Dc Magnetic Properties Research Articles

Method for the fabrication of thick multilayered nickel/iron oxide nanoparticle magnetic nanocomposites

Magnetic nanocomposites consisting of ferrite nanoparticles and magnetic metals have been of interest for use in power electronic components due to their ability to achieve relatively high magnetic permeabilities while also having low losses. Unfortunately, fabrication challenges limit the maximum achievable thickness of these films to ∼ 4 µm, though thicker films are desirable for increased power handling. To overcome these challenges this works seeks to demonstrate a fabrication method whereby thick composite films can be made by constructing sequential composite layers, performing electrophoretic deposition and electro-infiltration steps for each layer. Composite samples of iron oxide nanoparticles electro-infiltrated with nickel that are 1, 3, 5, 7, and 10 layers thick will be fabricated and characterized both structurally and magnetically. Structural measurements accomplished with SEM show that each layer appears to contribute 4 µm to the total thickness, with the one layer sample being 3.99 ± 0.12 µm thick and the ten layer sample being 39.19 ± 3.1 µm thick. Results show that the dc magnetic properties of these composites stay constant as thickness increases, having an average magnetic saturation of 464 kA/m, and coercivity of 2.5 kA/m. The ac magnetic properties similarly showed that the permeability of the composites also stayed consistent at 20. However, the dimensional resonance frequency of the composites decreased as thickness increased, lowering to ∼ 96 MHz for 1 layer (∼4 µm) to ∼ 8 MHz for 10 layers (∼40 µm), revealing a trade-off between thickness of a maximum operating frequency.

Large exchange bias and low-temperature glassy state in the frustrated triangular-lattice antiferromagnetBa3NiIr2O9

Here, we report both ac and dc magnetization, thermodynamic and electric properties of hexagonal Ba$_3$NiIr$_2$O$_9$. The Ni$^{2+}$ (spin-1) forms layered triangular-lattice and interacts antiferromagnetically while Ir$^{5+}$ is believed to act as magnetic link between the layers. This complex magnetic interaction results in magnetic frustration leading to a spin-glass transition at $T_f$ $\sim$ 8.5 K. The observed magnetic relaxation and aging effect also confirms the nonequilibrium ground state. The system further shows large exchange bias which is tunable with cooling field. Below the Curie-Weiss temperature $\theta_{CW}$ ($\sim$ -29 K), the magnetic specific heat $C_m$ displays a broad hump and at low temperature follows $C_m = \gamma T^\alpha$ dependence where both $\gamma$ and $\alpha$ show dependence on temperature and magnetic field. A sign change in magnetoresistace is observed which is due to an interplay among magnetic moment, field and spin-orbit coupling.

Europium(III), Terbium(III), and Gadolinium(III) Oxamato-Based Coordination Polymers: Visible Luminescence and Slow Magnetic Relaxation.

The reaction of aqueous solutions of EuIII, TbIII, and GdIII ions with Na2Hpcpa [H3pcpa = N-(4-carboxyphenyl)oxamic acid] afforded three new isostructural oxamate-containing lanthanide(III) coordination polymers of general formula {LnIII2(Hpcpa)3(H2O)5·H2O}n [Ln = Eu (1),Tb (2), and Gd(3)]. Their structure is made up of neutral zigzag chains running parallel to the [101] direction where double syn-syn carboxylate(oxamate)-bridged dilanthanide(III) pairs (Ln1 and Ln2) are linked by three Hpcpa2- ligands, one of them with the μ-κ2O,O':κO″ coordination mode and the other two with the μ3-κ2O,O':κO″:κO'''. Additionally, two of those chains are interlinked through hydrogen bonding and π-π type interactions, resulting in a porous structure with channels where water molecules are hosted. The emission properties of 1 and 2 are evaluated as a function of the temperature, exhibiting an emission in red and green, respectively. The external quantum yield for 2 is approximately 7 times that obtained for 1, indicating that the oxamate ligand is a better sensitizer for TbIII ions. The temperature dependence of the dc magnetic properties of 1-3 reveals a different magnetic behavior depending on the nature of the LnIII ion. A continuous decrease of χMT occurs for 1 upon cooling, and finally χMT tends to vanish, as expected for the thermal depopulation of the six magnetic 7FJ excited states (J = 1-6) of the EuIII ion with a nonmagnetic 7F0 ground state. χMT for 2 decreases sharply with decreasing the temperature due to the depopulation of the splitted mJ levels of the 7F7 ground state of the magnetically anisotropic TbIII ion. A very weak antiferromagnetic interaction between the magnetically isotropic GdIII ions across the double carboxylate(oxamate) bridge is responsible for the small decrease of χMT at low temperatures for 3. The dynamic (ac) magnetic properties of 2 and 3 reveal a slow magnetic relaxation with very incipient frequency-dependent χM″ signals below 6.0 K (2) and frequency-dependent χM″ peaks below 10.0 K (3) under nonzero applied dc magnetic fields, being thus new examples of field-induced single molecule magnets (SMMs).

