Density Fraction Research Articles

Stellar Characterization and Chemical Abundances of Exoplanet-hosting M Dwarfs from APOGEE Spectra: Future JWST Targets

Exoplanets hosting M dwarfs are the best targets to characterize Earth-like or super-Earth planetary atmospheres with the James Webb Space Telescope (JWST). We determine detailed stellar parameters (T eff, logg, and ξ) and individual abundances of 12 elements for four cool M dwarfs hosting exoplanets TOI-1685, GJ 436, GJ 3470, and TOI-2445, scheduled for future observations by the JWST. The analysis utilizes high-resolution near-infrared spectra from the Sloan Digital Sky Survey IV APOGEE survey between 1.51 and 1.69 μm. Based on 1D LTE plane-parallel models, we find that TOI-2445 is slightly metal poor ([Fe/H] = −0.16 ± 0.09 dex), while TOI-1685, GJ 436, and GJ 3470 are more metal rich ([Fe/H] = 0.06 ± 0.18, 0.10 ± 0.20, and 0.25 ± 0.15 dex, respectively). The derived C/O ratios for TOI-2445, TOI-1685, GJ 436, and GJ 3470 are 0.526 ± 0.027, 0.558 ± 0.097, 0.561 ± 0.029, and 0.638 ± 0.015, respectively. From the results for 28 M dwarfs analyzed homogeneously from Apache Point Observatory Galactic Evolution Experiment (APOGEE) spectra, we find exoplanet-hosting M dwarfs exhibit a C/O abundance ratio approximately 0.01–0.05 higher than those with nondetected exoplanets, at limits of a statistically significant offset. A linear regression of the [Fe/H] versus C/O distribution reveals a noticeable difference in the angular coefficient between FGK dwarfs (0.27) and M dwarfs (0.13). Assuming our abundance ratios of Ca/Mg, Si/Mg, Al/Mg, and Fe/Mg, we determine a mass of 3.276−0.419+0.448 M ⊕ for TOI-2445 b, which has a density (6.793 −0.099+0.005 g cm−3) and core mass fraction (0.329 −0.049+0.028 ) very similar to Earth’s. We also present an atlas of 113 well-defined spectral lines to analyze M dwarfs in the H band and a comprehensive evaluation of uncertainties from variations in the atmospheric parameters, signal-to-noise ratio, and pseudocontinuum.

Laser powder bed fusion of NbTi low-temperature superconductors

This study investigates the superconducting properties of additive manufactured in-situ NbTi alloy using laser powder bed fusion. Laser parameters were optimised for a maximum microstructural density and lowest Nb segregation fraction. These characters have been achieved at the sample built with an energy density of 3.33 J/mm2, where it shows a density value of 6.12 g/cm3, undissolved Nb fraction of 0.05 %, and randomly distributed equiaxed grains with an average size of 10–20 μm. Post-processing of the as-fabricated (AF) sample was explored as a route to collapse residual porosity and dissolve residual segregated Nb particles using hot isostatic pressing (HIP) and heat treatment, respectively. HIPing resulted in a decrease of the undissolved Nb particle fraction to 0.035 %. Heat treatment at 1250 °C for 24 h, followed by aging at 400 °C for 2 h, was found to result in the complete dissolution of Nb particles and precipitation of the ɑ-Ti phase that works as pinning centres to increase the superconducting properties. The grain size increased in both post-processes to 400–500 μm. Electrical and magnetic properties were also measured for the AF, HIP and heat-treated samples. The thermal variation of electrical resistivity showed a critical temperature (Tc) range of 9.8–9.0 K, 9.6–9.1 K and 9.9–8.8 K for the AF, HIP, and heat-treated samples, respectively, which were close to the values obtained from magnetic measurements. The critical current density (Jc) was calculated using Bean’s model employing the magnetic hysteresis loops. The AF condition showed a negligible value of Jc (5 × 10−3 kA/mm2), which improved to 0.28 kA/mm2 and 2.65 kA/mm2 for the HIPed, heat treated conditions, respectively (at 4.2 K, 5 T). Mechanical tensile testing was performed for the heat-treated sample to ensure both mechanical and superconducting properties would achieve the required performance, where achieves ultimate tensile strength value of 930 MPa, with 8 % elongation.

