Deep Crust Research Articles

Isotopic evidence of acetate turnover in Precambrian continental fracture fluids

The deep continental crust represents a vast potential habitat for microbial life where its activity remains poorly constrained. Organic acids like acetate are common in these ecosystems, but their role in the subsurface carbon cycle - including the mechanism and rate of their turnover - is still unclear. Here, we develop an isotope-exchange ‘clock’ based on the abiotic equilibration of H-isotopes between acetate and water, which can be used to define the maximum in situ acetate residence time. We apply this technique to the fracture fluids in Birchtree and Kidd Creek mines within the Canadian Precambrian crust. At both sites, we find that acetate residence times are <1 million years and calculated a rate of turnover that could theoretically support microbial life. However, radiolytic water-rock reactions could also contribute to acetate production and degradation, a process that would have global relevance for the deep biosphere. More broadly, our study demonstrates the utility of isotope-exchange clocks in determining residence times of biomolecules with possible applications to other environments.

Borehole disposal of spent fuel and other high-level wastes: the case for deep, vertical, fully cased holes in saturated “hard” rock

Driven by major advances in deep drilling technology and the geological understanding of the deep continental crust over the past 70 years, disposal in deep boreholes has moved from being technically unachievable to the point that it now offers a viable solution for the most hazardous nuclear wastes that could effectively be implemented “tomorrow”—i.e., within a few years. Moreover, disposal in deep boreholes is arguably superior in almost every respect to the mined and engineered repositories being pursued for high level waste by most countries. During the first 50 years of their evolution, almost all deep borehole disposal concepts shared five key aspects: (i) the hole was as deep as possible, (ii) it was vertical, (iii) it was fully cased, and (iv) it was in “hard” basement rock (v) saturated with aqueous fluid (groundwater). Technical advances in drilling over the last 20 years have encouraged proposed versions of the concept which depart from one or more of these aspects, but it is our contention that all five fundamental aspects should be retained. This paper summarises the more important arguments supporting this view. In order to meet the necessary post-closure (radiological) safety requirements, engineer out possible operational problems during construction and waste-package deployment, and capitalise on the main benefits of borehole disposal, the hole itself must be over 3 km deep, vertical, fully cased, and in suitably hard (ideally granitic) host rock saturated with aqueous fluid.

Nd isotope mapping in the Go Home region of Georgian Bay: a misunderstood key to the geology of the Central Gneiss Belt, Grenville Province of Ontario

The Georgian Bay transect forms an important geological section across the deeply exhumed Central Gneiss Belt of the Ontario Grenville Province. Its geological mapping was one of Nick Culshaw’s major research contributions, but the tectonic structure of the southern part of this transect in the Go Home region was never properly established. New Nd isotope data show that the classically recognized Go Home domain should be divided into three structural “decks” with distinct TDM (depleted mantle) Nd model ages. The upper deck consists of the Pine Island and Honey Harbour domains, with TDM ages averaging 1.56 and 1.57 Ga, respectively, which form two isolated units of the Grenvillian allochthonous belt. These are underlain by the newly-recognized Six Mile Lake domain, whose average TDM age of 1.71 Ga is representative of the tectonic duplex entrained elsewhere onto the base of the allochthon. Finally, the lowermost deck yields an average TDM age of 1.87 Ga, which identifies it as part of the Grenvillian parautochthon, exposed here in a tectonic window. The presence of a large retrogressed eclogite body within the allochthonous Honey Harbour domain confirms the exhumation of this unit from the deep crust on a major structural ramp. The coherent boundaries of these domains are consistent with the ramp–flat thrusting model of the Ottawan (Grenvillian) orogeny and limit the action of later extensional tectonics in the southwest Grenville Province.

