Decrease In Compressive Strength Research Articles

Impact of adding waste polyethylene (PE) and silica fume (SF) on the engineering properties of cement mortar

Impact of adding waste polyethylene (PE) and silica fume (SF) on the engineering properties of cement mortar

The Influence of Recycled Coarse Aggregate Content on the Properties of High-Fly-Ash Self-Compacting Concrete

In Vietnam, solid waste from construction activities significantly impacts environmental pollution. Recycled concrete aggregate (RCA), derived from waste concrete, can serve as a coarse aggregate in concrete production. However, compared to natural aggregates, RCA exhibits distinct characteristics, including lower strength, higher water absorption, and an increased angular and rough surface. These properties may influence concrete’s workability, compressive strength, and durability. This research investigates the influence of RCA on the properties of High-Fly-Ash Self-Compacting Concrete (SCC). The study explores various replacement levels of natural coarse aggregate with RCA (0%, 50%, 75%, and 100%), alongside a 50% volume fraction of fly ash. Key concrete properties evaluated include workability, compressive strength, flexural strength, and chloride ion permeability. The findings reveal that using 100% RCA in combination with a high fly ash content (50%) produces SCC that meets workability requirements according to EFNARC standards. However, there are trade-offs: the compressive strength decreases by 4.61%, the flexural strength decreases by 3.1%, and chloride ion permeability increases by 57.57% compared to the control sample (using natural aggregates). Notably, the chloride ion permeability of SCC using 100% RCA falls into the category of low permeability. Doi: 10.28991/CEJ-SP2024-010-04 Full Text: PDF

Experimental and Numerical Simulation Investigation of Cement Sheath Integrity during Multi-Stage Fracturing in Offshore Tight Oil Reservoir

The integrity of the cement sheath is susceptible to failure during multi-stage fracturing. In this study, the failure mechanisms of cement sheath integrity during multi-stage fracturing in the A offshore tight oil reservoir wells were investigated. The cement samples were subject to triaxial compression test (TCT), triaxial cyclic loading test (TCLT), and permeability test. A full-scale device was constructed for cement sheath integrity experiments. Additionally, a 3-D finite element model was developed to simulate the interface debonding and the subsequent growth of micro-annuli throughout multi-stage fracturing. The results revealed that TCLT induced cumulative plastic deformation in the cement samples, resulting in a 10.7% decrease in triaxial compressive strength, an 8.3% decrease in elastic modulus, and a 150% increase in permeability. Despite these significant variations, no serious damage was caused to the cement sheath matrix. It was observed that gas leakage occurred at the 8th, 10th, and 14th cycles under cyclic loading with upper limits of 70 MPa, 80 MPa, and 90 MPa, respectively. After 15 cycles, the experimentally measured widths of micro-annuli were 117 μm, 178 μm, and 212 μm, which were in good agreement with simulation results of 130 μm, 165 μm, and 205 μm, respectively. These findings elucidate the causes of cement sheath integrity failure, providing insights into the failure mechanisms of cement sheath integrity during multi-stage fracturing.

Mechanics and permeability properties of ecological concrete mixed with recycled engineering muck particles

The excavation of construction foundation pits, tunnels, channels, and other projects generates a significant volume of engineering muck, posing challenges in management. Prolonged accumulation of this muck can lead to environmental pollution. The effective recycling of this type of construction waste is crucial for the advancement of a circular economy, necessitating immediate attention to research and solutions. In this study, a novel method is introduced for the preparation of low-carbon and environmentally friendly ecological concrete. This method involves the utilization of recycled engineering muck particles to substitute a portion of the natural aggregate and enables the comprehensive recycling of engineering muck. Subsequently, the mechanical and permeability properties of ecological concrete under varying muck particle content and porosity conditions are analyzed through experiments, taking into account the impact of relative average pore diameter and pore tortuosity. A predictive model has been developed for the tortuosity of pore channels in ecological concrete, taking into account effective porosity and average pore diameter. The enhanced Kozney-Carman model is employed to describe the correlation between pore properties and hydraulic conductivity. The findings indicate that a composite curing agent is formed by combining ordinary Portland cement with a hydrophilic polyurethane solution. This composite curing agent demonstrates superior performance compared to pure cement in the solidification of engineering muck. As the replacement rate of unsintered recycled residue particles increases, the porosity of concrete may increase by up to 29.7 %. This results in enhanced permeability characteristics but a decrease in compressive strength. In contrast to lightweight aggregates manufactured through the sintering process, the carbon emissions of unsintered recycled residue particles are reduced by 57.7 %. This study provides suggestions for the repurposing of construction waste and contributes to the advancement of sustainable practices within the concrete production sector.