A long-pulse small edge-localized-mode high-confinement plasma with detachment feedback control by floating potential in an experimental advanced superconducting tokamak in a metal wall environment

Abstract One of the key challenges facing the magnetic fusion research is to demonstrate the compatibility between high confinement and radiative divertor in long-pulse discharges with a metal wall environment. A small edge localized mode (ELM) high confinement plasma is obtained in the upgraded lower divertor of Experimental Advanced Superconducting Tokamak (EAST) with an energy confinement factor H98~1.1 and a Greenwald density fraction fGW ~ 0.65 maintained for 26 s, and periodical detachment is achieved through active control of neon impurity seeding in this long-pulse discharge. For the divertor region, partial detachment is achieved periodically on the outer divertor target plates with the plasma temperature near the outer strike point decreased to below 5 eV and peak surface temperature on the outer divertor target plates maintained below 350C. The peak heat flux of the lower outer divertor decreases significantly and its profile along the target becomes very flat in the detached state. Two low-frequency (<10 kHz) fluctuations that are related to rippling mode caused by a resistive instability appear in the detached state. For the pedestal region, the electron pressure profile is flatter and ELM amplitude is smaller in the detached state than that in the attached state. Edge coherent mode (ECM) appears in the attached state and disappears in the detached state. To achieve this experimentally, a new impurity seeding feedback control scheme is applied, where the floating potential measured by divertor Langmuir probes is used as the feedback sensor, which is more reliable in the long-pulse discharges with high heat fluxes, thus more suitable for application in future devices. This work provides a new approach for the actively controlled radiative divertor as a solution to the divertor heat loads of the future fusion reactors.

Hydrogen production with a novel coaxial cylindrical electrolyser: A CFD study

This study introduces a unique coaxial cylindrical electrode design for Alkaline Water Electrolysers (AWEs) that is analyzed to show possible enhancements over the traditional stacked plate design. It investigates the performance of the proposed coaxial AWE for enhanced hydrogen production. Through comprehensive computational simulations, key performance indicators, such as current density and hydrogen volume fraction, are analyzed across various operating parameters. The results of this study indicate that the production rate of hydrogen achieves its highest level at a volume percentage of 3.4 %. This rate is significantly influenced by the concentration of the electrolyte, the distance between the cathode and anode rings, and, to a lesser degree, the porosity of the separator. Consequently, the optimized conditions demonstrate a promising increase in current densities, reaching 1000 mA/cm2 at an operating voltage of 2 V, showcasing the potential for developing more efficient and cost-effective AWE systems. This study further contributes valuable insights into the design and operational improvements needed for the advancement of large-scale hydrogen production technologies.

Improved model of large-field inflation with primordial black hole production in Starobinsky-like supergravity

Abstract A viable model of large-field (chaotic) inflation with efficient production of primordial black holes is proposed in Starobinsky-like (modified) supergravity leading to the ‘no-scale-type’ Kähler potential and the Wess-Zumino-type (‘renormalizable’) superpotential. The cosmological tilts are in good (within 1σ) agreement with Planck measurements of the cosmic microwave background radiation. In addition, the power spectrum of scalar perturbations has a large peak at smaller scales, which leads to a production of primordial black holes from gravitational collapse of large perturbations with the masses about 1017 g. The masses are beyond the Hawking (black hole) evaporation limit of 1015 g, so that those primordial black holes may be viewed as viable candidates for a significant part or the whole of the current dark matter. The parameters of the superpotential were fine-tuned for those purposes, while the cubic term in the superpotential is essential whereas the quadratic term should vanish. The vacuum after inflation (relevant to reheating) is Minkowskian. The energy density fraction of the gravitational waves induced by the production of primordial black holes and their frequency were also calculated in the second order with respect to perturbations.

