Degree Of Weathering Research Articles

Provenance of a Late Permian retroarc foreland basin along the eastern Gondwanan margin: northern Sydney Basin, eastern Australia

Abstract The Upper Permian sedimentary successions in the northern Sydney Basin have been the subject of several stratigraphic, sedimentological and coal petrographic studies, and recently, extensive U-Pb zircon dating has been carried out on tuffs in the Newcastle Coal Measures. However, detailed petrographic and geochemical studies of these successions are lacking. These are important because a major change in tectonic setting occurred prior to the Late Permian because of the Hunter-Bowen Orogeny that caused the uplift of the Carboniferous and Devonian successions in the Tamworth Group and Tablelands Complex adjacent to the Sydney Basin. This should be reflected in the detrital makeup of the Upper Permian rocks. This study provides data that confirms major changes did take place at this time. Petrographic analysis indicates that the source area is composed of sedimentary, felsic volcanic and plutonic and low-grade metamorphic rocks. Conglomerate clast composition analysis confirms these results, revealing a source region that is composed of felsic volcanics, cherts, mudstones and sandstones. Geochemical analysis suggests that the sediments are geochemically mature and have undergone a moderate degree of weathering. The provenance data presented in this paper indicate that the southern New England Orogen is the principal source of detritus in the basin. Discrimination diagrams confirm that the source rocks derive from an arc-related, contractional setting and agree with the provenance analyses that indicate sediment deposition in a retroarc foreland basin. This study offers new insights on the provenance and tectonic setting of the Northern Sydney Basin, eastern Australia.

Permeability Tests and Numerical Simulation of Argillaceous Dolomite in the Jurong Pumped-Storage Power Station, China

Due to its poor hydro-physical properties and other characteristics, argillaceous dolomite is susceptible to seepage failure under high water pressure, affecting the seepage stability of a rock mass. To ensure the safety of the project, when the argillaceous dolomite is present, it is necessary to study the conditions pertaining to its seepage failure. Taking the argillaceous dolomite of Jurong Pumped Storage Power Station as the research object, the spatial distribution, occurrence, scale, degree of weathering, and mechanical and hydrogeological characteristics of the argillaceous dolomite were studied. Through on-site water pressure tests and laboratory variable head tests, the permeability characteristics of argillaceous dolomite were analyzed, and the hydraulic conductivity of the argillaceous dolomite in the upper reservoir and underground powerhouse areas was quantified. The argillaceous dolomite specimens were collected, and seepage failure tests were conducted to determine the critical water pressure for its seepage failure. Based on the results of the laboratory tests, a numerical model of groundwater flow was established. By changing the water level of the upper reservoir and the measures of the anti-seepage and drainage, the seepage stability of the argillaceous dolomite was discussed. The actual water pressure of argillaceous dolomite in the underground powerhouse area was identified during the operation of the Jurong pumped-storage power station. The calculations show that when fully enclosed anti-seepage and drainage measures are taken for the underground powerhouse, the maximum head of water is 98 m, which is lower than the critical water pressure of seepage failure for the argillaceous dolomite. Therefore, no seepage failure will occur. The results provide a scientific basis for the anti-seepage and drainage design of the underground powerhouse area.

Petrology and geochemistry of sandstone from Lower Cretaceous Kikhla Formation, NW Libya: Implications for provenance and depositional setting.

This study aims to determine and investigate the provenance of the source rocks and the depositional setting of the Kikhla Formation, northwestern Libya. It is mainly composed of mature quartzitic sandstone alternating with conglomerate and clay. The study proved that the sandstone is yellow-white in color and commonly carries quartz granular and small fragments of silicified wood. The environmental deposition is under differing fluvial conditions and by a large braided river. Texturally, the Kikhla sandstone is poorly cemented, coarse to very coarse grained and strongly unimodal and is classified as litharenite and subarkose by the modal composition, which is supported by geochemical studies. According to petrography and geochemistry, the Kikhla sandstone was deposited in a passive continental margin basin, mainly from granitic sources. On the basis of major elements ratios, and petrographic interpretation, the source rocks are most likely recognized as Proterozoic granites that were exposed via rifting. The CIA values (73.28-93.97) indicate a high degree of chemical weathering, which could be attributed to the arid climate conditions in the source area and mainly controlled by the source-rock provenance, hydraulic sorting during transport and deposition, diagenesis and depositional environment. According to chemical investigations, sandstone exhibits significant concentrations of SiO2, Na2O> K2O, and Fe2O3, which is compatible with the modal data.

