Mechanical Strength Degradation Research Articles

Mechanism of Crack Development and Strength Deterioration in Controlled Low-Strength Material in Dry Environment

The continuous expansion at the urban scale has produced a lot of construction waste, which has created increasingly serious problems in the environmental, social, and economic realms. Reuse of this waste can address these problems and is critical for sustainable development. In recent years, construction waste has been extensively recycled and transformed into highly sustainable construction materials called controlled low-strength materials (CLSMs) in backfilling projects, pile foundation treatment, roadbed cushion layers, and other applications. However, CLSMs often experience shrinkage and cracking due to water loss influenced by climatic temperature factors, which can pose safety and stability risks in various infrastructures. The purpose of this paper was to study the mechanism of crack formation and strength degradation in a CLSM in a dry environment and to analyze the deterioration process of the CLSM at the macro- and micro-scales by using image analysis techniques and scanning electron microscopy (SEM). The test results show that with the drying time, the CLSM samples had different degrees of cracks and unconfined compressive strength (UCS) decreases, and increasing the content of ordinary Portland cement (OPC) reduced the number of cracks. The addition of bentonite with the same OPC content also slowed down the crack development and reduced the loss of UCS. The development of macroscopic cracks and UCS is caused by the microscopic scale, and the weak areas are formed due to water loss in dry environments and the decomposition of gel products, and the integrity of the microstructure is weakened, which is manifested as strength deterioration. This research provides a novel methodology for the reuse of construction waste, thereby offering a novel trajectory for the sustainable progression of construction projects.

Corrigendum to “Strength degradation and damage mechanism of TA1 titanium alloy clinched joints under fatigue loading” [Thin–Walled Structures 202 (2024) 112125

Corrigendum to “Strength degradation and damage mechanism of TA1 titanium alloy clinched joints under fatigue loading” [Thin–Walled Structures 202 (2024) 112125

Thermal fluctuations on the corrosion behaviour of 17-4PH stainless steel alloys fabricated via material extrusion additive manufacturing technique

Herein, the influence of fluctuating thermal conditions on the corrosion behaviour of 17-4PH stainless steel alloys manufactured via fused filament fabrication is reported. The printed samples were sintered and then exposed to different temperature-fluctuating conditions to simulate the application environment of such alloys. The first set of samples (A) was studied as-sintered, the second set of samples (B) was aged at 480°C for 3 h followed by quenching in water, the third set (C) was exposed to conditions of B followed by aging at 360°C for 3 h and quenching in water and the final set of samples (D) was exposed to conditions of C followed by aging at 200°C for 3 h, quenching in water, aging at 400°C for 3 h, and finally quenching in water. The surface roughness evolved with the temperature conditions. The optical microscopy revealed that sample B had a fine and homogenous distribution of precipitates. Sample B had the highest microhardness values followed by C, D, and A in that order. XRD analysis revealed the presence of retained FCC austenitic phases within the microstructure whose peaks became stronger with the increased thermal fluctuations. The potentiodynamic polarisation studies revealed a distinct linear Tafel region on the cathodic region and a dual-slope inflection point on the anodic region of the polarisation curves. Sample D exhibited the highest corrosion rate whereas sample B revealed the lowest. As such, exposing fused filament fabricated 17-4 PH SS to fluctuating temperature conditions leads to degradation of mechanical strength and corrosion resistance.