Artificial intelligence for computation and development of nanodrug solubility in supercritical solvent: Analysis of temperature and pressure influence

This paper presents an investigation into the modeling and prediction of the density of supercritical carbon dioxide (SC-CO2) and mole fraction of Erlotinib hydrochloride using machine learning techniques. The dataset consists of temperature and pressure as input variables, with density of SC-CO2 and mole fraction of Erlotinib hydrochloride as output variables. The process is supercritical-based operation which can be used for production of nanomedicines with improved aqueous solubility. Three models, Multilayer Perceptron (MLP), Orthogonal Matching Pursuit (OMP), and Extreme Gradient Boosting (XGB) were trained and optimized using the Firefly Optimization Algorithm (FA). The models’ performance in correlating solubility and density were evaluated via statistical analyses to measure their accuracy. The MLP model achieved high accuracy, with scores of 0.99714 and 0.97749 for density and mole fraction prediction, respectively in term of coefficient of determination (R2). The OMP and XGB models also provided reasonably accurate results. These findings demonstrate the effectiveness of machine learning in understanding and predicting SC-CO2 behavior, with potential applications in industrial processes and pharmaceutical formulations.

Quantitative assessment of rotator cuff injuries using synthetic MRI and IDEAL-IQ imaging techniques

PurposeTo evaluate synthetic magnetic resonance imaging (SyMRI) and iterative decomposition of water and fat with echo asymmetry and least squares estimation (IDEAL-IQ) imaging for a comprehensive evaluation of rotator cuff injuries (RCI). MethodsNinety-seven patients with RCI were classified into four groups based on the arthroscopic results: (grade II), partial tear (grade III), complete tear (grade IV), and controls (grade I). T1 (Transverse Relaxation Time 1), T2 (Transverse Relaxation Time 2), proton density (PD), and fat fraction (FF) were evaluated using SyMRI and IDEAL-IQ. Measurement reliability was assessed using intraclass correlation coefficients (ICC). The diagnostic potential for grading RCI was evaluated using ordinal regression and ROC analyses. ResultsA high measurement reliability (ICC > 0.7) was observed across subregions. T1 and T2 significantly varied across grades, particularly T2 in the lateral subregion between grades III and IV (P < 0.001) and the central subregion between grades II and III (P < 0.001). ROC analyses yielded valuable diagnostic accuracy, including T2 in the lateral subregion with an AUC of 0.891, distinguishing grade I from grade IV. Positive correlations were found between T2 values in specific shoulder subregions and injury grade (r = 0.615 for lateral, r = 0.542 for medial, both P < 0.001). In grade IV, FF was notably increased in the supraspinatus, infraspinatus, and subscapularis muscles compared with grades I-III. There were no significant FF variations in the teres minor muscle among grades. ConclusionsQuantitative MRI parameters from SyMRI and IDEAL-IQ, especially T2 and FF, may classify and assess RCI severity. The results could help improve the accuracy of diagnosing different grades of RCI, offering clinicians additional tools for improving patient outcomes through personalized medicine.

Structural reorganization of medullary dorsal horn astrocytes in a rat model of neuropathic pain.

Multiple studies have shown that astrocytes in the medullary dorsal horn (MDH) play an important role in the development of pathologic pain. However, little is known about the structural reorganization of the peripheral astrocytic processes (PAP), the main functional part of the astrocyte, in MDH in neuropathic state. For this, we investigated the structural relationship between PAP and their adjacent presynaptic axon terminals and postsynaptic dendrites in the superficial laminae of the MDH using electron microscopical immunohistochemistry for ezrin, a marker for PAP, and quantitative analysis in a rat model of neuropathic pain following chronic constriction injury of the infraorbital nerve (CCI-ION). We found that, compared to controls, in rats with CCI-ION, (1) the number, % area, surface density, and volume fraction of ezrin-positive (+) PAP, as well as the fraction of synaptic edge apposed by ezrin + PAP and the degree of its coverage of presynaptic axon terminals and postsynaptic dendrites increased significantly, (2) these effects were abolished by administration of the mGluR5 antagonist 2-methyl-6-(phenylethynyl) pyridine (MPEP). These findings indicate that PAP undergoes structural reorganization around the central synapses of sensory afferents following nerve injury, suggest that it may be mediated by mGluR5, and may represent the structural basis for enhancing astrocyte-neuron interaction in neuropathic pain.

