses. This work investigates the effect of the discharge current pulse amplitude on the average ion current density on the substrate in short-pulse high power impulse magnetron sputtering (s-HiPIMS). During sputtering, the peak discharge current varied from 25 to 250 A with a fixed pulse duration of 6 μs and an average discharge power of 1 kW. Experimental results and theoretical calculations show that the average ion current density on the substrate increases twofold when the amplitude of the discharge current pulses is increased from 25 to 60 A. As the amplitude of the discharge current pulses is further increased, the average ion current density on the substrate stops growing and begins to decrease at currents above 150 A. The paper discusses the reasons for the nonlinear dependence of the average ion current density on the substrate on the amplitude of the discharge current pulses.

Comparison of the Field Trapping Ability of MgB2 and Hybrid Disc-Shaped Layouts.

Superconductors have revolutionized magnet technology, surpassing the limitations of traditional coils and permanent magnets. This work experimentally investigates the field-trapping ability of a MgB2 disc at various temperatures and proposes new hybrid (MgB2-soft iron) configurations using a numerical approach based on the vector potential (A→) formulation. The experimental characterization consists in measurements of trapped magnetic flux density carried out using cryogenic Hall probes located at different radial positions over the MgB2 sample, after a field cooling (FC) process and the subsequent removal of the applied field. Measurements were performed also as a function of the distance from the disc surface. The numerical modelling of the superconductor required the evaluation of the critical current density dependence on the magnetic flux density (Jc(B)) obtained through an iterative procedure whose output were successfully validated by the comparison between experimental and computed data. The numerical model, upgraded to also describe the in-field behavior of ARMCO soft iron, was then employed to predict the field-trapping ability of hybrid layouts of different shapes. The most promising results were achieved by assuming a hollow superconducting disc filled with a ferromagnetic (FM) cylinder. With such a geometry, optimizing the radius of the FM cylinder while the external dimensions of the superconducting disc are kept unchanged, an improvement of more than 30% is predicted with respect to the full superconducting disc, assuming a working temperature of 20 K.

Bulk Heterojunction or Layer‐by‐Layer Structure PM6:L8‐BO Based Polymer Solar Cells Exhibiting an Efficiency of 17.84 % or 18.43 %

AbstractTwo kinds of polymer solar cells (PSCs) were fabricated with polymer donor PM6 and small molecule non‐fullerene acceptor L8‐BO as accepted based on bulk heterojunction (BHJ) or layer‐by‐layer (LbL) structure. The power conversion efficiency (PCE) of 18.43 % and 17.84 % can be achieved from the PSCs based on BHJ and LbL structure, respectively. Two kinds of PSCs exhibit the same open circuit voltage (VOC) of 0.88 V, which can be well explained from the same donor and acceptor materials and the same electrodes. The LbL based PSCs exhibit a relatively large short circuit current density (JSC) of 26.97 mA cm−2 and fill factor (FF) of 77.64 % in comparison with JSC of 26.64 mA cm−2 and FF of 76.07 % for BHJ based PSCs. The relatively high PCE of LbL based PSCs should be attributed to the sufficient exciton dissociation and charge collection efficiency, as well as the more balanced charge transport, which can be confirmed from the photogenerated current density dependence on the effective bias. This work demonstrates that layer‐by‐layer structure may have great potential in preparing highly efficient PSCs.

Tuning the superconducting performance of YBa2Cu3O7-δ films through field-induced oxygen doping.

The exploration of metal-insulator transitions to produce field-induced reversible resistive switching effects has been a longstanding pursuit in materials science. Although the resistive switching effect in strongly correlated oxides is often associated with the creation or annihilation of oxygen vacancies, the underlying mechanisms behind this phenomenon are complex and, in many cases, still not clear. This study focuses on the analysis of the superconducting performance of cuprate YBa2Cu3O7-δ (YBCO) devices switched to different resistive states through gate voltage pulses. The goal is to evaluate the effect of field-induced oxygen diffusion on the magnetic field and angular dependence of the critical current density and identify the role of induced defects in the switching performance. Transition electron microscopy measurements indicate that field-induced transition to high resistance states occurs through the generation of YBa2Cu4O7 (Y124) intergrowths with a large amount of oxygen vacancies, in agreement with the obtained critical current density dependences. These results have significant implications for better understanding the mechanisms of field-induced oxygen doping in cuprate superconductors and their role on the superconducting performance.