Multiproxy provenance analyses in the Devonian Villavicencio Formation of the Mendoza Precordillera, Argentina: correlation and geotectonic implications for the SW Gondwana margin

Abstract This work focuses on the sedimentary provenance of the Villavicencio Formation of the Mendoza Precordillera and integrates the information obtained with previous work on other coeval units of the Precordillera Central of San Juan province (Gualilán Group: Talacasto and Punta Negra formations) in western Argentina. Multiproxy provenance analyses are carried out from different applied methodologies (petrography, geochemistry, morphological, and cathodoluminescence studies of detrital zircon grains, and analysis of U-Pb and Lu-Hf isotopes). The Villavicencio Formation is mostly composed of pelites and very fine-grained psammites. The major components are quartz, both monocrystalline and polycrystalline, and metamorphic lithics that associate this unit with a recycled orogen. Regarding geochemistry, the Chemical Index of Alteration (CIA) values are similar to the Post-Archean Australian Shales (PAAS), indicating a null to incipient degree of weathering. The ratios between different trace elements and rare earth elements (REEs) suggest the felsic composition of the source area. Th/U ratios differ, but a secondary uranium enrichment is inferred. The morphological analysis of the zircon grains reveals their mainly plutonic origin. The integration of U-Pb data with Lu-Hf data shows a juvenile-mantle origin in which the populations are dominantly Mesoproterozoic and ɛHf of positive values (up to 12), indicating poor differentiation. The Villavicencio Formation would be the product of deltaic deposits in which its components are dominantly from the Western Pampean Sierras associated with the Grenville orogen, assuming exhumation and erosion of the Mesoproterozoic basement. The data support the hypothesis of equivalence and correlation with the Punta Negra Formation in the Devonian depocenters of the south-central region of the San Juan Precordillera.

Modern sedimentation on the eastern continental shelf of India: Assessing the provenance and sediment dispersal pattern

Sediments deposited on the eastern continental shelf of India are studied for texture, mineralogy and their major, trace, and rare earth elemental composition in lithogenic fraction. The objective of this study was to identify the sources, and evaluate the factors affecting the erosion and weathering in the catchment area and dispersal and deposition of sediments over the shelf region. Here, we present an extensive dataset covering the entire eastern continental shelf of India from the Ganges-Brahmaputra (G-B) basin in the north including the shelf off major peninsular Indian river basins of Mahanadi, Godavari, and Krishna up to the Kaveri basin in the southern tip.Textural and geochemical studies have shown that the lithology of the source rocks plays an important role in governing the chemistry and mineralogy of the sediments. The results show that the G-B shelf sediments are primarily derived from the Higher Himalaya Crystalline sequence (HHCS) and the Tethyan sedimentary series (TSS) exposed along the peaks and drainage divide of the Himalayas. Mahanadi shelf sediments are mainly derived from the felsic rocks belonging to Precambrian metamorphic formations of the Eastern Ghats, limestones, sandstones, and shales of the Gondwanas and recent deltaic alluvium deposits, whereas the Krishna-Godavari (K-G) sediments find a part of their source in the Deccan Basalts. The shelf sediments off River Kaveri are derived from a mixture of peninsular granitic gneisses, tonalite-trondjhemite gneisses, and charnockites. The sediment geochemistry has also allowed us in assessing the weathering patterns in the source areas. The sediments have undergone a moderate degree of weathering. Weathering intensities were found to have varied with the source area lithology.The least square regression of the geochemical data allowed us to estimate the relative contribution of each of these sources and their geographic extent. Unlike the massive offshore deposition and formation of a major Fan system (the Bengal fan), the fluvial sediment dispersal of the mighty Himalayan Rivers on the continental shelf is significant only at the G-B mouth and their contribution reduces to <50% at about 18oN. The sediment dispersal from the Godavari River is seen to extend on either side of the mouth of the river which is attributed to the reversing East India Coastal Current (EICC), which plays an important role, in the sediment transport along the central and south-central part of the east coast of India. The influence of the Mahanadi, Krishna, and Kaveri River sediments is however confined to a small area near their mouths and has a limited geographic extent of influence in the shelf region.

