Decoherence In Systems Research Articles

Loss and decoherence in superconducting circuits on silicon: Insights from electron spin resonance

Solid-state devices used for quantum computation and quantum sensing applications are adversely affected by loss and noise caused by spurious, charged two-level systems (TLS) and stray paramagnetic spins. These two sources of noise are interconnected, exacerbating the impact on circuit performance. We use an on-chip electron spin resonance (ESR) technique, with niobium nitride (NbN) superconducting resonators, to study surface spins on silicon and the effect of postfabrication surface treatments. We identify two distinct spin species that are characterized by different spin-relaxation times and respond selectively to various surface treatments (annealing and hydrofluoric acid). Only one of the two spin species has a significant impact on the TLS-limited resonator quality factor at low-power (near-single-photon) excitation. We observe a three- to fivefold reduction in the total density of spins after surface treatments and demonstrate the efficacy of ESR spectroscopy in developing strategies to mitigate loss and decoherence in quantum systems. Published by the American Physical Society 2024

Decoherence in exchange-coupled quantum spin-qubit systems: Impact of multiqubit interactions and geometric connectivity

Decoherence in exchange-coupled quantum spin-qubit systems: Impact of multiqubit interactions and geometric connectivity

Single-molecule electron spin resonance by means of atomic force microscopy

Understanding and controlling decoherence in open quantum systems is of fundamental interest in science, whereas achieving long coherence times is critical for quantum information processing1. Although great progress was made for individual systems, and electron spin resonance (ESR) of single spins with nanoscale resolution has been demonstrated2–4, the understanding of decoherence in many complex solid-state quantum systems requires ultimately controlling the environment down to atomic scales, as potentially enabled by scanning probe microscopy with its atomic and molecular characterization and manipulation capabilities. Consequently, the recent implementation of ESR in scanning tunnelling microscopy5–8 represents a milestone towards this goal and was quickly followed by the demonstration of coherent oscillations9,10 and access to nuclear spins11 with real-space atomic resolution. Atomic manipulation even fuelled the ambition to realize the first artificial atomic-scale quantum devices12. However, the current-based sensing inherent to this method limits coherence times12,13. Here we demonstrate pump–probe ESR atomic force microscopy (AFM) detection of electron spin transitions between non-equilibrium triplet states of individual pentacene molecules. Spectra of these transitions exhibit sub-nanoelectronvolt spectral resolution, allowing local discrimination of molecules that only differ in their isotopic configuration. Furthermore, the electron spins can be coherently manipulated over tens of microseconds. We anticipate that single-molecule ESR-AFM can be combined with atomic manipulation and characterization and thereby paves the way to learn about the atomistic origins of decoherence in atomically well-defined quantum elements and for fundamental quantum-sensing experiments.

Controlled-Controlled-Phase Gates for Superconducting Qubits Mediated by a Shared Tunable Coupler

Applications for noisy intermediate-scale quantum computing devices rely on the efficient entanglement of many qubits to reach a potential quantum advantage. Although entanglement is typically generated using two-qubit gates, direct control of strong multiqubit interactions can improve the efficiency of the process. Here, we investigate a system of three superconducting transmon-type qubits coupled via a single flux-tunable coupler. Tuning the frequency of the coupler by adiabatic flux pulses enables us to control the conditional energy shifts between the qubits and directly realize multiqubit interactions. To accurately adjust the resulting controlled relative phases, we describe a gate protocol involving refocusing pulses and adjustable interaction times. This enables the implementation of the full family of pairwise controlled-phase and controlled-controlled-phase gates. Numerical simulations result in fidelities around 99% and gate times below 300 ns using currently achievable system parameters and decoherence rates.

Self-protected adiabatic quantum computation

Recent experiments show the existence of collective decoherence in quantum systems. We study the possibility of quantum computation in decoherence free subspace which is robust against such kind of decoherence processes. This passive protection protocol can be especially advantageous for continuous quantum computation such as quantum annealers. As an example we propose to use decoherence protected adiabatic quantum computation for the Grover search problem. Our proposal contains only two-body interactions, making it feasible in near-term quantum devices.