Morphometry and active tectonics of the Konkan coast, western India

The Indian western coast is petroliferous drawing attention from academicians and industrial experts. In this work, geomorphic indices have been calculated to decode neotectonics of the Konkan onshore region on India’s west coast. Earthquake and Bouguer anomaly data have been used along with the present-day stress data from the World Stress Map project. Gravity modeling was performed in order to gain seismotectonic insights. The b-values were determined using Z-MAP 7.1 (2021). Morphometric analysis at both linear and spatial scales were performed using the digital elevation model from the data derived from the Shuttle Radar Topography Mission, analysed with ArcGIS 10.3 (2014) software. Maps depicting slopes, aspects, and reliefs were created. NW-SE trending lineaments in the Konkan plain guided the major stream courses. Two of the five watersheds, watersheds 4 and 5, reveal high tectonic activity, are landslide-prone and host hot springs. Interestingly, watersheds 4 and 5 show high b-values (except near the rivers’ sources), low Bouguer anomalies, and higher Hypsometric integral values (0.18523 and 0.16698) than the other watersheds. A low b-value in watershed 3 indicates stress accumulation. Over a larger area, the gravity trend varies from ∼ -80 to 30 mGal. The lineaments diagram deduced from the first vertical derivative technique shows that the structural fabrics mostly trend ∼ NW-SE at the west of the Western Ghat Escarpment (WGE) while it is NE-SW at the east. The tilt derivative ratio technique reveals a major NE-SW trend to the west of the WGE and an E-W trend to the east. Structural interpretations based on drill-cores around Koyna combined with geophysical studies for deep crust will be required are required for a better understanding of the blind (active) structures in the region.

Geochemical Evidence of Ore-Forming Processes in the Shuiyindong Gold Deposit of Southwest Guizhou Province, China.

The Shuiyindong deposit is one of the ultralarge Carlin-type gold deposits in Southwest Guizhou Province, China. Gold mineralization mainly occurs in the Permian Longtan Formation and the early Triassic Yelang Formation. It is controlled by both strata and faults. Detailed studies of the mineralogy and geochemistry characteristics of the Shuiyindong deposit are conducted to investigate the ore-forming process. Arsenian pyrite and arsenopyrite are the main Au-hosting minerals. Three types of pyrite can be recognized, including euhedral and subhedral pyrite, framboidal pyrite, and bioclastic pyrite. The euhedral and subhedral pyrite is the main Au-hosting type. The Au appears as a solid solution (Au+) and natural nanoscale gold (Au0) in the sulfide minerals. The Co/Ni ratios of sulfides (0.07-3.13) reveal that the ore-forming fluids were mainly affected by hydrothermal activity, but magmatic activity cannot be excluded. Organic matter in the ores is abundant (0.11-3.04%), which might provide sulfur for pyrite and favor an increase in the porosity and permeability of the host rocks by releasing organic acids. The REE and trace element results suggest that halogens (F and Cl) were contained in the reducing magmatic hydrothermal fluids. The sulfur isotopic data (from -8.64‰ to 27.17‰) suggest that the source of sulfur is complicated and is probably a combination of a magmatic source, the reduction of marine sulfate, and bacterial sulfate reduction. The Pb isotopic data of the sulfides indicate that Pb is from a mixture of crust and mantle sources. The obvious enrichment zones exist along the boundary faults in the geochemical map of As, implying that As may originate from the deep crust and then move to the strata with basinal fluids. By combining these results, it can be inferred that the ore-forming fluids were a mixture of basinal and deep source fluids. A probable ore-forming model of the Shuiyindong gold deposit is established.

