Deformation Mechanisms Research Articles

Mechanical Characterization of Electrolyzer Membranes and Components Under Compression

Proton-exchange membrane (PEM) water electrolysis is a promising technology for producing clean hydrogen by electrochemically splitting water when paired with renewable energy sources. A major roadblock to improving electrolyzer durability is the mechanical degradation of the cell components, which requires an understanding of their mechanical response under device-relevant conditions. However, there is a lack of studies on the mechanical characterization of the PEM and other components, as well as and their interactions. This study aims to address this gap by using a custom-designed testing apparatus to investigate the mechanics of electrolyzer components in uniaxial compression at 25 and 80 °C. Findings show stress-strain response of components have a varying degree of nonlinearity owing to their distinct deformation mechanisms and morphologies, from porous structures to polymers. These results are used to develop an expression for compressive stress-strain response of Nafion membranes and then analyze the deformation of components under applied pressure by using a 1-D spring network model of cell assembly. This work provides a new understanding of mechanical responses of the electrolyzer membrane and cell components, which can help assess material design and cell assembly strategies for improved electrolyzer durability.

Investigation on the machining mechanism of silicon modified by Au ion irradiation in elliptical vibration diamond cutting

Single-crystal silicon (Si) has important applications in semiconductor, infrared optics, and photovoltaic industries. However, Si is difficult to be machined precisely due to its hard and brittle characteristics. Ion irradiation is proposed as an advanced technology to reduce the hardness and brittleness for a covalent crystal, which is beneficial for the ductile machining process. In the present research, the simulation and experimental investigation of Si with Au ion irradiation were carried out firstly. As following, the grooving experiment is carried out by elliptical vibration cutting (EVC). the machining performance is compared with ordinary cutting (OC) and the material removal mechanism is elaborated. The critical depth of cut for brittle-to-ductile transition is nearly 7 times higher by EVC compared to OC. Initial verification of material modification was conducted by Raman spectra and cutting microgrooves. Finally, the ion irradiation damage mechanism and amorphous Si (a-Si)/crystalline Si (c-Si) machining deformation mechanism were analyzed in detail by transmission electron microscopy. The irradiated sample contains an amorphous layer of 1050 nm, a transition layer containing dislocations and nanocrystals, and a fully crystalline layer. During machining a-Si/c-Si interface, the machining defects in the amorphous layer will first absorb the energy and ensure that the crystalline layer does not produce subsurface damage. In summary, ion-irradiated Si can be achieved in the amorphous region at any depth position and the substrate ductile machining without subsurface damage generation by EVC.

Crashworthiness design for novel polygonal asymmetric origami tubes

Origami tubes have attracted widespread attention because it is inclined to deform in the complete diamond mode (DM) with a low initial peak force Fmax and high average crushing force Fave. Although conventional origami tubes can improve crashworthiness, there are still many areas that fail to generate traveling plastic hinge lines, and the crashworthiness can be further improved. This paper presents a novel polygonal asymmetric origami tube (PAT) with origami patterns that can trigger more traveling plastic hinge lines compared to those of conventional origami patterns. The theoretical analysis of the deformation mechanism suggests that the PAT can realize hierarchical deformation and avoid stress concentration at sharp corners. The quasi-static experiments and numerical simulations reveal that the novel origami pattern can successfully trigger up to four times more traveling plastic hinge lines than the conventional square box (CSB) under the premise that each plastic hinge line is similar in length. Compared with the CSB, the PAT can deform in DM with a 56.0 % reduction of Fmax and a 59.1 % increase of Fave. Notably, the stableness of load-carrying capacity SLC is 90.2 %, which is 260.8 % higher than the CSB. A series of parametric studies reveal that the dihedral angle ratio α / β and the width-to-thickness ratio c / t of the PAT have a significant effect on crashworthiness. A smaller ratio of α / β and c / t provides the PAT with superior crashworthiness. Comparing the PAT with other types of origami tubes and multi-cell tubes indicates that the PAT also exhibits outstanding crashworthiness. The impact experiments also unveil a significantly enhanced crashworthiness of the PAT. Compared with the CSB, the Fmax decreases by approximately 46.4 %, while the Fave increases by around 92.7 %. The SLC and SEA values for the PAT surpass those of the CSB by about 260.8 % and 93.1 %, respectively. Furthermore, the theoretical analysis for predicting the Fave of the PAT is developed, with a maximum error not exceeding 8.5 %.