Stronger aggregation reduces temperature sensitivity of soil organic carbon decomposition in croplands

AbstractThe temperature sensitivity (Q10) of soil organic C (SOC) decomposition is an important parameter to predict C dynamics under climate change. Given that SOC is mainly protected by aggregates and minerals, differentiating the Q10 of the two C fractions helps to explain bulk soil C dynamics. In the present study, we collected agricultural soils from adjacent paddy and upland areas in mid‐temperate (Mollisols) and subtropic (Ultisols) regions of China. We employed density fractionation to separate aggregate‐protected and free mineral‐associated C fractions of soil samples and determined the Q10 of SOC and the two C fractions at 15 and 25°C incubated conditions. Results showed that the Q10 of SOC for Mollisols were lower than that for Ultisols, with an exception of aggregates in upland soils. Aggregate‐protected C had lower Q10 than free mineral‐associated C, except in the upland Mollisols. The Q10 of SOC was negatively correlated with the proportion of C protected in aggregates, whereas it was positively correlated with the proportions of mass or C of free minerals. Given that the mass and C proportion of aggregates in bulk soils of Mollisols were 271% and 80% higher than of Ultisols, respectively, the SOC of Mollisols exhibited lower Q10 than Ultisols. Therefore, stronger soil aggregation and higher proportion of aggregate‐protected C contributed to the lower temperature sensitivity of SOC in Mollisols. Consequently, agricultural practices aimed at promoting soil aggregation will alleviate SOC loss under future global warming scenarios.

FeSiBCCr bulk metallic glasses with excellent soft magnetic properties prepared using spark plasma sintering technology

Fe-based amorphous alloys have received much attention in the fields of electronics and electrical due to their excellent soft magnetic properties at high frequency. However, the controllable preparation of large-sized Fe-based bulk metallic glasses (BMGs) still faces numerous challenges. In this study, FeSiBCCr amorphous powders prepared by gas-water combined atomization were used as raw materials, and FeSiBCCr BMGs were prepared through spark plasma sintering (SPS) at different pressures. The microstructure, phase and magnetic properties of the compacts were systematically characterized using SEM, XRD, TEM, DSC, and VSM. The results showed that when the sintering pressure was 50 MPa, the slow densification process dominated by particle rearrangement at the initial densification process made the internal contact resistance of the compacts larger. This led to macroscopic inhomogeneous physical fields and severe local overheating during the later stages of sintering, causing the precipitation of α-(Fe, Si) and Fe3B phases. Although the material exhibited a relatively high saturation magnetization (Bs) of 1.08 ± 0.01 T, the low density and amorphous fraction resulted in a high coercivity (Hc) of 1060.8 ± 37.8 A·m-1. When the sintering pressure was increased to 250 MPa, the degree of particle densification significantly improved, and the temperature inhomogeneity was markedly suppressed due to reduced internal resistance. Thus, the prepared FeSiBCCr BMGs exhibited an extremely high density of 6.66 ± 0.06 g·cm-3 and excellent soft magnetic properties with Bs of 1.23 ± 0.01 T and Hc of 18.8 ± 1.8 A·m-1. This indicated that the FeSiBCCr BMGs prepared in this study exhibited broad application prospects in efficient electromagnetic conversion and advanced electronic devices.