The presences of water in the generation of calc-alkaline I-type granitic magmas at continental arc: Insight from Neoproterozoic Ailaoshan magmatism at the southwestern margin of the Yangtze Block, South China

Water is crucial in generating granitic systems; however, its role (i.e., dehydration, low to high water-fluxed melting) in granitic magmatism in continental arcs remains unsettled and poorly understood. Neoproterozoic arc-related igneous rocks are uncovered along the western margin of the Yangtze Block, presenting a complex compositional array ideal for deciphering the influence of water content within the continental arc and its geodynamic significance. The Jinping granites, in the Ailaoshan zone, are emplaced at 750 ± 4 Ma, as determined by zircon U-Pb dating. These medium to coarse-grained granites consist predominantly of plagioclase, quartz, K-feldspar, muscovite, and biotite. Characterized by high SiO2 (71.2–73.5 wt%), alkalis (K2O+Na2O=7.54–9.56 wt%) and low Fe2O3T (1.01–1.66 wt%), MgO (0.53–0.85 wt%), and CaO (0.15–0.93 wt%) concentrations, they exhibit high-K calc-alkaline signatures. The negative correlation between P2O5 and SiO2, alongside the positive correlation between Rb and Y, typifies the Jinping granites as I-type granites. Low La/Nb (1.96–3.43) and Nb/Ta (8.57–11.3) ratios, but high Th/La (0.28–0.46) and Zr/Sm (30.5–47.7) ratios, as well as whole rock εNd(t) (−0.4 to +1.3) and zircon εHf(t) values (+5.25 to +8.53) of the studied granites are similar to synchronous mafic rocks at the western margin of the Yangtze Block. These features suggest partial melting origin from the mafic lower crust. Thermodynamic modeling posits that the Neoproterozoic Ailaoshan I-type granitic rocks may have formed through water-fluxed melting (2.0–3.5 wt% H2O) under medium pressure conditions (9 kbar). It is postulated that slab rollback could have prompted water (as hydrous melt or fluids) release from hydrous minerals in the underlying cumulate mafic rocks, subsequently triggering water-fluxed melting in the lower crust. In contrast, high water-fluxed melting-generated adakitic granites with low K2O/Na2O ratios (<0.8) in the region, spatially and temporally associated with the Jinping granites, reflect higher water content in the deeper crust. This supports the notion that water was conveyed from depths to surface, facilitating the conversion of adakitic rocks into I-type granites as water content diminished. Thus, water content within the lower crust plays a pivotal role in the genesis of granitic rocks with varied compositions in a continental arc setting.

Mercury isotope fractionation and mercury source analysis in coal

Understanding the sources of mercury (Hg) in coal is crucial for understanding the natural Hg cycle in the Earth's system, as coal is a natural Hg reservoir. We conducted analyses on the mass-dependent fractionation (MDF), reported as δ202Hg, and mass-independent fractionation (MIF), reported as Δ199Hg, of Hg isotopes among individual Hg species and total Hg (THg) in Chinese coal samples. This data, supplemented by a review of prior research, allowed us to discern the varying trend of THg isotope fractionation with coal THg content. The Hg isotopic composition among identified Hg species in coal manifests notable disparities, with species exhibiting higher thermal stability tending to have heavier δ202Hg values, whereas HgS species typically display the most negative Δ199Hg values. The sources of Hg in coal are predominantly attributed to Hg accumulation from the original plant material and subsequent input from hydrothermal activity. Hg infiltrates peat swamps via vegetation debris, thus acquiring a negative Δ199Hg isotopic signature. Large-scale lithospheric Hg recycling via plate tectonics facilitates the transfer of Hg with a positive Δ199Hg from marine reservoirs to the deep crust. The later-stage hydrothermal input of Hg with a positive Δ199Hg enhances coal Hg content. This process has resulted in an upward trend of Δ199Hg values corresponding with the increase in coal THg content, ultimately leading to near-zero Δ199Hg in high-Hg coals. Coal Hg reservoirs are affected by large-scale natural Hg cycling, which involves the exchange of Hg between continents and seas.

