Under boundary measurement (BM), this paper solves the synchronization problem via intermittent boundary proportional–derivative (PD) control of delayed reaction–diffusion neural networks (RDNNs), where the random time-varying delay (RTVD) belongs to two intervals and is considered by a probabilistic way to take the influence of uncertain factors. The intermittent boundary PD synchronization scheme, which considers the inevitable actuator limitations, is based on BM and only available at some specified boundary position. By using the inequality techniques and switching Lyapunov functional, the mean square exponential stability (MSES) of the synchronization error system (SES) containing the response and drive dynamics is ensured by some synchronization criteria, which are established via an intermittent boundary PD controller under BM and expressed as linear matrix inequalities. Lastly, the proposed intermittent boundary PD synchronization approach is verified by a numerical example.