Improvement in bioactivity, hardness and friction resistance of 3 % manganese-doped hydroxyapatite coated on alumina using radio frequency magnetron sputtering

Hydroxyapatite (HAP) is a common hard tissue implant material known for its superior biocompatibility and osteoconductivity. However, its poor mechanical strength, brittleness and slow degradation limit the applications. This study explores the enhancement of HAP mechanical properties and bioactivity by coating 3 wt% manganese-doped HAP (Mn-HAP) on another inert biomaterial alumina (Mn-HAP/Al2O3) substrates using the RF magnetron sputtering technique. Characterization of these samples was performed using Field Emission Scanning Electron Microscopy (FESEM), Energy Dispersive X-ray Spectroscopy (EDS), Grazing Incidence X-ray Diffraction (GIXRD), Fourier Transform Infrared Spectroscopy (FTIR) and Brunauer-Emmett-Teller (BET) techniques. Mechanical property was assessed through Vicker's hardness and adhesion of the film was studied by scratch testing. Corrosion resistance was evaluated using Tafel plots in Ringer's solution by Electrochemical analyser (ECA), and dielectric properties were measured using Impedance analyser. Biocompatibility was examined by wettability tests, thrombogenicity, antioxidant test, antimicrobial investigation and MTT [3-(4, 5-dimethythiazol-2-yl)-2, 5-diphenyl tetrazolium bromide] assay. The results show that Mn-HAP/Al2O3 coatings exhibit superior properties as compared to pure HAP, alumina, and HAP/Al2O3. Mn-HAP showed enhanced crystallinity and grain refinement, leading to improved hardness of 1198 HV for Mn-HAP/Al2O3 as compared to 39.84 HV for pure HAP and 1028 HV for HAP/Al2O3. The friction coefficient was found to be best in the Mn-HAP/Al2O3 sample. Corrosion rate significantly decreases in Mn-HAP/Al2O3 (1.63 ± 0.28) mmpy after coating on alumina. In vitro studies demonstrated enhanced cell attachment, proliferation, and differentiation after Mn-HAP coating on alumina. Antimicrobial tests revealed improved resistance against E. coli and S. aureus, with Mn-HAP/Al2O3 showing a larger zone of inhibition. The study concludes that 3 wt% Mn-HAP coatings deposited by RF magnetron sputtering hold great promise for enhancing the performance and longevity of hard tissue implants, paving the way for advanced biomedical applications.

Improvement of aerogel-incorporated concrete by incorporating polyvinyl alcohol fiber: Mechanical strength and thermal insulation

Aerogel incorporated concrete (AIC) effectively improves its thermal insulation performance. However, the potential mechanical strength degradation in AIC limits its further promotion and application. Fiber reinforcement is an effective means for improving the properties of cement-based materials. However, there is currently a lack research on enhancement mechanisms involved in fiber-reinforced AIC. In this study, polyvinyl alcohol (PVA) fibers with high strength and low thermal conductivity are introduced. The influence on the properties of AIC with various lengths (6–12 mm) and proportions (0–1.2 wt%) of PVA fiber was analyzed, and the mechanism of AIC enhancement was discussed based on microscopic test. The enhancing mechanism of PVA fiber on AIC was studied at microscopic scale to establish new solutions to the development of cementitious materials with both excellent load-bearing capacity and thermal insulation performance. The results revealed a synergistic effect of hydrophobic aerogel and PVA fiber on the fluidity of the mix due to the improvement of particle dispersibility and distribution uniformity. Additionally, the PVA fibers crossed aerogel particles around could inhibit crack expansion caused by aerogel fractures, thus effectively mitigating the loss of strength heat transfer with aerogel incorporation. At the same time, PVA fiber also plays a role in thermal resistance. Specifically, the incorporation of 0.6 wt% 9-mm fibers yielded the best overall reinforcement results, with an increase of 31.4 % and 15.5 % in flexural and compressive strengths, respectively, and a 28.5 % decrease in thermal conductivity. The microstructural tests indicated that incorporating PVA fibers at 0–0.6 wt% could optimize the pore structure, reduce the porosity, and increase the water resistance of AIC. The hydration degree of the cement matrix increased due to Ca2+ adsorption by PVA fibers. This study provides an optimized design strategy incorporating PVA fibers to enhance both the physical properties, mechanical strength, and thermal insulation properties of AIC.

Highly concentrated collagen/chondroitin sulfate scaffold with platelet-rich plasma promotes bone-exposed wound healing in porcine.