Compositional diversity of late Mesozoic granites rooting from the subducted crust in the Qinling–Dabie orogenic belt

Continental subduction has been identified in many orogens, such as the Alps, the Himalayas, and the Dabie; however, better understanding of the mechanism and outcome of different subduction processes remains desirable. The Qinling–Dabie orogen in Central China shows an asymmetric distribution of Triassic ultrahigh-pressure metamorphic rocks and syn- and post-tectonic granitoid plutons, thereby providing an excellent means by which to probe the diverse processes of continental subduction. Many late Mesozoic granitoid plutons that formed in post-orogenic or even anorogenic settings are widely distributed in both the Qinling and Dabie tectonic units and can be useful for studying the composition of materials beneath the crust because of their conspicuous compositional diversity. In the present study, we report zircon ages and NdHf isotopic compositions for the Shangcheng and Heyu granite plutons, which represent late Mesozoic plutons in Dabie and Qinling. When compared with those of the Shangcheng pluton, the wide range of Nd isotopic values and the slightly depleted Hf isotopic compositions of the Heyu pluton indicate that there may be juvenile crust beneath the Qinling tectonic unit that is not present beneath the southern margin of North China. The currently undetectable juvenile material in this region may be an important candidate source of the late Mesozoic magmatism and metal mineralization in the southern margin of North China. The compositional diversity of these granites, as indicated by the NdHf isotopic compositions, is attributed to the nature of the deep crust within the orogenic belt, and the magmatic origins of this region are discussed in the present study.

Resistivity anomalies in the shallow and deep crust beneath West Tasmania from a broadband magnetotelluric 2D transect

West Tasmania has a complex geological history, including a Cambrian tectonic collision and related orogenesis, which formed ore deposits in a volcanic hosted massive sulfide (VHMS) setting. While the topography and dense vegetation covering the area presents challenges for on-ground investigations, the area is relatively well-studied such that 3D geological models are available. This contribution presents results of a broadband magnetotelluric (MT) 2D transect across the area (∼30 stations over a ∼ 80 km line, deployed in early 2016) that enables a combined interpretation of regional-scale geoelectric and geological structures. After accounting for noise, distortion and geoelectric strike; we produce 2D resistivity models using OCCAM2D inversion. We infer low resistivity anomalies in the shallow ( < 3 km ), mid (3–8 km) and deeper crust. Along this MT transect the shallow and mid crust low resistivity zones correspond to major crustal faults. Deep low resistivity features in the east of the transect suggest fluid pathways associated with metamorphism along the western boundary of the Tyennan block during the Cambrian Tyennan Orogeny, while others potentially represent the metasomatism of lower crustal rocks and fluid pathways converging into the mid crust.

Subsurface structural trends in Central-Western India: Inferences from magnetotelluric data using the complex MT apparent resistivity tensor

The central-western part of the Indian subcontinent exhibits significant geological diversity and possesses a rich record of different tectonothermal events in the earth's evolutionary history, spanning from the Archean to the present. Precambrian geology in the region is mostly obscured by Cretaceous-Tertiary/Paleocene volcanic eruptions and Proterozoic to Quaternary/recent sedimentary cover. Magnetotelluric (MT) impedance and tipper responses from 146 stations, covering central-western India in a grid fashion with a spacing of ∼55 km, were analyzed to evaluate the subsurface structural trends, dimensionalities, and qualitative characteristics of the electric lithosphere in the region. An advanced Complex Apparent Resistivity Tensor (CART) approach, along with the popular Phase Tensor (PT) approach and induction arrows are utilized to achieve the above goals. The analysis revealed a high degree of 3D induction effects in the data at almost every station and period. The directionality information retrieved from the tensor properties showed that the structural trends in the deep crust and upper mantle of the major geologic domains correlate with the known surface tectonic trend of the respective geologic domain. This study provides vital evidence to support the suspected bifurcation of the Precambrian Aravalli-Delhi Mobile Belt (ADMB) tectonic trend and its extensions into neighboring Kutch, Saurashtra, and Central Indian Tectonic Zone (CITZ) domains. The analysis results indicate a lithospheric scale enhanced conductivity beneath the Malwa plateau, which marks the first major phase of the Reunion mantle plume eruption in India. A critical finding of this study is that the Resistivity Phase Tensor better defines the subsurface resistivity structure and provides much clearer structural information than the conventional Phase Tensor.

