Decompression Melting Research Articles

Ultra-depleted melt product preserved in the Ladong ophiolitic peridotites of the North Qilian Orogenic Belt, Northern Tibet

In Earths upper mantle, the compositions of both migrating magmas and solid residues are basically controlled by source materials and melting behavior which are related to tectonic dynamics. Thus, infrequent geochemical signatures recorded by ophiolitic lithologies may reflect a unique source or specific melting history. Here, we report whole-rock and mineral compositions of the harzburgite, wehrlite, and olivine websterite in the Ladong ophiolite complex of the North Qilian Orogen Belt (northern Tibet). The dominant spinel harzburgite has high spinel Cr# values of 65–70 and light rare earth element (LREE) depleted patterns (LaN/YbN = 0.04–0.12), resembling the residua after 20% or more of melt extraction. Wehrlite lenses within the harzburgite display extremely depleted LREE patterns (whole-rock LaN/YbN = 0.04–0.05) and low Na and Ti contents in clinopyroxene. They are interpreted as products of reaction between the host harzburgite and an ultra-depleted melt produced by asthenospheric decompression melting. Outcrops of olivine websterite have well-equilibrated triple junction textures between pyroxene grains and high-Mg olivine (Fo = 85–86; bulk rock Mg# = 93), consistent with a cumulate origin. In the olivine websterite, the depleted LREE concentrations (LaN/YbN = 0.05–0.18) in clinopyroxene suggest a less depleted nature than the wehrlite-forming melt. Thus, the Ladong ophiolite records two episodes of melt activity that produced depleted to ultra-depleted magmas, which may have been generated during subduction initiation in eastern Proto-Tethyan belt.

The Causes of Volcanic Eruptions and How They Affect Our Environment

Volcanic eruptions often have an impact on the environment. In the context of the environmental problem of global warming, a large amount of carbon dioxide released by volcanic eruptions will aggravate the greenhouse effect, which has aroused widespread concern. This article first explains the volcano's cone-shaped structure with several craters, cones, and vents. Although each volcano is unique, most volcanoes can be separated into three major types, the first type is a cinder cone, the second type is a composite volcano, and the third type is a shield volcano. Furthermore, this article interprets the causes of volcanic eruptions by decompression melting, and crustal movement. In addition to this, the environmental impacts of volcanic eruptions from three different angles are explained in the article. The First is the environmental impact of volcanic eruptions at different latitudes. It not only examines the sea surface temperatures' responses to volcanic forcing but also mentions a phenomenon of wind (El Niño de Navidad) caused by volcanic. The second argument is the impact of volcanic eruption on climate. It explains the effects of volcanic dust, Sulphur dioxide, and greenhouse gases, these three main volcanic substances that contribute to environmental cooling, acid rain, and global warming respectively. The final point is the impact of volcanic eruption on the benefits and disadvantages of plant cultivation, hoping this article could raise awareness of volcanoes and global environmental problems and prevent them.

Protolith and metamorphic age of the Sieggraben Eclogites: Implications for the Permian to Cretaceous Wilson cycle in the Austroalpine unit

The Austroalpine eclogite-bearing Sieggraben Complex, exposed at the eastern margin of the Eastern Alps, is considered to represent a subducted and then exhumed fragment of the continental rift, which led to the formation of the Meliata oceanic basin. Combined zircon U-Pb dating, whole rock geochemistry and Hf isotope analysis of the Sieggraben Complex revealed that the eclogite sample shows a protolith age of 242.3 ± 2.6 Ma (Middle Triassic) and displays tholeiitic basalt/N-MORB geochemical characteristics. Associated ultramafic rocks as part of oceanic or subcontinental mantle lithosphere suggest a depleted mantle source and a deep subduction environment. Two zircon grains of eclogites with low Th/U ratios yield ages of 113 ± 2 Ma and 86 ± 4 Ma and represent the approximate age of eclogite metamorphism during Cretaceous. A trondhjemite dike cutting through eclogite gives a crystallization age of 82.19 ± 0.4 Ma and formed by partial melting during decompression. The host metasedimentary rocks are interpreted as old continental crust close to the margin of the Meliata basin were affected by Permian migmatitic metamorphism. The results of this study combined with previous results from the Sieggraben Complex are used to present an updated model for the tectonic evolution of the distal Austroalpine unit associated with the oceanic Meliata relics The Austroalpine Sieggraben Complex represents a location on the distal continental margin during Permian rifting. This piece of continental crust of an inferred paleotectonic position adjacent to the Meliata oceanic lithosphere subducted during Early Cretaceous times to mantle depth. The subducted continental crust was then exhumed incorporating even ultramafic mantle rocks. During exhumation and decompression of mafic rocks, partial melting took place forming the trondhjemite dike in Late Cretaceous times. • A Middle Triassic ptotolith age was found for eclogites of the Sieggraben Complex. • A Cretaceous-aged trondhjemite dike report formed by decompressional melting after eclogite metamorphism. • Paragneiss hosts a Panafrican detrital zircon memory and was affected by Permian migmatization. • A new tectonic model for the distal Austroalpine unit relates with the Meliata Ocean in a Wilson cycle.

