Deep Convective Events Research Articles

Effect of convection on the thermal structure of the troposphere and lower stratosphere including the tropical tropopause layer in the South Asian monsoon region

Influence of convection on the thermal structure of Troposphere and Lower Stratosphere (TLS) is investigated using radiosonde data, obtained from Trivandrum (8.5°N, 76.9°E), Gadanki (13.5°N, 79.2°E), Bhubaneswar (20.25°N, 85.83°E), Kolkata (22.65°N, 88.45°E) and Singapore (1.37°N, 103.98°E), collected during different convective categories classified based on the altitude of deep convective cloud tops (CT) in the period 2008–2014. During deep convective events, the temperature showed lower tropospheric cooling, an upper tropospheric warming and an anomalous cooling (warming) below (above) the cold point tropopause (CPT) with respect to the clear-sky value. While warming in the upper troposphere is strongest (∼2–4 K) around 10–12 km, anomalous cooling (warming) below (above) the CPT is maximum around 15.5 km (17.5 km) with values in the range of−2 to −4 K (3–6 K). These temperature perturbations are observed 5–6 days prior to the convective events. In response to deep convection, surface cooling up to ∼ −4 K is also observed. This study showed that the magnitude of cold and warm anomalies increases with strength of convection. During deep convection, the potential temperature (θ) shows a decrease (<5 K) in the tropical tropopause layer (TTL) from the TTL-base up to CPT compared to that on clear-sky days, confirming the vertical mixing of convective air from the lower atmosphere to the TTL-levels. Correlation analysis between different TTL parameters suggests that, as the cloud top altitude increases, along with the adiabatic process, diabatic process also plays a major role in the TTL. An interesting feature observed during deep convection is the ascent of TTL-base by ∼1.5 km and descent of CPT and TTL-top by 0.5 km, which effectively thins the TTL by ∼2 km.

An Evaluation of the Large-Scale Implementation of Ocean Thermal Energy Conversion (OTEC) Using an Ocean General Circulation Model with Low-Complexity Atmospheric Feedback Effects

Previous investigations of the large-scale deployment of Ocean Thermal Energy Conversions (OTEC) systems are extended by allowing some atmospheric feedback in an ocean general circulation model. A modified ocean-atmosphere thermal boundary condition is used where relaxation corresponds to atmospheric longwave radiation to space, and an additional term expresses horizontal atmospheric transport. This produces lower steady-state OTEC power maxima (8 to 10.2 TW instead of 14.1 TW for global OTEC scenarios, and 7.2 to 9.3 TW instead of 11.9 TW for OTEC implementation within 100 km of coastlines). When power production peaks, power intensity remains practically unchanged, at 0.2 TW per Sverdrup of OTEC deep cold seawater, suggesting a similar degradation of the OTEC thermal resource. Large-scale environmental effects include surface cooling in low latitudes and warming elsewhere, with a net heat intake within the water column. These changes develop rapidly from the propagation of Kelvin and Rossby waves, and ocean current advection. Two deep circulation cells are generated in the Atlantic and Indo-Pacific basins. The Atlantic Meridional Overturning Circulation (AMOC) is reinforced while an AMOC-like feature appears in the North Pacific, with deep convective winter events at high latitudes. Transport between the Indo-Pacific and the Southern Ocean is strengthened, with impacts on the Atlantic via the Antarctic Circumpolar Current (ACC).

Influence of the Phytoplankton Community Structure on the Spring and Annual Primary Production in the Northwestern Mediterranean Sea

AbstractSatellite ocean color observations revealed that unusually deep convection events in 2005, 2006, 2010, and 2013 led to an increased phytoplankton biomass during the spring bloom over a large area of the northwestern Mediterranean Sea (NWM). Here we investigate the effects of these events on the seasonal phytoplankton community structure, we quantify their influence on primary production, and we discuss the potential biogeochemical impact. For this purpose, we compiled in situ phytoplankton pigment data from five ship surveys performed in the NWM and from monthly cruises at a fixed station in the Ligurian Sea. We derived primary production rates from a light photosynthesis model applied to these in situ data. Our results confirm that the maximum phytoplankton biomass during the spring bloom is larger in years associated with intense deep convection events (+51%). During these enhanced spring blooms, the contribution of diatoms to total phytoplankton biomass increased (+33%), as well as the primary production rate (+115%). The occurrence of a highly productive bloom is also related to an increase in the phytoplankton bloom area (+155%) and in the relative contribution of diatoms to primary production (+63%). Therefore, assuming that deep convection in the NWM could be significantly weakened by future climate changes, substantial decreases in the spring production of organic carbon and of its export to deep waters can be expected.