Effect of Cr3+ substitution on dc electrical resistivity and magnetic properties of Cu0.7Co0.3Fe2−xCrxO4 ferrite nanoparticles prepared by sol-gel auto combustion method

Using sol-gel auto combustion technique complex ferrite nanoparticles have been synthesized. Characterization with the help of X-ray diffraction (XRD) revealed that the synthesized materials Cu0.7Co0.3Fe2−xCrxO4 are of a single-phase cubic spinel structure with Fd-3 m space group. And also, the samples’ crystallite sizes calculated using XRD data yielded in the range of 19.28–32.92 nm. The lattice constants are calculated to be between 8.4099 Å and 8.4441 Å. The FTIR results revealed that the spinel structure remained undisturbed even after the Cr ions were doped. FESEM images display the materials constitute polygonal-shaped grains though at times irregularly shaped gains with slight agglomeration appear. EDS analysis confirmed that the sample contained the constituent elements. A decreasing pattern in DC resistivity with an increase in temperature was observed, ensuring the semiconducting character of the ferrites under investigation. VSM was utilized to characterize and estimate the magnetic features like magnetic saturation and coercivity of the samples.

Unexpected formation of a dodecanuclear {CoII6CuII6} nanowheel under ambient conditions: magneto-structural correlations.

We report the unique heterobimetallic dodecanuclear oxamate-based {CoII6CuII6} nanowheel obtained using an environmentally friendly synthetic protocol. The effective Hamiltonian methodology employed herein allows the rationalisation of magnetic isotropic or anisotropic metal clusters, being a significant advance for future studies of exciting properties only observed at low and ultralow temperatures.

Magnetism at an iridate/manganite interface: Influence of strong spin-orbit interaction

The complex investigation of dc transport and magnetic properties of the epitaxial manganite/iridate heterostructure was carried out by mean of X-ray (XRD), dc resistance measurements, ferromagnetic resonance (FMR) and polarized neutron reflectivity (PNR). Epitaxial growth of the heterostructure proceeded according to the cube-to-cube mechanism with the small lattice turn. The dc measurement indicates the presence of a conduction channel at the iridate/manganite interface due to the charge leakage from iridate that makes it hole doped, while the manganite side becomes electron doped. This is confirmed by the first principles calculations based on density functional theory [Sayantika Bhowal, and Sashi Satpathy AIP Conference Proceedings 2005, 020007 (2018)] that show the charge transfer at the interface from the half-filled spin-orbit entangled Jeff = 1/2 state of the iridate to the empty e states of manganite. The neutron scattering data show the turn of magnetization vector of the heterostructure (mainly manganite) on 26 degree closer to the external field with reducing temperature down to 10K. Additional ferromagnetic state appearing at T<100K indicate on emergence of ferromagnetism in the thin (10 nm) paramagnetic SIO film close to the interface. We have measured the dc voltage aroused on the SIO film caused by spin pumping and the anisotropic magnetoresistance in the heterostructure.

