Decay Process Research Articles

Dithieno[3,2‐b; 2′,3′‐f]phosphepinium‐Based Near‐Infrared Fluorophores: px–π* Conjugation Inherent to Seven‐Membered Phosphacycles

AbstractPositively charged phosphorus‐containing heterocycles are characteristic core skeletons for functional molecules. While various phosphonium‐containing five‐ or six‐membered‐ring compounds have been reported, the seven‐membered‐ring phosphepinium have not been fully studied yet. In this study, dithieno[3,2‐b; 2′,3′‐f]phosphepinium ions containing electron‐donating aminophenyl groups were synthesized. An X‐ray crystallographic analysis of the resulting donor–acceptor–donor dyes revealed a bent conformation of the central seven‐membered ring. These compounds exhibit fluorescence in the near‐infrared region with a bathochromic shift of ca. 70 nm compared to a phosphepine oxide congener and a large Stokes shift. High fluorescence quantum yields were obtained even in polar solvents due to the suppression of the nonradiative decay process. A theoretical study revealed that the phosphepinium skeleton is highly electron‐accepting owing to the orbital interaction between a px orbital of the phosphonium moiety and a π* orbital of the 1,3,5‐hexatriene moiety. Due to the lower‐lying px orbital in the phosphonium moiety compared to that of the phosphine oxide and the bent conformation of the seven‐membered ring, the phosphepinium ring permits effective px–π* conjugation. A large structural relaxation with a contribution of a quinoidal resonance structure is suggested in the excited state, which should be responsible for the bright emission with a large Stokes shift.

Study of [formula omitted]/EC-decay properties of [formula omitted] shell nuclei using nuclear shell model

Our study employs the nuclear shell model to systematically compute the half-lives of β-decay for nuclei in the mass range of A=18−39, encompassing the majority of sd shell nuclei. This analysis utilizes the USDB and SDNN Hamiltonians. The theoretical outcomes contain calculations of various parameters such as Q-values, half-lives, excitation energy, logft values, and branching ratios. We explore these results with axial–vector coupling constant for weak interactions, denoted as gA(=1.27), and κ value (=6289). We perform calculations of Gamow Teller matrix elements for 116 decay processes to calculate the quenching factor; we found a quenching factor of q=0.794±0.05 for the USDB interaction and q=0.815±0.04 for the SDNN interaction. We have also calculated superallowed transitions 0+→0+ for seven nuclei. Further, we have also included the electron capture phase space factor for the required nuclei to calculate the half-lives. This inclusion leads to small contribution in results, particularly for nuclei where electron capture (EC) plays a significant role. The overall results are in agreement with the experimental data.

Distinct vibrational motions promote disparate excited-state decay pathways in cofacial perylenediimide dimers.

A complex interplay of structural, electronic, and vibrational degrees of freedom underpins the fate of molecular excited states. Organic assemblies exhibit a myriad of excited-state decay processes, such as symmetry-breaking charge separation (SB-CS), excimer (EX) formation, singlet fission, and energy transfer. Recent studies of cofacial and slip-stacked perylene-3,4:9,10-bis(dicarboximide) (PDI) multimers demonstrate that slight variations in core substituents and H- or J-type aggregation can determine whether the system follows an SB-CS pathway or an EX one. However, questions regarding the relative importance of structural properties and molecular vibrations in driving the excited-state dynamics remain. Here, we use a combination of two-dimensional electronic spectroscopy, femtosecond stimulated Raman spectroscopy, and quantum chemistry computations to compare the photophysics of two PDI dimers. The dimer with 1,7-bis(pyrrolidin-1'-yl) substituents (5PDI2) undergoes ultrafast SB-CS from a photoexcited mixed state, while the dimer with bis-1,7-(3',5'-di-t-butylphenoxy) substituents (PPDI2) rapidly forms an EX state. Examination of their quantum beating features reveals that SB-CS in 5PDI2 is driven by the collective vibronic coupling of two or more excited-state vibrations. In contrast, we observe signatures of low-frequency vibrational coherence transfer during EX formation by PPDI2, which aligns with several previous studies. We conclude that key electronic and structural differences between 5PDI2 and PPDI2 determine their markedly different photophysics.

