Decreasing Temperature Research Articles

Influence of water saliny changes on the operation of the RAS biological treatment system under low temperature conditions

In fish-breeding circulation systems the change-over of a biofilter from operation in fresh water conditions to sea water conditions (or vice versa) requires a smooth gradual transition. However, a one-time water change is feasible faster and technologically easier. This determined the relevance of the study. The goal was to determine the influence of one-time water salinity changes (sea to fresh and fresh to sea) on the ability of the activated sludge biocenosis of biofilters to maintain or restore its activity in a cold-water RAS. Six model biofilters were filled with sea water and six with fresh water. With a simultaneous decrease of water temperature from 21 to 9 °C, at the first stage a start-up period of biological treatment was carried out. At the second stage — in a stable operating regime, sea water was simultaneously changed to fresh water, and fresh water to sea water. Concentrations of ammonium, nitrites and nitrates were determined at the start of experiment, then on the next day after a bacterial culture and ammonia as a source of ammonium nitrogen adding, and then — 2 times a week. A steady decrease in the concentration of ammonium in water to 0.2 mg/l, nitrite — to 0.3 mg/l was considered as the indicator of the end of each stage. The duration of the start period of biological treatment in both fresh and sea water was approximately the same and amounted to 138 and 134 days, respectively. With the simultaneous change of sea water to fresh or fresh water to sea, the complete destruction of the biofilter activated sludge biocenosis didn’t happen, that indicated by the continuing increase of the nitrates concentration. However, the ability of the biofilter biocenosis to purify circulating water from ammonia nitrogen and nitrites naturally decreases with the following gradual performance restoration. The adaptation of biofilter biocenosis to work under conditions of rapid desalination was 1.5 times faster than the adaptation of biocenosis to rapid salination.

Large coercivity and enhanced magnetization in La-substituted Sm6Mn23 alloys

The magnetic properties of Sm6Mn23-based alloys are still not fully understood for their high complexity in magnetic and crystallographic structures. This work presents studies of the structure and magnetic properties of Sm6Mn23 and Sm5LaMn23 alloys. The results show that both the binary and La-substituted ternary alloys crystallize in a cubic Th6Mn23 type structure (Fm-3m) with trace amount of Mn impurities. The lattice parameter of Sm5LaMn23 is slightly larger than that of Sm6Mn23. The Curie temperature of Sm5LaMn23 is ∼403 K, which is lower than that of Sm6Mn23. A field-dependent magnetic transition was observed in Sm5LaMn23, which shows a decreasing temperature at which Sm5LaMn23 exhibiting maximal magnetization with increasing field, indicating a suppression of the antiferromagnetic coupling of the rare earth and Mn moments under applied field. Large coercivities up to 0.74 T and 1.2 T are observed in Sm5LaMn23 bulk alloys and powders, respectively. The saturate magnetization, the remanent magnetization, and the coercivity of Sm5LaMn23 at 5 K are much higher than that of Sm6Mn23. The ball-milled Sm5LaMn23 powders exhibit significantly enhanced coercivity and magnetization. The refinement of the grain size during ball-milling results in the enhanced coercivity. The magnetic purification of the powders and possible local ferromagnetic configuration of the surface Mn atoms may result in the enhanced magnetization.

Ferroelectric Smectic C Liquid Crystal Phase with Spontaneous Polarization in the Direction of the Director.

In the previous study, the existence of an unidentified ferroelectric smectic phase is demonstrated in the low-temperature region of the ferroelectric smectic A phase, where the layer spacing decreases with decreasing temperature. In the present study, the phase is identified by taking 2D X-ray diffraction images of a magnetically oriented sample while allowing it to rotate and constructed a 3D reciprocal space with the sample rotation angle as the third axis for the whole picture of the reciprocal lattice vectors originating from the smectic structure. Consequently, circular diffraction images are obtained when the reciprocal lattice vectors are evenly distributed on the conical surface at a certain inclination angle in the reciprocal space. This result provides clear evidence that the phase in question is smectic C. The polarization properties also showed that the observed smectic C phase has spontaneous polarization in the direction parallel to the director and is identified as ferroelectric smectic C. These results provide a new type of classification for liquid crystalline phases that has been established over many years and is a significant contribution to the basic science of soft matter research.

