Degree Of Surface Oxidation Research Articles

Full-color biomass carbon dots for high-level information encryption and multi-color light emitting diode applications.

Six biomass carbon dots (BCDs) with adjustable emission from 450 to 680nm under a single wavelength excitation were successfully synthesized from spinach via solvent control strategy. The obtained BCDs show blue, green, yellow, violet, pink, and red emission with high photoluminescence quantum yield (PLQY = 12.68 ~ 30.77%). Detailed characterizations disclose that the tunable-emission mechanism is caused by the synergistic effect of carbon conjugate and surface oxidation degree. Meanwhile, full-color photoluminescence BCDs/PVP powder and BCDs/PVP/PVA films were fabricated by utilizing the prepared BCDs combined with polyvinylpyrrolidone (PVP) and polyvinyl alcohol (PVA), respectively, which presented excellent high-level information encryption application. Importantly, multi-color and white light-emitting diode (LED) with Commission Internationale de L' Eclairage (CIE) of blue (0.25, 0.29); green (0.25, 0.31); yellow (0.42, 0.45); red (0.52, 0.31); and white (0.32, 0.31) were achieved by only using our prepared BCDs. This work provides a valuable strategy of preparing multi-color BCDs using readily available biomass materials and paves a way for high-level information encryption and LED applications.

In-situ heteroatoms stabilization of zero-dimensional boron nanospheres for high-energy nanofluid fuels combustion enhancement

Since boron powder has the highest volume energy density, it has long been desired for use as fuel in aerospace and other fields. However, boron has poor ignition performance and low combustion efficiency due to uneven microstructure and oxide layers of boron. Here, we report a facile strategy to prepare zero-dimensional boron nanospheres from micrometer-scale amorphous boron through ultrasound-assisted in-situ stabilization of heteroatoms for inhibition of boron oxide layer by using hexachlorocyclotriphosphazene (HCCP) and 4,4′-sulfonyldiphenol (BPS) polycondensation and carbonization. The diameter of the obtained boron nanospheres was in the range of 500–800 nm, which is the smallest reported diameter of regular boron nanoparticles. The initial reaction temperature of CPZS@B-1.0 decreased from 791.1 to 641.7 °C, and the ignition delay time of 20 wt% CPZS@B-1.0/RP-3 nanofluid fuel decreased to 393 ms. The addition of CPZS@B promoted RP-3 oxidation at both low temperatures (<200 °C) and high temperatures (>200 °C) by in-situ FTIR analysis. Notably, the prepared zero-dimensional nano-boron exhibited removal of surface oxidation and complete combustion degree (from 42.06 % to 80.36 %). This work provides a new method for the preparation of nano-boron and a solution for increasing the fuel energy density of hydrocarbon fuels.

Enhanced fretting fatigue strength of TC11 titanium alloy using laser-assisted ultrasonic surface rolling process

In this paper, ultrasonic surface rolling (USRP) and laser heating-assisted USRP (Laser-USRP) techniques are employed to enhance the fretting fatigue strength of TC11 titanium alloy. Furthermore, the surface deformation mechanism and fretting fatigue behavior are investigated. The properties of the reinforced surfaces were observed using transmission electron microscope (TEM), microhardness test, residual stress test and fretting fatigue experiments. The results showed that laser-USRP led to a remarkable enhancement in the fretting fatigue life of TC11 titanium alloy compared to traditional USRP. This was mainly due to the fact that laser heating improved the plasticity of TC11 titanium alloy, contributed to the formation of a smoother surface and increased the degree of surface oxidation, which could improve surface lubrication. Under high temperature, more slip systems were activated and more stable dislocations were formed, which resulted in larger compressive residual stress (CRS) with higher stability. The superposition of the elevated temperature field and the kinetic energy of the ultrasonic vibration produced an annealing effect in localized regions, resulting in the formation of more stable gradient nanograins. This study demonstrated the immense potential of laser-assisted plastic deformation in improving the surface properties of titanium alloys.