Effects of carbonation curing on chemical attack in cement paste incorporating liquid-crystal display glass powder as a partial binder replacement

This study investigates the chemical resistance of cement paste by incorporating liquid-crystal display (LCD) glass powder as a partial replacement for cement. The samples, cured under water and carbonation, were subjected to adverse chemical attacks over a period of up to 90 days, using MgSO4 and H2SO4 for the sulphate attack and acid attack, respectively. The results demonstrate a decrease in compressive strength by upto 14.63% and 32.32% for water- and carbonation-cured samples, respectively, and an increase in carbonation degree by upto 100% with the incorporation of glass powder at 28 days. Under sulphate attack, water curing and carbonation curing displayed strength increase of 21.24–36.13% and 7.56–8.06%, respectively, at 90 days. However, carbonation-cured samples experienced greater leaching of silica and calcium. The compressive strength decreased with acid attack duration, with glass powder incorporation mitigating strength loss in carbonation-cured samples. At 30 days, with an incorporation rate of 30% glass powder, the strength loss was reduced by 37.66% for the carbonation-cured samples. The enhanced resistance with incorporation of glass powder was also evident from mercury intrusion porosimetry results that indicated decreased intrusion levels. Visual inspection revealed a different consistency of white substance deposition, suggesting resistance mechanisms differed between curing methods.

Development and characterization of a composite material with geopolymer matrix obtained by incorporation of microparticles from plastic bottles

The composite material with a geopolymer matrix of 7 M molarity, obtained by incorporating microparticles from plastic bottles is developed and characterized in the present paper. To do this, we made cylindrical specimens whose the diameters are the half of their heights and stored them at a temperature of (31±2°C). The compression test using a hydraulic press is carried out, as well as the thermal characterization test using a device respecting the experimental method of the asymmetric hot plane, which was used to determine the thermal conductivity, the volumetric heat capacity, the effusivity and the diffusivity. Then optical characterization tests on hardened samples were carried out, namely chemical analyses of the composition of the kaolin, and particle size characterization of the raw microscopic imaging of the specimens. The results found showed that as the amount of polyethylene terephthalate increases, the compressive strength decreases by 33.65 % for 10%polyethylene terephthalate and 67.77 % for 20 % polyethylene terephthalate. According to the thermal conductivity, it improves with the percentage of polyethylene terephthalate added as: at 10% it is 1.19Wm−1K−1 and at 20%, one has 0.595Wm−1K−1; similarly for effusivity where we obtained 1376.05 JK−1m−2s−1/2 and 560.81 JK−1m−2s−1/2 for 0 and 20% respectively. According to these results, the use of polyethylene terephthalate aggregates as a partial substitute of aluminosilicate raw material for the development of a composite can be a good alternative for recycling plastic bottle waste. The composite obtained could be used for the manufacture of ceiling lights and brick facings, and therefore would significantly reduce the amount of waste plastic produced every day in environment.

Study on the evolution patterns of concrete lining’s physical and mechanical properties under sulfuric acid corrosion conditions