Isothermal compressibility and water self-diffusion coefficient in supercooled salt aqueous solutions using the Madrid-2019 model

The isothermal compressibility and self-diffusion coefficient of water in Li + , Na + , K + , Mg 2 + and Ca 2 + chloride and sulfate salts aqueous solutions is calculated by means of molecular simulations using the Madrid-2019 force-field, that uses TIP4P/2005 model for water and assigns scaled charges for ions. Our simulations predict that the isothermal compressibilities of these salts retain the anomalous behaviour of water, i.e. compressibility increases as temperature decreases, contrary to the behaviour of normal liquids. A maximum in the isothermal compressibility, analogous to that of pure water, is observed for some of the salt solutions. For the 1 m NaCl solution, simulations are performed at several pressures up to 1000 bar to estimate the location of the second critical point. We estimate that the liquid-liquid critical point is located at 190 K and 1000 bar, i.e. it is shifted to slightly higher temperatures and lower pressures with respect to the most accurate estimation of its location in pure TIP4P/2005 water (172 K and 1861 bar). Regarding the self-diffusion of water, all salts increase water mobility in the very supercooled regime (at temperatures within 200–230 K), with K 2 SO 4 producing the largest increase in water mobility, while MgCl 2 and MgSO 4 are the least effective in enhancing the self-diffusion coefficient of water.

Effect of Isotropic and Anisotropic Permeability on Gas Production Behavior of Site NGHP-01-10D in Krishna-Godavari Basin

This study reports an investigation into both isotropic and anisotropic permeability effects on gas production behavior during depressurization-induced natural gas hydrate dissociation at site NGHP-01-10D in the Krishna-Godavari basin. Numerical simulations were performed on a reservoir-scale model incorporating a single vertical well, examining different scenarios of permeability ratios (rrz). The investigation assessed gas and water production rates, cumulative production volumes, the gas-to-water ratio, and the spatial distribution of reservoir parameters throughout a production duration of 3 years. The findings indicate that permeability anisotropy has a substantial impact on hydrate dissociation and gas recovery. For rrz > 1, horizontal pressure propagation was promoted and gas production increased. For example, at t = 1100 days, the total gas production improved from 7.88 × 105 ST m3 for rrz = 1 to 55.9 × 105 ST m3 for rrz = 10. For rrz < 1, vertical pressure propagation resulted in higher water production with concomitantly lower rates of gas production rates. Spatial distribution analysis revealed that higher rrz values led to more extensive radial propagation of pressure drop, temperature decrease, gas saturation increase, and hydrate dissociation. The study concludes that higher horizontal permeability enhances depressurization effects, resulting in higher gas production rates and more favorable gas-to-water ratios.

Numerical and experimental study on corrosion mechanism of the water-oil two-phase flow in the atmospheric tower top system

The atmospheric tower is the main component of the crude oil refining units and is a critical area of concern due to the risk of corrosion failure. Research on the corrosion mechanism and risk protection of atmospheric tower top systems plays a vital role in the safe operation of refineries. In this paper, the water-oil two phase process flow of the atmospheric tower top system was simulated by Aspen software. A corresponding flow corrosion simulation experiment was designed according to the main characteristic parameters of the simulated stream. The experimental results under varying temperature and impact angle conditions were analyzed by using microanalysis technology and CFD simulation methods. The process and mechanism of corrosion failure of tower top system under ammonia salt and dew point corrosion environment are revealed in physicochemical aspects. The results show that the corrosion rate was highest at the dew point temperature, but as the temperature decreases, the corrosion products adsorbed and accumulated on the surface are more difficult to remove from the surface, which slows down the corrosion rate. When the impact angle increased from 0° to 60°, the increment of the surface fluid impact force and turbulence intensity makes the corrosion products easier to be stripped off, which enhances the mass transfer efficiency between the corrosive medium and the surface to accelerate the corrosion rate. Different phase states and flow modes affected the morphology of corrosion pits on the surface. The depth and size of the pits in only water phase corrosion were larger than those in the two-phase flow corrosion, Additionally, as the impact angle increased from 0°, the morphology of pits changes from a relatively flat pattern to a more undulating shape. The research results reveal the characteristics of the main corrosion types occurring in the atmospheric tower top system of the oil refining industry, and provide a reference for corrosion risk protection methods.