Radiometric and magnetic susceptibility characterization of soil profiles: Geophysical data and their relationship with Antarctic periglacial processes, pedogenesis, and lithology

Maritime Antarctica is still pedologically unexplored by proximal geophysical sensors. In-depth soil geophysical characterizations in depth can provide comprehensive information regarding how weathering, pedogenesis, and periglacial processes operate in periglacial environments, with advantages like non-invasive methodology, fast and precise data acquisition, practical equipment operation, and cost-effectiveness. This research aimed to carry out the first proximal gamma-spectrometric and magnetic geophysical characterization of soil profiles in maritime Antarctica and to relate the geophysical variables analyzed with periglacial processes, weathering, pedogenesis, geology, and landscape dynamics. The study was carried out in the Keller Peninsula (King George Island, Maritime Antarctica) with the pedological characterization of soil profiles, using two proximal geophysical sensors (gamma spectrometer and susceptibility meter) that quantify, respectively, soil radionuclides uranium, thorium and potassium as well as soil magnetic susceptibility. For that, twenty soil profiles were described and characterized, and soil samples were collected for physico-chemical analysis. In addition, readings were carried out with the two geophysical sensors in each soil profile, through soil horizons up to the lithic contact and/or permafrost top. We performed exploratory statistical analyses in R software as follows: visualizing the geophysical variables in soil depth for each profile and soil class, obtaining descriptive statistics among soil classes, analyzing geophysical variables by geology and soil classes, performing Spearman correlation between geophysical variables and soil physico-chemical attributes, and applying principal component analysis to pedological classes, geophysical variables, and soil physico-chemical attributes. The results showed that radionuclide contents increased with soil profile depth in all profiles and soil classes analyzed, except for Cryosols where permafrost is present, and cryoturbation was more pronounced. The potassium content was high in all soil profiles, evidencing the low degree of chemical weathering and leaching. The soil magnetic susceptibility values tended to decrease in depth, mainly where permafrost was present. The gravel content contributed more to the levels of radionuclide content. The clay content in some soil classes present contributed secondarily to uranium and thorium contents. Soil profiles located on marine terraces were influenced by periglacial reworking and deposition of different materials, showing increases in magnetic susceptibility values with soil depth by the absolute accumulation of ferrimagnetic minerals. Principal component analyses efficiently separated Regosols from other soil classes by soil κ related to lithology, whereas Cambisols and other soil classes were separated by radionuclide contents related to incipient pedogenesis. These findings may give new insights into understand this inhospitable continent.

Variations in soil nutrient availabilities and foliar nutrient concentrations of trees between temperate monsoon karst and non‐karst forest ecosystems on Mount Ibuki in Japan

AbstractPlants growing on karst soils, which are characterized by high pH (&gt;7.5–8.0) and low phosphorus availability, often exhibit phosphorus deficiency. However, little is known about the soil nutrient availabilities and foliar nutrient concentrations of trees in karst ecosystems with lower soil pH (&lt;7.0). In this study, we analyzed soil properties and nutrient concentrations of leaf litter from two secondary forests in the Asian monsoon temperate region of Japan, one on karst (limestone) soil and the other on non‐karst (sandstone) soil. We also compared the live leaf nutrient concentrations of four dominant tree species (Carpinus tschonoskii, Cornus macrophylla, Neolitsea sericea, and Quercus variabilis) found in both sites. The karst soil had a higher pH (6.5) than the non‐karst soil (5.6), as well as higher phosphorus concentrations and calcium availability, but lower potassium availability. The phosphorus concentrations measured using Truog ([NH4]2SO4) and Olsen (NaHCO3) extraction methods were both higher in the karst soil. The availabilities of ammonium and nitrate in the soil did not differ significantly between the sites. The concentrations of calcium, potassium, and phosphorus in the live leaves and leaf litter reflected their availability in the soil, and the litter nitrogen concentration was higher in the karst forest. Overall, this karst soil with a relatively low pH (6.5) was rich in phosphorus but poor in potassium. Karst soil may provide a large quantity of phosphorus for trees at low pH. Future research should investigate the change in phosphorus availability of karst soils at different degrees of weathering.