During operation, deep water storage and drainage tunnels may face sulfuric acid corrosion resulting from microbiologically induced chemical reactions. In this study, sulfuric acid corrosion experiments were performed on C60 concrete specimens with steel fiber volume ratios of 0% (plain) and 1% using a sulfuric acid solution with an initial pH of 1. For one-face corrosion, five faces of cubic concrete samples were coated with exposed resin, leaving only one face exposed to sulfuric acid. For all-face corrosion, all faces were exposed to sulfuric acid. Concrete corrosion under different loading conditions was compared by adding weights on top of the concrete. Rate of mass change variations and uniaxial compressive strength at various corrosion time points were monitored. The results indicated that after sulfuric acid corrosion, there was an increase in the mass but an overall decrease in the strength of the specimens. Compared with all-face corrosion, one-face corrosion led to a smaller increase in the mass of the concrete specimens and a more substantial decrease in strength, primarily because of the slower corrosion rate and reduced gypsum formation. Compared to plain concrete, steel fiber-reinforced concrete experienced a lower increase in the mass of the concrete specimens because the steel fibers obstructed sulfuric acid infiltration. However, there was significant corrosion of the steel fibers and surrounding concrete owing to accumulation of sulfuric acid around the former, resulting in a more substantial decrease in the uniaxial compressive strength of the steel fiber-reinforced concrete. With increasing load, the rate of change in the concrete mass initially decreased and then increased; this could be because increased loads densify the concrete, hindering sulfuric acid infiltration and promoting the development of microcracks within the concrete, thereby enhancing the effects of sulfuric acid corrosion.

A comprehensive study on bioactivity, mechanical and tribological behavior of copper-doped borosilicate glass derived from natural waste for dental applications

The present study investigates in-vitro biomineralization, mechanical, and tribological properties of bioactive borosilicate glass composed of 31B2O3–20SiO2-(24.5-x)Na2O-24.5CaO and xCuO (mol%). Glass was manufactured using conventional melt-quench technique, utilizing chemicals partially derived from bio-waste, with varying copper oxide (CuO) content (x = 0, 1, 3, and 5). In-vitro study was conducted by immersing the specimens in simulated body fluid for 21 days. The formation of apatite layer was confirmed using FTIR, XRD and FESEM-EDS. Vicker's micro hardness tester and a universal testing machine measured hardness and compressive strength, while a pin-on-disc tribometer assessed wear. MTT assay was performed for all the specimens using osteosarcoma MG63 cell line. The study revealed that substituting copper in place of sodium increased the ion dissolution and improved the formation of the apatite layer hence, enhanced the bioactivity, however, accompanied by a gradual decrease in hardness and compressive strength. BSG-0 exhibited the highest hardness (6.64 GPa) and compressive strength (86.81 MPa), while wear resistance weakened with higher CuO content, notably in BSG-5 with the highest specific wear rate (0.072 mm³/N-m) under a 5 N load. Although MTT assay showed non-toxicity for all specimens, except BSG-5, the compounds demonstrated cell tolerance and growth stimulation. In conclusion, the study suggests that CuO-doped borosilicate glasses exhibit superior bioactivity, making them potentially effective for bone filling, wound healing, and dental applications, despite a compromise in mechanical strength and wear resistance.

Effect of activator concentration on setting time, workability and compressive strength of sustainable concrete with alkali-activated slag binder

The global need to reduce carbon dioxide (CO2) emissions prompted studies on sustainable alternatives to conventional concrete made with ordinary Portland cement (OPC) binders. Alkali-activated ground granulated blast furnace slag (GGBS) is a promising sustainable to OPC in terms of the impact on the environment and reduction of CO2 emissions. Concretes and mortars made with alkali-activated binders demonstrate promising fresh and mechanical properties. This article presents the findings of an experimental study investigating the fresh and mechanical properties of mortar using alkali-activated GGBS binder. The activators used were sodium silicate (Na2SiO3) and sodium hydroxide (NaOH) solution with 6 M, 8 M, 10 M, and 12 M molarities. The study assessed their initial setting time, workability, and 28-day compressive strength. The study evaluated the effect of partial replacement of GGBS with 5 % silica fume. The compressive strength was determined after 28 days of curing in three different environments: 1) ambient air temperature, 2) water submersion, and 3) water immersion for 7 days followed by 21 air curing in ambient temperature. The results showed an increase in compressive strength with higher NaOH concentration but a corresponding decrease in initial setting time and flowability. Depending on the curing method, efflorescence, and blue-green pigmentation were seen during the physical assessment of the samples. The highest 28-day compressive strength was 67.5 MPa when the NaOH activator molarity was 10 mol/L which represents an optimum concentration for strength development. Replacing 5 % of the GGBS binder with silica fume resulted in a decrease in the 28-day compressive strength and workability without affecting the initial setting time.