Vertical depletion of ophiolitic mantle reflects melt focusing and interaction in sub-spreading-center asthenosphere

Decompressional melting of asthenosphere under spreading centers has been accepted to produce oceanic lithospheric mantle with vertical compositional variations, but these gradients are much smaller than those observed from ophiolites, which clearly require additional causes. Here we conduct high-density sampling and whole-rock and mineral analyses of peridotites across a Tibetan ophiolitic mantle section (~2 km thick), which shows a primary upward depletion (~12% difference) and local more-depleted anomalies. Thermodynamic modeling demonstrates that these features cannot be produced by decompressional melting or proportional compression of residual mantle, but can be explained by melt-peridotite reaction with lateral melt/rock ratio variations in an upwelling asthenospheric column, producing stronger depletion in the melt-focusing center and local zones. This column splits symmetrically and flows to become the horizontal uppermost lithospheric mantle, characterized by upward depletion and local anomalies. This model provides insights into melt extraction and uppermost-mantle origin beneath spreading centers with high melt fluxes.

Editorial: Advances in the spatial and temporal evolution of oceanic arc-backarc systems

Oceanic arcs and their associated backarc basins are highly dynamic systems as their evolution is 12 strongly linked with far-field plate tectonic stresses, the regional geodynamic setting, local crustal 13 structure and mantle dynamics. The individual evolutionary stages of arc and backarc systems are 14 associated with significant changes in the physical and chemical conditions that control the 15 compositions of melts during generation, transport and storage, and eventually volcanic eruption. The 16 magmas are generated under variable conditions that range from fluxed melting due to the 17 devolatilization of the slab underneath the forearc and arc to dry adiabatic decompressional melting of 18 the mantle, especially underneath the backarc (Figure). The structure, composition and geometry of 19 the slab from the forearc to the backarc thus exerts an important control on metamorphic and 20 metasomatic processes and melting in the overlying mantle wedge. This research topic covers the 21 spatial evolution of arcs from the mantle (Bénard et al., 2022;Bénard, 2022) common in these settings and their location is controlled by regional geodynamics, magmatism and 72 local tectonics.

Middle-late Miocene rift-related magmatism in Guaymas, Sonora, Mexico at the eastern margin of the Gulf of California: Petrogenetic implications associated to the Pacific-north American plate boundary

Miocene volcanism in the Guaymas region at the eastern margin of the Gulf of California, in coastal Sonora, NW Mexico, was dominated by arc magmatism. However, the presence of rift-related magmatism is also exposed. Rocks associated with subduction of the Farallon plate beneath North America plate are of Oligocene-Miocene ages, while the magmatic rocks with ages between ca. 12.5 to ca. 6 Ma occur in a post-subduction tectonic setting. This period is sometimes referred to as the proto-Gulf phase. The proto-Gulf magmatic rocks are exposed as part of a volcanic igneous plumbing system, herein named Guaymas Group. The Guaymas Group has an age range between ∼12 and 10 Ma and is defined by two magmatic events: an intermediate compositional pulse (Unit 1) and a felsic pulse (Unit 2).The lithological units from the Guaymas Group have similar geochemical features, exhibiting LILE and LREE enrichment and Nb, Ta and Ti depletion. These rocks show a transitional to tholeiitic composition affinity that differs from the arc magmatism from coastal Sonora. The geochemical data suggest that assimilation and fractional crystallization (AFC) processes played an important role in the geochemical variations observed in volcanic and subvolcanic rocks. The geochemical characteristics of the Guaymas Group rocks also could indicate an origin by decompression melting of a mantle source metasomatized by subduction processes.Finally, considering the geological, geochronological and geochemical study, we suggest that the emplacement of the Guaymas Group rocks is contemporaneous with the oblique rifting environment associated with an incipient Pacific-North American plate boundary.