Improving Yield and Quality of ‘Balady’ Mandarin Trees by Using Shading Techniques and Reflective Materials in Response to Climate Change Under Flood Irrigation Conditions

Considering climate change predictions, it is logical to anticipate detrimental effects on the mandarin tree, an essential citrus crop. Therefore, scientists should promptly focus on developing methods to enhance its resistance to climatic stress effects such as sunscald. This study assesses the strategies employed in ‘Balady’ mandarin trees when covered by shading nets of varying colors and percentages (white 50%, green 50% or 63%, black 50% or 63%), as well as the application of reflective materials (kaolin at 4% and CaCO3 at 3%) on the micro-climate of orchards, leaf, and fruit surface temperatures, fruit sunburn%, productivity, and fruit quality. The results indicated that shade nets effectively reduced temperature and enhanced humidity, especially during the period from June to September, when compared to open-field treatments. Black shade nets, particularly those with a shading level of 63%, demonstrated the most notable decrease in canopy temperature and an elevation in humidity, surpassing the performance of green and white shade nets. The present study found that shade nets and reflecting materials like kaolin and calcium carbonate significantly reduced fruit sunburn. Trees without shade had a sunburn rate of 8.74%, while those with shade treatments suffered no sunburn. Kaolin foliar spray at a concentration of 4% and calcium carbonate at a concentration of 3% reduced sunburn incidence to 3.64% and 7.32%, respectively. These treatments also reduced the intensity of sunburn. All treatments increased fruit yield % compared to the control and yield efficiency (kg/m2), especially the trees covered with white shade net of a 50% shading rate provided the highest values (43.70 and 40.17%) and (5.24 and 5.47 kg/m2) compared to other treatments in both seasons, respectively. Trees covered with a white shade net of a 50% shading rate, followed by a green shade net of 50% and a 63% shading rate, as well as a black shade net of 50% and a 63% shading rate, tended to improve the physical and chemical fruit properties. Therefore, it could be recommended that trees be covered with a white shade net of a 50% shading rate or a green shade net of a 50 and 63% shading rate in summer months due to its beneficial impact on mitigating fruit sunburn damage and enhancing the productivity and quality of ‘‘Balady’’ mandarin trees. Hence, shade nets can be a beneficial technology to protect citrus fruits from sunburn without affecting fruit quality in commercial citrus farms.

Theoretical analysis of water-droplet condensation and evaporation in prescribed environment with radiation

Abstract A quasi-explicit algebraic solution of the problem of quasi-steady water droplet heat- and mass-transfer with condensation or evaporation in a prescribed environment including radiation has been obtained. The solution is based on the mass-fraction form of Fick’s law of species diffusive mass transport, which allows accounting for variation in gas density through the diffusion layer surrounding the droplet. A new term, the average vapor supersaturation through the diffusion layer, has been included that allows the model to be extended to environmental conditions significantly outside those for which it is theoretically derived (dilute or near-saturation), even to conditions of relatively high temperature, low relative humidity, and low pressure. The latter two have atmospheric significance because evaporative cooling can induce significant decrease in droplet temperature and possibly induce freezing. Basic modeling assumptions are confirmed by comparison with time-dependent temperature and evaporation-rate measurements of a laboratory laser-heated droplet. Accuracy of the new model is assessed by comparison with exact equations. For temperatures between −30 and 0°C and negligible radiation, relative-error magnitudes in droplet temperature and evaporation rate are less than 5%, even for relative humidity down to 10% and pressure down to 60 kPa. This represents an improvement in accuracy over the conventional model, in which property variations of density and supersaturation through the diffusion layer are not taken into account. Differences in predicted evaporation rates between the mass-fraction and the more common partial-density Fick’s laws, which can be significant (>10% above 70% relative humidity) in coupled, implicit equations, are shown to be made negligibly small (<0.5%) by linearizing about the saturation state.

Investigation of Structural, Elastic and Magnetic Properties of CoCr2-xZrxO4 Nanoparticles.