In the case of wounds with exposed bone, it is essential to provide not only scaffolds with sufficient mechanical strength for protection, but also environments that are conducive to the regeneration of tissues and blood vessels. Despite the excellent biocompatibility and biodegradability of collagen and chondroitin sulfate, they display poor mechanical strength and rapid degradation rates. In contrast to previous methodologies that augmented the mechanical properties of biomaterials through the incorporation of additional substances, this investigation exclusively enhanced the mechanical strength of collagen/chondroitin sulfate scaffolds by modulating collagen concentrations. Furthermore, platelet-rich plasma (PRP) was employed to establish optimal conditions for vascular and tissue regeneration at the wound site. High-concentration collagen/chondroitin sulfate (H C-S) scaffolds were synthesized using high-speed centrifugation and combined with PRP, and their effects on endothelial cell proliferation were assessed. A porcine model of bone-exposed wounds was developed to investigate the healing effects and mechanisms. The experimental results indicated that scaffolds with increased collagen concentration significantly enhanced both tensile and compressive moduli. The combination of H C-S scaffolds with PRP markedly promoted endothelial cell proliferation. In vivo experiments demonstrated that this combination significantly accelerated the healing of porcine bone-exposed wounds and promoted vascular regeneration. This represents a promising strategy for promoting tissue regeneration that is worthy of further exploration and clinical application.

Asymmetric and mechanically enhanced MOF derived magnetic carbon-MXene/cellulose nanofiber films for electromagnetic interference shielding and electrothermal/photothermal conversion

The prosperity of wearable and microelectronic devices tremendously facilitates to exploit thin and flexible composite films with multifunction. Free-standing MXene films have aroused considerable interest in the fields of electromagnetic interference (EMI) shielding and thermal management because of brilliant electrical conductivity, distinctive layered architecture and remarkable localized surface plasmon resonance effect. Nevertheless, the inferior mechanical strength and potential performance degradation in humid environments seriously constrain their practical applications. In this regard, robust and multifunctional CoNi-MOF-74 derived magnetic carbon/cellulose nanofibers (CNF)-MXene/CNF composite films with Janus architecture were successfully constructed via two-step vacuum-assisted filtration technology. The rational arrangement of functional fillers effectively improves the impedance matching, promoting the incident electromagnetic waves to enter the films for consumption. Constructing double-layered structure could induce the generation of “absorption-reflection-reabsorption” dissipation manner, dramatically enhancing EMI shielding performance. The bi-layered magnetic carbon/CNF-MXene/CNF composite membranes (0.1 mm in thickness) realize a fascinating EMI shielding effectiveness of 68.86 dB and a superior absorption efficiency of 58.82 dB. Meanwhile, the brilliant conductivity and significant localized surface plasmon resonance effect of MXene/CNF layer endow the composite films with excellent electrothermal/photothermal conversion capability, greatly broadening application prospects. The steady temperature of the composite films is as high as 112.9 °C within 10 s under the low driven voltage of 3.0 V and the saturation temperature reaches up to 154.2 °C within 15 s at the light intensity of 1500 W/m2, respectively. Moreover, the plentiful hydrogen bonding interaction and compact interfacial combination jointly enable the composite films to possess robust mechanical flexibility, satisfying the demands in practice. This work supplies a prospective guidance for preparing flexible and multifunctional composite films with Janus architecture, revealing great application potential in wearable and microelectronic devices even under harsh conditions.