Graphitic nanoflakes modulate the structure and binding of human amylin.

Human amylin is an inherently disordered protein whose ability to form amyloid fibrils is linked to the onset of type II diabetes. Graphitic nanomaterials have potential in managing amyloid diseases as they can disrupt protein aggregation processes in biological settings, but optimising these materials to prevent fibrillation is challenging. Here, we employ bias-exchange molecular dynamics simulations to systematically study the structure and adsorption preferences of amylin on graphitic nanoflakes that vary in their physical dimensions and surface functionalisation. Our findings reveal that nanoflake size and surface oxidation both influence the structure and adsorption preferences of amylin. The purely hydrophobic substrate of pristine graphene (PG) nanoflakes encourages non-specific protein adsorption, leading to unrestricted lateral mobility once amylin adheres to the surface. Particularly on larger PG nanoflakes, this induces structural changes in amylin that may promote fibril formation, such as the loss of native helical content and an increase in β-sheet character. In contrast, oxidised graphene nanoflakes form hydrogen bonds between surface oxygen sites and amylin, and as such restricting protein mobility. Reduced graphene oxide (rGO) flakes, featuring lower amounts of surface oxidation, are amphiphilic and exhibit substantial regions of bare carbon which promote protein binding and reduced conformational flexibility, leading to conservation of the native structure of amylin. In comparison, graphene oxide (GO) nanoflakes, which are predominantly hydrophilic and have a high degree of surface oxidation, facilitate considerable protein structural variability, resulting in substantial contact area between the protein and GO, and subsequent protein unfolding. Our results indicate that tailoring the size, oxygen concentration and surface patterning of graphitic nanoflakes can lead to specific and robust protein binding, ultimately influencing the likelihood of fibril formation. These atomistic insights provide key design considerations for the development of graphitic nanoflakes that can modulate protein aggregation by sequestering protein monomers in the biological environment and inhibit conformational changes linked to amyloid fibril formation.

Silicon-Germanium on Insulator CMP Slurry Designed with Oxidant and Accelerator Heading an Amine Functional Group for Remarkably Enhancing Polishing Rate

High quality single crystal silicon-germanium-on-insulator (SGOI) has a potential to enable the next generationof photonic and electronic devices. However, to utilize an SGOI structure, a high SiGe-film polishing rate isnecessary (i.e., > 200 nm/min) for polishing the facet crystalline SiGe during the fabrication of SiGe on insulatorthrough epitaxial growth processes.In previous studies, amine-based chemicals as SiGe-film polishing rate accelerators have been reported, butthere were limitations in increasing the SiGe-film polishig rate by considering only the chemical reaction of SiGe-film surface. In this study, for the first time, both oxidant(i.e., H2O2) and accelerator with amine functional groups(i.e., triethanolamine) were designed, resulting in a surprising increase in the SiGe-film polishing rate of 270nm/min, as shown Fig. 1a.The SiGe chemical mechanical planarization (CMP) mechanism was clearly demonstrated by preciselyinvestigating both chemical properties(i.e., GeO2 spectra intensity via X-ray photoelectron spectroscopy) andmechanical properties(i.e., electrostatic repulsive force between colloidal silica abrasives and the SiGe-film viaelectrophoretic light scattering). The remarkable enhancement of the SiGe-film polishing rate for oxidant andtriethanolamine was the result of (i) minimizing the loss of degree of SiGe surface oxidation, as shown Fig. 2, (ii)enhancing degree of adsorption of the CMP slurry on the polished SiGe-film surface during CMP, and (iii)decreasing the electrostatic repulsive force between colloidal silica abrasives and the SiGe-film surface, as shownFig 1b. Finally, successful removal of the facets in SiGe on insulator wafers was achieved, securing excellentsurface roughness characteristics. SiGe-film polishing mechanism and the SiGe slurry characteristics will bepresented in detail. Figure 1