Modeling Postconvective Submesoscale Coherent Vortices in the Northwestern Mediterranean Sea

AbstractFor the first time, the formation of submesoscale coherent vortices (SCVs) during intermediate and deep convection events is documented in a realistic high‐resolution (1 km) numerical simulation of the oceanic circulation in the northwestern Mediterranean Sea. Winter intermediate and deep convection leads to the formation of anticyclonic and cyclonic eddies with lifetimes exceeding 1 year. By focusing on three typical eddies, the main characteristics of such vortices are discussed. The anticyclonic eddies are typical of SCVs observed in deep convection areas so far. They are characterized by a small radius (∼6.5 km) and orbital peak velocities of about 7 cm/s located at great depth (∼1500 m) or intermediate depth (∼500 m). The cyclonic vortices show very similar characteristics, such as a high Rossby number (∼0.4), but with surface‐intensified structures. The long lifetimes of both anticyclonic and cyclonic eddies reflect very slow diffusive processes between their core and their surroundings and a strong resistance to external perturbations. These long‐lived eddies are found to participate in the spreading of a significant portion (from 15 to 35%) of the convected waters in the Gulf of Lions and contribute to the ventilation of the deep basin.

Physical and Biogeochemical Controls of the Phytoplankton Blooms in North Western Mediterranean Sea: A Multiplatform Approach Over a Complete Annual Cycle (2012–2013 DEWEX Experiment)

AbstractThe North Western Mediterranean Sea exhibits recurrent and significant autumnal and spring phytoplankton blooms. The existence of these two blooms coincides with typical temperate dynamics. To determine the potential control of physical and biogeochemical factors on these phytoplankton blooms, data from a multiplatform approach (combining ships, Argo and BGC‐Argo floats, and bio‐optical gliders) were analyzed in association with satellite observations in 2012–2013. The satellite framework allowed a simultaneous analysis over the whole annual cycle of in situ observations of mixed layer depth, photosynthetical available radiation, particle backscattering, nutrients (nitrate and silicate), and chlorophyll‐a concentrations. During the year 2012–2013, satellite ocean color observations, confirmed by in situ data, have revealed the existence of two areas (or bioregions) with comparable autumnal blooms but contrasting spring blooms. In both bioregions, the ratio of the euphotic zone (defined as the isolume 0.415 mol photons m−2 d−1, Z0.415) and the MLD identified the initiation of the autumnal bloom, as well as the maximal annual increase in [Chl‐a] in spring. In fact, the autumnal phytoplankton bloom might be initiated by mixing of the summer shallowing deep chlorophyll maximum, while the spring restratification (when Z0.415/MLD ratio became &gt;1) might induce surface phytoplankton production that largely overcomes the losses. Finally, winter deep convection events that took place in one of the bioregions induced higher net accumulation rate of phytoplankton in spring associated with a diatom‐dominated phytoplankton community principally. We suggest that very deep winter MLD lead to an increase in surface silicates availability, which favored the development of diatoms.