Influence of mesenchymal and biophysical components on distal lung organoid differentiation

BackgroundChronic lung disease of prematurity, called bronchopulmonary dysplasia (BPD), lacks effective therapies, stressing the need for preclinical testing systems that reflect human pathology for identifying causal pathways and testing novel compounds. Alveolar organoids derived from human pluripotent stem cells (hPSC) are promising test platforms for studying distal airway diseases like BPD, but current protocols do not accurately replicate the distal niche environment of the native lung. Herein, we investigated the contributions of cellular constituents of the alveolus and fetal respiratory movements on hPSC-derived alveolar organoid formation.MethodsHuman PSCs were differentiated in 2D culture into lung progenitor cells (LPC) which were then further differentiated into alveolar organoids before and after removal of co-developing mesodermal cells. LPCs were also differentiated in Transwell® co-cultures with and without human fetal lung fibroblast. Forming organoids were subjected to phasic mechanical strain using a Flexcell® system. Differentiation within organoids and Transwell® cultures was assessed by flow cytometry, immunofluorescence, and qPCR for lung epithelial and alveolar markers of differentiation including GATA binding protein 6 (GATA 6), E-cadherin (CDH1), NK2 Homeobox 1 (NKX2-1), HT2-280, surfactant proteins B (SFTPB) and C (SFTPC).ResultsWe observed that co-developing mesenchymal progenitors promote alveolar epithelial type 2 cell (AEC2) differentiation within hPSC-derived lung organoids. This mesenchymal effect on AEC2 differentiation was corroborated by co-culturing hPSC-NKX2-1+ lung progenitors with human embryonic lung fibroblasts. The stimulatory effect did not require direct contact between fibroblasts and NKX2-1+ lung progenitors. Additionally, we demonstrate that episodic mechanical deformation of hPSC-derived lung organoids, mimicking in situ fetal respiratory movements, increased AEC2 differentiation without affecting proximal epithelial differentiation.ConclusionOur data suggest that biophysical and mesenchymal components promote AEC2 differentiation within hPSC-derived distal organoids in vitro.

Deformation and melt–rock interaction in the upper mantle: Insights from the layered structure of the Horoman peridotite, Japan

To obtain a better understanding of melt–rock interactions in the upper mantle, microstructural and petrological analyses were conducted on deformed mantle peridotites from the Horoman peridotite complex, Hokkaido, Japan. The Horoman peridotite complex is lithologically heterogeneous and contains various kinds of ultramafic and mafic rocks. We studied an outcrop of 3 × 70 m in size that contains layered spinel harzburgite, plagioclase lherzolite, and mafic rocks. The results indicate that reactive melts migrated preferentially along the foliation in the already deformed peridotite, and that these melt-rich zones became especially prone to further deformation. This inference is supported by (1) the parallelism of the boundaries of rock layers and foliation in the deformed peridotite, and the shape and crystallographic preferred orientations (SPOs and CPOs) of olivine in the peridotites; (2) the diffusive trends of magnesium and modal compositions of pargasite grains near the boundaries between peridotite and mafic layers; (3) variations in the NiO content of olivine crystals; (4) variations in olivine CPOs with orthorhombic (010)[100] slip system patterns and weak fiber-[010] patterns; and (5) the strong pargasite SPOs, the cuspate shapes of the pargasites, and the absence of intercrystallite deformation. The results, combined with previously reported P–T conditions for the Horoman peridotite complex, indicate that the deformed peridotites and mafic rocks with a layered structure represent temperatures of 1050–1150 °C and pressures of 0.7–1.5 GPa. Our results suggest that a decrease in pressure led to the transition from a melt-free to a melt-bearing system with a consequent change in the deformation mechanism, from dislocation creep in the melt-free system to diffusion creep in the melt-bearing system, with strain localization in the fine-grained melt-rich layers. The change in deformation mechanism is likely to have occurred in the uppermost mantle beneath a mid-ocean ridge, where strong rheological contrasts are controlled by spatial variations in the melt fraction.