Spontaneous regeneration of active sites against catalyst deactivation

Catalyst deactivation is one of the long-standing challenges in heterogeneous catalysis. Here, we found that the Ni/MgAl2O4 catalyst shows an atmosphere-dependent deactivation behavior during dry reforming of methane (DRM) process, i.e., oxidation and redispersion of Ni near the inlet in an oxidizing atmosphere while coking and sintering of Ni near the outlet in a reducing atmosphere. These structural evolutions of the Ni species are revealed to be driven by the surface oxidation degree of the catalyst, such that it is reversible when the redox atmosphere changes. It inspired us to develop an alternating-feeding gas strategy that periodically changes the gas flow direction to balance the structural evolution of Ni species across catalyst bed through the spontaneous regeneration of deactivated sites, enabling a supra-stable DRM process. This study provides new insights into the catalyst deactivation for DRM process, while opens a new avenue to address catalyst deactivation in various redox-catalyzed processes.

Influence of laser-induced surface carbonization on the tribological properties of UHMWPE in a seawater environment

The influencing mechanism of laser treatment on the tribological behavior of ultrahigh molecular weight polyethylene (UHMWPE) in a seawater environment was studied. The relation between the surface chemical composition and morphology of UHMWPE under different laser processing parameters and tribological properties in seawater environment was obtained. Oxidation and amorphization occurred when UHMWPE was laser-treated at relatively low-power densities (1.92 × 105 and 3.94 × 105 W/cm2), causing the slightly increase in wear rate of UHMWPE. Carbonization occurred after relatively high-power densities laser treatment (6.01 × 105, 8.12 × 105 and 1.00 × 106 W/cm2), causing significantly increase in wear resistance and decrease in friction coefficient. The laser-induced carbonization products were mainly composed of amorphous and graphitic carbon, which served as a solid lubricant during friction, thereby significantly improving the tribological properties of UHMWPE in the seawater environment. A method of laser-induced carbonization was proposed to improve the tribological properties of polymer materials in a seawater environment. Controlling the degrees of surface oxidation and carbonization of UHMWPE effectively regulated its tribological properties in seawater environments.

Superior pore size for enhancing the competitive adsorption of VOCs under high humid conditions: An experiment and molecular simulation study

Water vapor greatly decreases the adsorption capacity of activated carbons (AC) for low-concentration volatile organic compounds (VOCs) under high humid conditions. However, the design and synthesis of AC with high adsorption selectivity for VOCs/water vapor still remains a challenge. In this paper, a hydrophobic hierarchical porous AC was synthesized by using g-C3N4 as the pore-forming agent and the roles of pore sizes on the competitive adsorption were studied by experiments and simulation calculations. The results showed that pore size of 0.59–1.50 nm had a stronger correlation with toluene dynamic adsorption capacity. The largest adsorption capacity of single toluene and water vapor occurred in the 1.0 nm and 0.7 nm slit pore, respectively. During the toluene adsorption at 70 RH%, the superior pore size was 0.7–1.30 nm, and the maximum value appeared in the 1.0 nm pore without pore condensation of water clusters. Furthermore, a quantitative relationship that the superior pore size of VOCs at 70 RH% was 0.86–1.52 S (S is the longest distance of VOCs molecule) was summarized. In addition, a lower surface oxidation degree would broaden superior pore size range. This study provides a theoretical preference for designing AC for target VOCs removal from high humid conditions.