Predicting the failure of rock using critical slowing down theory on acoustic emission characteristics

The joint surfaces and size affect the mechanical behavior and failure precursors of shale. Therefore, this paper studies the mechanical behavior, the response characteristics of acoustic emission (AE) and critical slowing down (CSD) characteristics of AE for shale with different joint surfaces and size. The results show that with an increase in the number of joint surfaces and the size of the sample, the crack initiation stress, uniaxial compressive strength (UCS), peak strain, and fractal dimension decrease. During the plastic stage, the occurrence of a sharp rise in AE ringing count, RA, a low-frequency, high-amplitude AE signal, and a rapid drop in AF can be characteristics of impending sample failure. Variance and autocorrelation coefficients can be used to characterize the CSD phenomenon. The optimal window length and lag step are determined to be 400 and 100, respectively. The CSD characteristics of the autocorrelation coefficient and the variance of multi-AE parameters are obtained. The variance-based early warning time provides short-term early warning, while the autocorrelation coefficient-based early warning time provides early warning. The research results can provide theoretical references for the mechanical design and failure prediction of underground rock engineering.

The effects of temperature and hygrothermal aging on the properties of CF/PA6 composite and its compression failure mechanisms

AbstractCarbon fiber reinforced polyamide composites have outstanding properties, but their applications are significantly affected by the service environment. This work evaluates the effects of temperature (25, 80, 140, and 200°C) and hygrothermal conditions on the mechanical properties of CF/PA6 composite containing delamination damage, and studies its damage behaviors and failure mechanisms. After hygrothermal aging, recrystallization of PA6 improves the heat resistance of CF/PA6 composites, but water absorption reduces the interfacial strength of composites, resulting in the decrease of modulus and compressive strength (24% and 42%, respectively). With the increase in temperature, the compressive strength of CF/PA6 composites gradually decreases (from 132 MPa at 25°C to 24 MPa at 200°C), and the failure mode transitions from fiber fractures, interlayer shear fractures, delamination to kinking. In addition, the compressive failure process of CF/PA6 composites is divided into three stages: buckling, delamination bulging and kinking failure.Highlights Hygrothermal aging reduces the fiber/resin interface performance. Fiber fracture, interlayer shear and delamination convert to kinking failure. The failure process is divided into buckling, delamination and kinking.

Size effect of compressive performance of concrete under elevated temperatures: Tests and meso-scale analysis

This study investigates the size effect of concrete under ambient and elevated temperatures through tests and numerical simulations. Compressive performance of prismatic and cylindrical concrete specimens with varying dimensions were tested at temperatures ranging from ambient temperature to 600°C. Meso-scale finite element analysis (FEA), assuming that the mechanical properties of matrix and interfacial transition zones (ITZ) followed Weibull distribution, was employed to simulate the tested specimens and to conduct parametric analysis on specimens with larger or smaller sizes and under temperatures up to 800°C. Both experimental and numerical results showed that the cracks on the specimen surface became finer and denser as an increase of specimen sizes under elevated temperatures. A noticeable decrease in concrete compressive strength with increasing specimen dimensions was observed below 600°C, but peak strain and elastic modulus did not exhibit significant size effect. Size effect on strength diminished at temperatures exceeding 800°C. Classic Size Effect Laws (SEL), such as Weibull's and Bažant's SEL, were applicable to characterize the size effect on strength of specimens within common lab test dimensions under elevated temperatures. Based on the results from experiments, FEA and Bažant's SEL, a stress-strain model under elevated temperatures considering size effect was proposed. The predicted results from this model showed good agreement with test results.