This study investigates the impact of zirconium substitution on the structural, elastic and magnetic properties of CoCr2O4 nanoparticles. A series of CoCr2-xZrxO4 nanoparticles, x = 0.00, 0.05, 0.10, 0.15 and 0.20, are synthesized via the co-precipitation method. X-ray diffraction (XRD) patterns affirm the formation of single-phase cubic structure with the space group Fd3m. Special attention is given to accurately calculating the average crystallite size (D) and lattice parameter (a) using Williamson-Hall (W-H) analysis and the Nelson-Riley (N-R) extrapolation function, respectively. The increase in Zr4+ content leads to a reduction in crystallite size and an increase in the lattice parameter. Elastic properties are estimated from force constants and the lattice constant, determined from FTIR and XRD, respectively. The observed changes in the elastic constants are attributed to the strength of interatomic bonding. The stiffness constants decrease, while Poisson's ratio increases with increasing Zr4+ content, reflecting the increase in the ductility of the prepared samples. As the Zr4+ content increases, the stiffness constants decrease, and Poisson's ratio increases, reflecting enhanced ductility of the samples. Furthermore, as Zr4+ content rises, Young's modulus, the rigidity modulus and Debye temperature decrease. The magnetic hysteresis loop measurements are carried out at room temperature using a vibrating sample magnetometer (VSM) over a field range of 25 kg. Unsubstituted CoCr2O4 exhibits ferrimagnetic behavior. As Zr4+ content increases, saturation magnetization (Ms) and magnetic moment decrease, while remanent magnetization (Mr) and coercivity (Hc) initially decrease up to x = 0.10, then increase with further increases in x. The novel key of this study is how Zr4+ substitution in CoCr2O4 nanoparticles can effectively modify their elastic moduli and magnetic properties, making them suitable for various applications such as flexible electronics, protective coatings, energy storage components and biomedical implants.

Global and Local Shear Behavior of the Frozen Soil–Concrete Interface: Effects of Temperature, Water Content, Normal Stress, and Shear Rate

The interface between soil and concrete in cold climates has a significant effect on the structural integrity of embedded structures, including piles, liners, and others. In this study, a novel temperature control system was employed to conduct direct shear tests on this interface. The test conditions included normal stress (25 to 100 kPa), temperature (ranging from 20 to −6 °C), water content (from 10 to 19%), and shear rates (0.1 to 1.2 mm/min). Simultaneously, the deformation process of the interface was continuously photographed using a modified visual shear box, and the non-uniform deformation mechanism of the interface was analyzed by combining digital image correlation (DIC) technology with the photographic data. The findings revealed that the shear stress–shear displacement curves did not exhibit a discernible peak strength at elevated temperatures, indicating deformation behavior characterized by strain hardening. In the frozen state, however, the deformation softened, and the interfacial ice bonding strength exhibited a positive correlation with decreasing temperature. When the initial water content was 16% and the normal stress was 100 kPa, the peak shear strength increased significantly from 99.9 kPa to 182.9 kPa as the test temperature dropped from 20 °C to −6 °C. Both shear rate and temperature were found to have a marked effect on the peak shear strength, with interface cohesion being the principal factor contributing to this phenomenon. At a shear rate of 0.1 mm/min, the curve showed hardening characteristics, but at other shear rates, the curves exhibited strain-softening behavior, with the softening becoming more pronounced as shear rates increased and temperatures decreased. Due to the refreezing of interfacial ice, the residual shear strength increased in proportion to the reduction in shear rate. On a mesoscopic level, it was evident that the displacement of soil particles near the interface exhibited more pronounced changes. At lower shear rates, the phenomenon of interfacial refreezing became apparent, as evidenced by the periodic changes in interfacial granular displacement at the interface.

X-ray diffraction and quasielastic neutron scattering studies of the structure and dynamic properties of water confined in ordered microporous carbon pores

The structure and dynamic properties of capillary-condensed water confined in ordered microporous carbon (OMC) of pores diameter 18.7 Å are investigated over a temperature range of 200–300 K by adsorption/desorption isotherms, X-ray diffraction (XRD), and quasielastic neutron scattering (QENS). The nitrogen adsorption/desorption isotherm of OMC pores at 77 K exhibits an I-type pattern. The water adsorption/desorption isotherm of OMC pores at 298 K is of type V. The XRD data on water confined in OMC reveal that the tetrahedral network structure of water is perturbed from the bulk water structure, but not to such an extent as found for water confined in MCM-41 and Ph-PMO previously reported. With decreasing the temperature, the ∼2.8 Å peak shifts to shorter distances, while the second-neighbor H2O– H2O interaction distances gradually increase from 3.95 Å and 4.49 Å to 4.43 Å and 4.84 Å, indicating a tendency to form a more tetrahedral-like hydrogen-bonded water structure at subzero temperatures. Below 230 K, the hexagonal ice Ih was partially formed in OMC pores. The QENS spectra were analyzed using a jump-diffusion model to translate water molecules. The translational diffusion of water molecules in OMC pores is comparable to that of bulk water at 300 K and higher than that in MCM-41, and the mobility slows as the temperature decreases. The elastic incoherent structure factor (EISF) analysis found evidence for immobile and mobile fractions of confined water. The mobile fraction exhibited jump diffusion, with a jump length consistent with a sphere of confinement radius of 4–8 Å. The results obtained in the present work are compared with those reported for MCM-41 with a hydrophilic interface and Ph-PMO with an amphiphilic interface, and the influence of interface effect on local structure and dynamic properties of confined water is discussed.