Isotope diffusion and re-equilibration of copper and evaporation of mercury during weathering of tetrahedrite in an oxidation zone

To understand the mobility of heavy metals during oxidative weathering of sulfides, we investigated weathering processes of tetrahedrite [(Cu,Fe,Zn,Hg)12(Sb,As)4S13] in an oxidation zone with abundant siderite (FeCO3) and baryte (BaSO4) at Rudňany (Slovakia). The focus of this work lied in the isotopic (δ65Cu, δ202Hg, δ34S) variations of the minerals during weathering and the interpretation of such changes. In the studied oxidation zone, Hg-rich tetrahedrite converts in situ to pockets of powdery cinnabar (HgS) and an X-ray amorphous mixture rich in Sb, Fe, and Cu that slowly re-crystallizes to Cu-rich tripuhyite (FeSbO4). Copper is mobile and precipitates as malachite [Cu2(OH)2(CO3)], azurite [Cu3(OH)2(CO3)2], or less abundant clinoclase [Cu3(AsO4)(OH)3]. The isotopic composition (δ65Cu) of tetrahedrite correlates well with the degree of weathering and varies between 0.0 ‰ and −4.0 ‰. This correlation is caused by isotopic changes during dissolution and subsequent rapid equilibration of δ65Cu values in the tetrahedrite relics. Simple diffusion models showed that equilibration of Cu isotopic values in the tetrahedrite relics proceeds rapidly, on the order of hundreds or thousands of years. Abundant secondary iron oxides draw light Cu isotopes from the aqueous solutions and shift the isotopic composition of malachite and azurite to higher δ65Cu values as the distance to the primary tetrahedrite increases. Clinoclase and tripuhyite have lower δ65Cu values and are spatially restricted near to the weathering tetrahedrite. The Hg and S isotopic composition of tetrahedrite is δ202Hg = −1.27 ‰, δ34S = −1.89 ‰, that of the powdery secondary cinnabar is δ202Hg = +0.07 ‰, δ34S = −5.50 ‰. The Hg isotopic difference can be explained by partial reduction of Hg(II) to Hg(0) by siderite and the following evaporation of Hg(0). The S isotopic changes indicate no involvement of biotic reactions in the oxidation zone, probably because of its hostility owing to high concentrations of toxic elements. This work shows that the Cu isotopic composition of the primary sulfides minerals changes during weathering through self-diffusion of Cu in those minerals. This finding is important for the use of Cu isotopes as tracers of geochemical cycling of metals in the environment. Another important finding is the Hg in the oxidation zones evaporates and contributes to the global cycling of this element through atmospheric emission.

Geochemical enrichment, speciation and mobilization of arsenic and antimony in black shales (southern China): Evidence from sequential fractionation and XANES spectroscopy