Accessing the Characteristics of Nuclear Reactions: A Radioactive Decay and Half-Life Measurement Study

This study investigates the impact of external environmental factors, specifically electromagnetic fields and pressure variations, on the decay constants and half-lives of three radioactive isotopes: 60Co, 137Cs, and 226Ra. By conducting controlled laboratory experiments, the research aimed to quantify the extent to which these factors influence decay rates, challenging the traditional assumption of invariant half-lives. The isotopes were exposed to varying levels of electromagnetic fields (0-100 Gauss) and pressure (1-10 atm), with decay rates measured using high-resolution gamma-ray spectrometers. The results revealed that while 137Cs exhibited the most significant sensitivity, with a 13.04% increase in decay constant under extreme conditions, 60Co and 226Ra showed moderate and minimal changes, respectively. These findings have important implications for fields such as nuclear medicine, radiometric dating, and nuclear waste management, where precise knowledge of decay rates is crucial. The study contributes to a deeper understanding of nuclear decay processes and highlights the need for further research on the effects of other environmental factors, such as temperature and chemical composition, on radioactive decay.

The solvation shell probed by resonant intermolecular Coulombic decay

Molecules involved in solvation shells have properties differing from those of the bulk solvent, which can in turn affect reactivity. Among key properties of these molecules are their nature and electronic structure. Widely used tools to characterize this type of property are X-ray-based spectroscopies, which, however, usually lack the capability to selectively probe the solvation-shell molecules. A class of X-ray triggered “non-local” processes has the recognized potential to provide this selectivity. Intermolecular Coulombic decay (ICD) and related processes involve neighbouring molecules in the decay of the X-ray-excited target, and are thus naturally sensitive to its immediate environment. Applying electron spectroscopy to aqueous solutions, we explore the resonant flavours of ICD and demonstrate how it can inform on the first solvation shell of excited solvated cations. One particular ICD process turns out to be a potent marker of the formation of ion pairs. Another gives a direct access to the electron binding energies of the water molecules in the first solvation shell, a quantity previously elusive to direct measurements. The resonant nature of the processes makes them readily measurable, providing powerful new spectroscopic tools.

METTL14-mediated m6A mRNA modification of G6PD promotes lung adenocarcinoma

METTL14 functions as an RNA methyltransferase involved in m6A modification, influencing mRNA biogenesis, decay, and translation processes. However, the specific mechanism by which METTL14 regulates glucose-6-phosphate dehydrogenase (G6PD) to promote the progression of lung adenocarcinoma (LUAD) is not well understood. Quantitative measurement and immunohistochemistry (IHC) analysis have demonstrated higher levels of m6A in LUAD tissues compared to adjacent normal tissues. Additionally, the expression of METTL14 was significantly increased in LUAD tissues. In LUAD cell lines, both METTL14 and m6A levels were elevated compared to normal human lung epithelial cells. Knockdown of METTL14 markedly reduced LUAD cell proliferation, migration, and invasion. Conversely, overexpression of METTL14, but not the mutant form, significantly enhanced these cellular processes in LUAD. In vivo studies using nude mice with subcutaneously transplanted LUAD cells demonstrated that stable METTL14 knockdown led to notably reduced tumor volume and weight, along with fewer Ki67-positive cells and lung metastatic sites. Importantly, METTL14 knockdown reduced glycolytic activity in LUAD cells. Through a combination of RNA sequencing and MeRIP-sequencing, we identified numerous altered genes and confirmed that IGF2BP2 enhances G6PD mRNA stability after METTL14-mediated m6A modification, thereby promoting tumor growth and metastasis. Moreover, LUAD patients with higher levels of G6PD had poorer overall survival (OS). In conclusion, our study indicates that METTL14 upregulates G6PD expression post-transcriptionally through an m6A-IGF2BP2-dependent mechanism, thereby stabilizing G6PD mRNA. These findings propose potential diagnostic biomarkers and effective targets for anti-metabolism therapy in LUAD.