Physics, electrochemistry, chemistry, and electronics of the vanadium redox flow battery by analyzing all the governing equations.

The vanadium redox flow battery has been intensively examined since the 1970s, with researchers looking at its electrochemical time varying electrolyte concentration time variation equations (both tank and cells, for negative and positive half cells), its thermal time variation equations, and fluid flow equations. Chemistry behavior of the electrolyte ions have also been intensively examined too. In this perspective, all of the phenomena have been examined, unified and presented together with their physical chemistry shown in the appropriate equations. This is done by providing the field equations for the battery, which are electronic, electrochemical, chemical, physics of fluid dynamics, and thermal physics of heat transport, in character. They are interpreted in new analytical equations providing fundamental scientific insights, as well as allowing engineering and manufacturing assessments. Graphs of pressure trend in electrodes, power and temperature tables for electrode and current collector loss mechanisms are provided. Current density, concentration, electrostatic, and overpotential functional dependences in the electrodes are given.

A Disposable Sensor for Rapid Histamine Detection in Fish Using Molecularly Imprinted Carbon Paste Electrode

Introduction: Histamine (HM), a toxic compound, is produced due to an enzymatic reaction when histidine (HS)-rich red fish such as tunas and other fish and their processed products are improperly stored, e.g., leaving them at room temperature. With the increasing popularity of raw fish consumption, HM analysis is mandatory for these fish in various countries. However, the conventional immunoassay method is time-consuming, costly, and technically demanding, burdening wholesalers heavily.Molecularly Imprinted Polymers-based materials are attractive materials for sensor fabrication due to their high selectivity, stability, and ease of production. In this study, we attempted to develop a Molecularly Imprinted Polymer grafted Carbon Paste (MIP-CP) for histamine sensing. Experimental Methods First, a radical polymerization initiator was fixed on the surface of graphite particles [1]. Next, histamine dihydrochloride, itaconic acid, and ethylene glycol dimethacrylate (EDMA) were dissolved in a mixture of distilled water and dimethylformamide to prepare a polymerization solution. The polymerization solution and initiator-fixed graphite were placed in a quartz tube and irradiated with a xenon lamp for 1 hr. HM was extracted and removed using acetic acid. MIP-CP was prepared by mixing MIP-grafted graphite and silicon oil containing ferrocene in a 7:3 weight ratio. Non-imprinted polymer (NIP)-CP was also prepared using the same procedure, except that HM was not added.Differential pulse voltammetry (DPV) was performed with electrodes packed with the obtained MIP-CPs on a disposable chip [2]. The performance of the HM sensor was evaluated based on the relationship between the oxidation current of ferrocene and HM concentration. (Measurement range 0 μg/mL~100 μg/mL) Experimental results The dependence of the oxidation current density on HM concentration at the NIP and MIP electrodes was confirmed (0.0085 μA-mL/μg, R²=0.9357). The increase in current density with increasing HM concentration at the MIP-CP electrode was more than three times greater than at the NIP-CP electrode. This confirmed that MIP-CP exhibited current changes corresponding to the interaction between HM and HM-imprinted sites. Furthermore, the current increased linearly with increasing HM concentration from 0-100 µg/mL. This dynamic range includes 50 µg/mL, which is considered the lower limit of acceptable Hm concentration in fish meat.However, the current value was constant for HS concentration at 0.75 µA over the range of 40-100 µg/mL and below. Therefore, the sensor is saturated with HS at concentrations above 40 µg/mL, and histidine interference can be excluded by subtracting 0.75 µA from the current value obtained when measuring the fish meat sample. Conclusion We successfully developed a reagentless, disposable histamine sensor using MIP-CP, which provides a rapid, reliable, and cost-effective method for histamine detection in fish.