Emergent decoherence induced by quantum chaos in a many-body system: A Loschmidt echo observation through NMR

In the long quest to identify and compensate the sources of decoherence in many-body systems far from the ground state, the varied family of Loschmidt echoes (LEs) became an invaluable tool in several experimental techniques. A LE involves a time-reversal procedure to assess the effect of perturbations in a quantum excitation dynamics. However, when addressing macroscopic systems one is repeatedly confronted with limitations that seem insurmountable. This led to the formulation of the central hypothesis of irreversibility stating that the timescale of decoherence, ${T}_{3}$, is proportional to the timescale of the many-body interactions we reversed, ${T}_{2}$. We test this by implementing two experimental schemes based on Floquet Hamiltonians where the effective strength of the dipolar spin-spin coupling, i.e., $1/{T}_{2}$, is reduced by a variable scale factor $k$. This extends the perturbation timescale, ${T}_{\mathrm{\ensuremath{\Sigma}}}$, in relation to ${T}_{2}$. Strikingly, we observe the superposition of the normalized Loschmidt echoes for the bigger values of $k$. This manifests the dominance of the intrinsic dynamics over the perturbation factors, even when the Loschmidt echo is devised to reverse that intrinsic dynamics. Thus, in the limit where the reversible interactions dominate over perturbations, the LE decays within a timescale, ${T}_{3}\ensuremath{\approx}{T}_{2}/R$ with $R=(0.15\ifmmode\pm\else\textpm\fi{}0.01)$, confirming the emergence of a perturbation independent regime. These results support the central hypothesis of irreversibility.

Measurement and suppression of magnetic field noise of trapped ion qubit

Magnetic field noise is an important factor causing quantum decoherence in quantum systems. In order to suppress the decoherence effect, magnetic field noise needs to be properly measured and controlled. Magnetic field noise power spectrum measurement using a single trapped ion based quantum spectrum analyzer is a very effective way. In this paper, the magnetic field noise measurement based on dynamic decoupling technique is analyzed theoretically. Furthermore, we use magnetically insensitive transition to measure the magnetic field noise, which has the potential to measure stronger magnetic field noise and speed up the measurement process. In our experiment, we suppress the magnetic field noise by using active feedback control and passive compensation, where the required passive compensation amplitude is obtained by measuring the magnetic field noise spectrum of a single 25Mg+ ion. With the magnetic field noise suppressed, the expected contribution of the magnetic field noise to the stability of the 25Mg+–27Al+ ion optical clock can be decreased from to .

Entanglement-Assisted Quantum Codes From Algebraic Geometry Codes

Quantum error-correcting codes play the role of suppressing noise and decoherence in quantum systems by introducing redundancy. Some strategies can be used to improve the parameters of these codes. For example, entanglement can provide a way for quantum error-correcting codes to achieve higher rates than the one obtained by means of the traditional stabilizer formalism. Such codes are called entanglement-assisted quantum error-correcting (EAQEC) codes. In this paper, we utilize algebraic geometry codes to construct several families of EAQEC codes derived from the Euclidean and the Hermitian construction. Three families constructed here consist of codes whose quantum Singleton defect is equal to zero, one, or two. We also construct families of EAQEC codes with an encoding rate exceeding the quantum Gilbert-Varshamov bound. Additionally, asymptotically good towers of linear complementary dual codes are used to obtain asymptotically good families of EAQEC codes consuming maximal entanglement. Furthermore, a simple comparison with the quantum Gilbert-Varshamov bound demonstrates that, by utilizing the proposed construction, it is possible to generate an asymptotically family of EAQEC codes that exceeds this bound.

Master equation incorporating the system-environment correlations present in the joint equilibrium state

We present a general master equation, correct to second order in the system-environment coupling strength, that takes into account the initial system-environment correlations. We assume that the system and its environment are in a joint thermal equilibrium state, and thereafter a unitary operation is performed to prepare the desired initial system state, with the system Hamiltonian possibly changing thereafter as well. We show that the effect of the initial correlations shows up in the second-order master equation as an additional term, similar in form to the usual second-order term describing relaxation and decoherence in quantum systems. We apply this master equation to a generalization of the paradigmatic spin-boson model, namely a collection of two-level systems interacting with a common environment of harmonic oscillators, as well as a collection of two-level systems interacting with a common spin environment. We demonstrate that, in general, the initial system-environment correlations need to be accounted for in order to accurately obtain the system dynamics.