Bottom quark dynamics from nonprompt D0 and J/ψ production in Pb+Pb collisions at sNN=5.02 TeV

We study bottom quark energy loss via the nuclear modification factor (RAA) and elliptic flow (v2) of nonprompt D0 and J/ψ in relativistic heavy-ion collisions at the Large Hadron Collider (LHC). The space-time profile of quark-gluon plasma is obtained from the hydrodynamics simulation, the dynamical evolution of heavy quarks inside the color deconfined QCD medium is simulated using a linear Boltzmann transport model that combines Yukawa and string potentials of heavy-quark-medium interactions, the hadronization of heavy quarks is performed using a hybrid coalescence-fragmentation model, and the decay of B mesons is simulated via . Using this numerical framework, we calculate the transverse momentum (pT) dependent RAA and v2 of direct D mesons, B mesons, and nonprompt D0 and J/ψ from B meson decay in Pb+Pb collisions at sNN=5.02 TeV. We find the mass hierarchy of the nuclear modification of prompt D and B mesons depends on their pT. Both RAA and v2 of heavy flavor particles show strong pT and centrality dependences due to the interplay between parton energy loss, medium geometry and flow, and hadronization of heavy quarks. Nonprompt D0 and J/ψ share similar patterns of RAA and v2 to B mesons except for a pT shift during the decay processes. Therefore, future more precise measurements on nonprompt D0 and J/ψ can help further pin down the bottom quark dynamics inside the quark-gluon plasma. Published by the American Physical Society 2024

Manipulation and applications of ultrafast all-optical switching based on transient absorption and dispersion in KTN crystals.

Potassium tantalate niobate (KTN) represents a noteworthy category of optical crystals known for their superior nonlinear optical properties. In this study, we conducted measurements of femtosecond time-resolved transient absorption (TA) spectra in KTa0.57Nb0.43O3 crystals. Notably, a rapid and pronounced "plateau" phase, ∼1.5 ps in duration, was detected at the onset of the TA kinetics and succeeded by two distinct decay components, exhibiting lifetimes of ∼140 ps and over 10 ns, respectively. We attribute these observations to a decay process involving two-photon absorption, dispersion characteristics, and excited state absorption. Based on this unique TA characteristic of KTN crystals, an all-optical switching strategy was proposed and utilized to measure the ultrafast lasing dynamics of single-crystal CH3NH3PbBr3 nanowires. This polarization-independent TA gate approach offers an adjustable gate width combining ps and ns time scales and introduces a versatile tool for advanced optical applications.

Production of pentaquarks with hidden charm and double strangeness in Ξb and Ωb decays

Recently, several pentaquark states Pcss, with global flavor c¯cssn, have been predicted within a theoretical framework based on unitary coupled channels. We study theoretically the feasibility to observe the Pcss with I(JP)=12(12−) in the decays Ξb0→ηηcΞ0 and Ωb−→K−ηcΞ0. Indeed, within the model, the ηcΞ0 channel is the lowest mass pseudoscalar-baryon channel to which this pentaquark state couples, thus we can expect to observe its signal in the ηcΞ0 invariant mass distribution of the mentioned decays. We identify the dominant weak decay processes and then implement the hadronization into the different meson-baryon channels in the final state, linked by flavor symmetry. The dominant meson-baryon final state interaction is then implemented to generate the full amplitude, implicitly accounting for the dynamical emergence of the pentaquark states. We obtain a clear Breit-Wigner-like resonant signal in the spectrum of the Ωb− decay, exceeding that in the Ξb0 decay by two to three orders of magnitude. In the case of the latter decay, the resonant state would manifest as a significant dip in the spectrum. We study the feasibility of searching for these b-hadron decay modes and analyzing their resonant components using the current and future data samples from the LHCb experiment. Published by the American Physical Society 2024

Mechanical Tuning of Fluorescence Lifetime and Bandgap in an Elastically Flexible Molecular Semiconductor Crystal.