Geochemistry of meta‐mafic and meta‐tonalite‐trondhjemite intrusives from Jaintia and Karbi Anglong hills of Shillong Plateau, North East India: Implications on the evolution of the Proterozoic Shillong Basin

We present the whole‐rock and mineral chemical data of the Khasi meta‐mafic/basic‐trondhjemite intrusives (KMI) and meta‐tonalite‐trondhjemite (MTT) that coevally emplaced the Proterozoic Shillong Group (SG) of Shillong Plateau, northeast (NE) India and discuss their petrogenetic‐tectonic origin. The calc‐alkaline to tholeiite KMI are compositionally transitional between hornblende‐gabbro; hornblende‐diorite and minor‐hornblendite. They show Ta–Nb troughs and strong decoupling large‐ion lithophile/high field strength elements (HFSE) signature consistent with subduction zone‐related basic magmas. The calcic to calc‐alkaline, low‐Al2O3, and I‐type metaluminous Fe‐hedenbergite‐trondhjemite (KMT) exhibits similar trace and rare earth elements (REE) distribution to the KMI. The MTT on the other hand are depleted in trace elements and REE, and correspond with the I‐type granitoids, and are comparable to Proterozoic to Phanerozoic tonalite‐trondhjemite‐granodiorites. Gentle negative sloping of REE in KMI ([La/Lu]CN = 4.04 to 6.35) with moderate LREE, suggests partial melting or, fractional crystallization from a transitional source between garnet and spinel lherzolite. Although almost a flat pattern ([La/Lu]CN = 3.70 to 4.05) for MTT entails a high degree of partial melting from sources similar to Archaean Mafic Composite or Archaean Tholeiite. Trace elemental modellings ([Sr/Y] vs. Y and [La/Yb]N vs. YbN) for MTT infer low pressure (<15 kbar) and high degree partial melting of >50% in equilibrium with 10% garnet +90% amphibole residue. A relatively flat REE pattern with some elevated HREE of MTT compared to KMI suggests for depleted source. Bimodal plutonism and the prevalence of meta‐dacite‐rhyolite in SG invokes for tonalite‐trondhjemite‐dacite setting of a continental arc or, active continental margin tectonic setting. Emplacement of KMI initiated in a temporary relax‐extensional phase and MTT in a compressional regime. This is possibly caused by an over‐thickened crust later subjected to orogenic collapse, exhumation‐metamorphism, and decompressional melting. This event might have taken place between 1.0 to 0.5 Ga during the Pan‐African Orogenic crustal growth, linked to the amalgamation of Gondwana.

The effects of source composition and melting conditions on the composition of syn-exhumation granites in collisional orogen

Partial melting of the deeply subducted continental crust during exhumation has been widely recognized recently in collisional orogens. However, it is little known about the effects of source composition and melting conditions on the composition of syn -exhumation granitic rocks. This is investigated by studying zircon and titanite U Pb geochronology and whole-rock geochemistry for syn -exhumation granites from the Weihai area in the Sulu orogen. The U Pb dating of relict zircon cores yields concordant Neoproterozoic and Late Triassic ages, respectively, for the meta-igneous protolith and granulite-facies metamorphism. Magmatic zircon rims give U Pb ages of 207 ± 1 to 214 ± 2 Ma for the formation of Weihai granites, in agreement with magmatic titanite ages of 209 ± 6 to 217 ± 5 Ma in the Late Triassic. The compositional zonation of titanite shows decreases of Nb/Ta and (La/Yb) N from core to rim, indicating the geochemical changes during granitic magmatism. In general, these granites show arc-like trace element distribution patterns and enriched Sr–Nd–Hf isotope compositions with an affinity to deeply subducted crustal slices from the South China Block. Compared with previously reported syn -exhumation granites from Lanshan in the southern Sulu orogen, the Weihai granites in the northeastern Sulu orogen exhibit different Sr-Nd-O isotope compositions. The Weihai granites have relatively low SiO 2 and Na 2 O contents but high Al 2 O 3 and K 2 O contents with high A/CNK and K/Na ratios. They contain high Ba and Sr but low Y with high Sr/Y and (La/Yb) N ratios. Both zircon and whole-rock of the Weihai granites exhibit no significant negative Eu anomalies. Based on the differences in geochemical features and the spatial-temporal distributions, it is inferred that the syn -exhumation granites in the Weihai area are derived from decompressional melting of the lower crustal slice at greater depth, whereas those in the Lanshan area are derived from decompressional melting of the upper crustal slice at relatively shallower depth. These differences indicate that both source compositions and melting conditions have exerted significant influences on the geochemical composition of syn -exhumation granites in the collisional orogen. This has bearing on the crust-mantle interaction in continental subduction channel through metasomatic reaction of the mantle wedge with these granitic melts produced during the exhumation. • The Weihai granites in the northern Sulu orogen indicate syn -exhumation magmatism. • The Weihai granites are characterized by relatively high Sr/Y and (La/Yb) N ratios. • Syn-exhumation granites in the Sulu orogen are distinct from south to north. • Differences in source compositions and melting conditions caused the compositional diversity of granites.