Granulitic xenoliths from the Eocene and Oligocene volcanic rocks in NW of Central-East Iranian microcontinent: Evidence from petrology of deep crust

Granulitic xenoliths from the Eocene and Oligocene volcanic rocks in NW of Central-East Iranian microcontinent: Evidence from petrology of deep crust

The thermal structure of the Colombian lithosphere: A regional and basin-scale analysis

It is well-established that the thermal state of the lithosphere strongly influences various regional and local geological processes, including crustal deformation, hydrocarbon maturation, hydrogen generation, and geothermal phenomena. Moreover, the thermal structure exhibits high sensitivity to tectonic features, a property of particular significance in Colombia, where three main tectonic plates converge, and lithospheric tearing has been documented. In this contribution, we focus on elucidating the impact of plate architecture on the thermal field in central-eastern Colombia at both shallow and deep levels. To accomplish this, we constructed a series of two-dimensional profiles and derived a numerical solution of the heat equation using the conservative finite difference method. As constraints, we incorporate an inferred distribution of rocks in the deep crust and upper mantle based on global and local lithospheric thickness models. Material parameters for the various rocks, both exposed and inferred, were obtained from the literature. Additionally, we used superficial heat flow estimates and apparent geothermal gradients compiled by the Colombian Geological Survey.Our results suggest a significant influence of the lithospheric Caldas tear on the thermal state of Colombia, with the breaking off occurring in the Nazca plate under the Eastern Cordillera range around 5°N. The modeled asthenospheric heat flow remains approximately 25 mWm−2, except in the northern Eastern Cordillera range, where the background heat flow increases rapidly to 40 mWm−2. Consequently, our model predicts partial melting in the lower crust to the north and a thermally unstable lower crust to the south of the Caldas tear. The material parameters that best fit the surface data suggest the presence of a basement moderately enriched in radioactive elements in the Eastern Llanos basin. After accounting for compaction, we also confirm a strong influence of the tectonic setting on the thermal state of sedimentary basins.

Geochronology and geochemistry of granites from the Longhua Ni-Co deposit, South China: Implication for the formation of Ni-Co mineralization

Mineral exploration activities since 2010 in a previously poorly explored region of northeastern Guangxi province, South China, confirmed the existence of a potentially large hydrothermal Ni-Co deposit. As a newly discovered deposit, many aspects of this deposit are still unclear, including in which tectonic setting the deposit formed and how the high-grade mineralization developed. To address these questions, in this study, we conduct a comprehensively geochronological and geochemical study on the Dajin pluton (consisting of biotite monzogranite and sericitized monzogranite), which is the only pluton occurring in the district. LA-ICP-MS zircon U-Pb dating shows that two types of granites were emplaced nearly at the same time, with biotite monzogranite and sericitized monzogranite being 449 ± 15 Ma and 448.4 ± 8.8 Ma, respectively. This, combined with previously published studies, confirms that the Dajin pluton was broadly emplaced during the formation of the Longhua deposit. These granites are characterized by high K2O, and noticeable depletion of Eu, Sr, P and Ti, with whole-rock εNd(t) values ranging from −1.99 to −4.26 and zircon εHf(t) values ranging from −0.9 to 4.1. These features support that the studied granites are typical of A2-type granites, which experienced strong fractional crystallization and formed in a post-collisional environment. Although Co and Ni might not have been originally derived from granitic magmas, we suggest that the emplacement of the Dajin pluton facilitated the formation of high-grade Ni-Co mineralization in two ways: (1) melting the Co– and Ni-enriched mafic basement probably existing in the deep crust, and (2) remobilizing and concentrating metals from wall rocks.