Flat-top plasma operational space of the STEP power plant

Abstract STEP is a spherical tokamak prototype power plant that is being designed to demonstrate net electric power. The design phase involves the exploitation of plasma models to optimise fusion performance subject to satisfying various physics and engineering constraints. A modelling workflow, including integrated core plasma modelling, MHD stability analysis, SOL and pedestal modelling, coil set and free boundary equilibrium solvers, and whole plant design, has been developed to specify the design parameters and to develop viable scenarios. The integrated core plasma model JETTO is used to develop individual flat-top operating points that satisfy imposed criteria for fusion power performance within operational constraints. Key plasma parameters such as normalised beta, Greenwald density fraction, auxiliary power and radiated power have been scanned to scope the operational space and to derive a collection of candidate non-inductive flat-top points. The assumed auxiliary heating and current drive is either from electron cyclotron systems only or a combination of electron cyclotron and electron Bernstein waves. At present stages of transport modelling, there is a large uncertainty in overall confinement for relevant parameter regimes. For each of the two auxiliary heating and current drive systems scenarios, two candidate flat-top points have been developed based on different confinement assumptions, totalling to four operating points. A lower confinement assumption generally suggests operating points in high-density, high auxiliary power regimes, whereas higher confinement would allow access to a broader parameter regime in density and power while maintaining target fusion power performance.

Impact of dark energy on the structure of neutron stars: The vacuum case

The potential role of a cosmic vacuum dark component in the properties of neutron stars is investigated. It is assumed that the static, spherically symmetric distribution of matter within neutron stars is supported by two distinct components: ordinary matter and a vacuum fluid. For normal matter we use a set of state-of-the-art nuclear matter equations of state, each grounded in nuclear physics experiments. The vacuum energy component is inhomogeneously distributed within the star and obeys the standard equation of state (pv=−εv). This is characterized by an energy density fraction y=εm/(εm+εv), which we model as either a constant or radius-dependent. Our findings reveal that the inclusion of vacuum energy significantly affects the mass-radius relationships in neutron stars, influencing both the maximum achievable masses and the qualitative form of these relationships. Some constraints from current multimessenger observational data limiting the amount of vacuum energy within neutron stars are also discussed. Published by the American Physical Society 2024

Precision and bias of carbon storage estimations in wetland and mangrove sediments.

Peaty sediments in coastal wetlands play an important role in the sequestration of atmospheric carbon dioxide and its belowground storage. Sediment cores are used to quantify organic matter (OM) density, estimated by multiplying the bulk density of a core segment by its OM fraction. This method can be imprecise, as repeated samples often differ widely. Recent studies have shown that sediment bulk density and OM fraction are not independent but tightly related by a function called the ideal-mixing model. Thus, the bulk density of the sediment can be directly estimated from its OM fraction. Statistical theory and simulations demonstrate that the high variance in the product estimation of OM density is the result of error propagation in the product of two functionally related variables with independent errors. Estimating OM density in wetland sediments using the ideal-mixing model is more precise than the traditionally used product estimate, especially in highly organic sediments.

Simultaneous access to high normalized density, current, pressure, and confinement in strongly-shaped diverted negative triangularity plasmas

Strongly-shaped diverted negative triangularity (NT) plasmas in the DIII-D tokamak demonstrate simultaneous access to high normalized density, current, pressure, and confinement. NT plasmas are shown to exist across an expansive parameter space compatible with high fusion power production, revealing surprisingly good core stability properties that compare favorably to conventional positive triangularity plasmas in DIII-D. Non-dimensionalizing the key parameters, expanded operating spaces featuring edge safety factors below 3, normalized betas above 3, Greenwald density fractions above 1, and high-confinement mode (H-mode) confinement qualities above 1 are observed, even simultaneously, and all with a robustly stable edge free from deleterious edge-localized mode instabilities. Scaling of the confinement time with engineering parameters reveals at least a linear dependence on plasma current although with significant power degradation, both in excess of expected H-mode scalings. These results increase confidence that NT plasmas are a viable approach to realize fusion power and open directions for future detailed study.

Girk3 deletion increases osteoblast maturation and bone mass accrual in adult male mice.