An evolutionary system of mineralogy, Part VII: The evolution of the igneous minerals (>2500 Ma)

AbstractPart VII of the evolutionary system of mineralogy catalogs, analyzes, and visualizes relationships among 919 natural kinds of primary igneous minerals, corresponding to 1665 mineral species approved by the International Mineralogical Association—minerals that are associated with the wide range of igneous rock types through 4.566 billion years of Earth history. A systematic survey of the mineral modes of 1850 varied igneous rocks from around the world reveals that 115 of these mineral kinds are frequent major and/or accessory phases. Of these most common primary igneous minerals, 69 are silicates, 19 are oxides, 13 are carbonates, and 6 are sulfides. Collectively, these 115 minerals incorporate at least 33 different essential chemical elements.Patterns of coexistence among these minerals, revealed by network, Louvain community detection, and agglomerative hierarchical clustering analyses, point to four major communities of igneous primary phases, corresponding in large part to different compositional regimes: (1) silica-saturated, quartz- and/or alkali feldspar-dominant rocks, including rare-element granite pegmatites; (2) mafic/ultramafic rock series with major calcic plagioclase and/or mafic minerals; (3) silica-undersaturated rocks with major feldspathoids and/or analcime, including agpaitic rocks and their distinctive rare-element pegmatites; and (4) carbonatites and related carbonate-bearing rocks.Igneous rocks display characteristics of an evolving chemical system, with significant increases in their minerals’ diversity and chemical complexity over the first two billion years of Earth history. Earth’s earliest igneous rocks (>4.56 Ga) were ultramafic in composition with 122 different minerals, followed closely by mafic rocks that were generated in large measure by decompression melting of those ultramafic lithologies (4.56 Ga). Quartz-normative granitic rocks and their extrusive equivalents (>4.4 Ga), formed primarily by partial melting of wet basalt, were added to the mineral inventory, which reached 246 different mineral kinds. Subsequently, four groups of igneous rocks with diagnostic concentrations of rare element minerals—layered igneous intrusions, complex granite pegmatites, alkaline igneous complexes, and carbonatites—all first appeared ~3 billion years ago. These more recent varied kinds of igneous rocks hold more than 700 different minerals, 500 of which are unique to these lithologies.Network representations and heatmaps of primary igneous minerals illustrate Bowen’s reaction series of igneous mineral evolution, as well as his concepts of mineral associations and antipathies. Furthermore, phase relationships and reaction series associated with the minerals of a dozen major elements (H, Na, K, Mg, Ca, Fe, Al, Si, Ti, C, O, and S), as well as minor elements (notably Li, Be, Sr, Ba, Mn, B, Cr, Y, REE, Ti, Zr, Nb, Ta, P, and F), are embedded in these multi-dimensional visualizations.

Petrogenesis of Bonai volcanic rocks from Singhbhum Craton (Eastern India): Geophysical and geodynamic implications for pervasive plume-lithospheric interaction

• Petrogenesis and geodynamic evolution of Bonai volcanic, Singhbhum Craton. • Volcanic rocks generated by mantle plume within spinel lherzolite stability field. • Mantle potential temperature of 1300-1700°C and pressure 0.5-3.5 GPa. • Lower crustal exhumation, highly denudated lithospheric keel and magma underplating. • Crust-mantle thermal interaction, contamination and fractional crystallization. Singhbhum Craton of the Indian Shield is one of the oldest Eoarchean segments on the Earth, which contains several well-preserved Mesoarchean-Paleoproterozoic volcanic suites. In this study, we investigate petrogenesis of the Bonai suite of volcanic rocks located in the western part of the craton on the basis of detailed geological, geochemical and geophysical data, which provide a new understanding of its regional geodynamic evolution. These volcanics are generally fine to medium-grained, exhibit porphyritic texture and contain plagioclase and pyroxene as primary minerals and amphiboles, epidote, sericite and chlorite as secondary minerals. The accessory phases are mainly zircon, ilmenite, pyrite and chalcopyrite. They can be petrographically and geochemically classified as basalt and basaltic andesite of tholeiitic nature. They are characterized by moderate to high contents of SiO 2 (49.35-57.81 wt%), MgO (7.14-11.39 wt%), Al 2 O 3 (10.21-14.68 wt%), CaO (5.14-11.15 wt%), TiO 2 (0.48-2.03 wt%), Cr (32-483 ppm) and Ni (34-175 ppm). Their HFSE/REE ratios and REE patterns indicate their derivation from a relatively low melting of a similar mantle source within the spinel lherzolite stability field. They are formed as a result of decompressive melting of the mantle plume near the crust-mantle boundary, which underwent fractional crystallization and crustal contamination. The plume had an initial mantle potential temperature between 1300°C and 1700°C with corresponding pressure of 0.5 to 3.5 GPa. In Nb/Y-Zr/Y plot, almost all the samples fall in the field of oceanic plateau basalt with mantle plume affinity. This region is underplated by about 14 km thick magmatic rocks above the Moho, over which gravity field and regional elevation are consistently high and the lithosphere is extremely thin. These characteristics corroborate well with the mantle plume signatures. Subduction related geochemical signatures appear absent.