Photochromic webbing structures for monitoring UV-induced mechanical strength degradation

Abstract Webbing structures are critical load-bearing components in a wide array of applications from structural restraint layers in inflatable space habitats to safety harness belts used by construction workers. In the field, webbings are subjected to ultraviolet (UV) irradiation from sunlight, leading to material degradation and a loss of mechanical strength. To date, health monitoring of webbings has relied on empirically correlating UV-induced strength loss with variations in their inherent color, which often yields inconsistent and imprecise results. To fill this gap, we propose a novel class of photochromic webbing structures that afford noninvasive monitoring of UV-induced degradation of their mechanical strength. The webbings’ sensing capabilities are achieved by integrating a class of photochromic yarns, fabricated through a pressurized coating process. Under continuous UV irradiation, the proposed photochromic webbings exhibit a substantial color change, demonstrating a sensing lifetime equivalent to several months in field conditions. We establish a strong correlation between the webbings’ photochromic response and their strength loss, supporting the feasibility of the proposed webbings in monitoring their mechanical integrity. To elucidate the sensing mechanism, we propose a physics-based mathematical model that describes the underlying photochemical reactions. Through an asymptotic analysis, we demonstrate that the model accurately predicts the webbing’s long-term photochromic responses under extended UV irradiation. The proposed photochromic webbing structures and the predictive mathematical model could enhance the safety and integrity of webbing-based engineering systems.

Thermal Treatment Effects on Structure and Mechanical Properties of Polybutylene Terephthalate and Epoxy Resin Composites Reinforced with Glass Fiber.

In this study, two types of composites, polybutylene terephthalate (PBT) and epoxy resin (ER), reinforced with 20% of glass fiber (GF) are used as the comparative research objects. Their mechanical properties after thermal aging at 85~145 °C are evaluated by tensile strength and fracture morphology analysis. The results show that the composites have similar aging laws. The tensile strength of GF/PBT and GF/ER decrease gradually with the increase of aging temperature, while their elastic moduli are independent of the thermal treatment temperature. Scanning electron microscopy study of the fracture surface shows that separation of glass fiber from PBT and ER matrix becomes more obvious at higher aging temperature. The fibers on the matrix surface appear clear and smooth, and the whole pulled out GFs can be observed. As a main mechanical strength degradation mechanism, the deterioration of interface adhesion between the matrix and GF is discussed. A large difference in coefficients of thermal expansion of the matrix and GF is a main factor of the mechanical degradation.

Water-rock interfacial softening model of cemented soft rock: An experimental and numerical study

Cemented soft rock is prone to softening when exposed to water, and its mechanical properties deteriorate rapidly, which is an important reason to induce the instability and failure of engineering soft rock mass. The softening mechanism of soft rock is essentially the deterioration of microstructure caused by the change of water-rock interface. Considering the general characteristics of soft rock, the microstructural evolution characteristics and element loss over varying immersion time are then compared and analyzed. The Interfacial Cemented Bonding (ICB) structure is proposed to describe the evolution of water-rock interface. Based on the diffusion theory, the theoretical equation describing the evolution of water-rock interface is derived and compared with the experimental results. The meso-softening damage factor (MSDF) of soft rock is proposed and introduced into a numerical method to establish a strength degradation discrete element method (SD-DEM) model. The results show that the softening process of soft rock is accompanied by the shedding and suspension of particles and the dissolution of soluble substances. Besides, the softening of soft rock has obvious nonlinear dynamic characteristics. The fitting degree between the theoretical values and the experimental results is relatively high, which verifies the reliability and rationality of the dissolution-diffusion interfacial softening model. The numerical results are in good agreement with the experimental ones. This study provides a new idea for understanding the mechanism of water-induced softening characteristics and strength degradation of soft rock.

Experimental Study on the Effect of Unloading Paths on Coal Damage and Permeability Evolution