Impact of Electronic Waste Glass on the Properties of Cementitious Materials

The article analyses the impact of two different types of dispersive glass on cement hydration and compressive strength at 7 and 28 days. The study employed dispersive glass from various LCDs (TV sets, computer monitors, smart phones), characterised by a composition of approximately 8% SrO, and dispersive glass from washing machines, which consists mainly of SiO2, Na2O, and CaO. The chemical composition and particle-size distribution of different types of dispersive glass were analysed. The study compares the effect of electronic waste glass on cement hydration by evaluating the amount and rate of heat released during the process. In addition, the results of X-ray diffraction (XRD), thermogravimetric analysis (TG), and scanning electron microscopy (SEM) are provided. Different types of glass were determined to have a similar effect on the physical and mechanical properties as well as the mineral composition of cementitious samples: density and UPV decrease up to 6% and compressive strength decreases by about 30%, when 5–20% of cement was replaced by glass waste. However, more prominent differences were observed in the workability of the mixtures: the waste glass from home appliances increased the spread by up to 25%, while the waste glass from electronic devices decreased the spread compared to the reference sample by approximately 20%. The mixtures modified with the waste glass of electronic devices had a higher degree of early hydration (96%) due to the higher water absorption of the mixtures compared to the waste glass of home appliances (88%).

Gas CO2 foaming and intermixing in portland cement paste to sequester CO2

In this study, concentrated CO2 gas was used to create foamed cement paste, and concentrated CO2 gas was intermixed in fresh cement paste to produce regular cement paste materials that were not foamed. The potential of both methods to form CaCO3 from calcium ions that would form Ca(OH)2 was investigated. After curing the materials for different ages, the Ca(OH)2 and CaCO3 contents were measured using thermogravimetric analysis; the large void size distributions, dynamic modulus, and compressive strength were tested and compared against Control (no gas added), and N2 foamed and N2 intermixed specimens. A 10% increase in dynamic modulus and compressive strength was measured in CO2 foamed specimens compared to N2 foamed specimens. The increase in mechanical properties was the result of both a narrow void diameter distribution and CaCO3 formation in place of Ca(OH)2. The CO2 foamed cement generation method shows the potential to sequester 0.06 ton of CO2 for every ton of cement which is a CO2 emission reduction of 7.0% of the CO2 production associated with cement production. For the CO2 intermixing method, the void content, compressive strength, and dynamic modulus results were consistent between the Control and CO2 intermixed specimens while the N2 intermixed specimens showed a decrease in compressive strength and dynamic modulus. The CO2 intermixing method showed potential to sequester 0.04 ton of CO2 for every ton of cement or a 4.7% CO2 emission reduction of the total CO2 production associated with cement manufacturing. The reported CO2 emissions are not based on life cycle assessment and do not account for emissions associated with CO2 collection, transportation, and intermixing. The present paper does not investigate the mechanisms of hydration under CO2 intermixing.

Assessing the risk of ASR in LC3 binders based on low-grade calcined clay

The research investigates the impact of limestone calcined clay cement (LC3) on the mechanical properties and durability of cement-based materials in the context of alkali-silica reactions (ASR) for sustainable construction. Comparative experiments were conducted on binary and ternary blends of low-grade kaolinitic calcined clays and conventional supplementary cementitious materials (SCMs). Two distinct low-grade kaolinitic clays were calcined, and blends with Portland cement, ground-granulated blast-furnace slag (GGBFS), and silica fume (SF) were prepared for comparative analysis. Results reveal that replacing 30 wt% of Portland cement with these calcined clay blends substantially reduces expansion in mortar and concrete during accelerated and long-term tests, altering micropore structure. These blends demonstrate superior performance compared to other studied SCMs. Despite a slight decrease in compressive strength compared to the control mixture, there is a noteworthy improvement in permeability and resistance against expansion. Also, in the early stages of ASR, an improvement in concrete's mechanical properties and durability is observed, attributed to the ASR gel filling the pores.