On deep convection events and Antarctic Bottom Water formation in ocean reanalysis products

Abstract. Open ocean deep convection is a common source of error in the representation of Antarctic Bottom Water (AABW) formation in ocean general circulation models. Although those events are well described in non-assimilatory ocean simulations, the recent appearance of a massive open ocean polynya in the Estimating the Circulation and Climate of the Ocean Phase II reanalysis product (ECCO2) raises questions on which mechanisms are responsible for those spurious events and whether they are also present in other state-of-the-art assimilatory reanalysis products. To investigate this issue, we evaluate how three recently released high-resolution ocean reanalysis products form AABW in their simulations. We found that two of the products create AABW by open ocean deep convection events in the Weddell Sea that are triggered by the interaction of sea ice with the Warm Deep Water, which shows that the assimilation of sea ice is not enough to avoid the appearance of open ocean polynyas. The third reanalysis, My Ocean University Reading UR025.4, creates AABW using a rather dynamically accurate mechanism. The UR025.4 product depicts both continental shelf convection and the export of Dense Shelf Water to the open ocean. Although the accuracy of the AABW formation in this reanalysis product represents an advancement in the representation of the Southern Ocean dynamics, the differences between the real and simulated processes suggest that substantial improvements in the ocean reanalysis products are still needed to accurately represent AABW formation.

Multiscale Aspects of the Storm Producing the June 2013 Flooding in Uttarakhand, India

Conditions producing disastrous flooding in Uttarakhand, India, in June 2013 differed from conditions that produced other notorious floods in the Himalayan region in recent years. During the week preceding the Uttarakhand flood, deep convection moistened the mountainsides, making them vulnerable to flooding. However, the precipitation producing the flood was not associated with a deep convective event. Rather, an eastward-propagating upper-level trough in the westerlies extended abnormally far southward, with the jet reaching the Himalayas. The south end of the trough merged with a monsoon low moving westward across India. The merged system produced persistent moist low-level flow oriented normal to the Himalayas that advected large amounts of water vapor into the Uttarakhand region. The flow was moist neutral when it passed over the Himalayan barrier, and orographic lifting produced heavy continuous rain over the region for 2–3 days. The precipitation was largely stratiform in nature although embedded convection of moderate depth occurred along the foothills, where some mild instability was being released. The Uttarakhand flood had characteristics in common with major 2013 floods in the Rocky Mountains in Colorado and Alberta, Canada.

Analysis and evaluation of WRF microphysical schemes for deep moist convection over south-eastern South America (SESA) using microwave satellite observations and radiative transfer simulations

Abstract. In the present study, three meteorological events of extreme deep moist convection, characteristic of south-eastern South America, are considered to conduct a systematic evaluation of the microphysical parameterizations available in the Weather Research and Forecasting (WRF) model by undertaking a direct comparison between satellite-based simulated and observed microwave radiances. A research radiative transfer model, the Atmospheric Radiative Transfer Simulator (ARTS), is coupled with the WRF model under three different microphysical parameterizations (WSM6, WDM6 and Thompson schemes). Microwave radiometry has shown a promising ability in the characterization of frozen hydrometeors. At high microwave frequencies, however, frozen hydrometeors significantly scatter radiation, and the relationship between radiation and hydrometeor populations becomes very complex. The main difficulty in microwave remote sensing of frozen hydrometeor characterization is correctly characterizing this scattering signal due to the complex and variable nature of the size, composition and shape of frozen hydrometeors. The present study further aims at improving the understanding of frozen hydrometeor optical properties characteristic of deep moist convection events in south-eastern South America. In the present study, bulk optical properties are computed by integrating the single-scattering properties of the Liu(2008) discrete dipole approximation (DDA) single-scattering database across the particle size distributions parameterized by the different WRF schemes in a consistent manner, introducing the equal mass approach. The equal mass approach consists of describing the optical properties of the WRF snow and graupel hydrometeors with the optical properties of habits in the DDA database whose dimensions might be different (Dmax′) but whose mass is conserved. The performance of the radiative transfer simulations is evaluated by comparing the simulations with the available coincident microwave observations up to 190 GHz (with observations from Tropical Rainfall Measuring Mission's (TRMM) Microwave Imager (TMI), Microwave Humidity Sounder (MHS) and Special Sensor Microwave Imager/Sounder (SSMI/S)) using the χ2 test. Good agreement is obtained with all observations provided special care is taken to represent the scattering properties of the snow and graupel species.