Rotational Coupling in Methyl-Tunneling Electron Spin Echo Envelope Modulation

Coherence between tunnel-split states of a methyl quantum rotor can be generated and observed in stimulated and spin-locked echo experiments, if hyperfine coupling of a nearby electron spin to the methyl protons breaks C_3 symmetry and is of the same order of magnitude as the tunnel splitting. Here, we consider the case of two methyl groups bound to the same sp^{3}-hybridized atom, which is important in the context of common nitroxide spin labels. For a simple form of the rotor-rotor coupling Hamiltonian, we provide an approach that allows for density operator computations of this system with 1152 quantum states with moderate computational effort. We find that, in the regime where the ratio between rotor-rotor coupling and rotational barrier is much smaller than unity, three-pulse ESEEM and hyperfine-decoupled ESEEM depend only on the tunnel splitting, but not on this ratio. This finding may simplify the treatment of tunnel-induced electron decoherence in systems where the methyl groups are bound to sp^{3}-hybridized atoms.

Time-delayed quantum feedback and incomplete decoherence suppression with a no-knowledge measurement

The no-knowledge quantum feedback was proposed by Szigeti et al., Phys. Rev. Lett. 113, 020407 (2014), as a measurement-based feedback protocol for decoherence suppression for an open quantum system. By continuously measuring environmental noises and feeding back controls on the system, the protocol can completely reverse the measurement backaction and therefore suppress the system's decoherence. However, the complete decoherence cancellation was shown only for the instantaneous feedback, which is impractical in real experiments. Therefore, in this work, we generalize the original work and investigate how the decoherence suppression can be degraded with unavoidable delay times, by analyzing non-Markovian average dynamics. We present analytical expressions for the average dynamics and numerically analyze the effects of the delayed feedback for a coherently driven two-level system, coupled to a bosonic bath via a Hermitian coupling operator. We also find that, when the qubit's unitary dynamics does not commute with the measurement and feedback controls, the decoherence rate can be either suppressed or amplified, depending on the delay time.

Dynamical decoupling with initial system-environment correlations

Dynamical decoupling (DD) technique is one of the most successful methods to suppress decoherence in qubit systems. In this paper, we studied a solvable pure dephasing model and investigated how DD sequences and initial correlations affect this system. We gave the analytical expressions of decoherence functions and compared the decoherence suppression effects of DD pulses in Ohmic, sub-Ohmic and super-Ohmic environments. Our results show that (1) The initial system-environment correlation will cause additional decoherence. In order to control the dynamic process of open quantum system more accurately and effectively, the initial correlation between the system and reservoir must be considered. (2) High frequency DD pulses can significantly reduce the amplitude of the decoherence function even in the presence of initial system-environment correlations.

Dynamical decoupling in water-glycerol glasses: a comparison of nitroxides, trityl radicals and gadolinium complexes.

Our previous study on nitroxides in o-terphenyl (OTP) revealed two separable decoherence processes at low temperatures, best captured by the sum of two stretched exponentials (SSE) model. Dynamical decoupling (DD) extends both associated dephasing times linearly for 1 to 5 refocusing pulses [Soetbeer et al., Phys. Chem. Chem. Phys., 2018, 20, 1615]. Here we demonstrate an analogous DD behavior of water-soluble nitroxides in water-glycerol glass by using nitroxide and/or solvent deuteration for component assignment. Compared to the conventional Hahn experiment, we show that Carr-Purcell and Uhrig DD schemes are superior in resolving and identifying active dephasing mechanisms. Thereby, we observe a partial coherence loss to intramolecular nitroxide and trityl nuclei that can be alleviated, while the zero field splitting-induced losses for gadolinium labels cannot be refocused and contribute even at the central transition of this spin-7/2 system. Independent of the studied spin system, Uhrig DD leads to a characteristic convex dephasing envelope in both protonated water-glycerol and OTP glass, thus outperforming the Carr-Purcell scheme.

Quantum information leakage.

Decoherence in quantum systems compromises the quantum information processing. However, in molecular systems, coherence is not completely lost and residual coherence can provide important information to guide the design of efficient molecular qubits.