Coal seam cavitation is one of the most effective techniques for gas disaster control in low-permeability coal. Due to the difference in cavitation method and process, the damage degree and fracture development range of the coal body around the cavern are greatly different, and the effect of increasing the permeability of the coal body is further changed. In order to further understand the permeability enhancement mechanism of cavitation technology on low-permeability coal and effectively guide engineering applications, this paper conducted experimental research on the unloading damage and permeability evolution characteristics of coal under different cavitation paths using a coal-rock “adsorption-percolation-mechanics” coupling test system. Through the analysis of coal strength and deformation characteristics, coal damage characteristics, and the evolution law of coal permeability combined with the macroscopic damage characteristics of coal, the strength degradation mechanism of unloaded coal and the mechanism of increased permeability and flow were revealed. The results show that unloading can significantly reduce the strength of coal, and the greater the unloading rate, the more obvious the reduction. The essence of this is that unloading reduces the cohesion and internal friction angle of coal—damage and breakage are the most effective ways to improve the permeability of the coal body. Unloading damaged coal bodies not only significantly improves the permeability of the coal body but also improves the diffusion ability of gas, and finally, shows a remarkable strengthening effect of gas extraction.

Drilling mud contamination effect on wellbore cement strength: An experimental investigation

Cementing is an essential downhole operation during the drilling of oil, gas, and geothermal wells, with the primary objective of providing structural support and a seal in the wellbore. It is important to attain adequate cement strength to preserve well integrity, inhibit fluid movement, enhance zonal isolation, and hold the wellbore casing in place. However, a significant challenge arises from the potential contamination of the cement by drilling mud (DM) during the placement process. This study aims to assess the impact of both water-based drilling mud (WBDM) and oil-based drilling mud (OBDM) contamination on the strength of API Class G wellbore cement by comprehensively investigating the underlying causes and the mechanism of strength degradation. Following a systematic methodological approach and the guidelines provided by API and ASTM, cement slurries were prepared and contaminated with DM at 10 %, 20 %, and 30 % concentrations by volume. Subsequently, both neat and contaminated samples were cured for 1, 3, 7, and 14 days, after which a series of uniaxial compressive strength (UCS) tests were conducted, and the results were further reinforced by microstructural and petrophysical property analysis. The results demonstrate that both WBDM and OBDM contamination significantly reduce cement strength, irrespective of curing time. Though the effect of OBDM contamination appears to be more pronounced, the effect of WBDM contamination is also remarkable. After final curing of 14 days, WBDM-contaminated cement samples exhibited an average strength reduction of 45.06 %, while OBDM contamination led to a 66.32 % reduction in strength compared to the neat cement with 30 % contamination. Additionally, for the same curing time and contamination percentage, porosity was found to be increased by 71.18 % and 91.33 %, respectively. The mechanism of neat and contaminated cement hydration is explained with the support of SEM-EDS tests, which confirmed the presence of contamination and revealed how two different drilling muds generate dissimilar pore structures within the cement sheath, affecting the hydration and ultimately contributing to the observed reduction in strength. The findings quantify the negative impact of WBDM and OBDM contamination on wellbore cement, emphasizing the importance of mitigating mud contamination during cementing operations.

Hydrogen Production in Microbial Electrolysis Cells Using an Alginate Hydrogel Bioanode Encapsulated with a Filter Bag.

The bacterial anode of microbial electrolysis cells (MECs) is the limiting factor in a high hydrogen evolution reaction (HER). This study focused on improving biofilm attachment to a carbon-cloth anode using an alginate hydrogel. In addition, the modified bioanode was encapsulated by a filter bag that served as a physical barrier, to overcome its low mechanical strength and alginate degradation by certain bacterial species in wastewater. The MEC based on an encapsulated alginate bioanode (alginate bioanode encapsulated by a filter bag) was compared with three controls: an MEC based on a bare bioanode (non-immobilized bioanode), an alginate bioanode, and an encapsulated bioanode (bioanode encapsulated by a filter bag). At the beginning of the operation, the Rct value for the encapsulated alginate bioanode was 240.2 Ω, which decreased over time and dropped to 9.8 Ω after three weeks of operation when the Geobacter medium was used as the carbon source. When the MECs were fed with wastewater, the encapsulated alginate bioanode led to the highest current density of 9.21 ± 0.16 A·m-2 (at 0.4 V), which was 20%, 95%, and 180% higher, compared to the alginate bioanode, bare bioanode, and encapsulated bioanode, respectively. In addition, the encapsulated alginate bioanode led to the highest reduction currents of (4.14 A·m-2) and HER of 0.39 m3·m-3·d-1. The relative bacterial distribution of Geobacter was 79%. The COD removal by all the bioanodes was between 62% and 88%. The findings of this study demonstrate that the MEC based on the encapsulated alginate bioanode exhibited notably higher bio-electroactivity compared to both bare, alginate bioanode, and an encapsulated bioanode. We hypothesize that this improvement in electron transfer rate is attributed to the preservation and the biofilm on the anode material using alginate hydrogel which was inserted into a filter bag.