Oceanic Uptake of Oxygen During Deep Convection Events Through Diffusive and Bubble‐Mediated Gas Exchange

The concentration of dissolved oxygen (O2) plays fundamental roles in diverse chemical and biological processes throughout the oceans. The balance between the physical supply and the biological consumption controls the O2 level of the interior ocean, and the O2 supply to the deep waters can only occur through deep convection in the polar oceans. We develop a theoretical framework describing the oceanic O2 uptake during open‐ocean deep convection events and test it against a suite of numerical sensitivity experiments. Our framework allows for two predictions, confirmed by the numerical simulations. First, both the duration and the intensity of the wintertime cooling contribute to the total O2 uptake for a given buoyancy loss. Stronger cooling leads to deeper convection and the oxygenation can reach down to deeper depths. Longer duration of the cooling period increases the total amount of O2 uptake over the convective season. Second, the bubble‐mediated influx of O2 tends to weaken the diffusive influx by shifting the air‐sea disequilibrium of O2 toward supersaturation. The degree of compensation between the diffusive and bubble‐mediated gas exchange depends on the dimensionless number measuring the relative strength of oceanic vertical mixing and the gas transfer velocity. Strong convective mixing, which may occur under strong cooling, reduces the degree of compensation so that the two components of gas exchange together drive exceptionally strong oceanic O2 uptake.

A submesoscale coherent vortex in the Ligurian Sea: From dynamical barriers to biological implications

AbstractIn June 2013, a glider equipped with oxygen and fluorescence sensors has been used to extensively sample an anticyclonic Submesoscale Coherent Vortex (SCV) in the Ligurian Sea (NW Mediterranean Sea). Those measurements are complemented by full‐depth CTD casts (T, S, and oxygen) and water samples documenting nutrients and phytoplankton pigments within the SCV and outside. The SCV has a very homogeneous core of oxygenated waters between 300 and 1200 m formed 4.5 months earlier during the winter deep convection event. It has a strong dynamical signature with peak velocities at 700 m depth of 13.9 cm s−1 in cyclogeostrophic balance. The eddy has a small radius of 6.2 km corresponding to high Rossby number of −0.45. The vorticity at the eddy center reaches . Cross‐stream isopycnic diffusion of tracers between the eddy core and the surroundings is found to be very limited due to dynamical barriers set by the SCV associated with a diffusivity coefficient of about 0.2 m2 s−1. The deep core is nutrients‐depleted with concentrations of nitrate, phosphate, and silicate, 13–18% lower than the rich surrounding waters. However, the nutriclines are shifted of about 20–50 m toward the surface thus increasing the nutrients availability for phytoplankton. Chlorophyll‐a concentrations at the deep chlorophyll maximum are subsequently about twice bigger as compared to outside. Pigments further reveal the predominance of nanophytoplankton inside the eddy and an enhancement of the primary productivity. This study demonstrates the important impact of postconvective SCVs on nutrients distribution and phytoplankton community, as well as on the subsequent primary production and carbon sequestration.

Open‐ocean convection process: A driver of the winter nutrient supply and the spring phytoplankton distribution in the Northwestern Mediterranean Sea

AbstractThis study was a part of the DeWEX project (Deep Water formation Experiment), designed to better understand the impact of dense water formation on the marine biogeochemical cycles. Here, nutrient and phytoplankton vertical and horizontal distributions were investigated during a deep open‐ocean convection event and during the following spring bloom in the Northwestern Mediterranean Sea (NWM). In February 2013, the deep convection event established a surface nutrient gradient from the center of the deep convection patch to the surrounding mixed and stratified areas. In the center of the convection area, a slight but significant difference of nitrate, phosphate and silicate concentrations was observed possibly due to the different volume of deep waters included in the mixing or to the sediment resuspension occurring where the mixing reached the bottom. One of this process, or a combination of both, enriched the water column in silicate and phosphate, and altered significantly the stoichiometry in the center of the deep convection area. This alteration favored the local development of microphytoplankton in spring, while nanophytoplankton dominated neighboring locations where the convection reached the deep layer but not the bottom. This study shows that the convection process influences both winter nutrients distribution and spring phytoplankton distribution and community structure. Modifications of the convection's spatial scale and intensity (i.e., convective mixing depth) are likely to have strong consequences on phytoplankton community structure and distribution in the NWM, and thus on the marine food web.