An efficient strategy based on proper orthogonal decomposition for rapid determination of the location and rate of water vapor humidification in aircraft cabins

Currently, the air in commercial aircraft cabins during flights routinely exhibits extremely low relative humidity. But none of the previously published studies have addressed optimization of the humidification parameters in order to, create the desired humidity distributions in aircraft cabins at minimal cost. This study proposed an efficient strategy to accomplish the task. Under this strategy, a database of various potential humidification locations for aircraft cabins is first constructed. One scenario in the database is then selected by computational fluid dynamics (CFD)-based enumeration. Next, with the humidification location as prior information, the humidification rate and the air-supply temperature from the main ventilation system can be inversely designed by proper orthogonal decomposition. The above strategy was applied to a three-dimensional aircraft cabin model for the validated CFD cases. The results showed that an appropriate humidification for the cabin might both improve the thermal comfort of passengers and increase the humidity levels in the cabin; a decrease of the air-supply temperature from the main ventilation system would be beneficial in reducing the water vapor humidification rate required for passengers and allowing a higher humidification rate to be tolerated for the cabin walls. The parameters that improved the cabin air environment without significant moisture accumulation on walls were also provided by the proposed strategy. Compared with the full CFD simulation method, the proposed strategy is capable of providing accurate ranges of parameters while reducing the computing time by more than 95%, which demonstrates its competitive prospects.

Effects of Dihydroquercetin on the Intensity of Oxydative Stress in Rat Liver Mitochondria at Hypothermia

A decrease in body temperature in homeothermic animals can cause a state of the body called hypothermic. It is accompanied by the development of a number of pathological processes, many of which are associated with mitochondrial dysfunction and the development of oxidative stress. In connection with the widespread introduction of hypothermia into medical practice, the question of the possibility of a regulatory influence on the proxidant-antioxidant status of mitochondria at low body temperatures remains relevant. In recent years, plant polyphenols, in particular dihydroquercetin (DHQ), have gained wide popularity as therapeutic agents with antioxidant and membrane protective effects. In this work, we investigated the effects of DHQ on the intensity of oxidative stress in rat liver mitochondria under moderate hypothermia. It was found that a course (5 days) oral administration of DHA at a dose of 100 mg/kg significantly reduces the levels of LPO and OMP products in the liver mitochondria of control rats, increasing the content of non-enzymatic components of the thiol-disulfide antioxidant system`s. DHQ effectively protects liver mitochondria from the development of oxidative stress during hypothermia, as evidenced by a significant decrease (and in some cases, complete normalization) in the levels of diene conjugates, MDA, Schiff bases and carbonyl groups in a group of animals subjected to hypothermia with prior administration of this polyphenol. At the same time, DHQ significantly increases the levels of glutathione and vitamin E, and also normalizes the content of thiol groups in mitochondrial proteins. In vitro, DHQ exhibits a dose-dependent antioxidant effect, suppressing OMB in mitochondria incubated in Fenton's medium (IC50 = 0.160 mg/ml).

Fin angles optimization of water-cooled plate-fin heat sink based on anisotropic Darcy–Forchheimer theory

Flat heat sinks are devices for efficient heat dissipation and are important components in manufacturing. For example, in precision glass molding, it is utilized as a cooling plate contributing to improve the quality of the product by reducing residual stress and shape deviation, during the gradual cooling phase. In this study, we attempted to achieve precise temperature design of the cooling plate using variable lattice optimization. Fins allow for controlling the flow direction and achieving efficient heat transfer. Therefore, elliptical cylindrical fins were adopted as lattice unit cells, increasing the design freedom of the flow field. To account for the asymmetric flow field within the unit cell, we introduced an asymmetric tensor for the coefficients of the effective physical properties in the Darcy–Forchheimer equation. The proposed method's effectiveness and validity are discussed through numerical calculations with effective material properties, reproduced detailed shapes, and experimental verification. The optimization aiming to minimize the average temperature yielded a numerical simulation temperature decrease of 24.6 % and an experimental temperature decrease of 14.1 % compared to the benchmark model.