Temporal evolution of mantle temperature and lithospheric thickness beneath the ∼1.1 Ga Midcontinent Rift, North America: Implications for rapid motion of Laurentia

The production of the magma volumes necessary for the formation of continental flood basalts is thought to result from extension-related decompression melting of thermo-chemically anomalous mantle. The relative importance of elevated mantle temperature or decompression associated with lithospheric thinning remains difficult to constrain because the temporal relationship between the initiation of extension and continental flood basalt is often ambiguous. The ∼1.1 Ga Midcontinent Rift (MCR) in North America provides an opportunity to probe these magma generation factors because the mantle thermo-chemical anomaly (Keweenaw plume) thought responsible for the continental flood basalts of the Keweenaw Large Igneous Province (LIP) intersected an existing rift. The role of elevated mantle temperatures in Keweenaw LIP magmatism remains ambiguous because a temporal decrease in MgO content in primitive lavas may reflect decreasing melting depths with time due to progressive lithospheric thinning, a temporal decrease in mantle temperature, or both. Furthermore, paleomagnetic studies show that Laurentia was moving rapidly during Keweenaw LIP magmatism, raising the question of how the plume remained connected to the MCR during 25 Myr of volcanism. Using samples from the most complete volcanic section preserved at Mamainse Point, Ontario, Canada, we constrain mantle potential temperature and lithospheric thickness by combining three major element thermobarometry models with forward modeling of rare earth element compositions. We find that the earliest stage of Keweenaw LIP magmatism (Early phase; 1109-1104 Ma) was governed by initially deeper melting (>85-100 km thick lithosphere) and high mantle potential temperatures (>1480-1630°C) related to the plume. Potential temperatures decreased to near-ambient conditions (∼1400-1445°C) during the latter portion of the Early phase, with these lower temperatures persisting throughout the Latent (1104-1098 Ma) and Main (1098-1090 Ma) phases. Major element-derived pressures of melt equilibration place broad constraints on lithospheric thickness, which decreased from ∼60-110 km at the onset of magmatism to 45-65 km by the Main phase. The decrease in primitive MgO contents thus reflects thinning lithosphere and decreasing mantle potential temperatures. We argue that the temporal decrease in mantle potential temperature reflects the severing of the connection between the MCR and Keweenaw plume after the Early phase of magmatism by the rapid plate motion. Our constraints on mantle potential temperature resolve the relationship between the MCR, the plume, Keweenaw LIP magmatism, and rapid plate motion, and indicate that an alternative mechanism, such as enhanced small-scale convection due to rapid plate motion and plume-lithosphere interaction, was required to generate the voluminous Main magmatic phase.

A relic thickened crustal root beneath the Cenozoic rift zone of the NW Ordos margin, North China, revealed by receiver functions

We investigate the crustal structure and Moho topography beneath the northwest Ordos rift zone by employing receiver functions analysis at dense broadband seismic stations. The results delineate a depressed Moho zone (by ∼5 km) beneath the Cenozoic rifts, which is unconventional for classical continental rift zones. We interpret this depressed Moho zone as a relict of the thickened crustal root formed during the intracontinental orogeny in late Mesozoic. The Cenozoic rift has not yet reequilibrated the crustal-mantle boundary possibly due to the lack of decompressional melting during the lithospheric extension.

Mapping the Lithosphere and Asthenosphere Beneath Alaska With Sp Converted Waves

AbstractWe obtained a 3D image of crust and mantle seismic velocity gradients beneath the state of Alaska using common‐conversion point (CCP) stacking of S‐to‐p converted body waves recorded by hundreds of stations from the NSF EarthScope Transportable Array and other portable arrays and permanent networks. Moho depths delineate the thick crust of the underthrust Yakutat terrane and the crustal root beneath the Brooks Range. The North American lithosphere is particularly thin close to the subducting lithosphere in the Alaska subduction zone, consistent with thinning of the upper plate by subduction zone flow and melt rising from the mantle wedge. The lithosphere remains relatively thin far to the northwest and north, including the Seward Peninsula and regions to the south of the Brooks Range where lithospheric extension and foundering may have played a role. The lithosphere dramatically thickens beneath the Brooks Range and northern Arctic Alaska terrane where it appears to be both cold and highly viscous. The CCP stack also revealed a pronounced positive velocity gradient at depths of 130–230 km that represents the base of a layer within the asthenosphere whose low velocities are best explained by the presence of partial melt. Although this gradient is present close to the subducting lithosphere, where partial melting is enabled by slab‐derived fluids, it is strongest beneath the Seward Peninsula and northeast of the Wrangell volcanic field, suggesting the presence of partial melt in the asthenosphere hundreds of kilometers away from the slab, likely due to decompression melting in upwelling asthenosphere.