Differentiating Jurassic Cu-, W-, and Sn (—W)-bearing plutons in the Nanling Range (South China): An integrated apatite study

The Nanling mineralization belt, South China, is well-known for widespread W-, Sn (—W), and Cu-polymetallic ore deposits. At present, how to better trace their magma sources and constrain their magmatic processes is currently a conundrum. As a resistant mineral, apatite has shown great potential in metallogenic studies. In this study, we present a comprehensive investigation of apatite from the Baoshan (BS) and Tongshanling (TSL) Cu-bearing granites, the Wangxianling (WXL) W-bearing granite, and the Qitianling (QTL) Sn-bearing granite in South Hunan, to trace the nature of parental magma and to establish apatite discrimination criteria to be used in regional prospecting. The U-Pb age dating of apatite indicates that these different types of ore-bearing granites were all formed in the Middle-Late Jurassic. The εNd(t) values results suggest that (1) Cu-bearing granites in the Nanling Range were formed by melting of meta-igneous rocks in the deep crust, (2) W-bearing granitic magmas were generated by melting of old continental crust, while (3) Sn-bearing granitic magmas were produced by melting of crust material with various input of mantle-derived components. Apatite from the BS and TSL plutons exhibits lower F/Cl ratios compared to those from WXL, and QTL plutons, with higher Cl contents in the BS and TSL plutons, implying that the crustal basement of the suture zone was metasomatized by a Cl-enriched fluid. We used a partial least squares discriminant analysis (PLS-DA) of trace element data in apatite to differentiate Cu-, W-, and Sn (—W)-bearing plutons. We find that the most influential elements for classification are Sr, Eu, Ga, Nd, and Li. Trace elements differences reveal distinguished degrees of fractionation, and redox conditions for different types of ore-bearing granites. A comparative study of apatite from different ore-bearing granites indicates that, apatite can be a useful mineral exploration tool to differentiate Cu-, W-, and Sn (—W)-bearing plutons in the Nanling Range and South China.

The subsurface anatomy of a mid-upper crustal magmatic intrusion zone beneath the Boku volcanic complex, Main Ethiopian Rift inferred from gravity data

Strain accommodation in the Main Ethiopian Rift has been localized since the Quaternary in axial magmatic segments that contain magma intrusion, volcanic complexes, and fault zones. However, the crustal structure and magmatic plumbing features of the individual volcanic complexes within these magmatic segments are poorly constrained. In this study, gravity data from the Global Gravity Model plus2013 was used to interpret the crustal structure and subsurface volcanic network at and near the Boku Volcanic Complex (Boku VC). Two-dimensional gravity models and an upward continuation map analysis of the upper crust reveal a gravity maximum that is interpreted as mafic intrusion at depths between 5 and 10 km beneath the Boku VC. A circular gravity maximum on the upward continued and residual gravity anomaly maps over the Boku VC and adjacent segments suggest the shallow plumbing systems beneath the segments are discrete, but that they merge into the deeper crust. The gravity models suggest that below 5 km beneath the center of magmatic segments nearly all the extension over the last 2 My can be accounted for by magmatic intrusion. Our models require faults in the uppermost crust which likely contribute to extension and may serve locally as conduits for the conveying melts or hydrothermal fluids. Our gravity analysis supports petrological studies that indicate a two-level magmatic plumbing system beneath the Wonji fault belts in which a melt supply from the upper mantle moves to mid-crust and then to shallow upper crust where the magma fractionates into more siliceous magma within smaller magma chambers.

High-Resolution 3D Shallow S-Wave Velocity Structure Revealed by Ambient-Noise Double Beamforming with a Dense Array in Guangzhou Urban Area, China