Osteoporosis and other metabolic bone diseases are prevalent in the aging population. While bone has the capacity to regenerate throughout life, bone formation rates decline with age and contribute to reduced bone density and strength. Identifying mechanisms and pathways that increase bone accrual in adults could prevent fractures and accelerate healing. G protein-gated inwardly rectifying K+ (GIRK) channels are key effectors of G protein-coupled receptor signaling. Girk3 was recently shown to regulate endochondral ossification. Here, we demonstrate that deletion of Girk3 increases bone mass after 18weeks of age. Male 24-week-old Girk3 -/- mice have greater trabecular bone mineral density and bone volume fraction than wildtype (WT) mice. Osteoblast activity is moderately increased in 24-week-old Girk3 -/- mice compared to WT mice. In vitro, Girk3-/- bone marrow stromal cells (BMSCs) are more proliferative than WT BMSCs. Calvarial osteoblasts and BMSCs from Girk3 -/- mice are also more osteogenic than WT cells, with altered expression of genes that regulate the wingless-related integration site (Wnt) family. Wnt inhibition via Dickkopf-1 (Dkk1) or β-catenin inhibition via XAV939 prevents enhanced mineralization, but not proliferation, in Girk3 -/- BMSCs and slows these processes in WT cells. Finally, selective ablation of Girk3 from cells expressing Cre recombinase from the 2.3kb-Col1a1 promoter, including osteoblasts and osteocytes, is sufficient to increase bone mass and bone strength in male mice at 24weeks of age. Taken together, these data demonstrate that Girk3 regulates progenitor cell proliferation, osteoblast differentiation, and bone mass accrual in adult male mice.

Microstructure evolution and impact toughness degradation of a 3.6%Si austenitic stainless steel during high-temperature exposure

Si-modified Fe–Cr–Ni austenitic stainless steel is a promising candidate structural material in lead-cooled fast reactor systems and high-temperature microstructural stability is the challenge for developing this kind of materials. In the present research, the microstructure and corresponding impact toughness evolutions of a 3.6 wt%Si austenitic stainless steel (3.6Si-ASS) aged between 510 and 650 °C up to 5000 h were investigated. It was found that the microstructure showed nearly no change within 2000 h at 510 °C. Subsequently, the G-phase (Cr3Ni2Si) began to form at grain boundaries after 3000 h. This made the matrix near grain boundaries Ni-depleted and promoted the formation of ferrite. Finally, a mixed microstructure consisting of G-phase and ferrite was formed after 5000 h. The appearance of ferrite caused a slight decrease in impact toughness. This evolution was further accelerated during aging at 550 °C, and the impact toughness showed a significant decrease when ferrite appeared. Interestingly, the G-phase and ferrite were suppressed, replaced by intergranular M6C ((Cr, Mo)3Ni2SiC) carbide and intragranular (Cr, Si, Mo)-rich χ-phase during aging at 600 and 650 °C. Herein, M6C carbides preferred to form at grain boundaries, making intergranular cracking easier and reducing the toughness. When aged at 650 °C, the higher diffusion rates of Cr, Ni, Si and Mo increase grain boundaries coverage of M6C and also the number density, diameter, and area fraction of the χ-phase.

Experimental investigation of an electronegative cylindrical capacitively coupled geometrically asymmetric plasma discharge with an axisymmetric magnetic field

In this study, we have investigated the production of negative ions by mixing electronegative oxygen gas with electropositive argon gas in a geometrically asymmetric cylindrical capacitively coupled radio frequency plasma discharge. The plasma parameters such as density (electron, positive, and negative ion), negative ion fraction, and electron temperature are investigated for fixed gas pressure and increasing axial magnetic field strength. The axisymmetric magnetic field creates an E × B drift in the azimuthal direction, leading to the confinement of high-energy electrons at the radial edge of the chamber, resulting in decreased species density and negative ion fraction in the plasma bulk. However, the electron temperature increases with the magnetic field. It is concluded that low magnetic fields are better suited for negative ion production in such devices. Furthermore, in addition to the percentage ratio of the two gases, the applied axial magnetic field also plays a vital role in controlling negative ion fraction.