Dephasing due to semi-conductor charging masks decoherence in electron-wall systems

In the interaction between a quantum mechanical electron wave and a wall, loss of interference contrast is observed. It is of general interest to identify the mechanism and categorize its nature as dephasing or decoherence. Decoherence is of fundamental importance for the transition between the classical and quantum boundary, while dephasing is often an experimental detriment that needs to be understood and overcome. We find that the loss of contrast is attributed to a local charge distribution induced by secondary emission: a dephasing mechanism. This mechanism is expected to be present for many materials, is clearly visible for copper oxide, and can mask decoherence mechanisms. The local charge distribution on the wall causes a loss of contrast and electron beam deformation. A model based on Coulomb interaction with the surface charge gives good agreement for both features. Our model can thus be used to improve the experimental design and lead to separate out decoherence phenomena in the electron-wall system.

Adiabatic Fock-state-generation scheme using Kerr nonlinearity

We propose a theoretical scheme to deterministically generate Fock states in a Kerr cavity thorough adiabatic variation of the driving field strength and the cavity detuning. We show that the required time to generate a $n$-photon Fock state scales as the square root of $n$. Requirements for the Kerr coefficient relative to the system decoherence rate are provided as a function of desired state fidelity, indicating that the scheme is potentially realizable with the present state of the art in microwave superconducting circuits.

Benchmarking Maximum-Likelihood State Estimation with an Entangled Two-Cavity State.

The efficient quantum state reconstruction algorithm described by Six etal. [Phys. Rev. A 93, 012109 (2016)PLRAAN2469-992610.1103/PhysRevA.93.012109] is experimentally implemented on the nonlocal state of two microwave cavities entangled by a circular Rydberg atom. We use information provided by long sequences of measurements performed by resonant and dispersive probe atoms over timescales involving the system decoherence. Moreover, we benefit from the consolidation, in the same reconstruction, of different measurement protocols providing complementary information. Finally, we obtain realistic error bars for the matrix elements of the reconstructed density operator. These results demonstrate the pertinence and precision of the method, directly applicable to any complex quantum system.

Phonon-induced relaxation and decoherence times of the hybrid qubit in silicon quantum dots

We study theoretically the phonon-induced relaxation and decoherence processes in the hybrid qubit in silicon. Hybrid qubit behaves as a charge qubit when the detuning is close to zero and as spin qubit for large detuning values. It is realized starting from an electrostatically defined double quantum dot where three electrons are confined and manipulated through only electrical tuning. By employing a three-level effective model for the qubit and describing the environment bath as a series of harmonic oscillators in the thermal equilibrium states, we extract the relaxation and decoherence times as a function of the bath spectral density and of the bath temperature using the Bloch-Redfield theory. For Si quantum dots the energy dispersion is strongly affected by the physics of the valley, i.e. the conduction band minima, so we also included the contribution of the valley excitations in our analysis. Our results offer fundamental information on the system decoherence properties when the unavoidable interaction with the environment is included and temperature effects are considered.

Collisional unfolding of quantum Darwinism

We examine the emergence of objectivity via quantum Darwinism through the use of a collision model, i.e. where the dynamics is modeled through sequences of unitary interactions between the system and the individual constituents of the environment, termed "ancillas". By exploiting versatility of this framework, we show that one can transition from a "Darwinistic" to an "encoding" environment by simply tuning their interaction. Furthermore we establish that in order for a setting to exhibit quantum Darwinism we require a mutual decoherence to occur between the system and environmental ancillas, thus showing that system decoherence alone is not sufficient. Finally, we demonstrate that the observation of quantum Darwinism is sensitive to a non-uniform system-environment interaction.

Ehrenfest Statistical Dynamics in Chemistry: Study of Decoherence Effects.

In previous works, we introduced a geometric route to define our Ehrenfest statistical dynamics (ESD) and we proved that, for a simple toy model, the resulting ESD does not preserve purity. We now take a step further: we investigate decoherence and pointer basis in the ESD model by considering some uncertainty in the degrees of freedom of a simple but realistic molecular model, consisting of two classical cores and one quantum electron. The Ehrenfest model is sometimes discarded as a valid approximation to nonadiabatic coupled quantum-classical dynamics because it does not describe the decoherence in the quantum subsystem. However, any rigorous statistical analysis of the Ehrenfest dynamics, such as the described ESD formalism, proves that decoherence exists. In this article, decoherence in ESD is studied by measuring the change in the quantum subsystem purity and by analyzing the appearance of the pointer basis to which the system decoheres, which for our example is composed of the eigenstates of the electronic Hamiltonian.