Heavy Rare Earth Elements and the Sources of Continental Flood Basalts

AbstractHeavy rare earth elements (HREEs) in mafic and ultramafic volcanic rocks are useful recorders of mantle source processes because their ratios are not easily modified by differentiation. Here we utilize REEBOX PRO, a simulator of adiabatic decompression melting of the mantle, to study the behavior of HREEs in the formation of continental flood basalt (CFB) parental magmas in the mantle. We simulate partial melting of depleted peridotite, pyrolitic peridotite, pyroxenite, and peridotite-pyroxenite mixtures at mantle potential temperatures of 1350–1650°C and lithospheric thicknesses of 50–150 km, and compare the results to natural data. Many large igneous provinces are typified by low-Ti and high-Ti CFBs with contrasting HREE patterns. Our results show that low-Ti CFBs originate mainly from peridotitic sources. Flat mid-ocean ridge basalt-like HREE patterns typical of low-Ti CFBs can be generated beneath thick lithosphere (~100 km), given that mantle potential temperatures are high (>1500°C) and garnet is completely consumed from the source. We thus challenge the common interpretation that flat HREE patterns always indicate shallow sources for CFB parental magmas. High-Ti CFBs require pyroxenite-bearing sources (≥10%). Contrary to a common view, their steep oceanic island basalt-like HREE patterns can be generated beneath quite a thin lithosphere (~50 km), which is due to increased garnet stability in pyroxenite sources. When applied to CFBs of the Karoo large igneous province, the results are compatible with a model where a mantle plume penetrates a progressively thinning Gondwana lithosphere.

Mid-Devonian basaltic magmatism and associated sedimentation: the Ooloo Hill Formation, central-eastern South Australia

We report composition and age data from a restricted <370 km2, volcano-sedimentary basin beneath Mesozoic cover to the northwest of the Flinders Ranges, South Australia. This volcano-sedimentary basin comprises two components: a sedimentary sequence that includes shales, siltstones and sandstones, and a basalt–sedimentary member. Together, these components are defined as the Ooloo Hill Formation. Whole-rock K–Ar geochronology for five basalt samples yields a preferred mean K–Ar age of 392 ± 8 Ma. Two samples of detrital zircons from the sedimentary rock yield SHRIMP U–Pb maximum depositional ages of ca 527 and 510 Ma. These ages are significant, as they rule out a Neoproterozoic age for the sedimentary basin and demonstrate that this basin is not part of the Adelaide Superbasin. Lower eruptive sequences are calc-alkaline and mafic in composition (SiO2 = 46.1–47.8 wt%, Na2O + K2O = 3.7–6.1 wt%, MgO = 6.85–8.37 wt%, Mg# = 57–65 and εNd(390 Ma) = 3.4–4.0) and may represent two small-scale melting events from compositionally distinct mantle reservoirs. The uppermost eruptive sequence is tholeiitic andesite (SiO2 = 51.6 wt%, Na2O + K2O = 8.1 wt%, MgO = 2.2 wt%, Mg# = 27 and εNd(390 Ma) = 3.0) and displays geochemical affinity to the first two eruptive sequences, possibly representing a differentiated magma from a similar source region. Incompatible trace-element ratios and isotopic compositions suggest the source was a heterogeneous oceanic island basalt-like parent magma derived from partial melting of the asthenospheric mantle. We envisage decompressional melting was linked to large-scale tectonic processes inboard of the Tasman Orogen, with magma ascent facilitated by crustal faulting. KEY POINTS First record of a mid-Devonian intracontinental volcano-sedimentary basin in South Australia. Basalts have an oceanic island basalt-like mantle source that represents at least two small-scale melting events from compositionally distinct mantle reservoirs. A localised mid-Devonian backarc basin or transpressional/transtensional basin linked to intracontinental faulting formed inboard of the Tasman Orogen.