Through-Plane Cerium Ion Migration and Diffusion Analysis on Plymer Electrolyte Membrane by Operando X-Ray Fluorescence Spectroscopy

High durability is a critical requirement for expanding the use of polymer electrolyte fuel cells (PEFCs). One degradation factor of PEFCs under typical operating conditions is electrolyte membrane degradation. Radical species formed from the reaction between hydrogen peroxide and impurities during fuel cell operation cause significant degradation of the PEM. To scavenge the radicals, cerium species are added to the PEM, which react with the radicals by redoxing the cerium ion [1]. To maintain the effectiveness of the cerium radical quencher in the PEM, the concentration of cerium in the PEM must be maintained during the long-term operation of the PEFC. However, cerium species easily diffuse and migrate out of the PEM [2]. If the cerium ion is depleted, the PEM will be severely attacked by radicals. To prevent such cerium depletion, it is important to understand the cerium migration phenomena. Experimental detection of cerium distribution phenomena through PEM by operando X-ray fluorescence spectroscopy with resolution of several micrometers has been reported [3]. We have also developed operando XRF using focused micron X-ray with submicrometer resolution [4]. In this study, we further develop the analysis method for cerium diffusion through planar PEM with sub-second time resolution. This method is used to estimate the apparent diffusion coefficient of cerium in PEM.MEAs were prepared by a conventional method using a Pt/C catalyst and a cerium-containing polymer electrolyte with a thickness of 12 μm(GORE-SELECT® MEMBRANEM788.12). The active electrode area was 1.0 cm2. Single cells were assembled using custom end plates with an X-ray permeation window. Operando X-ray fluorescence spectroscopy measurements were performed on BL37XU at SPring-8 (Japan). The monochromated X-ray at an energy of 45 keV was focused to less than 500 nm by a Kirkpatrick-Baez mirror. To detect the cerium distribution in MEA, the fluorescence intensity of Ce-Kα was counted with a Ge semiconductor detector by scanning the position of the cell.In the open circuit condition, most of the cerium is present in the PEM, but during cell loading, the cerium moves to the cathode layer. Immediately after the start of 2.0 A cm-2 loading, the intensity of cerium in the cathode layer increases in a few seconds. Simultaneously, a cerium concentration gradient is observed through the MEA. The cerium concentration gradient shows the current density dependence. When the current load is stopped, the concentrated cerium in the catalyst layer diffuses into the PEM. The diffusion coefficient of cerium ion is estimated from the time dependence of cerium concentration in PEM.Acknowledgments: This work is based on results obtained from the project commissioned by the New Energy and Industrial Technology Development Organization (NEDO) of Japan. E. Endoh et al, ECS Electrochem. Lett., 2, F73 (2013).S. M. Stewart et al, ECS Electrochem. Lett., 3, F19 (2014).A. M. Baker et al, ECS Trans., 92, 107 (2019).Y. Orikasa et al, ECS Trans., 109 109 (2022).

Physicochemical and Electrochemical Properties of Materials Based on Titanium Suboxides