Effects of biogenic sulfuric acid on simulated concrete septic tanks

Concrete is the major construction material for infrastructure development. Concrete sewer septic tanks are Constructed using the conventional ordinary portland cement (OPC) and the Portland pozzolana cement (PPC). However, OPC based concrete sewer systems are susceptible to biological, mechanical, and chemical degradation. Degradation of the concrete septic leads to their failure hence imposing tremendous environmental problems. The aftermath is the emergence of sanitation-related diseases. The wastewater from failing septic systems leads to contamination of the groundwater or the surface water resulting in the pollution of drinking water. Therefore, the need to explore other possibilities and potential construction materials to achieve sustainable sanitation is inevitable. The use of Limestone Calcined Clay Cement (LC3) in the construction of degradation-resistant concrete sewer septic systems has not been well explored in Kenya. LC3 concrete is resistant to the deterioration effects of aggressive media such as acids, chlorides, and sulfates. This paper presents experimental performance and findings of LC3 in aggressive media vis a vis OPC. The LC3 was formulated by mixing clinker, Calcined clay, limestone, and gypsum at percentages of 50 %, 30 %, 15 %, and 5 % respectively. Compressive strength, Sorptivity, and weight loss during the wet and dry cycles for both LC3 and OPC were evaluated. Simulated concrete septic tanks made of LC3 and OPC were made by casting cubes at water cement ratio of 0.5 and cured in fresh water at ambient temperature for 28 days. These cubes were passed through a regime of W-D cycles in the 3% concentration of Biogenic sulfuric acid. It was observed that after 28 days of curing OPC cubes had slightly higher compressive strength than LC3. However LC3 concrete cubes are expected to have higher compressive strength than the OPC. Cubes curing time increases due to increased pozzolanic activity. Biogenic sulphuric acid attacks on hydrated cement products cause a decrease in compressive strength. The water absorption profile of LC3 cubes was lower as compared to OPC cubes. In conclusion, LC3 cubes had a high potential of resisting degradation as compared to OPC cubes. LC3 show more impressive performance, hence LC3 It’s a potential binder for use in the construction of sewer system.
 Keywords: Septic tank, Sorptivity, compressive strength, wet-dry cycles, biological, mechanical, and chemical degradation, sustainable sanitation, LC3.

Compressive Strength parallel to grains of Charred Paulownia Wood

Wood is a common flammable in the building fire and the dominant fuel in the wildland fire. In this study, the surface of wood specimens has been pre-heated by various radiative heat fluxes and heating times to achieve varying char layer thicknesses. The compressive strength parallel to grains versus various charring thicknesses has been obtained by an electronic universal testing machine (WDW-20). Experimental results demonstrate that a higher heat flux and longer heating times promote the formation of the char layer, but the compressive strength versus the charring thickness first decreases to its minimum value and subsequently remains stable. For the 7 kW/m2 case, there is a rapid decrease in compressive strength for the 5-7 heating period. For example, the compressive strength is 31.7 MPa after the initial 5-minute period, and 3.69 MPa after the initial 7-minute period. For the radiative heat fluxes from 7 kW/m2 to 10 kW/m2, the reduction rate of compressive strength will increase from 1.32 MPa/min to 3.75 MPa/min for the initial 5-minute period, and increase from 4.95 MPa/min to 5.34 MPa/min for the initial 7-minute heating period. This study helps us understand the influence of charring processes on the mechanical properties of wood and the failure of timber structures.

Advancing Sustainable Construction Materials: Wood, Rubber, and Cenospheres Geopolymer Masonry Units Development

As the environmental impact of modern society continues to escalate, the construction industry actively pursues environmentally friendly materials to revolutionize its practices. Recycling, especially repurposing end-of-service materials and industrial wastes, emerges as a pivotal strategy offering a promising path towards sustainable construction. This study focuses on the innovative reuse of end-of-service wood, crumb rubber, and cenosphere with geopolymer binder to produce sustainable alternatives to masonry units. The study was conducted in two stages. In the first stage, cube samples were produced and tested to establish an optimal mix design. Results indicated that as the relative volume of waste increased, the compressive strength decreased. The compressive strength of the wood geopolymer composite decreased from 25 MPa to 4 MPa as the wood-to-binder ratio increased from 0.1 to 0.5. An increasing trend was observed for density with the increase of the rubber-to-wood ratio. The compressive strength also increased with the increase of the rubber-to-wood ratio for most of the investigated ranges. As fly ash is gradually replaced by cenospheres, a significant decrease in compressive strength was noted, about 70% and 80% for wood-to-binder (ratios of 0.2 and 0.3, respectively). In the second stage, three distinct types of masonry units were produced and tested based on the optimized mix design. The compressive strength results indicated promising performance, with wood-geopolymer masonry units exhibiting a strength of 8.39 MPa, wood-rubber-geopolymer masonry units achieving 8.32 MPa, and wood-cenosphere-geopolymer masonry units resulting in 7.33 MPa. While these values fell below the target 10 MPa, it is noteworthy that wood-geopolymer masonry units and wood-rubber-geopolymer masonry units met the minimum compressive strength requirements of some standards and demonstrated significantly better ductility compared to traditional masonry units. The results showcase significant promise in the viability and performance of these innovative masonry units.