Laser powder bed fusion of metastable β titanium alloys: Enhanced strength and plasticity through simultaneous activation of multiple deformation mechanisms

The excellent mechanical properties of metastable β titanium alloys make them suitable for use in aerospace and biomedical fields. However, the deformation mechanisms of these alloys are currently limited to slip/twinning or twinning/transformation-induced plasticity (TRIP) based on β phase stability, hindering high strength and plasticity. In this study, we regulated the laser powder bed fusion (LPBF) parameters to control ω phase density and β phase stability, thereby simultaneously triggering slip/twinning/TRIP deformation mechanisms and resulting in a high strength-plastic metastable β titanium alloy. The results demonstrated that reducing laser energy density decreased the ω phase fraction, leading to a decrease in β phase stability. The formation of the ω phase in specimens with low energy density increased the strain requirements for TRIP to occur, promoting dislocation slip and twinning initiation under low strain conditions. Due to TRIP effect activation at high strains, the α′ phase rather than the α″ phase became the transformation product, subsequently promoting twin formation within the α′ phase during further deformation. Generation of dislocation/twinning/TRIP and twins in the α’ phase resulted in an LPBF-ed metastable β Ti-1023 alloy with excellent strength and plasticity, which surpassed previous research findings for LPBF metastable β titanium alloys and overcame the strength-plasticity trade-off observed in traditional metal materials.

The Deformation Mechanism of Low Symmetric Ti-Pt Intermetallic Compounds Containing High Density of Planar Defects

Intermetallic compounds typically exhibit limited plastic deformation capacity due to challenges in activating dislocation slip and deformation twinning, coupled with a lack of alternative deformation mechanisms. Ti-Pt alloys are a prevalent type of intermetallic compound utilized in high-temperature shape memory alloys and as materials for energy applications in electric fields. However, they often exhibit poor deformation capability. Here, we prepared a low-symmetry intermetallic phase, Ti4Pt3, which demonstrates significant plastic deformation capability. This phase features a high density of parallel planar defects, resulting in an exceptionally large lattice periodicity perpendicular to these defects. Through in-situ scanning electron microscope compression tests, we observed substantial plastic deformation in this new phase. Analysis of the deformed Ti4Pt3 phase revealed that the dense planar defects create uniformly distributed sites of internal stress concentration, enabling a rapid increase in back stress within crystals. This phenomenon leads to notable lattice rotation and localized order-disorder transitions, both crucial mechanisms facilitating plastic deformation and enhancing deformation capacity. Our research underscores the potential of leveraging structural asymmetry to enable unconventional deformation mechanisms, thereby enhancing the plasticity of intermetallic materials.

Deformation mechanism and life prediction model of titanium alloy laser-arc hybrid welded joint during fatigue

The deformation mechanism and life prediction model of titanium alloy laser-arc hybrid welded joint during fatigue were studied. At the relatively small maximum cyclic stresses σmax (310 MPa to 350 MPa), the fatigue cracks initiated at the interface of lamellar α′ and needle-like α′ around the pore. At σmax=370MPa, the elongated lamellar α′ around the pore promoted fatigue crack propagation, leading to the formation of secondary cracks. At σmax=390MPa, the formation of two fatigue crack initiation locations and the occurrence of secondary cracks led to the maximum fatigue damage and the minimum fatigue life. In addition, the plastic deformation mainly occurred in β at σmax=310MPa, and it transformed into the phase interface of secondary α-β and granular β-α′ at σmax=350MPa. At σmax=390MPa, the main deformation forms were the cross-slip in β and the dislocations entanglement in α′. Finally, the fatigue life prediction model was established based on the equivalent cyclic stress, and the predicted fatigue life fell within a 3-fold error band.