Tracing the plasma kallikrein-kinin system-activating component in the atmospheric particulate matter with different origins

Atmospheric particulate matter (PM) perturbs hematological homeostasis by targeting the plasma kallikrein-kinin system (KKS), causing a cascade of zymogen activation events. However, the causative components involved in PM-induced hematological effects are largely unknown. Herein, the standard reference materials (SRMs) of atmospheric PM, including emissions from the diesel (2975), urban (1648a), and bituminous coal (2693), were screened for their effects on plasma KKS activation, and the effective constituent contributing to PM-induced KKS activation was further explored by fraction isolation and chemical analysis. The effects of three SRMs on KKS activation followed the order of 2975 > 1648a > 2693, wherein the fractions of 2975 isolated by acetone and water, together with the insoluble particulate residues, exerted significant perturbations in the hematological homeostasis. The soot contents in the SRMs and corresponding isolated fractions matched well with their hematological effects, and the KKS activation could be dependent on the soot surface oxidation degree. This study, for the first time, uncovered the soot content in atmospheric PM with different origins contributed to the distinct effects on plasma KKS activation. The finding would be of utmost importance for the health risk assessment on inhaled airborne fine PM, given its inevitable contact with human circulatory system.

Photodegradation of Microplastics by ZnO Nanoparticles with Resulting Cellular and Subcellular Responses.

Both zinc oxide nanoparticles (ZnO NPs) and microplastics (MPs) were extracted from one commercial sunscreen, while other ingredients were removed based on the "like dissolves like" principle. MPs were further extracted by acidic digestion of ZnO NPs using HCl and characterized as spherical particles of approximately 5 μm with layered sheets in an irregular shape on the surface. Although MPs were stable in the presence of simulated sunlight and water after 12 h of exposure, ZnO NPs promoted the photooxidation by producing hydroxyl radicals, with a 2.5-fold increase in the carbonyl index of the degree of surface oxidation. As a result of surface oxidation, spherical MPs were more soluble in water and fragmented to irregular shapes with sharp edges. We then compared the cytotoxicity of primary MPs and secondary MPs (25-200 mg/L) to the HaCaT cell line based on viability loss and subcellular damages. The cellular uptake of MPs transformed by ZnO NPs was enhanced by over 20%, and MPs caused higher cytotoxicity compared with the pristine ones, as evidenced by a 46% lower cell viability, 220% higher lysosomal accumulation, 69% higher cellular reactive oxygen species, 27% more mitochondrial loss, and 72% higher mitochondrial superoxide at 200 mg/L. Our study for the first time explored the activation of MPs by ZnO NPs derived from commercial products and revealed the high cytotoxicity caused by secondary MPs, providing new evidence on the effects of secondary MPs on human health.

Impact of water ingress on deuterium release, oxidation, and dust generation in beryllium plasma-facing components

Beryllium samples from the JET ITER-like wall limiter tiles with either co-deposits or surface cracks caused by melt damage, were immersed into boiling water for 4 h 15 min to simulate and assess the impact of coolant water ingress into a tokamak on the state of Be components. Microscopy of the water-treated surfaces and the lack of residue in the water revealed that no thermomechanical damage (cracking or exfoliation) occurred to the samples during the exposure. Ion beam analysis showed no measurable release of deuterium from the samples. Combined ion beam analysis and Raman spectroscopy indicated only some degree of surface oxidation, but no thick oxide films were formed.

Orbital hybridization manipulated by doped Cu+ in NbC for boosting hydrogen evolution

Surface adsorption behavior and electron transfer determine the catalytic activity in hydrogen evolution reaction (HER). However, the inevitable surface oxidation of NbC hinders electron transfer and hydrogen conversion. The surface adsorption behavior and electron transfer of NbC are optimized by doping Cu+ as well as modifying the orbital hybridizations. Benefiting from the introduced electron interaction of Cu+, the lower p-d hybridization between Nb and O reduces the Nb-O bond and affords the Cu-NbC thinner surface oxidation layer. The reduced surface oxidation degree favors electron transfer. Further, the electron orbital hybridization modulates the electron states and optimizes the hydrogen adsorption behavior of Cu-NbC for efficient hydrogen conversion. As the electrochemical results, the obtained Cu-NbC demands 271 mV to drive 10 mA cm−2, which is 50 times higher than that of NbC (only 0.2 mA cm−2 at the same overpotential). Hence, we believe the orbital hybridization manipulation strategy renders a valuable solution for designing efficient HER catalysts.