The influence of the synthesis conditions on the surface morphology, phase composition, and electrocatalytic activity of materials in oxygen and hydrogen evolution reactions was investigated. For instance, the slopes in the potential vs the logarithm of the current density dependencies during oxygen evolution were 221 and 109 mV/dec for TiO2 nanotubes and platinum-coated layers, respectively. In the latter case, small deviations may be attributed to the structural heterogeneity of the material or the developed surface of the coating. As for pristine TiO2 nanotubes, an atypical Tafel slope was observed, almost twice the theoretical value, indicating the presence of a semiconductor component in the electrode capacitance. Studies showed that the materials are n-type semiconductors. The cathodic polarization stage leads to the formation of titanium suboxides in the nanotube recovery phase, contributing to an increase in the material electrical conductivity. This also allows for the creation of a porous developed surface matrix for the electrodeposition of catalytic metal layers. Tafel slopes were calculated for the investigated materials in the hydrogen evolution reaction. For TiO2 nanotubes, a slope of 175 mV/dec was observed. The material surface was partially blocked by hydroxides, resulting in a low num-ber of active centers for the hydrogen evolution, and the polarization curve had a steep slope. In the case of TiO2 nanotubes coated with a platinum layer, a high number of cationic vacancies in the matrix and a deficit of oxygen ions facilitated the mobility of platinum atoms, leading to the emergence of a large number of active centers for the hydrogen evolution. As a result, the Tafel slope of the polarization curve was found to be 30 mV/dec.

Temperature dependence of transport critical current density for REBCO superconducting tapes deposited by MOCVD

The temperature-dependent transport critical current density () behavior of REBa2Cu3O7−δ (REBCO) superconducting tapes with various RE substitutions and combinations has been systematically studied in the temperature range of 4 K–77 K. The measured values were found to be highly in accordance with with the values of the exponent coefficients s ranging from 1.9 to 2.6 in the magnetic-field range of 1–5 T depending on RE ion(s), revealing the dominative pinning mechanism of flux core pinning. The RE-ionic-radius (r) dependences of showed reversed trends for temperatures below and above 50 K, with increasing with r at higher temperatures while it decreased with r at lower temperatures, which was consistent with previously reported results. In particular, the in-field of REBCO tapes at 4 K as a function of r was consistent with the –r trend for low temperatures. We propose to attribute the –r trends to the higher charge carrier density and the lower critical transition temperature () in REBCO films with smaller r. The Gd0.5Yb0.5BCO tape with superior at low temperatures exhibited the furthest diversion from the –r trendlines due to enhanced correlated pinning by the high-density of vertically aligned second-phase nanocolumns in the film. The temperature dependence of for REBCO tapes with a larger r was found to be more susceptible to the magnetic field. Meanwhile, the exponent coefficients s showed a more precipitous increase with the increasing magnetic field, partially due to the lack of effective pinning defects, which was also confirmed by the two-dimensional x-ray diffraction patterns and the higher α values. This work contributes to the study of the of REBCO superconducting tapes below 20 K and leads to a deeper understanding of the temperature-dependent behavior of REBCO films with various RE substitutions and combinations. This provides more comprehensive guidelines for the optimization of RE ions in REBCO for applications at specific temperatures and magnetic fields.

Ic measurement of twisted multifilamentary MgB2 wires with non-magnetic sheath over a wide range of temperatures and fields

All-superconducting rotating machines have the potential for meeting the high power density and high efficiency required for electrical aircraft applications. However, very high AC loss encountered in superconducting armature windings could hinder their development. Multifilamentary MgB2 wires are one of the promising candidates for the stator windings, due to their potentially low AC loss properties with small filament size and twist pitches. As the first step, the dependence of critical current and n-value on magnetic fields and temperatures Ic(B, T) and n(B,T), which are basic input parameters for AC loss simulation, needs to be measured. In this work, we present transport Ic measurements in three non-magnetic multifilamentary MgB2 wires (MgB2/Nb/CuNi/CuZn): one large wire with a 0.70 mm diameter and 25 mm twist pitch, and two small wires with a 0.48 mm diameter each and a 10 mm and 30 mm twist pitch respectively. A four-probe direct current method is used to measure Ic of the MgB2 wires with variations in temperature (15 – 35 K) and magnetic field (0 – 5.5 T). Full Ic data for the small wire with 10 mm twist pitch was obtained, and the n-values were mostly less than 20. While the Ic data for the large wire at low fields was more limited due to heating, the n-values were higher and could be up to around 100. The difference is attributed to the different filament sizes. Experiments also found that there is no significant hysteresis in the transport critical current measured by decreasing or increasing magnetic fields due to the non-magnetic sheaths. This non-hysteretic characteristic is critical for lowering AC loss because the additional losses from magnetic sheaths can be eliminated. From the magnetic-field dependence of critical current density, an empirical expression has been developed that provides suitable extrapolations to lower fields for the large wire.