The high geogenic levels of trace metal(loid)s preserved within black shale can be released during natural weathering, causing global concern. Currently, the accumulation, speciation and potential mobilization of two highly toxic metal(loid)s, arsenic (As) and antimony (Sb), from black shale to soils remain unresolved, which hinders the evaluation of their potential risk to surrounding environments. Here, we demonstrate the geochemical enrichment, species transformation, and leaching behavior of As and Sb by applying weathering-induced alteration, sequential extraction and synchrotron-based X-ray absorption near edge spectroscopy (XANES) in the analysis of a range of black shale and weathered samples from two profiles collected from typical Cambrian sedimentary strata of the Pearl River Delta, southern China. The results showed significant accumulation of trace metal(loid)s, including As (43.8–458.0 mg/kg), Sb (7.2–34.5 mg/kg), Cu (8.8–451.0 mg/kg) and Ni (22.2–108.0 mg/kg), in the black shale and weathered products, and high enrichment factors for As (22.0–266.8) and Sb (1.2–6.4) were observed, consistent with the very high degrees of weathering (chemical index of alteration: 83–91). Arsenic in the shale was dominated by arsenate (46–85%), as identified using XANES, and this was resulted from extensive weathering, which facilitated the oxidation of arsenite and arsenopyrite species. Accordingly, significant decreases in sulfide-associated As and Sb were observed in highly weathered products. As a result, As and Sb were primarily in the immobilizable fractions associated with amorphous and well-crystallized Fe/Mn oxides, largely due to the increased formation of secondary Fe (oxyhydr)oxides, including goethite-like minerals, which mainly derived from the oxidative weathering of chlorite-like minerals. Nevertheless, high concentrations of As (<64 μg/L), Sb (14–70 μg/L), and Ni (3–92 μg/L) still leached from black shale samples exposed to synthetic acid rain in the 18-h batch leaching experiment. Our combined characterization results indicated that a small percentage of the high contents of geogenic As and Sb could potentially be released. However, soluble trace metal(loid)s in shale leachate could still endanger surrounding ecosystems, and continual monitoring during long-term natural weathering processes is merited for global black shale regions.

Stones that stand the test of time: exploring the durability and weathering of metamorphic Rocks of Sri Lanka

Weathering and durability are the key properties of the rock to evaluate the suitability and end-use for different kinds of applications such as building and construction material and engineering structures. Weathering is simply known as the alteration or breaking down of rocks due to air, water, etc. whereas durability of rock can be defined as the ability to resist the weathering to maintain the characteristics of strength under various environmental conditions. To evaluate the strength of rock, the degree of weathering and durability can be used as main indicators[1] as the measure of strength depends on the external force resistance.

Chemical weathering detection in the periglacial landscapes of Maritime Antarctica: New approach using geophysical sensors, topographic variables and machine learning algorithms

The chemical weathering intensity in Antarctica is underestimated. As the chemical weathering intensity increases, hydrological, geochemical and geophysical changes occur in the different environmental spheres and at their interfaces through reactions and energy flows. Thus, once chemical weathering rates are understood and estimated, they can be used to predict and assess changes and trends in different environmental spheres. Few studies on the chemical weathering intensity have been performed in Antarctica. We used radiometric and magnetic properties associated with terrain attributes and the chemical degree of alteration of the igneous rock to model the chemical weathering intensity in Maritime Antarctica by using machine learning. Then, we related the chemical weathering intensity and geophysical variables with periglacial processes. To do this, gamma-spectrometric and magnetic readings were carried out using proximal-field sensors at 91 points located on different lithologies in a representative area of Maritime Antarctica. A qualitative analysis of chemical alteration for the different lithologies was carried out based on field observations and rock properties, and the levels of the chemical weathering degree were established. The geophysical data associated with terrain attributes were used as input data in the modeling of the weathering intensity. Then, the levels of the rock weathering degree were used as the “y” variable in the models. The results indicated that the C5.0 algorithm had the best performance in predicting the weathering intensity, and the most important variables were eTh, 40K, 40K/eTh, 40K/eU, the magnetic susceptibility and terrain attributes. The contents of radionuclides and ferrimagnetic minerals in different lithologies, concomitantly with the intensity at which chemical weathering occurs, determine the contents of these elements. However, the stability and distribution of these elements in a cold periglacial environment are controlled by periglacial processes. The chemical weathering intensity prediction model using gamma-spectrometric and magnetic data matched the in situ estimate of the chemical degree of alteration of the rock. The pyritized andesites showed the highest intensities of weathering, followed by tuffites, diorites, andesitic basalts and basaltic andesites, and the lowest weathering intensity was shown by undifferentiated marine sediments. This work highlighted the suitability of using machine learning techniques and proximal-field sensor data to study the chemical weathering process on different rocks in these important and inhospitable areas of the cryosphere system.