Compressive Behaviors of High-Strength Geopolymeric Concretes: The Role of Recycled Fine Aggregate

In this study, natural fine aggregates (NFAs) in high-strength fly ash (FA)/ground granulated blast furnace slag (GGBFS)-based geopolymer concretes were both partially and completely replaced by RFAs to prepare geopolymer recycled fine aggregate concrete (GRFC). Herein, the impacts of RFA content (0%, 25%, 50%, 75%, and 100%) on the fresh and hardened performance and microstructural characteristics of a GRFC were investigated. The results indicated that with increasing RFA substitution ratio, the setting time of the GRFC decreases. In addition, the compressive strength and elastic modulus decrease. However, owing to the enhanced adhesion of the geopolymer matrix and recycled aggregate, RFA has a relatively small impact on the compressive strength, with a maximum strength loss of 9.7% at a replacement level of 75%. When the RFA content is less than 75%, the internal structure of the concrete remains relatively compact. The incorporation of RFA in concrete has been found to adversely affect its compressive strength and elastic modulus, while simultaneously increasing its brittleness. The increase in dosage of RFA leads to a reduction in the compressive strength and elastic modulus of concrete, while partial failure occurs when the GRFC constitutes 100% of the RFA. The existing stress–strain model for conventional concrete is recalibrated for the GRFC. Observed by SEM, with increasing RFA, the damage is mainly concentrated at the interface associated with the attached cement. Although the recalibrated model predicts the stress–strain responses of the GRFC reasonably well, an acceptable range of deviation is present when predicting the residual stress due to the relatively high strength and brittle behavior of the GRFC during compression. Through this research, the applicability of RFA is expanded, making it feasible to apply large quantities of this material.

The Influence of Quartz Powder on the Mechanical–Thermal–Chemical–Durability Properties of Cement-Based Materials

Using industrial by-products to replace cement is an important way to reduce carbon emissions in the cement industry. The purpose of this article is to understand the effect of quartz powder on the properties of cement-based materials. Experimental studies were conducted on the macroscopic and microscopic properties of cement-based materials mixed with quartz powder to evaluate their feasibility as a replacement for cement. The substitution rates of quartz powder were 0% (Qu0), 7.5% (Qu7.5), and 15% (Qu15). The test time was from 1 day to 28 days, and the main results are as follows: In the early stage of the hydration reaction, as the amount of quartz powder substitution increases, the cumulative hydration heat increases. This is mainly because the nucleation effect of quartz powder accelerates the hydration reaction of cement. In the later stage of the hydration reaction, as the amount of quartz powder substitution increases, the cumulative heat of hydration decreases. This is mainly due to the diluting effect of quartz powder. For Qu0, Qu7.5, and Qu15, the decrease in compressive strength after 1 day is not obvious. The decrease in compressive strength at 28 days is more obvious. Overall, there are exponential relationships between the UPV measurement or surface resistivity results and the compressive strength measurement results at 1, 3, 7, and 28 days. The XRD test results show that the main products of the reaction are AFt, CH, Hc, and Mc. From Day 1 to Day 28, the content of Mc becomes evident. The test results for TG showed that, as the amount of quartz powder substitution increases, the mass loss decreases. For different specimens of Qu0, Qu7.5, and Qu15 at different test times (3 and 28 days), there is an exponential function relationship between chemically bound water and strength. A numerical hydration model is proposed for cement–quartz binary blends. The parameters of the hydration model are determined based on the hydration heat normalized by the cement mass. Moreover, the hydration heat at 28 days is calculated using the proposed model. The strength development of all specimens and all test ages can be expressed as an exponential function of hydration heat.