TWO STAGES OF THE CENOZOIC ALKALINE-BASALT VOLCANISM IN THE DARKHAD DEPRESSION (NORTHERN MONGOLIA) – GEOCHRONOLOGY, GEOCHEMISTRY, AND GEODYNAMIC CONSEQUENCES

The isotopic data showed that there are two stages distinguished in the Cenozoic history of the Darkhad depression volcanic activity, the Late Oligocene initial stage (~28.0–26.6 Ma) and the final Late Miocene – Early Pliocene stage (~5.8–4.2 Ma). It has been stated that the rocks of the initial stage are only represented by trachybasalts; however, among the final-stage basaltoids there are series of shield-volcano hawaite-basanite-phonotephrite rocks and compex trachybasaltic "valley" lava flows, the formation of which is the last stage in the territorial volcanic evolution. It has been shown that the initial-stage trachybasaltic andesites are characterized by their enrichment of TiO2, P2O5, Sr, Zn, Ga and low concentrations of Al2O3, MnO, CaO, Sc and HREE (La/Yb=27.2–30.2). Basaltoids of the final stage have a similar rare-element distribution and show an increase in the contents of TiO2, Al2O3, P2O5, LILE, HFSE, Th, U and in the degree of fractionation of REE (La/Yb from 12.2 to 20.9) towards the rocks alkalinity enhancement. Modeling of eclogite, pyroxenite and peridotite melting processes in the La/Yb – Sm/Yb system shows that trachybasaltic andesite melts could be formed at ~7–8 % melting of eclogitic matter or at ~10–11 % melting of Grt-containing pyroxenites, with trachybasalt formed at ~3 % melting of Grt-containing peridotites. The composition distribution of rocks in coordinates (Mg# – Fe/Mn) indicates that the parental magmas are the initial-stage trachybasaltic andesite magmas as well as the Early Pliocene trachybasaltic "valley" lava flows. Sr, Nd, Pb isotope characteristics of the Darkhad depression basaltoids show significant shift of isotopic ratios in time towards the relatively enriched mantle as compared with the depleted MORB mantle. The initial formation of trachybasaltic andesite melts occurred in the Late Oligicene at the pre-rift stage of the territory development involving metasomatized mantle matter, with the pyroxenite or eclogite component contained in the magma formation source. The origin of trachybasalt magmas of the final stage is associated with the processes of decompression melting of peridotites in a weakly metasomatized lithospheric mantle at the rift stage of the Darkhad structure development.

Breakup mechanism of the northern South China Sea: Evidence from the deep crustal structure across the continent-ocean transition

To improve constraints on breakup processes that eventually lead to seafloor spreading and the subsequent formation of new oceanic crust in the northern margin of the South China Sea (SCS), we collect a 172-km-long deep-penetration wide-angle seismic data OBS2018-L5. In the continental domain, the results present a gradually thinning crust with thickness ranging from ∼17 km to ∼8 km, with a slight thickening crust at the Outer Margin High. The attenuated continental crust is fairly rough and highly offset by distinctly different scale faults system. In the oceanic domain, the top of the basement is highly reflective with weak faulting and relatively constant crust thickness ranging from 5 km to 8 km (average 6 km). The continent-ocean boundary is characterized by an abrupt change in crustal thickness accompanied by a specific boundary between mostly positive gravity anomalies in the oceanic basin and grossly negative anomalies in the thinned continental crust, and between low amplitude, out-of-shape magnetic anomalies in the thinned continental domain and high amplitude, linear anomalies in the oceanic domain. A 0–5 km thick high-velocity layer (7.0–7.5 km/s) is present in the distal margin, which might represent mafic magma underplating. We also identify other magmatic features such as distinct buried volcanic edifices overprinting the original velocity structure. We propose that three mechanisms control the extension and breakup of the SCS: (1) the rapid transition from continental to oceanic crust, (2) elevated potential mantle temperature, and (3) the ductile lower crustal necking. Their interactions lead to the intense thinning of the continental lithosphere, decompression melting of the enriched asthenosphere followed by fast upwelling of mafic melt, relatively strong volcanic activities during the final stage of syn-rift and breakup, and finally generating a margin with intermediately rich magma, referred to as in intermediate-type margin.

Zircon U–Pb and titanite U–Th–Pb ages of the Ghorveh mixed granitoid pluton: Implications for the Late Jurassic supra‐subduction extension of the Sanandaj–Sirjan Zone, Iran

The Ghorveh batholith, located in the central part of the Sanandaj–Sirjan Zone (SSZ), Iran, preserves several sequences of Mesozoic plutonic and volcanic rocks. This study presents systematic analyses of the calc‐alkaline granites and monzodiorites from the southern part of the Ghorveh pluton. The granites are metaluminous to slightly peraluminous with A/CNK ratios of 0.97–1.02, indicating an A‐type granitic affinity. High Rb, Th, and K and low Sr, P, and Ti concentrations indicate an involvement of crustal materials. Whole‐rock negative εNd(t) values and relatively high TDM1 model ages support a continental crustal source. Thus, the granites are of fractionated A‐type in composition produced by partial melting of crustal materials. The monzodiorites have incompatible trace element patterns with enrichment in light rare earth elements (LREEs) and large‐ion lithophile elements (LILEs) relative to heavy rare earth elements and high‐field strength elements. This combined with the high Mg# values and the positive εNd and εHf(t) values, indicate a mantle‐derived origin. Dating results show that the granites and monzodiorites have uniform crystallization ages of ~150 Ma. Previous results and our new data suggest that the Jurassic subduction of Neo‐Tethyan Oceanic crust under the Eurasian continent was followed by slab rollback that induced back‐arc extension. Heat transfer from arc magmas increased the degree of decompressional melting in the thinned lithosphere. Melting of the presumably homogeneous crust was concurrent with emplacement of the intermediate composition magmas. Consequently, we propose that the Ghorveh area of the central SSZ developed in a supra‐subduction extensional phase during the Late Jurassic.