Abstract Shallow velocity structure surveys are very important for urban seismic hazard monitoring and risk assessment. Ambient-noise tomography provides an ideal way to obtain urban fine structure. In this study, we obtained a high-resolution 3D VS model of the metropolitan areas of the Pearl River Delta (PRD) using the ambient-noise double-beamforming method with a dense nodal array. The new model reveals shallow structures that correlate well with surface geological features, with low-velocity anomalies in fault depressions and high-velocity anomalies in fault uplifts. Our findings reveal detailed fault geometries and basin characteristics of the PRD. The Guangzhou–Conghua fault emerges as a prominent velocity boundary, playing a significant role in controlling the development and subsidence of the Longgui basin. The Xinhui–Shiqiao fault and Shougouling fault are identified as major faults that control the formation and evolution of depressions in the PRD. The basin structures in the PRD are classified as semigraben basins controlled by synsedimentary faults. The long axes of the sub-basins align with the strike of the major faults, and the deposit centers are located in close proximity to these faults. Furthermore, our investigation reveals low-velocity anomalies along the faults, suggesting the existence of pre-existing faults facilitating heat transfer and fluid/melt migration from the deep crust. Our results provide new constraints on the geometric structure of the sedimentary basins and fault systems in the PRD area, thereby contributing to urban seismic hazard assessment and offering valuable insights into potential geothermal resources.

Magmatic sulfide oxidation drives crustal PGE mobilization: Implications for hydrothermal PGE mineralization

Platinum-group elements (PGEs) have a strong affinity for sulfur and tend to accumulate in the deep continental crust, either concentrated within magmatic Cu-Ni-PGE deposits or dispersed throughout disseminated sulfides. However, PGE enrichment in shallow magmatic-hydrothermal systems implies an obscure link to deep sulfide destabilization, which releases PGEs into ore-forming fluids. To bridge this gap, our study investigates the PGE composition of magmatic sulfides with oxidative textures in dacitic rocks from the southwestern Okinawa Trough. We identified three groups of magmatic sulfides, primarily precipitated as Cu-poor monosulfide solid solution (MSS), which formed at distinct stages of magma evolution from deep to shallow crustal levels. Group A sulfides manifest as small-sized inclusions (<30 μm) within most high-Mg olivines, whereas Group B and C sulfides are larger (50–500 μm) and occur within cognate xenoliths of mafic cumulate rocks and the groundmass of host dacites. Group B and C sulfides exhibit distinct oxidative textures and newly-formed mineral assemblages, including magnetite, hematite, goethite, and magnetite ± pyrite, alongside hydrothermal silicate minerals, respectively. We attribute the oxidation process to the infiltration of orthomagmatic fluids exsolved from mafic magma that had underplated the sulfide-bearing felsic magma reservoir, which was nearly solidified. By comparing the chemical compositions between pristine sulfides and their oxidative remnants, we observed extensive mobilization of Pd, Pt, Cu, Ag, Ni, and Co from the altered sulfides of Group B, while Au enrichment occurred as nanoparticles under high oxidation states. In contrast, Au was extracted along with other mobile metals from the altered sulfides of Group C, with Pt remaining in place under more reduced conditions. These distinct scenarios may lead to the formation of PGE-rich and Au-rich fluids, respectively. The formation of deep crustal MSS and subsequent hydrothermal oxidation under varying redox conditions thus provides a viable mechanism for trans-crustal PGE mobilization and inter-element fractionation, typical of PGE-rich magmatic-hydrothermal deposits.

Hydrous shear zones are sites of melt transfer in the lower arc crust: A case study from Fiordland, New Zealand