Investigating the impacts of heat sink design parameters on heat dissipation performance of semiconductor packages

This study investigates the impacts of various heat sink design parameters on the thermal dissipation performance of semiconductor packages using a heat sink as the thermal solution. A multiphase finite volume model was developed for heat transfer simulations to determine the heat sink and junction temperatures of the semiconductor assembly. Additionally, a heat transfer experiment was conducted to measure these temperatures over time. The numerical predictions closely matched the experimental results, with a maximum disparity of 0.26 % for junction temperature and 0.42 % for heat sink temperature, confirming the reliability of the numerical model. The results revealed that pin fin heat sinks demonstrated marginally superior thermal performance, reducing the junction temperature by 0.05 % compared to parallel heat sinks. Increasing the base area from 20x20 mm² to 50x50 mm² resulted in a significant 31.64 % reduction in junction temperature and a corresponding reduction in heat sink temperature from 60.41 °C to 36.42 °C. Extending fin height from 10 mm to 50 mm led to an 18.73 % decrease in junction temperature and a reduction in heat sink temperature from 46.07 °C to 34.56 °C. Enhancing the base thickness from 2 mm to 15 mm achieved a 24.35 % reduction in junction temperature and a decrease in heat sink temperature from 63.2 °C to 44.05 °C. The study concludes that optimizing these design parameters can substantially enhance heat dissipation, improving the reliability and efficiency of semiconductor devices.

Theoretical Investigation of Rate Coefficients and Dynamical Mechanisms for N + N + N Three-Body Recombination Based on Full-Dimensional Potential Energy Surfaces

Three-body recombination reactions, in which two particles form a bound state while a third one bounces off after the collision, play significant roles in many fields, such as cold and ultracold chemistry, astrochemistry, atmospheric physics, and plasma physics. In this work, the dynamics of the recombination reaction for the N3 system over a wide temperature range (5000–20,000 K) are investigated in detail using the quasi-classical trajectory (QCT) method based on recently developed full-dimensional potential energy surfaces. The recombination products are N2(X) + N(4S) in the 14A″ state, N2(A) + N(4S) in the 24A″ state, and N2(X) + N(2D) in both the 12A″ and 22A″ states. A three-body collision recombination model involving two sets of relative translational energies and collision parameters and a time-delay parameter is adopted in the QCT calculations. The recombination process occurs after forming an intermediate with a certain lifetime, which has a great influence on the recombination probability. Recombination processes occurring through a one-step three-body collision mechanism and two distinct two-step binary collision mechanisms are found in each state. And the two-step exchange mechanism is more dominant than the two-step transfer mechanism at higher temperatures. N2(X) formed in all three related states is always the major recombination product in the temperature range from 5000 K to 20,000 K, with the relative abundance of N2(A) increasing as temperature decreases. After hyperthermal collisions, the formed N2(X/A) molecules are distributed in highly excited rotational and vibrational states, with internal energies mainly distributed near the dissociation threshold. Additionally, the rate coefficients for this three-body recombination reaction in each state are determined and exhibit a negative correlation with temperature. The dynamic insights presented in this work might be very useful to further simulate non-equilibrium dynamic processes in plasma physics involving N3 systems.

Late-stage evolution of hypogene caves at Tyuya-Muyun (Kyrgyzstan): Quantitative insights from mineral deposits

The Tyuya-Muyun massif in SW Kyrgyzstan hosts a number of caves some of which contain Ra- and U-bearing minerals that were extensively mined in the early 20th century. Previous studies have suggested that the caves of the Tyuya-Muyun have experienced a complex speleogenetic history, including epigene and hypogene processes. Here, we reconstruct the late stages of hypogene processes by studying subaqueous (calcite and barite spars, cave clouds), near-water table (rafts, folia) and vadose (flowstone) mineral deposits in Great Barite and Surprise caves. We determined the chronology (230Th dating), stable isotope composition (δ18O, δ13C and Δ47), and formation temperature (fluid inclusion microthermometry and Δ47) of these minerals and reconstructed the oxygen isotopic composition of the paleo-water (δ18Ow). In contrast to previous hypotheses about cave evolution, we found no evidence of an initial epigenic karst phase. The earliest mineral deposits suggest already hydrothermal conditions, with calcite and barite forming at ∼40–50 °C prior to 600 ka. Cave clouds in Great Barite Cave mark the beginning of the lowering of the groundwater table and also record a decrease in water temperature from 29.7 ± 8.3 °C to 12.7 ± 5.6 °C, as shown by Δ47 thermometry. The latter temperature remained stable, within analytical uncertainties, during the past 600 ka, as indicated by Δ47 results of near-water table and vadose speleothems in Surprise Cave. At the same time, the decrease in δ18Ow suggests a reduced contribution of thermal water and an increased input of colder meteoric water. By around 540–450 ka Surprise Cave emerged from the phreatic zone, as indicated by 230Th ages of the highest folia and flowstone. This lowering of the water table continued until 84 ka and may have been related to the final uplift phase of the Tyuya-Muyun massif and the concomitant incision of the Aravan River forming the Dangi Gorge.