Fatigue damage evolution and residual strength analysis of 3D5D braided composites using X-ray computed tomography, acoustic emission, and digital image correlation

The accumulation of fatigue damage leads to continuous degradation of the residual strength of three-dimensional braided composites, directly determining the fatigue life. However, the inability to continuously collect residual strength and multiple damage modes pose a challenge to study the residual strength degradation mechanisms of three-dimensional braided composites. In this work, digital image correlation and acoustic emission techniques are employed to assess the strain field and damage events of the specimens during the residual strength tests. X-ray computed tomography facilitates the visualization and quantification of the fatigue damage evolution in three-dimensional braided composites. Moreover, the “two-step” damage classification method is applied to isolate the damage mechanisms. The Pearson correlation analysis is preformed between the quantitative results of three non-destructive techniques and residual strength degradation of 3D braided composites. The integration of the outcomes provides a comprehensive depiction of the residual strength degradation mechanisms.

Experimental Study on the Strength Deterioration and Mechanism of Stabilized River Silt Reinforced with Cement and Alginate Fibers.

River silt deposited by water in coastal areas is unsuitable for engineering construction. Thus, the in situ stabilization treatment of river silt as the bearing layer has been an important research area in geotechnical engineering. The strength degradation behavior and mechanism of stabilized river silt reinforced with cement and alginate fibers (AFCS) in different engineering environments are crucial for engineering applications. Therefore, freeze-thaw (F-T) cycle tests, wetting-drying (W-D) cycle tests, water immersion tests and seawater erosion tests were conducted to explore the strength attenuation of stabilized river silt reinforced with the same cement content (9% by wet weight) and different fiber contents (0%, 0.3%, 0.6% and 0.9% by weight of wet soil) and fiber lengths (3 mm, 6 mm and 9 mm). The reinforcement and damage mechanism of AFCS was analyzed by scanning electron microscopy (SEM) imaging. The results indicate that the strength of AFCS was improved from 84% to 180% at 15 F-T cycle tests, and the strength of AFCS was improved by 26% and 40% at 30 W-D cycles, which showed better stability and excellent characteristics owing to the hygroscopic characteristics of alginate fiber arousing the release of calcium and magnesium ions within the alginate. Also, the strength attenuation of AFCS was reduced with the increase in the length and content of alginate fibers. Further, the strength of specimens in the freshwater environment was higher than that in the seawater environment at the same fiber content, and the softening coefficient of AFCS in the freshwater environment was above 0.85, indicating that the AFCS had good water stability. The optimal fiber content was found to be 0.6% based on the unconfined compressive strength (UCS) reduction in specimens cured in seawater and a freshwater environment. And the strength of AFCS was improved by about 10% compared with that of cement-stabilized soil (CS) in a seawater environment. A stable spatial network structure inside the soil was formed, in which the reinforcing effect of fibers was affected by mechanical connection, friction and interfacial bonding. However, noticeable cracks developed in the immersed and F-T specimens. These microscopic characteristics contributed to decreased mechanical properties for AFCS. The results of this research provide a reference for the engineering application of AFCS.