Influence of hydrogen on deformation and embrittlement mechanisms in a high Mn austenitic steel: In-Situ neutron diffraction and diffraction line profile analysis

Austenitic steels have relatively high resistance to hydrogen embrittlement and play a critical role in hydrogen service applications. In particular, high Mn austenitic steels are considered economically viable alloy alternatives for these applications. The current study employed in-situ and ex-situ neutron diffraction techniques combined with diffraction line profile analysis (DLPA) to investigate the influence of hydrogen on deformation and embrittlement mechanisms in a high Mn (approximately 30 wt pct) austenitic steel. Investigation using both neutron diffraction and electron backscatter diffraction revealed the presence of extensive deformation twins and stacking faults within the steel microstructure after tensile deformation in the non-charged condition. These microstructural features suggest planar deformation behavior, which is expected from the relatively low stacking fault energy (SFE) of the alloy (approximately 29 mJ/m2). Hydrogen pre-charging resulted in apparent increases in both dislocations and stacking faults, contributing to macroscopic hardening and embrittlement mechanisms. Overall, numerical parameters obtained through neutron DLPA were used to elucidate the underlying mechanisms associated with hydrogen effects on the mechanical behavior, i.e. macroscopic strengthening, strain hardening rate, and embrittlement.

Integrating dynamic relaxation with inelastic deformation in metallic glasses: Theoretical insights and experimental validation

Metallic glasses (MGs), a metastable material far from equilibrium, exhibit intricate dynamic relaxation behaviors. The challenge lies in developing a model that accurately describes the dynamics and deformation mechanisms of MG. This paper introduces a model integrating dynamic relaxation with deformation behavior. Validation through dynamic mechanical analysis, stress relaxation, creep, and strain recovery tests confirm the existence of four deformation modes: elasticity, anelasticity from β relaxation, anelasticity from α relaxation at low temperatures, and viscoplasticity from α relaxation at high temperatures. The model captures all of these deformation modes. The dynamical mechanical spectrum and stress relaxation spectrum unveil dynamic features during glass to liquid transition, and a simple and effective experimental method was developed for identifying ultra-low-frequency dynamic relaxation. This work provides new perspectives on the study of relaxation dynamics in glassy states and establishes important connections between dynamic relaxation behavior and deformation mechanisms. These findings lay a theoretical and experimental foundation for the broad application of MGs.

Atomic-scale insights into the effect of layer thickness ratio on the tensile properties of heterostructured nano-aluminum

Gradient-structured alloys with lamellar microstructures show extraordinary potential in breaking the strength-ductility trade-off dilemma. When partial grain size exceeds the Hall-Petch limit, the deformation mechanism is not fully understood. In this study, the competing relationship between grain boundary (GB) softening and hetero-deformation-induced (HDI) strengthening in laminated nano-grained aluminum was investigated under uniaxial tensile loading. In the soft domains, the high activity of grain boundaries results in pronounced GB softening. However, when the volume fraction of the soft layer exceeds 50 %, the flow stress surpasses the predicted values of the rule of mixtures (ROM), demonstrating a significant HDI strengthening. A detailed analysis of microstructural evolution is conducted, including strain gradients, GB migration, and dislocation distribution. The effects of mechanical incompatibility between soft and hard layers on the distribution of plastic strain and overall material strength are elucidated in gradient structures. The study provides critical theoretical insights into the design and development of high-performance gradient nanocrystalline aluminum alloys, particularly in applications where a balance between strength and ductility is of paramount importance.

The preparation and axial compressive properties of 3D-printed polymer lattice-reinforced cementitious composite columns

Research on the mechanical properties of 3D-printed lattice-reinforced cementitious materials is becoming increasingly widespread. The bending and compression performances of such materials have been studied from the perspectives of the lattice preparation materials, structural forms, gradient design, and cement-based material types. The extant research has primarily focused on the bending performance of lattice-reinforced specimens, while little research has been conducted on the compressive properties. In addition, the reinforcing effect of the lattice on cementitious materials under lateral constraints has not been considered. This article investigates the compressive performance of cement mortar reinforced by 3D-printed spiral lattices or skin structures with different volume reinforcement ratios (different grid constraint layers). Multi Jet Fusion (MJF) technology was used to print four types of spiral lattices, and six specimens, including a control group, were prepared. The experiment considered the performance differences of polymer-reinforced mortars with different volume reinforcement ratios, bonding performance, and skin reinforcement. The load, displacement, stress, strain and other data of the specimen were measured, and combined with the full field strain measured by DIC technology, the strength, energy absorption performance, ductility, elastic modulus, constraint effect, deformation mechanism, and failure mode of the specimen were comprehensively analyzed. The experimental results indicate that 3D-printed spiral or skin lattices can improve the ductility and energy absorption capacity of cementitious materials. However, the elastic modulus of the raw materials used to reinforce the structure is lower than that of cementitious materials, which will reduce the compressive strength and elastic modulus. In addition, the lateral deformation constraint effect of the lattice or skin structure on the cement mortar under axial compression is not significant. All cementitious specimens were found to exhibit the shear failure of the inclined section under axial compression. This article reveals that 3D printed spiral lattices can improve the deformation ability of cementitious composite materials under compression, providing new ideas for the ideal replacement of stirrups and the development of building energy conservation and emission reduction.