Green space-building integration for Urban Heat Island mitigation: Insights from Beijing's fifth ring road district

In this research, we delve into the complex arrangement of urban landscapes, where green spaces and buildings are not merely co-existing but are interwoven into a cohesive fabric that shapes the thermal environment. Our approach transcends the conventional methods of analysis, which typically isolate the roles of greenery or built environments. Instead, we adopt a synergistic perspective that recognizes the collective influence of these landscape constituents on the urban thermal pattern. Key insights are: (1) A linear decrease in average land surface temperature with increasing green space coverage is observed. However, substantial temperature variations (up to 8 °C) within the same coverage interval highlight the significant impact of built-up pattern on thermal conditions; (2) High Building Height and Floor Area Ratio, and low Building Coverage Ratio and Sky View Factor, are linked to cooler temperatures in areas with up to 50 % green space; (3) The study suggests that low-temperature areas can inform the adjustment of built-up patterns in high-temperature areas, offering a strategy for thermal environment optimization within specific green space coverage intervals. This research contributes insights into the integrated planning of green spaces and buildings, with implications for urban development and renewal initiatives aiming to enhance the urban thermal environment.

A zircon case for super-wet arc magmas

Arc magmas have higher water contents (2-6 wt.% H2O) than magmas generated in other tectonic environments, with a growing body of evidence suggesting that some deep arc magmas may be ‘super-wet’ (>6 wt.% H2O). Here, we use thermodynamic modelling to show that the behaviour of zirconium during magmatic differentiation is strongly sensitive to melt water contents. We demonstrate that super-wet magmas crystallise zircon with low, homogeneous titanium concentrations (75th percentile <10 ppm) due to a decrease in zircon saturation temperatures with increasing melt H2O. We find that zircon titanium concentrations record a transition to super-wet magmatism in Central Chile immediately before the formation of the world’s largest porphyry copper deposit cluster at Río Blanco-Los Bronces. Broader analysis shows that low, homogeneous zircon titanium concentrations are present in many magmatic systems. Our study suggests that super-wet magmas are more common than previously envisaged and are fundamental to porphyry copper deposit mineralisation.

In vivo pharmacokinetic, pharmacodynamic and brain concentration comparison of fentanyl and para-fluorofentanyl in rats.

In 2022, para-fluorofentanyl (pFF) rose to the 6th most reported drug and the most reported fentanyl analog in the United States according to the Drug Enforcement Administration (DEA). pFF differs from fentanyl by the addition of a single fluorine group. To date, pFF has not been extensively evaluated in vivo and is frequently seen in combination with fentanyl. In the present study, the pharmacodynamic (PD) and pharmacokinetic (PK) properties and brain region-specific concentrations of pFF were evaluated in male Sprague-Dawley rats and compared to fentanyl. A 300μg/kg subcutaneous dose of fentanyl or pFF was administered to assess PD and PK parameters as well as brain region concentrations. PD parameters were evaluated via a tail flick test to evaluate analgesia and core body temperature to measure hypothermia, a surrogate marker of overall opioid toxicity. Fentanyl and pFF were found to be equally active at the tested dose in terms of tail flick response with both compounds producing an analgesic response that lasted up to 240min post-drug treatment. pFF induced a significantly greater hypothermic effect compared to fentanyl with a maximum temperature decrease of -5.6 ℃. Plasma PK parameters (T1/2, AUC, etc.) did not differ between fentanyl and pFF. However, pFF concentrations in the medulla, hippocampus, frontal cortex and striatum were more than two times the fentanyl concentrations. The increase in brain concentrations and greater hypothermic effect suggests that pFF is potentially more dangerous than fentanyl.