Mammal taphonomy from a singular Late Pleistocene debris‐flow tank deposit in northeastern Brazil

ABSTRACTAn integrated taphonomic analysis was applied to a tank deposit from the Zabelê Palaeontological Site (ZPS) in northeast Brazil. The unique sedimentological evidence documents the origin of the mammal assemblage via debris flow. Optically stimulated luminescence (OSL) dates put the ZPS in the later Marine Isotope Stage (MIS) 3, which was a time when it was colder and there were fewer trees. The study revealed that the Zabelê's periphery accumulation was the result of the short transport of specimens and their entrainment by debris flow. This hydraulic transport caused the preferential orientation of the bioclasts (north–southwest). Comparisons were made with other Pleistocene tank deposits, suggesting the occurrence of common megamammal taxa. Temporal mixing was evidenced by the long time interval recorded by OSL ages and the co‐occurrence of distinct degrees of fragmentation, weathering, and fossil diagenesis. Permineralization and staining of Fe3+ and Mn colour patterns were identified as fossilization processes with preservation of the original bone hydroxyapatite without substitution. The comparison with other tank deposits revealed common signatures (disarticulated and fragmented with moderate abrasion) and signs of reworking. Finally, the savanna‐adapted herbivore megamammals from ZPS, such as Eremotherium, Notiomastodon, Toxodon, and Glyptotherium, are congruent with the forest decline from MIS 3 to the Last Glacial Maximum.

Geochemistry of the Lancang River (Upper Mekong River) overbank sediments: Implications for provenance, weathering and sedimentary characteristics

Large rivers originating from the Tibetan Plateau play a crucial role in sediment production and transportation and thus influence the ocean composition and global climate. This study focuses on the geochemical characteristics, including major, trace and rare earth elements of overbank sediments from the Lancang River (Upper Mekong), which drains southwest China and is one of the largest international rivers in Asia. We characterize sediment maturity and recycling, weathering and provenance in a typical, tectonically active cold-humid climate region. Lancang River (LR) sediments with an average chemical index of alteration (CIA) of 73 ± 6 and an average index of compositional variability (ICV) of 1.1 ± 0.6 suggest an intermediate mineralogy and chemical maturity corresponding to moderate weathering in a slightly warmer climate. The provenance of LR sediments is characterized by felsic source rocks, similar to the upper continental crust (UCC), followed by recycled sedimentary rocks, which were possibly derived from the Yidun, North Qiangtang (NQ) and Songpan-Ganzi (SGZ) terranes at upstream locations when the Lingcang basalt (LCB) provided mafic rocks for LR sediments. However, recycled materials have limited impacts on sediment maturity, as reflected by the degree of weathering. Highly physical weathering (erosion) has created a massive source for LR sediments due to active tectonics, while the impacts of climate on weathering processes have increased. Meanwhile, the overbank sediment in large rivers could be a good sampling medium for evaluating terrestrial weathering, provenance and sediment characteristics using geochemical evidence.

The weathering resistance of quaternary High‐density polyethylene (HDPE) composites: Effects of weld lines, formulation and degradation on tensile properties

AbstractIn this work, the effects of weld lines, additives and the degree of QUV weathering on the tensile behavior of a range of high‐density polyethylene composites with calcium carbonate, stabilizers and a carbon black/SEBS masterbatch are studied. The degree of weathering is characterized using FTIR‐derived carbonyl, double‐bond and carbonate indexes based on curve fitting, to allow for the fairer comparison of specimens with and without calcium carbonate. Weld‐line specimens exhibited more rapid degradation than that seen in the reference specimens, while the exposed surfaces of the specimens degraded more quickly than the unexposed surfaces. ISO G154 Cycle 1 and Cycle 6 weathering protocols were compared. The additives were found to be effective at decreasing oxidative degradation, albeit with reduced effects at higher loadings and in mixed systems. These findings were mirrored in the mechanical properties of the specimens, with the modified specimens even exhibiting broadly improved properties with increasing aging. Elongation at break was most sensitive to weathering, with increasing degradation with increasing weathering across almost all specimens.