Despite having superior transport properties, lack of mechanical flexibility is a major drawback of crystalline molecular semiconductors as compared to their polymer analogues. Here single crystals of an organic semiconductor are reported that are not only flexible but exhibit systematic tuning of bandgaps, fluorescence lifetime, and emission wavelengths upon elastically bending. Spatially resolved fluorescence lifetime imaging and confocal fluorescence microscopy reveals systematic trends in the lifetime decay across the bent crystal region along with shifts in the emission wavelength. From the outer arc to the inner arc of the bent crystal, a significant decrease in the lifetime of ≈1.9ns is observed, with a gradual bathochromic shift of ≈10nm in the emission wavelength. For the crystal having a bandgap of 2.73eV, the directional stress arising from bending leads to molecular reorientation effects and variations in the extent of intermolecular interactions- which are correlated to the lowering of bandgap and the evolution of the projected density of states. The systematic changes in the interactions quantified using electron density topological analysis in the compressed inner arc and elongated outer arc region are correlated to the non-radiative decay processes, thus rationalizing the tuning of fluorescence lifetime.

Diagnosis of archaeological bones: Analyzing the state of conservation of lower Pleistocene bones through diagenesis methods

Initial physicochemical assessment of cultural materials plays a critical role in the research and management of cultural heritage, serving as a foundation for comprehending deterioration mechanisms and developing effective conservation treatments. However, this knowledge is more advanced in several cultural materials such as artwork or historic buildings, than in bone and fossils. This study focuses on bone material conservation, applying diagenetic methods for characterizing and assessing the state of conservation of archaeological bones from Pit 1 at Barranc de la Boella (BB), an open-air archaeological site from the late Early Pleistocene, from a conservation perspective.Microstructural analyses, including mercury intrusion porosimetry (MIP) and histological analysis, alongside microchemical analyses through Attenuated Total Reflection Fourier Transform Infrared (ATR-FTIR), and FTIR with KBr pellets and X-ray Diffraction (XRD), were conducted to evaluate the decay processes affecting the bones. Results indicated poor bone preservation characterized by high porosity, significant microbial attack, collagen degradation, and the potential recrystallization of bioapatite into fluorapatite. These findings underscore the substantial challenges presented by open-site conditions to preservation efforts and highlight the need for suitable conservation treatments, such as consolidation to reinforce the microstructure.The study emphasizes the importance of characterizing archaeological bones to understand the factors influencing their preservation states and guide conservation works in this material. This work contributes to the knowledge of diagenesis studies to standardize the diagnosis of the state of conservation on archaeological bones.

Design, optimization, and inference of biphasic decay of infectious virus particles.

Virus population dynamics are driven by counter-balancing forces of production and loss. Whereas viral production arises from complex interactions with susceptible hosts, the loss of infectious virus particles is often approximated as a first-order kinetic process. As such, experimental protocols to measure infectious virus loss are not typically designed to identify non-exponential decay processes. Here, we propose methods to evaluate if an experimental design is adequate to identify multiphasic virus particle decay and to optimize the sampling times of decay experiments, accounting for uncertainties in viral kinetics. First, we evaluate synthetic scenarios of biphasic decays, with varying decay rates and initial proportions of subpopulations. We show that robust inference of multiphasic decay is more likely when the faster decaying subpopulation predominates insofar as early samples are taken to resolve the faster decay rate. Moreover, design optimization involving non-equal spacing between observations increases the precision of estimation while reducing the number of samples. We then apply these methods to infer multiple decay rates associated with the decay of bacteriophage ('phage') , an evolved isolate derived from phage . A pilot experiment confirmed that decay is multiphasic, but was unable to resolve the rate or proportion of the fast decaying subpopulation(s). We then applied a Fisher information matrix-based design optimization method to propose non-equally spaced sampling times. Using this strategy, we were able to robustly estimate multiple decay rates and the size of the respective subpopulations. Notably, we conclude that the vast majority (94%) of the phage population decays at a rate 16-fold higher than the slow decaying population. Altogether, these results provide both a rationale and a practical approach to quantitatively estimate heterogeneity in viral decay.