The lattice friction stress driven temperature-dependent tensile deformation behaviors of CoNiCr2 eutectic medium-entropy alloy

A heterogeneous CoNiCr2 eutectic medium-entropy alloy (EMEA), comprising soft face-centered cubic (FCC) and hard body-centered cubic (BCC) lamellae, associated with minor acicular hexagonal close-packed (HCP) phase precipitated in BCC phase, was synthesized towards excellent tensile strength and ductility synergy. The tensile mechanical properties demonstrated that this alloy was temperature-dependent, i.e., when the testing temperature reduced from room temperature (RT) to liquid nitrogen temperature (LNT), the yield strength, ultimate strength, and uniform elongation were enhanced from 449 MPa, 821 MPa, and 5.0% to 702 MPa, 1174 MPa, and 8.4%, respectively. The prominent elevation of yield strength at LNT mainly resulted from the dramatically enhanced lattice friction stress (σ0) and the FCC-BCC interfacial strengthening, while the improved ductility was attributed to the superior crack-arrest capability of FCC matrix stemmed from the accumulation of stacking faults (SFs) and enhanced σ0 at LNT. Additionally, although the deformation mechanisms were dominated by planar dislocation glides and SFs at both temperatures, the initiation of premature cracks in the BCC phase due to the inferior deformation capability at LNT constrained the better strength-ductility trade-off. The cracks in the BCC phase tended to propagate along the BCC-HCP interfaces because of the strain incompatibility. Furthermore, the sub-nanoscale L12 particles in the FCC matrix could not only strengthen this alloy but also improve the stacking fault energy leading to no deformation twinning even at LNT. This work may provide a guide for the design of remarkable strength and ductility synergy EMEAs combined with outstanding castability for applications at cryogenic temperatures.

Strengthening and deformation mechanisms of laser additively manufactured Ni2CoCrNb0.2V0.2 medium-entropy alloy: Cryogenic to elevated temperatures

To develop a medium-entropy alloy (MEA) with a high yield strength at temperatures ranging from cryogenic (-196 ℃) to elevated (800 ℃) temperatures, a strategy for strengthening nanoparticle precipitation while reducing the MEA stacking fault energy (SFE) is proposed. A novel Ni2CoCrNb0.2V0.2 MEA suitable for additive manufacturing (AM) was designed according to the first-principles calculations and the calculation of phase diagrams (CALPHAD) technique. Bulk MEA samples were printed using laser-directed energy deposition (LDED) with a vibration field. First-principles calculations indicated that V addition could reduce the SFE and stabilize the γ′′ strengthening phase. The aged MEA had excellent yield strengths of ∼1398 MPa and ∼751 MPa at −196 ℃ and 650 ℃, respectively. The specific strength of the MEA reached 94.16 MPa g−1 cm−3 at 650 ℃. The deformational mechanism transforms from stacking fault (SF), deformation twin (DT), and Lomer–Cottrell (L-C) lock synergy to slip-dominated plasticity when the tensile temperature increases from −196 ℃ to 800 ℃. This research provides new theoretical guidance for developing AM-ed MEAs with an ultrastrong combination of strength and ductility for extreme temperatures applications.