Analysis of the composition of ancient glass products based on Spearman's correlation coefficient

Ancient glass stored underground for a long time has undergone different degrees of weathering, which has led to changes in its chemical composition and affected the correct judgment of its category. Based on this, this paper uses various algorithms such as Spearman correlation coefficient, chi-square test and cluster analysis to establish a comprehensive model for glass composition evaluation. The results show that: (1) The surface weathering degree of glass artifacts is significantly correlated with their types; (2) The content of Lead oxide can be used to make a general distinction between high-potassium glass and lead-barium glass; (3) Among the known glass samples, high-potassium glass can be divided into three categories and lead-barium glass can be divided into four categories; (4) According to the reasonableness test, it is known that the model has good reliability and can provide guidance for the study of ancient glass.

Soil erosion after fire in volcanic terrain: Assessment and implications for post-fire soil losses

Wildfires can dramatically modify the hydrologic and erosion response of ecosystems, increasing risks to population and assets downslope of fire affected hillslopes. This applies especially to volcanic areas in fire-prone regions which often exhibit steep terrain and high population densities. However, the effects of fire on key hydrologic and erosion parameters, which are critical for modelling runoff-erosion processes, predicting related post-fire risks and for selecting effective mitigation measures, have not been extensively assessed in this terrain type. Here we evaluate water erosion processes of two contrasting volcanic soils in recently burned forest areas of Tenerife (Canary Islands, Spain) at hillslope scale using erosion plots monitoring and rill erosion simulation experiments. The results show that both the lithology and the degree of weathering of the volcanic material govern the post-fire water erosion by concentrated flow (rill erosion experiments) and by the combination of interrill and rill erosion (erosion plots). Mature volcanic soils showed less susceptibility to erosion than weakly weathered volcanic soils and soils with non-volcanic lithologies. The results also show that the availability of easily detachable and transportable soil particles swiftly decreases after the fire, leading to the exhaustion of sediments and a decrease of the erosion rates with cumulative runoff events. These findings have direct implications for the modelling of runoff-erosion processes in volcanic terrain.

Study on the characterization of differential weathering feature based on surface roughness theory and 3D laser scanning: A case study of the Suoyang Ancient City

Earthen heritage sites have been undergoing lengthy surface weathering since they were built, which can pose a severe threat to the protection and utilization of these cultural treasures. Especially for differential weathering, one of the most common surface weathering patterns of earthen heritage sites in northwestern China, has not been well studied yet. Hence, in this paper, Suoyang Ancient City was selected as the study area, and six analysis domains (S1 to S6) exhibiting various differential weathering degrees were determined on wall faces and their morphological data were collected by a 3D laser scanner. Based on the point cloud data, the morphology of each domain was digitalized and reconstructed, and ten typical profiles were selected for roughness analysis. Concretely, for these profiles, six roughness parameters, including average asperity inclination (Ai), mean curvature (R′da), textural slope parameter (Z2), roughness coefficient (Rp), self-affine fractal dimensions (A and D) and directional roughness metric (G(i)) were calculated to characterize their differential weathering features. The results show that the wall with a higher differential weathering degree has greater values of Rp, G(i), A and D. It can also be found that different roughness indicators can reflect different wall surface morphological characteristics. In addition, the main driver of differential weathering developing is the prevailing sediment-laden wind, and the degree of differential weathering is also affected by the building techniques, wall endowment environment, wall orientation and morphology. Finally, according to the roughness values and wall surface morphology, the differential weathering degrees were classified into five grades (from level I to level V). In this case, the differential weathering degrees of S2 (level IV) and S5 (level IV) are the highest, followed by S3 (level III), S6 (level III), S1 (level II) and S4 (level II) respectively. Overall, the proposed approach based on 3D scanning and surface roughness is feasible to characterize the differential weathering degree, contributing to better prevention and mitigation of damage on earthen heritage sites.