Evaluation of solid medical waste management system in Undata Regional General Hospital, Palu city, Central Sulawesi Province, Indonesia

Waste is an environmental problem that is still not fully resolved properly even though the resulting impact has a major effect on environmental pollution, especially solid medical waste. The purpose of this study was to assess the characteristics of solid medical waste at Undata Hospital based on its sources and types, calculate the average weight of solid medical waste generated per day, and evaluate the solid medical waste management system with sorting, packaging, collection and transportation modes in accordance with the criteria of Permen of Environment and Forestry Number 56 of 2015 and Permenkes Number 2 of 2023. This research uses a qualitative approach with a descriptive research type. This research was conducted in August-September 2023. The sampling technique in this study used Purposive Sampling, with 18 informants selected from each unit/room/installation at Undata Hospital, Palu City. Based on the results of the study, it was found that every day Undata Palu Hospital produces domestic waste as much as ± 270 kg / day. The results of the evaluation of the solid medical waste management system at Undata Palu Hospital show that basically it is quite effective but not optimal, because the storage process shows non-compliance with the guidelines for medical waste management by the Ministry of Health Number 2 of 2023, namely storage in TPS which should not be more than 2x24 hours, but in fact the accumulation of solid medical waste is stored for 1 month in the LB3 TPS due to delays in transportation by third parties. This causes a large amount of solid waste in the TPS so that the TPS becomes full and dangerous because the waste undergoes a process of decomposition and decay, which is harmful to the environment and human health. Undata Hospital needs to maximize the procurement of internal medical waste processing equipment (incineration equipment) which needs to be supported by the Environmental Agency and the relevant Health Office to prevent environmental pollution from medical activities.

Modeling Intermolecular Coulombic Decay with Non-Hermitian Real-Time Time-Dependent Density Functional Theory.

In this work, we investigate the capability of using real-time time-dependent density functional theory (RT-TDDFT) in conjunction with a complex absorbing potential (CAP) to simulate the intermolecular Coulombic decay (ICD) processes following the ionization of an inner-valence electron. We examine the ICD dynamics in a series of noncovalent bonded dimer systems, including hydrogen-bonded and purely van der Waals (VdW)-bonded systems. In comparison to previous work, we show that RT-TDDFT simulations with a CAP correctly capture the ICD phenomenon in systems exhibiting a stronger binding energy. The calculated time scales for ICD of the studied systems are in the range of 5-50 fs, in agreement with previous studies. However, there is a breakdown in the accuracy of the methodology for the pure VdW-bonded systems. Overall, the presented RT-TDDFT/CAP methodology provides a powerful tool for differentiating between competing electronic relaxation pathways following inner-valence or core ionization without necessitating any a priori assumptions.

Recursive analytical solution for nonequilibrium multispecies transport of decaying contaminant simultaneously coupled in both the dissolved and sorbed phases

Multispecies transport analytical models that solve advection-dispersion equations (ADEs) are efficient tools for evaluating the transport of decaying contaminants and their sequential products. This study develops a novel semi-analytical model to simulate the multispecies transport of decaying contaminants, considering nonequilibrium sorption and decay in both dissolved and sorbed phases. First-order reversible kinetic sorption equations with decay processes are coupled to ADEs. Recursive analytical solutions, using the Laplace transform and generalized integral transform, are developed to address the mathematical complexity of the governing equations. The model's simulation results show excellent agreement with both numerical models and existing analytical solutions. Applied to a four-member radionuclide decay chain, the model reveals that including decay in the sorbed phase results in a lower concentration of the first member and avoids underestimating the radioactivity concentrations of daughter elements. These differences in dissolved radioactivity concentrations between models with and without sorbed phase decay may impact health risk assessments for radioactive waste disposal. Finally, this study provides a more sophisticated mathematical tool for analyzing multispecies transport in real field conditions where nonequilibrium sorption processes predominantly occur.