17β-estradiol promotes the progression of temporomandibular joint osteoarthritis by regulating the FTO/IGF2BP1/m6A-NLRC5 axis.

Temporomandibular joint osteoarthritis (TMJOA) is a degenerative cartilage disease. 17β-estradiol (E2) aggravates the pathological process of TMJOA; however, the mechanisms of its action have not been elucidated. Thus, we investigate the influence of E2 on the cellular biological behaviors of synoviocytes and the molecular mechanisms. Primary fibroblast-like synoviocytes (FLSs) isolated from rats were treated with TNF-α to establish cell model, and phenotypes were evaluated using cell counting kit-8, EdU, Tanswell, enzyme-linked immunosorbent assay, and quantitative real-time PCR (qPCR). The underlying mechanism of E2, FTO-mediated NLRC5 m6A methylation, was assessed using microarray, methylated RNA immunoprecipitation, qPCR, and western blot. Moreover, TMJOA-like rat model was established by intra-articular injection of monosodium iodoacetate (MIA), and bone morphology and pathology were assessed using micro-CT and H&E staining. The results illustrated that E2 facilitated the proliferation, migration, invasion, and inflammation of TNF-α-treated FLSs. FTO expression was downregulated in TMJOA and was reduced by E2 in FLSs. Knockdown of FTO promoted m6A methylation of NLRC5 and enhanced NLRC5 stability by IGF2BP1 recognition. Moreover, E2 promoted TMJ pathology and condyle remodeling, and increased bone mineral density and trabecular bone volume fraction, which was rescued by NLRC5 knockdown. E2 promoted the progression of TMJOA.

Carbon dynamics in an alluvial fan in the eastern Canadian Arctic

Alluvial fans are common features of mountainous landscapes in circumpolar regions and are characterized by a suit of hillslope processes that drive sediment distribution. At present there is little known about the biogeochemistry of these systems. Thus, this study aimed to understand alluvial fan soil carbon (C) dynamics. Surface and permafrost soil was retrieved in the apex, mid-section, and foot of a fan on Bylot Island in the Canadian Arctic. Soil characteristics such as grain size distribution, ice content and major ions, electric conductivity, as well as total C and nitrogen (N) contents were determined. Moreover, soil organic carbon (SOC) pools were assessed using density fractionation in combination with acid hydrolysis. Despite the strong influence of hillslope processes on physical sediment characteristics, hillslope location had no effect on SOC and N stocks. However, fractionation analysis showed that hillslope processes facilitate the degradation of soil C prior to its burial and integration into permafrost soil, where over 90% of the SOC pool associated with the mineral-fraction is resistant to degradation. Hence, SOC pools at the foot of alluvial fans may be considered relatively stable.

Unraveling the potential of Cu addition and cluster hardening in Al-Mg-Si alloys

With the aim of further exploiting the trade-off between formability and strength in Al alloys, this study addresses the influence of Cu in Al-Mg-Si alloys that achieve simultaneously high strength and high ductility via cluster hardening. The study carefully examines the mechanical properties and strain hardening behavior of various Mg/Si ratios with and without Cu and compares the effects of pre-aging and atypical long-term low-temperature aging treatments at 100°C to conventional heat treatments. Interestingly, in all cases adding Cu improved ductility. In the extremal case cluster hardening plus the addition of Cu quadruples elongation, while keeping yield strength similar to the classical T6 state. The results of the study are discussed with a focus on the dense distribution of clusters and partial hardening phases based on atom probe tomography data. Most importantly, the cluster-hardened alloys exhibit pronounced strain-hardening properties, which we evaluate using a Kocks-Mecking approach in combination with a microstructural analysis in the pre-aging and long-term aging condition. The key finding of the study involves the role of Cu in refining clusters/precipitates, where it causes a substantial increase in number density and volume fraction. This refinement, in combination with strain-induced clustering, contributes significantly to improving the alloys’ overall mechanical performance and underlines the central role of Cu in tailoring microstructural features, especially in alloys primarily strengthened by clusters.