Compression response and optimization design of a novel glass-sponge inspired lattice structure with enhanced energy absorption capacity

Lattice structures have shown tremendous prospects in engineering fields, because of the ultralight, strong and toughness properties. In this paper, a novel configuration of lattice structure (GSIBCC) inspired by the hierarchical skeleton system of glass sponges is proposed. The new configuration of the unit cell is based on modifying the inner cross struts of the body-centered cubic (BCC) lattice, by considering the double diagonal reinforcements and hybridization of unit cells. The compression properties and deformation mechanism of the GSIBCC lattice structure are compared with BCC, OCT (Octet) and other glass sponge inspired lattices. A multi-objective optimization method is established, for maximizing the specific energy absorption (SEA) and simultaneously reducing the compression strength. The novel GSIBCC lattice exhibits superior specific energy absorption than BCC, OCT, and other glass sponge inspired lattices. For example, GSIBCC shows maximum 145.06% improvement (ρ¯=0.124) of SEA with respect to BCC, and maximum 117.4% improvement (ρ¯=0.124) of SEA with respect to OCT. The novel lattice exhibits the whole deformation type and obvious second stress reinforcement effect. Besides, the mechanical properties of GSIBCC are further improved using the multi-objective optimization. The reported biomimicry design strategy, deformation and failure mechanism, and multi-objective optimization method will be beneficial for enriching the lattice system and promoting the multifunctional applications of lattice structures in engineering fields.

Investigation on in-situ tensile behaviors of 6061 aluminum alloy fabricated by wire additive friction stir deposition

Rod based additive friction stir deposition (R-AFSD) offers unique advantages for the integrated manufacturing of aluminum alloy near-net-shape large parts. However, the deposition process often faces issues like thick ends of raw material rods and difficulties in continuous feeding. In this study, wire based additive friction stir deposition (W-AFSD) was used for the solid state deposition of 3mm diameter 6061 aluminum alloy wire. The microstructure evolution and mechanical properties of the deposit along the build direction were systematically characterized, clarifying the recrystallization mechanism and isotropy of the mechanical properties. In-situ scanning electron microscopy (SEM) and electron backscattered diffraction (EBSD) were used to study the deformation behavior of the deposit during in situ tensile testing, revealing a cooperative deformation mechanism involving grain rotation and intragranular slip. Results show that during in-situ tensile testing, the average rotation angle of five selected grains is 6.90°. Additionally, deposits with numerous grain boundaries due to recrystallization can hinder dislocation movement and pin the slip system within the grains during tensile testing. Due to the synergy of these mechanisms, the yield strengths of the longitudinal and transverse samples of the deposit are 183MPa and 190MPa, respectively, much higher than previously reported values. This article introduces a new solid state additive manufacturing method, offering new insights for efficient, high-strength continuous additive manufacturing of aluminum alloys and their deformation mechanisms.

Deformation mechanism of Ni-based single crystal superalloy under ultrasonic surface rolling and subsequent thermal exposure

In present work, ultrasonic surface rolling (USR) is applied to DD6 Ni-based single crystal (NBSC) superalloys, and the thermal relaxation behavior of the pre-treated alloys are investigated at 650 °C. Combined with mechanical properties, the plastic deformation and recovery mechanisms of the hardened layers are revealed in detail. Results show that compressive residual stress amplitude of 1163 MPa, 75.1 % improvement of surface nano-hardness and 83.02 % reduction on surface roughness are achieved by USR. Both deformed layer thickness and slip density progressively increases with USR cycles, where initial octahedron {111}<110> slips transform to a mixture of octahedron {111}<110> and dodecahedron {111}<112> slips. Meanwhile, shear step length expansions form γ′ segment/γ terminal interface with superlattice extrinsic stacking fault (SESF) on 1¯11, which may have inferior energy threshold for γ dislocation invasions than primary ones through shortening mean free path. Also, this drives γ′/γ solute mingling to induce tortuous interfaces. While dislocation proliferation dominates γ channel hardening, the γ′ hardening derives from planar fault strengthening and net system energy augmentation. During thermal exposure, surface integrities of USRed DD6 are strongly degraded, attributable to slip trace elimination and local γ′ coarsening. Thermal exposure further compels the γ dislocation to migrate towards γ′ segment across γ′ segment/γ terminal interface. Then, they are probably consumed to motivate solutes to phase boundary to reshape the γ′ morphologies through interface rearrangements under the assistance of γ dislocation network. The orientation transformation of SESF on 1¯11 to 010 and the mixture of SESF and superlattice intrinsic stacking fault on 1¯11 are thought to be possible manipulated mechanisms for γ′ coarsening, significant impairing the work hardening of alloy due to interfacial coherency deterioration. This paper could provide guidance for USR strengthening designs of NBSC.