Decay-angular-distribution correlated CP violation in heavy hadron cascade decays

CP violation in baryon decay processes is still undiscovered to date. We present a general analysis of the decay-angular distributions and the corresponding CP asymmetries in cascade decays of the type H→R(→ab)c, where H is a heavy hadron that decays through weak interactions H→Rc and the resonance R decays strongly via R→ab. Based on the analysis, we propose to search for CP violation in the decay-angular distributions in the cascade decay processes B→BM, with B or M subsequently decaying through strong interactions, where B is the mother baryon, B and M are the daughter baryon and meson, respectively, and M has to be spin nonzero. We also present some typical decay channels in which the search for such kinds of CP asymmetries can be performed. Published by the American Physical Society 2024

Directional emission and photon bunching from a qubit pair in waveguide

Waveguide quantum electrodynamics represents a powerful platform to generate entanglement and tailor photonic states. We consider a pair of identical qubits coupled to a parity invariant waveguide in the microwave domain. By working in the one- and two-excitation sectors, we provide a unified view of decay processes and show the common origin of directional single-photon emission and two-photon directional bunching. Unveiling the quantum trajectories, we demonstrate that both phenomena are rooted in the selective coupling of orthogonal Bell states of the qubits with photons propagating in opposite directions. We comment on how to use this mechanism to implement optimized post-selection of Bell states, heralded by the detection of a photon on one side of the system. Published by the American Physical Society 2024

Field Theory of the Fermi Function.

The Fermi function F(Z,E) accounts for QED corrections to beta decays that are enhanced at either small electron velocity β or large nuclear charge Z. For precision applications, the Fermi function must be combined with other radiative corrections and with scale- and scheme-dependent hadronic matrix elements. We formulate the Fermi function as a field theory object and present a new factorization formula for QED radiative corrections to beta decays. We provide new results for the anomalous dimension of the corresponding effective operator complete through three loops, and resum perturbative logarithms and π enhancements with renormalization-group methods. Our results are important for tests of fundamental physics with precision beta decay and related processes.

Data from “A Registered Report Testing the Effect of Sleep on DRM False Memory: Greater Lure and Veridical Recall but Fewer Intrusions After Sleep”

This paper describes a rich dataset from a registered report investigating sleep’s effect on false memory in the Deese-Roediger-McDermott (DRM) paradigm. 534 young adults completed free recall either shortly or 12 hours after studying lists of semantic associates (e.g., hospital, nurse). Collected online, our recall data showcase high data quality, replicating classic behavioural effects (e.g., serial position curve). The dataset contains raw recall data with original spelling and recall order, accompanied by demographic information (e.g., gender, time-of-day preference). Its versatility supports reuse in modelling memory decay and search processes, understanding lexical effects and individual differences, and benchmarking online memory studies.

Dark matter production accompanied by gravitational wave signals during cosmological phase transitions

We investigate the temperature-dependent production of feebly interacting massive dark matter particle (FIMP DM) within a Z2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$Z_2$$\\end{document} model, incorporating two Z2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$Z_2$$\\end{document}-odd scalar fields. In specific parameter regions, three distinct mechanisms individually dominate the production of the FIMP DM. These mechanisms include the semi-production process, commonly known as the “exponential growth” process, the three-body decay process, and the production from pair annihilations of the bath particles. It is crucial to consider the thermal history during the evolution of FIMPs, as it involves multiple phase transitions occurring prior to the freeze-in of dark matter. Consequently, the scalar masses experience thermal variations, leading to distinctive evolutionary trajectories for FIMPs when compared to scenarios without accounting for the thermal effects. Notably, the unique patterns of FIMP evolution are accompanied by the production of gravitational waves, presenting promising opportunities for detection using forthcoming interferometers.