Amongst several spectral lines, some of the strongest chromospheric diagnostics are offered by the Ca II H K lines. These lines can be used to gauge the temperature stratification of the atmosphere since the line core and wings are formed in different regions of the solar atmosphere. Furthermore, the Ca II lines act as tracers for the magnetic structure of the solar atmosphere, as the line cores are formed in the upper chromosphere even though they are formed in non-local thermodynamic equilibrium (NLTE). In contrast, the formation of millimetre (mm) continuum radiation occurs under local thermodynamic equilibrium (LTE) conditions. As a result, the brightness temperatures obtained from observations with the Atacama Large Millimetre/Submillimetre Array (ALMA) offer a complementary perspective on the activity and thermal structure of stellar atmospheres. The overall aim is to establish more robust solar/stellar activity indicators using ALMA observations in comparison with classical diagnostics, such as the s index and infrared triplet (IRT) index. We employed the 1.5D radiative transfer codes RH1.5D and advanced radiative transfer (ART) to compute the synthetic spectra for the Ca II lines and the millimetre (mm) continua, respectively. These calculations were performed using an enhanced network atmosphere model, which incorporates non-equilibrium hydrogen ionisation generated by the state-of-the-art 3D radiation magnetohydrodynamics (rMHD) Bifrost code. To account for the limited spatial resolution of ALMA, we simulated the effect using a Gaussian point spread function (PSF). Additionally, we analysed the correlations and slopes of scatter plots between the Ca II indices and mm continuum for the original and degraded resolutions, focusing on the entire simulation box, quiet Sun regions, and enhanced network patches separately. The activity indices generated from these lines could further be used to compare the spectra of Sun-like stars with the solar spectrum. We present a comparative study between synthetic continuum brightness temperature maps at mm wavelengths (0.3 mm to 8.5 mm) and the Ca II activity indices; namely, the s index and infrared triplet (IRT) index. The Ca II activity indices and mm brightness temperatures are weakly correlated at the high resolution, with the highest correlation observed at a wavelength of 0.3 mm, corresponding to ALMA band 10. As the resolution decreases, the correlation consistently increases. Conversely, the slopes exhibit a decreasing trend with increasing wavelength, while the degradation of resolution does not noticeably affect the calculated slopes. As the spatial resolution decreases, the standard deviations of the Ca II activity indices and brightness temperatures decrease, while the correlations between them increase. However, the slopes do not exhibit significant changes. Consequently, these relationships could be valuable for calibrating the mm continuum maps obtained through ALMA observations.
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