Geochemistry of Jutogh Metasediments, Lesser Himachal Himalaya, India, and their Implications in Source Area Weathering, Provenance, and Tectonic Setting during Paleoproterozoic Nuna Assembly

Abstract This paper reports the results of the geochemical study of the Jutogh metasedimentary rocks that occur as a tectonic window between the Lesser and the Higher Himalaya. The Jutogh Group of rocks are mostly mica-schists of different metamorphic grade. The weathering intensity parameters, such as chemical index of alteration (CIA), plagioclase index of alteration (PIA), and index of compositional variability (ICV), range from 81 to 65 (mean = 72), 97 to 68 (mean = 84), and 1.9 to 0.6 (mean = 1.2), respectively indicating low to moderate degrees of weathering. Transition element ratios [Ni/Co (6.98 to 2.88), and V/Ni (2.32 to 1.27)], and major and trace element geochemistry imply recycled, felsic to intermediate, Archean to post-Archean are the sources for Jutogh rocks. The tectonic discrimination diagram implies an active continental margin setting for the deposition of the Jutogh metasediments. The geochemical data from the Jutogh rocks, when combined with the S-type Paleoproterozoic granite magmatism, imply the existence of an active tectonic setting during the deposition of the Jutogh sediments at the northern margin of the Indian continent during Nuna assembly.

Cord vitamin D levels in newborns and its clinical correlation

Vitamin D levels in newborns mainly depend on maternal vitamin D levels and maternal-fetal transfer of Vitamin D and its metabolites during pregnancy. Babies born to mothers with marked Vitamin D deficiency may have neonatal Rickets. There are many factors determining the Vitamin D levels in mother, like skin pigmentation, duration of sunlight exposure, body mass index, degree of altitude, clothing, sunscreen use, weather, air pollution, season and time of the day. Mothers with light - colored skin require a lesser duration of exposure as compared to mothers with dark-colored skin. If left untreated, children can develop hypocalcemic seizures, growth failure, irritability, lethargy, respiratory infections, and allergies, tetany, and laryngospasm and even dilated cardiomyopathy. Hence we performed this study to evaluated the role of cord vitamin D levels. Methods this was a prospective observational study performed on term neonates weighing &gt; 2.5 kg. Cord vitamin D was estimated at birth, and correlated with various maternal parameters such as anaemia, sun exposure, co-morbidities etc. Results: the mean cord vitamin D levels were low in those babies born to mothers with anaemia, lack of pre-natal supplementation of vitamin D and calcium, as well as less sun exposure. Conclusion: Cord vitamin D could be a marker of vitamin D deficiency in neonates born to mothers with risk factors like anaemia, lack of sun exposure and supplementation.

Natural fractures in a metamorphic buried hill reservoir, Bozhong 19–6 area, Bohai Bay Basin, China

The Bozhong (BZ) 19-6 gas field in the Bohai Bay Basin is a fractured metamorphic reservoir with proven reserves of over 1000 × 108 m3. However, the fracture development in the Archaean metamorphic buried hill reservoir in the BZ19-6 area is still not clear. In this study, cores, thin sections, imaging logs and laboratory measurements were used to elucidate the influences of lithology, tectonics and weathering on the formation and development of natural fractures. Both tectonic fractures and dissolution fractures are well developed, and 96.8% of these are interconnected. Lithology exerts the primary control on fracture formation, while stress and weathering influence the development of the fractures. Leucogneiss, cataclasite and gneiss with high contents of brittle minerals are favorable for fracture formation. Buried hill reservoirs near faults commonly exhibit a high linear density of fractures due to greater stress perturbation. Based on the degree of weathering in the study area, a metamorphic buried hill reservoir may be divided vertically into three zones: a weathered fracture zone, an inner fracture zone, and the basement. Fracture linear density and fracture aperture decrease significantly with a decrease in the intensity of weathering, while paleo-topographic highs with more intense weathering have a higher fracture density. A reservoir evolution pattern is proposed that can be used for targeting the favorable reservoirs in the study area.