Temporal evolution of 137Cs, 237Np, and 239+240Pu and estimated vertical 239+240Pu export in the northwestern Mediterranean Sea

The evolution of 137Cs, 237Np and 239+240Pu at the DYFAMED station (NW Mediterranean) is discussed in relation to physical processes, downward fluxes of particles, and changes in the main input sources. The data set presented in this study represents the first complete 237Np vertical profiles (0.12–0.27μBqL−1), and constitutes a baseline measurement to assess future changes. A similar behavior of Cs and Np has been evidenced, confirming that Np behaves conservatively. While the 137Cs decrease has been driven by its radioactive decay, the vertical distribution of 237Np has not substantially changed over the last decade. In the absence of recent major inputs, a homogenization of their vertical distribution occurred, partly due to deep convection events that became more intense during the last decade. In contrast, 239+240Pu surface levels in the NW Mediterranean waters have fallen in the past four decades by a factor of 5. This decrease in surface has been balanced by higher concentrations in the deep-water layers. A first estimate of the downward 239+240Pu fluxes in the NW Mediterranean Sea is proposed over more than two decades. This estimation, based on the DYFAMED sediment trap time-series data and published 239+240Pu flux measurements, suggests that sinking particles have accounted for 60–90% of the upper layer (0–200m) Pu inventory loss over the period 1989–2013. The upper layer residence time of Pu is estimated to be ~28years, twice as long as the residence time estimated for the whole western Mediterranean (~15years). This difference highlights the slow removal of Pu in the open waters of the NW Mediterranean and confirms that most of the Pu removal occurs along the coastal margin where sedimentation rates are high.

Observed warming trend in sea surface temperature at tropical cyclone genesis

AbstractTropical cyclone (TC) activity is influenced by environmental factors, and it is expected to respond to anthropogenic climate change. However, there is observational uncertainty in historical changes in TC activity, and attributing observed TC changes to anthropogenic forcing is challenging in the presence of internal climate variability. The sea surface temperature (SST) is a well‐observed environmental factor that affects TC intensity and rainfall. Here we show that the SST at the time of TC genesis has a significant warming trend over the three decades of the satellite era. Though TCs are extreme events, the warming trend at TC genesis is comparable to the trend in SST during other tropical deep convection events and the trend in SST in the TC main development regions throughout the TC season. This newly documented, observed signature of climate change on TC activity is also present in high‐resolution global atmospheric model simulations that explicitly simulate TCs.

Improved MJO‐simulation in ECHAM6.3 by coupling a Stochastic Multicloud Model to the convection scheme

AbstractWe implement a Stochastic Multicloud Model (SMCM) in an observation‐informed configuration into the convection scheme of the state‐of‐the‐art GCM ECHAM6.3. The SMCM configuration we use here has been tuned to represent observed tropical convection by associating the occurrence and strength of deep convection to midtropospheric vertical velocity and relative humidity. We show that compared to the ECHAM6.3 standard model, the SMCM‐modified version shows improved capacity to simulate features of tropical intraseasonal variability, including MJO‐like disturbances, without significantly distorting the mean model climate. This improvement goes in hand with ameliorated coupling of atmospheric convection to tropospheric moisture and spatiotemporal coherence of tropical convection compared to reanalysis and observations. We attribute these effects to (i) improved coupling of triggering and suppression of deep convective events to the model's large‐scale environment and (ii) the observations‐informed closure formulation which leads to an overall reduction of deep convective mass fluxes. Sensitivity tests show that while (ii) improves the convection‐moisture relationship, it is (i) which improves the spatiotemporal coherence of tropical rainfall and is important for MJO simulation. Further, the simulated spatiotemporal coherence of tropical rainfall is an intrinsic property of the convection schemes themselves and not of their parameters. We stress that this study serves as a proof‐of‐concept and motivates further efforts towards building a novel convection parameterization with the SMCM as a central element.

