• The Yb 2 O 3 and Y 2 O 3 co-stabilized ZrO 2 towards enhanced CMAS resistance was proposed. • Improvement of CMAS resistance owing to a low diffusion rate of Yb 3+ . • The first-principles calculation was used to investigate the corrosion behavior. • YbYSZ shows better thermo-physical properties as compared with traditional YSZ. In this study, corrosion behavior of Yb 2 O 3 -Y 2 O 3 co-stabilized ZrO 2 (YbYSZ) was systematically investigated under CMAS melt attack. The result was found that YbYSZ exhibited a better CMAS resistance than yttria stabilized zirconia (YSZ), which was attributed to the excellent phase stability. The degradation of grain caused by CMAS attack was greatly related to the diffusion rate of element substantially. Yb 3+ exhibited a low diffusion rate contributing to good phase stability during corrosion. A corresponding first-principles calculation further confirmed this conclusion. Besides, YbYSZ showed a higher thermal expansion coefficient and lower thermal conductivity as compared with YSZ counterpart.
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