3-Dimensional Bioprinting of a Tendon Stem Cell–Derived Exosomes Loaded Scaffold to Bridge the Unrepairable Massive Rotator Cuff Tear

Background: Unrepairable massive rotator cuff tears (UMRCTs) are challenging to surgeons owing to the severely retracted rotator cuff musculotendinous tissues and extreme defects in the rotator cuff tendinous tissues. Purpose: To fabricate a tendon stem cell–derived exosomes loaded scaffold (TSC-Exos-S) and investigate its effects on cellular bioactivity in vitro and repair in a rabbit UMRCT model in vivo. Study Design: Controlled laboratory study. Methods: TSC-Exos-S was fabricated by loading TSC-Exos and type 1 collagen (COL-I) into a 3-dimensional bioprinted and polycaprolactone (PCL)–based scaffold. The proliferation, migration, and tenogenic differentiation activities of rabbit bone marrow stem cells (BMSCs) were evaluated in vitro by culturing them in saline, PCL-based scaffold (S), COL-I loaded scaffold (COL-I-S), and TSC-Exos-S. In vivo studies were conducted on a rabbit UMRCT model, where bridging was repaired with S, COL-I-S, TSC-Exos-S, and autologous fascia lata (FL). Histological and biomechanical analyses were performed at 8 and 16 weeks postoperatively. Results: TSC-Exos-S exhibited reliable mechanical strength and subcutaneous degradation, which did not occur before tissue regeneration. TSC-Exos-S significantly promoted the proliferation, migration, and tenogenic differentiation of rabbit BMSCs in vitro. In vivo studies showed that UMRCT repaired with TSC-Exos-S exhibited significant signs of tendinous tissue regeneration at the bridging site with regard to specific collagen staining. Moreover, no significant differences were observed in the histological and biomechanical properties compared with those repaired with autologous FL. Conclusion: TSC-Exos-S achieved tendinous tissue regeneration in UMRCT by providing mechanical support and promoting the trend toward tenogenic differentiation. Clinical Relevance: The present study proposes a potential strategy for repairing UMRCT with severely retracted musculotendinous tissues and large tendinous tissue defects.

Strength degradation and damage mechanism of TA1 titanium alloy clinched joints under fatigue loading

A digital model for the strength degradation of titanium alloy clinched joints was established using strength degradation tests and a fatigue cumulative damage model. This model aims to investigate the strength degradation law and fatigue damage failure mechanism of titanium alloy clinched joints under fatigue loading. Fractured test specimens were scanned to analyse the fatigue damage failure mechanism by examining the evolution of fracture morphology under varying fatigue cyclic loading times. The results demonstrate that the power index degradation model accurately predicts the strength degradation of titanium alloy clinched joints. As the number of fatigue loading cycles increases, cleavage features emerge alongside fatigue cracks, leading to a gradual reduction in joint strength. Ultimately, the strength degradation power index model for titanium alloy clinched joints is verified by the test to have high accuracy in predicting residual strength.

Injectable hydrogel based on liposome self-assembly for controlled release of small hydrophilic molecules

Controlled release of low molecular weight hydrophilic drugs, administered locally, allows maintenance of high concentrations at the target site, reduces systemic side effects, and improves patient compliance. Injectable hydrogels are commonly used as a vehicle. However, slow release of low molecular weight hydrophilic drugs is very difficult to achieve, mainly due to a rapid diffusion of the drug out of the drug delivery system. Here we present an injectable and self-healing hydrogel based entirely on the self-assembly of liposomes. Gelation of liposomes, without damaging their structural integrity, was induced by modifying the cholesterol content and surface charge. The small hydrophilic molecule, sodium fluorescein, was loaded either within the extra-liposomal space or encapsulated into the aqueous cores of the liposomes. This encapsulation strategy enabled the achievement of controlled and adjustable release profiles, dependent on the mechanical strength of the gel. The hydrogel had a high mechanical strength, minimal swelling, and slow degradation. The liposome-based hydrogel had prolonged mechanical stability in vivo with benign tissue reaction. This work presents a new class of injectable hydrogel that holds promise as a versatile drug delivery system. Statement of significanceThe porous nature of hydrogels poses a challenge for delivering small hydrophilic drug, often resulting in initial burst release and shorten duration of release. This issue is particularly pronounced with physically crosslinked hydrogels, since their matrix can swell and dissipate rapidly, but even in cases where the polymers in the hydrogel are covalently cross-linked, small molecules can be rapidly released through its porous mesh. Here we present an injectable self-healing hydrogel based entirely on the self-assembly of liposomes. Small hydrophilic molecules were entrapped inside the extra-liposomal space or loaded into the aqueous cores of the liposomes, allowing controlled and tunable release profiles.