Global cloud-permitting simulations of Typhoon Fengshen (2008)

Large-scale fields and inner-core processes relevant to the formation and intensification of Typhoon Fengshen (2008) were examined by simulations using a global nonhydrostatic model with a cloud-permitting resolution. Five runs were performed by varying the cloud microphysics or initial condition settings. In three out of five runs, a middle tropospheric trough developed within a few days following a large-scale latent heat release, which enabled the successive occurrence of deep convective events within the 50-km radius of the incipient disturbance and subsequent tropical cyclone (TC) formation. In the run initialized by altering the analysis dataset, collocation between latent heat release and the large-scale gyre was less evident, and neither the trough nor a TC developed. In the run with weaker latent heating in the lower troposphere, the trough was weak and TC formation was significantly delayed. These results indicate that the superposition of large-scale disturbances in the lower and middle troposphere and their linkage through convective enhancement played an important role in the genesis of Fengshen by preconditioning the establishment of a deep upright inner core.

Observations of open-ocean deep convection in the northwestern Mediterranean Sea: Seasonal and interannual variability of mixing and deep water masses for the 2007-2013 Period

We present here a unique oceanographic and meteorological data set focus on the deep convection processes. Our results are essentially based on in situ data (mooring, research vessel, glider, and profiling float) collected from a multiplatform and integrated monitoring system (MOOSE: Mediterranean Ocean Observing System on Environment), which monitored continuously the northwestern Mediterranean Sea since 2007, and in particular high-frequency potential temperature, salinity, and current measurements from the mooring LION located within the convection region. From 2009 to 2013, the mixed layer depth reaches the seabed, at a depth of 2330m, in February. Then, the violent vertical mixing of the whole water column lasts between 9 and 12 days setting up the characteristics of the newly formed deep water. Each deep convection winter formed a new warmer and saltier “vintage” of deep water. These sudden inputs of salt and heat in the deep ocean are responsible for trends in salinity (3.3 ± 0.2 × 10−3/yr) and potential temperature (3.2 ± 0.5 × 10−3 C/yr) observed from 2009 to 2013 for the 600–2300 m layer. For the first time, the overlapping of the three “phases” of deep convection can be observed, with secondary vertical mixing events (2–4 days) after the beginning of the restratification phase, and the restratification/spreading phase still active at the beginning of the following deep convection event.

THE MIDLATITUDE CONTINENTAL CONVECTIVE CLOUDS EXPERIMENT (MC3E).

Abstract The Midlatitude Continental Convective Clouds Experiment (MC3E), a field program jointly led by the U.S. Department of Energy’s Atmospheric Radiation Measurement (ARM) Program and the National Aeronautics and Space Administration’s (NASA) Global Precipitation Measurement (GPM) mission, was conducted in south-central Oklahoma during April–May 2011. MC3E science objectives were motivated by the need to improve our understanding of midlatitude continental convective cloud system life cycles, microphysics, and GPM precipitation retrieval algorithms. To achieve these objectives, a multiscale surface- and aircraft-based in situ and remote sensing observing strategy was employed. A variety of cloud and precipitation events were sampled during MC3E, of which results from three deep convective events are highlighted. Vertical structure, air motions, precipitation drop size distributions, and ice properties were retrieved from multiwavelength radar, profiler, and aircraft observations for a mesoscale convective system (MCS) on 11 May. Aircraft observations for another MCS observed on 20 May were used to test agreement between observed radar reflectivities and those calculated with forward-modeled reflectivity and microwave brightness temperatures using in situ particle size distributions and ice water content. Multiplatform observations of a supercell that occurred on 23 May allowed for an integrated analysis of kinematic and microphysical interactions. A core updraft of 25 m s−1 supported growth of hail and large raindrops. Data collected during the MC3E campaign are being used in a number of current and ongoing research projects and are available through the ARM and NASA data archives.

Impact of an intense water column mixing (0-1500 m) on prokaryotic diversity and activities during an open-ocean convection event in the NW Mediterranean Sea.