Petrogenesis of continental intraplate alkaline basalts in the Tuoyun Basin, western Central Asian Orogenic Belt: implications for deep carbon recycling

Abstract The origin of intraplate volcanic provinces in continental interiors remains equivocal. One of the major gaps is the absence of a clear understanding of thermal state and the role of recycled carbon. Here we present results from detailed temperature estimation, trace element content of olivine and integrated Sr-Nd-O-Mg-Zn isotopic studies on Meso-Cenozoic basalt and basanite from the Tuoyun Basin in the western Central Asian Orogenic Belt. The calculated crystallization temperatures are in the range of 1101-1273 °C for basalt and 1037-1295 °C for basanite, consistent with ambient upper mantle-derived melts. Olivine Zn/Fe, Mn/Zn and Fe/Mn ratios fall in the hybrid source region composed of peridotite and pyroxenite for both basalt and basanite, which is also in agreement with their bulk-rock CaO-MgO trends, FeO/MnO ratios (62.8-77.4 for basalt and 57.8-65.1 for basanite) and FCKANTMS values (overall major element compositions; 0.52-0.68 for basalt and 0.43-0.64 for basanite). Trace elemental modeling shows that the basalt was produced by higher degrees of partial melting with more pyroxenite contribution than basanite. Mg and Zn isotopes show lighter Mg (-0.45 to -0.55 ‰ for basalt and -0.45 to -0.47 ‰ for basanite) and heavier Zn (0.37-0.41 ‰ for basalt and 0.38 to 0.48 ‰ for basanite) isotopic compositions than primitive mantle, indicating the possible involvement of recycled sedimentary carbonate in mantle source. Conversely, the basalt and basanite lack typical “carbonatitic fingerprints” such as high CaO/Al2O3 ratios and negative Zr, Hf and Ti anomalies. Furthermore, the Sr-O isotopes display typical mantle-affinity without explicit crustal signatures. Such a decoupling is attributed to carbonate species transition and decarbonation reactions between carbonate and surrounding silicate during plate subduction at a depth of &amp;gt; 150 km where the following reactions take place: CaMg(CO3)2 (dolomite) = MgSiO3 (magnesite) + CaCO3 (aragonite), and MgCO3 (magnesite) + SiO2 (coesite) → MgSiO3 (enstatite) + CO2. When the recycled carbonates are exhausted, crustal Sr-O is released but the Mg-Zn isotopic anomalies are inherited by the silicate products (“ghost carbonate”). These silicates are expected to be involved in the subsequent mantle upwelling that induces decompression melting to generate intraplate magmas. We therefore propose recycled carbonates in the mantle sources of the Tuoyun lavas underwent recycling at depths &amp;gt; 150 km and were incorporated as “ghost carbonate” with recycled Mg and Zn elements in the partial melting process rather than directly in the carbonate form.

Off-sequence plume magmatism near Ninetyeast Ridge in the Indian Ocean: evidence for extensive lateral flow of the Kerguelen plume

One of the fundamental questions about Earth processes that is still outstanding is how far a moving plate can drag plume material at its base after its initial impact with the plume. The IODP-362 Expedition recovered igneous samples from drilled sites near Ninetyeast Ridge (NER) in the Indian Ocean. A detailed geochemical and isotopic (Sr–Nd) investigation of these samples found that the basement basalts of the core are typical N-MORB tholeiites, but the igneous sills intruding the upper layer of sediments are highly alkaline, with a composition equivalent to the Kerguelen plume magma. Based on biostratigraphy, the minimum age of the alkaline samples was calculated as c. 58 Ma, which is younger than the adjacent NER crust ( c. 82–78 Ma). The existence of such young plume magma amidst the older blocks of the NER is unusual and contrary to its southwards-younging age pattern. We propose that the fast-moving Indian plate dragged a considerable amount of Kerguelen plume material underneath the Indian Ocean lithosphere northwards during the Cretaceous–Paleocene, covering a longitudinal distance of c. 2220 km. The reactivation of deep fractures triggered decompression melting of the underlying plume material and emplaced this as magmatic sills and lava flows near the NER at c. 58 Ma.