Design, preparation and mechanical properties of novel glass fiber reinforced polypropylene bending bars

Fiber reinforced thermoplastic composite bars offered the advantages of repeated molding, high toughness, and recyclability, making them a promising alternative to steel bars. For the stirrups applications in concrete structures, it was essential to develop efficient bending technologies for producing high-quality thermoplastic bending bars. In the present paper, the bending properties of glass fiber reinforced polypropylene (GFRPP) composite bars were investigated by experimental and theoretical methods. A novel bending fixture of GFRPP bars was specifically designed for GFRPP bars to ensure the reliable bending of the bars. Finite element simulation was employed to analyze the stress distribution of GFRPP bars, providing valuable insights into their mechanical behavior. Additionally, a bending strength model was developed based on the material mechanics, offering a theoretical framework for understanding and predicting the bending strength of GFRPP bars. Finally, the bending mechanism of bars was further revealed according to experimental and theoretical findings. The results of the study demonstrated that the specially designed bending fixture was successful in minimizing damage to the bending section of the GFRPP bars, leading to a significant improvement in bending strength retention of up to 43.2 %. Furthermore, the theoretical results and experimental test have a good agreement in terms of stress distribution and failure mode. The maximum strain in the transition zone between the straight section and the bending section of the GFRPP bars was nearly double that of the straight section at the same stress levels. With the increase of bending radius to diameter ratio from 3.0 to 7.0, the tensile strength of GFRPP bending bars increased by ∼7.9 %. The study identified the transition area between the bending section and straight section of GFRPP bars as the most critical failure point. The strength degradation mechanism during the bending were attributed to the shrinkage and torsion of inner fibers owing to the compression caused the local stress concentration, which caused the inner resin matrix to crack and interface debonding of fiber/resin, leading to the premature tensile failure.

Deformation and strength degradation mechanism of weathered mudstone soil during dry-wet process based on a developed DEM approach

The soils suffer dry-wet cycles in nature and engineering due to the change of temperature, rainfall and the fluctuation of the groundwater level. The shrinkage-swelling deformation and mechanical properties evolve with the variations of moisture content during a dry-wet process was investigated by laboratory dry-wet cycle tests of a weathered mudstone soil. A DEM approach was developed for simulating the mechanical behaviors during the dry-wet process of the studied soil, considering the shrinkage-swelling deformation by adjusting the shrinkage or swelling ratio of the clay aggregate particles. The irreversible shrinkage-swelling deformation mechanism and the strength degradation mechanism were revealed. The results showed the developed DEM simulations can represent the deformation and the mechanical properties of soils during the dry-wet process. The shrinkage rate of soil decreases with the moisture content from saturation value to 5%, due to the reduction of the shrinkage potence of the clay aggregates. The irreversible shrinkage deformation of soils during a dry-wet process is because the limit swell potence of clay aggregate particles during the wetting process, leading to the swell during the wetting less than the shrinkage during the drying process. The strength degradation was divided into reversible portion mainly affect by the moisture content, and the irreversible portion affected by the meso-crack evolution during the dry-wet process. The large increase of meso-crack number during the drying leads to the rapid reduction of irreversible soil strength, while the decrease of porosity leads the increase of particle contacts and healing of the irreversible soil strength.