Investigating the nonlinear dynamics of photosensitive Belousov-Zhabotinsky gels via bifurcation analyses.

Controlling the dynamics of active stimuli-responsive smart materials is essential to replicate the biomimetic functionalities at different length scales for a variety of biological systems-based applications. Photosensitive Belousov-Zhabotinsky (BZ) gels, powered by a nonlinear chemical oscillator, called a BZ reaction are one of the stimuli-responsive smart materials in demand due to their ability to continuously transduce chemical oscillations into mechanical deformations. The chemical oscillations in a BZ reaction and subsequent mechanical oscillations in photosensitive BZ gels occur due to the redox cycle of photosensitive ruthenium complex-based catalysts. In this work, our objective is to identify how the behavior of photosensitive BZ gels can be tuned and used for biomimetic applications by investigating its dynamical characteristics using bifurcation analyses. Specifically, we use the normal form approach and perform linear and nonlinear stability analyses to identify high-order bifurcations by computing higher-order Lyapunov and frequency coefficients. We revealed the existence of domains that encompass coexisting stable and unstable limit cycles (LCs), which merge to form a semi-stable LC at the limit point of cycle (LPC). Their existence shows how a slight variation in the BZ gel recipe can significantly alter its dynamics. Subsequently, we quantify the amplitude and frequency of oscillations in different domains under the effect of variation of BZ reaction formulations. We believe that the outcomes of our work serve as an efficient template for the design and control of BZ gel-based applications. The usage of a normal form and a systematic representation of nonlinear dynamics allow our framework to be extended for other nonlinear dynamical systems.

Discrete Element Study on Mechanical Properties of MICP-Treated Sand under Triaxial Compression

Microbial-induced calcium carbonate precipitation (MICP) has attracted much attention as a promising technology for soil improvement in the infrastructures of marine engineering. This paper introduces a novel numerical sample preparation technique for MICP-treated sand, with particular attention paid to the distribution patterns of calcium carbonate, including contact cementing, bridging, and grain coating. The effect of calcium carbonate content (CCC) on the deformation and failure mechanism is studied at macroscopic and granular scales. The findings show that a small amount of calcium carbonate can quickly increase the strength of sand. The strength improvement and deformation control of MICP technology are better than those of traditional compaction treatment. As the calcium carbonate content increases, the mechanical coordination number of the sand also increases, indicating a more stable microstructure of the sand phase. In the contact bonding mode, initial failure occurs as shear failure between sand and calcium carbonate. In the bridge mode, initial failure manifests as shear failure between calcium carbonate particles. In the coating mode, initial failure occurs as tensile failure between sand and calcium carbonate. Calcium carbonate contributes to a reduction in both sliding and rolling movements among sand particles.

X-ray microstructural insight into the mechanical behaviour of ligth-weight cemented soils

Light-weight cemented soils (LWCS) – that is, materials prepared by mixing natural soil, water and cement with air foam, are characterised by a heterogeneous microstructure, consisting of large foam-induced voids distributed in a cemented porous matrix. The reduced volume weight coupled with a good mechanical strength makes LWCS suitable for many geotechnical applications. However, the role of the microstructure on their macroscopic mechanical behaviour is not completely clear. A novel experimental investigation on the mechanical response of LWCS under triaxial loading paths using in situ x-ray microtomography is presented here, focusing on the evolution of foam-induced porosity. The tomographies are acquired during the shear phase of multiple triaxial compression tests, performed at different confining stress levels. Image analysis is employed for obtaining porosity maps and incremental strain fields of the samples. At low confining stress, the sample deformation essentially consists in the progressive opening of sub-vertical dilatant fractures connecting the foam-induced voids. At higher confining stresses, localised compactions develop in the cemented matrix along the directions coherent with the deviatoric load path. The results presented above indicate that the deformation and failure mechanisms of LWCS strongly depend on the mean stress level.