Rechargeable aqueous zinc-ion batteries are considered as the promising alternative for lithium-ion batteries due to their high safety, eco-friendly and low cost. However, problems, such as dendritic growth and corrosion reaction for zinc anode, hinder their further development. Here, combustion process is applied to modulate zinc electrode interface so as to solve above challenges, which disclose profound consequence for the zinc anode reversibility. Three functional layers can be constructed simultaneously:Induced stronger zinc (002) crystal plane resulting in corrosion resistance; In situ formed alloy phase also making modulation of ion flux with uniform and dense deposition; Adsorbed extra the chloride and carbon compounds acting solid electrolyte layer assessing in ion continuous transfer. As a result, Zn-X electrodes (ZXEs) exhibit lower polarization voltage and longer cycling life than pure Zn. In situ optical microscope monitors the ion nucleation behavior where no dendrites and side reactions for ZXEs can be found. Coupled with vanadium oxide cathode, the full cell exhibits better rate capability and 1000 cycles as well as good capacity retention. Consequently, this study provides a facile and unique strategy for advanced aqueous zinc batteries practical application with interfacial engineering.