Graphene oxide-mediated copper reduction allows comparative evaluation of oxygenated reactive residues exposure on the materials surface in a simple one-step method

Graphene Oxide (GO) is the oxidized form of graphene rich in surface groups comprising carbonyl, carboxyl, hydroxyl, and epoxy residues. The solubility in water makes GO an ideal material in the biomedical field though the plethora of synthesis methods available can modify the balance of oxygen groups and, consequently, the effects on eukaryotic and prokaryotic cells. For this reason, GO materials are always characterized with spectroscopic methods such as X-ray photoelectron and Fourier-transform Infrared spectroscopy. However, these techniques have some limitations, being disruptive and not clearly indicating oxygen functionalities available to react with polymers or biological media.In this work, we exploit GO reactivity with copper ions to develop a colorimetric method for the facile evaluation of surface oxidation degree and accessibility in polymeric samples. In the presence of GO, Cu2+ is reduced to Cu1+ and can react with bicinchoninic acid and induce light absorption at 562 nm. We observed that this reaction is dependent both on concentration and oxidation degree, and can be used to estimate GO exposure in thick composite samples. This technique will be fundamental in the future for scaffold characterization in tissue engineering and all the surface science studies analyzing GO-related materials' interactions with biological entities.

Influence of bridge structure manipulation on the electrochemical performance of π-conjugated molecule-bridged silicon quantum dot nanocomposite anode materials for lithium-ion batteries.

To assess the influence of bridge structure manipulation on the electrochemical performance of π-conjugated molecule-bridged silicon quantum dot (Si QD) nanocomposite (SQNC) anode materials, we prepared two types of SQNCs by Sonogashira cross-coupling and hydrosilylation reactions; one is SQNC-VPEPV, wherein the Si QDs are covalently bonded by vinylene (V)-phenylene (P)-ethynylene (E)-phenylene-vinylene, and the other is SQNC-VPV. By comparing the electrochemical performances of the SQNCs, including that of the previously reported SQNC-VPEPEPV, we found that the SQNC with the highest specific capacity varied depending on the applied current density; SQNC-VPEPV (1420 mA h g-1) > SQNC-VPV (779 mA h g-1) > SQNC-VPEPEPV(465 mA h g-1) at 800 mA g-1, and SQNC-VPV (529 mA h g-1) > SQNC-VPEPEPV (53 mA h g-1) > SQNC-VPEPV (7 mA h g-1) at 2000 mA g-1. To understand this result, we performed EIS and GITT measurements of the SQNCs. In the course of investigating the lithium-ion diffusion coefficient, charge/discharge kinetics, and electrochemical performance of the SQNC anode materials, we found that electronic conductivity is a key parameter for determining the electrochemical performance of the SQNC. Two probable causes for the unique behavior of the electrochemical performances of the SQNCs are anticipated: (i) the SQNC with predominant electronic conductivity is varied depending on the current density applied during the cell operation, and (ii) the degree of surface oxidation of the Si QDs in the SQNCs varies depending on the structures of the surface organic molecules of the Si QDs and the bridging molecules of the SQNCs. Therefore, differences in the amount of oxides (SiO2)/suboxides (SiOx) on the surface of Si QDs lead to significant differences in conductivity and electrochemical performance between the SQNCs.

Surface oxidation protection strategy of CoS2 by V2O5 for electrocatalytic hydrogen evolution reaction.