Evaluation of the Performance of Commercial High Temperature Superconducting Tapes for Dynamo Flux Pump Applications

High Temperature Superconducting (HTS) dynamo flux pumps are a promising alternative to metal current leads for energization and the persistent current mode operation of high current DC superconducting magnet systems for applications in rotating machines, such as Magnetic Resonance Imaging (MRI) or fusion systems. The viability of the flux pump concept has been widely proven by laboratory experiments and research is now in progress for the design and optimization of flux pump devices for practical applications. It has been widely established that the dependence of the critical current density (Jc) on the temperature (T), the magnetic field magnitude (B), and the orientation (θ), has a substantial impact on the overall DC voltage obtained at the terminals, as well as on the current limit and the loss of the flux pump. Since HTS tapes produced by different manufacturers, they show different dependencies of Jc with the amplitude and the orientation of the magnetic field. They also give rise to different outputs when employed in flux pumps. In this paper, we evaluate and compare the performance of several commercial HTS tapes used for flux pumping purposes through numerical simulation. We also investigate the dependence of the flux pump ‘s performance on the operating temperatures. A 2D finite element numerical model is first developed and validated against experimental data at 77 K. Afterward, the same HTS dynamo apparatus used for validation is exploited for the comparison. The Jc(B,θ,T) and n(B,θ,T) relations, which characterize each different tape in the model, are reconstructed via artificial intelligence techniques based on the open-access database of the Robinson Research Institute. It is shown in the paper that certain tapes are more suitable than others for flux pump applications and that the best overall operating temperature is in the vicinity of 77 K.

Physicochemical analysis of infiltrated cathode symmetric cells for intermediate temperature SOFCs

This study investigated the cathode parameter changes before and after infiltration based on Jamnik and Maier's MIEC transmission line model. To consider additional factors such as surface adsorption capacitance, chemical capacitance Cchem, and general capacitance effect CHN were introduced in parallel. To obtain the appropriate temperature dependence, oxygen partial pressure dependence, and current density dependence trends of transmission line parameters, the trend of Cchem was fixed according to each measurement condition using the thermodynamic parameters of previous papers. Infiltrating Sm0.5Sr0.5CoO3-δ (SSC), a better catalyst material, into the widely used La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF6428) perovskite electrode resulted in a decrease in surface reaction resistance Rp by about 1 order of magnitude and a decrease in oxygen ion diffusion resistance Rs. The oxygen ion adsorption capacitance CHN0 on the surface is larger after infiltration due to the larger surface area of the infiltrated electrode, which can be explained by the two arcs clearly separated in the impedance spectra of the infiltrated cell. Additionally, after infiltration, the diffusion characteristics depending on oxygen partial pressure changed relatively from bulk diffusion to surface diffusion. The value of Rs is larger than Rp under almost all conditions, indicating that the overall rate-determining step (rds) is the diffusion reaction in the current direction. Furthermore, to observe the changes in surface reaction characteristics only, the characteristics of Rp before and after infiltration were analyzed based on the Butler-Volmer-type equation and oxygen partial pressure dependence of the exchange current density of surface reactions. As a result, the rds of surface reactions changed from the reduction reaction of the intermediate stage of electrode reactions after infiltration to the dissociative adsorption reaction of the initial reaction stage.

Current Density Dependence of Transport Selectivity of Metal Ions in the Electrodriven Process across the Cation Exchange Membrane.