AbstractRecent studies of the Cretaceous lower arc crust exposed in Fiordland, New Zealand, conclude that shear zones are sites of melt migration and mass transfer through the deep crust. Here, we investigate the 4–10 km‐wide George Sound Shear Zone, which cuts the Western Fiordland Orthogneiss, comprising two main rock types: two‐pyroxene gneiss and hornblende gneiss. Previous studies infer a predominantly igneous origin for the two types of gneiss. However, this study finds that melt‐rock interaction within the George Sound Shear Zone formed the hornblende gneiss from the precursor two‐pyroxene gneiss. Petrographic analyses of samples collected in transects across the shear zone show hydration reaction textures ranging from rims of hornblende + quartz around pyroxene grains to complete replacement of pyroxene grains. Plagioclase is recrystallized and partially replaced by clinozoisite. Additionally, biotite mode increases towards the higher strain rocks in the shear zone. Backscatter images and polarized light microscopy show microstructures indicative of former melt‐present deformation, including (a) interconnected mineral films of quartz and K‐feldspar along grain boundaries, (b) grains that terminate with low apparent dihedral angles, (c) interstitial grains, with some (d) undulose extinction in plagioclase and (e) serrated grain boundaries. In addition, zircon microstructures are consistent with Zr mobility, further supporting the former presence of melt; geochemical data show enrichment of Zr in the hornblende gneiss as compared to the two‐pyroxene gneiss. From the above observations, it is inferred that a felsic to intermediate hydrous melt migrated through the George Sound Shear Zone reacting with the host two‐pyroxene gneiss of the Western Fiordland Orthogneiss. Melt migration along grain boundaries was deformation assisted, (i) causing hydration of pyroxene to hornblende + quartz, and plagioclase to clinozoisite, (ii) increasing proportions of biotite within the shear zone and (iii) causing depletion of Cr + Ni and Zr enrichment in the hydrated rock. Our interpretation is supported by published observations of pegmatite dyke swarms that intruded into the George Sound Shear Zone, the P‐T conditions of deformation and characterization of microstructures that contrast sharply with those typically found in mylonitic rocks formed under solid‐state metamorphic conditions. Our results confirm that hydrous shear zones within otherwise anhydrous country rock are retrogressive and may represent evidence of melt migration through zones of deformation.

Deciphering sources of lode gold deposits in the South Tianshan, NW China: Insights from Pb isotope systematics

The Tianshan hosts numerous giant and world-class lode gold deposits, forming one of the world’s largest gold provinces. However, the sources of gold remain equivocal. Herein, we present a comprehensive Pb isotopic investigation of the Precambrian basement, Neoproterozoic mafic dykes, and the Lower Paleozoic sequences of the South Tianshan in NW China. These data were compared with existing Pb isotope datasets from major lode gold deposits and coeval granitoid and mantle-related rocks, to trace the sources of gold and constrain the relative contributions from potential reservoirs. Gold-bearing sulfides from major lode gold deposits have relatively uniform Pb isotopic ratios, which are significantly different from regional coeval granitoid and mantle-related rocks. Conversely, the Pb isotopic characteristics from gold-bearing sulfides are comparable to those from the Paleoproterozoic metasedimentary rocks, showing well-defined linear relations. Binary mixing modeling shows that the Paleoproterozoic metasedimentary rocks might have contributed 70% to 90% for the source of Pb and, by inference other metals. Integrating geochemical and isotopic features from major lode gold deposits in the region, we propose that it invokes fertilization of ancient Au archives during metamorphic volatilization in the deep crust during subduction of the South Tianshan Ocean. Following the final closure of the South Tianshan Ocean, the regional tectonic uplift and thermal effect during widespread granitoids emplacement associated with the amalgamation of the Tarim with Kazakhstan-Yili terranes, mobilizing the deep roots of the fertilized ancient Au reservoirs, leading to the formation of the gold deposit hosted in fault systems of the South Tianshan.

Simultaneous rift-scale inflation of a deep crustal sill network in Afar, East Africa

Decades of studies at divergent plate margins have revealed networks of magmatic sills at the crust-mantle boundary. However, a lack of direct observations of deep magma motion limits our understanding of magma inflow from the mantle into the lower crust and the mechanism of sill formation. Here, satellite geodesy reveals rift-scale deformation caused by magma inflow in the deep crust in the Afar rift (East Africa). Simultaneous inflation of four sills, laterally separated by 10s of km and at depths ranging 9–28 km, caused uplift across a ~ 100-km-wide zone, suggesting the sills are linked to a common mantle source. Our results show the supply of magma into the lower crust is temporally episodic, occurring across a network of sills. This process reflects inherent instability of melt migration through porous mantle flow and may be the fundamental process that builds the thick igneous crust beneath magmatic rifts and rifted margins globally.