Transition metal sulfides (TMSs) are promising electrocatalysts for hydrogen evolution reaction (HER), while TMSs usually suffer from inevitable surface oxidation in air, and the impact of the surface oxidation on their HER catalytic activity remains unclear. Herein, we demonstrate an effective strategy for reducing the surface oxidation degree of easily oxidized CoS2 by introducing glued vanadium pentoxide (V2O5) nanoclusters, taking advantage of the preferential adsorption and strong interaction between high-valence V and O2. Combining oxidation protection and elaborate oxidation control experiments reveal that reduced surface oxidation degree of CoS2 is conducive to affording promising HER catalytic performance, as the oxidized surface of CoS2 can hinder the dissociation of water and thus is harmful to the HER process. Direct evidence is provided that surface oxidation should be carefully considered for TMS-based HER catalysts. The present work not only develops a new strategy for protecting CoS2 from surface oxidation, but also provides deep insight into the impact of surface oxidation on the HER performance of transition metal compounds.

Interface engineering of Co3S4@Co3O4/N, S-doped carbon core@shell nanostructures serve as an excellent bifunctional ORR/OER electrocatalyst for rechargeable Zn-air battery

Herein, a class of Co3S4@Co3O4/NSC (N, S-doped carbon) composites with core@shell nanostructures were facilely fabricated through a two-step pyrolysis-oxidation strategy using methyl orange and cobalt chloride as raw materials. By constructing heterointerfaces between different components and controlling the surface oxidation degree, the interfacial and synergistic effects endowed the composited catalysts tailorable and excellent bifunctional electrocatalytic activities on oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). A rechargeable Zn-air battery (ZAB) with the optimized catalyst Co3S4@Co3O4/NSC-260-8 as air cathode has shown excellent performance with a high specific capacity of 885 mAh·gZn−1 and energy density of 948 Wh·kgZn−1 (at 20 mA·cm−2), which is higher than 836 mAh·gZn−1 and 929 Wh·kgZn−1 of the one employing Pt/C (20%) + RuO2 as air cathode under the same conditions. The catalyst also showed robust stability and no obvious decrease in the voltage was observed after 200 h charging and discharging cycles.This work presents a feasible concept to design and construct heterostructural and multifunctional composite catalysts with heterointerfaces.

Oxidative Dissolution of Low-Grade Ni-Cu Ore and Impact on Flotation of Pentlandite

This paper investigated the effect of mineral surface oxidation on the floatability of Kevitsa low-grade Ni-Cu ore. Physicochemical measurements, ethylene diamine tetra acetic acid (EDTA) extraction, and oxygen uptake experiments were carried out with slurry and recycled process water samples obtained from the Kevitsa Cu-Ni sequential concentrator plant. The pH of recycled process water, copper flotation feed, and nickel flotation feed dropped by 0.7, 0.4, and 0.7 points, respectively, from May to July. The oxygen demand increased from recycled process water to the copper flotation feed, then dropped for the nickel flotation feed. The nickel flotation feed Redox potential (ORP) was lowest for July, while EDTA extractable metals increased from May to July. There was a 20% drop in nickel recoveries from May to July. Based on ORP measurements of the nickel flotation feed, good nickel flotation takes place in a moderately oxidizing (75–170 mV) and alkaline (9.2–9.7 pH) environment. Therefore, the ORP/pH of the nickel flotation feed is important to the nickel flotation. The results showed that at the Kevitsa plant, the grinding process is an electrochemically active environment, which, together with the incoming recycled process water quality, defines the degree of mineral surface oxidation for flotation. The increasing corrosiveness of the recycled process water increased mineral surface oxidation and depressed pentlandite flotation. Laboratory flotation experiments confirmed the observed poor plant flotation response when the corrosiveness of recycled process water increased. Total dissolved solids (TDS) was proven to be a reliable online parameter for the corrosiveness of the recycled process water and was inversely proportional to the pentlandite recovery. The findings of this study may help the plant develop ways to enable a timely response to changes in recycled process water quality to prevent harmful impacts on pentlandite flotation.