Understanding the mechanisms leading to the selective transport of cations in an electrodriven process across a cation exchange membrane is important to design and control the potential gradient-based separation process. In this study, a comprehensive description of the current density (I, over a broad current regime) dependence of transport selectivity (Si) between cations of the same/different valence is presented. The role of conventional transport mechanisms such as diffusion, electromigration, and electroconvection in controlling the Si was identified theoretically as well as by multiple experimental approaches. These parameters were found to be dependent on the limiting current density (Ilim). In general, irrespective of the cations involved, Si (over Na+) decreased gradually with increasing I and then increased slowly (and saturated) after Ilim. This extent of variation of Si was heavily dependent on the charge and hydration state of the cations. At I < Ilim, both diffusion and electromigration processes contributed and, notably, the sorption selectivity outweighed the migration selectivity. At I → Ilim, diffusion was the solitary mechanism responsible for cation transport and migration selectivity was the major contributor in Si. At I > Ilim, as also validated by the Peclet numbers, the overall transport was dictated by electroconvection.

Imaging Liquid Water in a Polymer Electrolyte Fuel Cell with High-Energy X-ray Compton Scattering

Compton scattering imaging with intense, high-energy synchrotron X-rays allows us to visualize a light element substance in an operating electrochemical device. In this paper, we report the first experiment of Compton scattering imaging (CSI) on an operating polymer electrolyte fuel cell (PEFC). The novelty of the CSI technique is a non-destructive direct observation of cross-sectional images with a sensitivity to light elements and a capability of simultaneous measurements with fluorescent X-rays of heavy elements. Analyses of the observed images provide the cross-sectional distribution of generated liquid water and its current density dependency. The results show that the amount of generated water increases in the vicinity of the cathode catalyst layer at current densities ranging from 100 to 500 mA/cm2, while it remains constant or slightly decreases from 500 to 900 mA/cm2. In both the gas diffusion layer and the channel, liquid water is observed near the channel and rib interface above 500 mA/cm2, indicating the formation of a liquid water flow path. In addition, simultaneous measurements of fluorescent Pt-Ka X-rays reveal a significant correlation between the generated liquid water and Pt catalysts, using the Pearson correlation coefficient. The result shows that water is dispersed in the catalyst layer without any correlation with the amount of Pt catalysts at low current densities, but water tends to be distributed in the Pt-rich areas at high current densities. This study demonstrates that Compton scattering imaging is one of the unique techniques to characterize the behavior of generated liquid water in an operating PEFC.

Analysis of Effect of Concentration Dependence of Exchange Current on the Metal Electrodeposition into Template Nanopores

Metal electrodeposition into the nanopores of template of porous anodic alumina type under the conditions of mixed kinetics is studied theoretically using analytical and numerical methods. Two main stages of the process are studied: the non-steady-state formation of diffusion layer in the template pores and much longer process of pore filling with metal. The effect of nonlinearity of the concentration dependence of exchange current density of metal electrodeposition on the current density of the diffusion layer formation and pore filling with metal is studied.

Large-scale vibrating coil magnetometer for the magnetic characterization of bulk superconductors

This work presents the design and validation of a vibrating coil magnetometer for the characterization of the field dependence of the critical current density of centimeter-sized bulk superconductors as an alternative to the destructive methods typically used. The magnetometer is also shown to be capable of measuring the magnetic moment in an applied field of up to 5 T for diverse magnetic materials, such as soft and hard ferromagnets and high-temperature superconducting pellets. The vibrating coil magnetometer was first optimized using finite element simulations and calibrated using a commercial vibrating sample magnetometer. The vibrating coil magnetometer was benchmarked with hysteresis measurements of a Nd2Fe14B disk made with a commercial hysteresisgraph, showing good agreement between the different setups. The magnetic hysteresis of a YBa2Cu3O7−x superconducting pellet was measured at 77 K, showing a penetration field of 1 T and an irreversibility field of 4 T. The field dependent critical current density of the superconductor was then inferred from the magnetic hysteresis measurements and extrapolated at low fields. Finally, the resulting critical current density was used to successfully reproduce the measured magnetization curve of the pellet at 2 T with finite element simulations.