Open-ocean convection is a fundamental process for thermohaline circulation and biogeochemical cycles that causes spectacular mixing of the water column. Here, we tested how much the depth-stratified prokaryotic communities were influenced by such an event, and also by the following re-stratification. The deep convection event (0-1500 m) that occurred in winter 2010-2011 in the NW Mediterranean Sea resulted in a homogenization of the prokaryotic communities over the entire convective cell, resulting in the predominance of typical surface Bacteria, such as Oceanospirillale and Flavobacteriales. Statistical analysis together with numerical simulation of vertical homogenization evidenced that physical turbulence only was not enough to explain the new distribution of the communities, but acted in synergy with other parameters such as exported particulate and dissolved organic matters. The convection also stimulated prokaryotic abundance (+21%) and heterotrophic production (+43%) over the 0-1500 m convective cell, and resulted in a decline of cell-specific extracellular enzymatic activities (-67%), thus suggesting an intensification of the labile organic matter turnover during the event. The rapid re-stratification of the prokaryotic diversity and activities in the intermediate layer 5 days after the intense mixing indicated a marked resilience of the communities, apart from the residual deep mixed water patch.

Search for methane isotope fractionation due to Rayleigh distillation on Titan

We search for meridional variation in the abundance of CH3D relative to CH4 on Titan using near-IR spectra obtained with NIRSPAO at Keck, which have a photon-limited signal-to-noise ratio of ∼50. Our observations can rule out a larger than 10% variation in the column of CH3D below 50 km. The preferential condensation of the heavy isotopologues will fractionate methane by reducing CH3D in the remaining vapor, and therefore these observations place limits on the amount of condensation that occurs in the troposphere. While previous estimates of CH3D fractionation on Titan have estimated an upper limit of −6‰, assuming a solid condensate, we consider more recent laboratory data for the equilibrium fractionation over liquid methane, and use a Rayleigh distillation model to calculate fractionation in an ascending parcel of air that is following a moist adiabat. We find that deep, precipitating convection can enhance the fractionation of the remaining methane vapor by −10 to −40‰, depending on the final temperature of the rising parcel. By relating fractionation of our reference parcel model to the pressure level where the moist adiabat achieves the required temperature, we argue that the measured methane fractionation constrains the outflow level for a deep convective event. Observations with a factor of at least 4–6 times larger signal-to-noise are required to detect this amount of fractionation, depending on the altitude range over which the outflow from deep convection occurs.

Role of deep convection on anthropogenic CO2 sequestration in the Gulf of Lions (northwestern Mediterranean Sea)

The most active deep convection area in the western Mediterranean Sea is located in the Gulf of Lions. Recent studies in this area provides some insights on the complexity of the physical dynamics of convective regions, but very little is known about their impacts on the biogeochemical properties. The CASCADE (CAscading, Surge, Convection, Advection and Downwelling Events) cruise, planed in winter 2011, give us the opportunity to compare vertical profiles of properties sampled either during stratified conditions or after/during a convection event. In the present study, we focus on the distributions of the carbonate system properties (mainly total alkalinity, AT; and total dissolved inorganic carbon, CT) because, in the context of the climate change, deep convection areas are suspected to significantly increase the sequestration of anthropogenic CO2 (CANT). Given its limited size, the impact of the Mediterranean Sea on the global carbon budget is probably minor but this marginal sea can be used as a laboratory to better understand carbon sequestration and its transfer to the basin interior by deep convection processes. Distributions of AT and CT, both measured from bottle samples, and that of CANT (estimated with the TrOCA approach) are first analyzed in the light of other key properties (salinity, temperature, and dissolved oxygen). An objective interpolation procedure is then applied to estimate CT and AT from CTD measured properties. With this procedure, the vertical resolution goes from a maximum of 32 samples per station to one property estimate every meter (more detailed distributions are obtained). Results provide arguments to conclude that CANT is rapidly transferred to the deepest layer due to deep convection events. During deep convection events, the increase of CANT in the water column is positively correlated to that of potential density and oxygen content. The challenge of quantifying the amount of sequestered carbon is however not resolved due to the complexity and the highly dynamical nature of the convective regions. Deep convection in the Gulf of Lions, in parallel with cascading along the continental slope, could thus potentially explain the very high levels of both CANT and acidification estimated in the deep layers of the western Mediterranean Sea.