New insights into the effects of particle size on the surface modification by low-temperature plasma from a perspective of surface oxidation degree

• Floatability was determined by surface oxidation rate and critical oxidation degree. • Fine particles exhibited a higher tolerance to surface modification. • Low SBX adsorption density on the coarse particle surface resulted in a poor recovery. • Low oxidation rate of pyrite overcame its low critical oxidation degree to maintain high hydrophobicity. Particle size is an important parameter to determine the surface modification degree of sulfide minerals by plasma as well as the floatability of minerals. However, little studies have been reported to quantitatively relate surface oxidation and sample particle size to flotation performance. In this study, X-ray photoelectron spectroscopy (XPS) was used to characterize the surface species of arsenopyrite and pyrite at different plasma modification times. The critical oxidation degree was quantified as the proportion of hydrophilic oxidation species to hydrophobic species and correlated with flotation recovery. The results showed that the flotation recoveries of minerals with different particle sizes were determined by surface oxidation rate and critical oxidation degree. Fine particles were more likely to become hydrophilic under low-temperature plasma modification and yet the critical oxidation degree was also higher. The coarse particles being plasma modification presented a poor flotation recovery due to its low adsorption density of collector, although its oxidation degree was lower than the fine size fraction. The critical oxidation degree of pyrite was expected to be less than arsenopyrite, but its flotation recovery was higher under the same plasma medication time because of its slower oxidation rate.

Synergistic effect of surface sinusoidal textures and oxide layer on tribological properties of 40Cr alloy steel

Researchers have been concentrating on enhancing the surface tribological properties and minimizing wear on mechanical components during the oil starvation stage. In this work, a nanosecond laser was used to prepare sinusoidal textures of different amplitudes on the surface of 40Cr alloy steel, and then the obtained surfaces were pre-oxidized at 100 °C, 300 °C, and 500 °C, respectively. The results demonstrated that excessively large or small amplitude values would reduce the wear debris trapping ability of the textures, which ultimately affected the formation of the tribofilm. In addition, the numerical simulation results reveal that the texture pressure difference is positively correlated with the texture amplitude, but excessively high or low amplitude leads to a significant micro-vortex effect within the texture. The tribological properties of the textured surfaces could be further enhanced by the pre-oxidation treatment. The experiment results indicated that the pre-oxidation treatment increased the degree of surface oxidation and promoted the formation of tribofilm. This work will pave the way to improve surface tribological properties by integrating sinusoidal textures and self-generated tribofilm.

A closed-loop recycling process for carbon fiber-reinforced polymer waste using thermally activated oxide semiconductors: Carbon fiber recycling, characterization and life cycle assessment

The objective of this study is to investigate the properties of recycled carbon fiber (rCF) and its environmental impact, with a specific focus on the energy consumption of the recycling process based on the use of thermally activated oxide semiconductors (TASC). The mechanical and surface properties of rCF obtained under the optimal process parameters were characterized. The life cycle assessment method was used to evaluate the environmental impact of a closed-loop recycling process for carbon fiber-reinforced polymer (CFRP) waste using TASC. The results indicated that the decomposition rate of resin was 95.5 %, and no carbonaceous solid was generated. The gaseous produced of the recycling process were mainly CO2 and H2O, and no liquid products were produced. The surface oxidation degree of rCF was relatively slight. COOH was generated on the surface of rCF, which was conducive to improving the interfacial adhesion viscosity with resin. The monofilament tensile strength of rCF was maintained above 97 %. Compared with landfill and incineration, CFRP waste recycling using TASC can make global warming potential, acidification potential and eutrophication potential reduced by 28 %, 32 %, and 25 %, respectively. Ozone layer depletion potential, human toxicity potential and terrestrial ecotoxicity potential in disposing CFRP waste using TASC were 30 %, 21 % and 41 % of that using pyrolysis, respectively. The energy consumption in carbon fiber recycling by TASC was only 23 % of that in virgin carbon fiber manufacturing. TASC is found to be a promising potential strategy for managing CFRP waste.