Modulating Magnetic and Photoluminescence Properties in 2-Aminonicotinate-Based Bifunctional Coordination Polymers by Merging 3d Metal Ions.

Herein, the synthesis and study of bifunctional coordination polymers (CPs) with both magnetic and photoluminescence properties, derived from a heterometallic environment, are reported. As a starting point, three isostructural monometallic CPs with the formula [M(μ-2ani)2 ]n (MII =Mn (1Mn ), Co (3Co ) and Ni (4Ni ); 2ani=2-aminonicotinate), crystallise as chiral 2D-layered structures stacked by means of supramolecular interactions. These compounds show high thermal stability in the solid state (above 350 °C), despite which, in aqueous solution, compound 1Mn is shown to partially transform into a novel 1D chain CP with the formula [Mn(2ani)2 (μ-H2 O)2 ]n (2Mn ). A study of the direct current (dc) magnetic properties of 1Mn , 3Co and 4Ni reveals a spin-canted structure derived from antisymmetric antiferromagnetic weak exchanges along the chiral network (as confirmed by DFT calculations) and magnetic anisotropy of the ions, in such a way that long-range ordering is observed with variable magnitude for the spin carriers. Moreover, compounds 3Co and 4Ni show no frequency-dependent alternating current (ac) susceptibility curves under zero dc field; this is characteristic behaviour of a glassy state that may be partially supressed for 3Co by applying an external dc field. To overcome long-range magnetic ordering, CoII ions are diluted in a diamagnetic ZnII -based matrix, which enables single-molecule magnet behaviour. Interestingly, this strategy allows a bifunctional Cox Zn1-x 2ani material, which is imbued with a strong photoluminescent emitting capacity, as characterised by an intense blue light followed by a green afterglow, to be obtained.

Hysteresis Measurements and Numerical Losses Segregation of Additively Manufactured Silicon Steel for 3D Printing Electrical Machines

Samples from FeSi4 powder were fabricated with a low power selective laser melting (SLM) system using a laser re-melting strategy. The sample material was characterized through magnetic measurements. The study showed excellent DC magnetic properties, comparable to commercial and other 3D printed soft ferromagnetic materials from the literature at low (1 T) magnetization. Empirical total core losses were segregated into hysteresis, eddy and excessive losses via the subtraction of finite element method (FEM) simulated eddy current losses and hysteresis losses measured at quasi-static conditions. Hysteresis losses were found to decrease from 3.65 to 0.95 W/kg (1 T, 50 Hz) after the annealing. Both empirical and FEM results confirm considerable eddy currents generated in the printed bulk toroidal sample, which increase dramatically at high material saturation after annealing. These losses could potentially be reduced by using partitioned material internal structure realized by printed airgaps. Similarly, with regard to the samples characterized in this study, the substantially increased core losses induced by material oversaturation due to reduced filling factor may present a challenge in realizing 3D printed electrical machines with comparable performance to established 2D laminated designs.

Enhanced Magnetic Properties of Barium Hexaferrite

Samples having the composition BaFe12−2xCoxSmxO19 (x = 0.0, 0.2, 0.4, 0.6) are prepared by a WOWS (without water and surfactants) sol–gel technique, and the structural, morphological, and AC and DC electrical and magnetic properties of the samples are investigated. The phase formation of M-type hexaferrite is studied by using indexed x-ray diffraction patterns. Scanning electron microscopy images show that the particle size of the synthesized nanopowder varies from 295 nm to 440 nm. The dielectric constant (e′) exhibits a decreasing trend while the dielectric loss (tan δ) increases with increased doping. DC electrical resistivity (ρDC) is investigated in a temperature range of 373–673 K and indicates an increasing trend with doping. The magnetic hysteresis loops reveal an increase in saturation magnetization (Ms) and remanence (Mr), and a decrease in coercivity (Hc), with the increase in doping content.

Effects of Mixed Valency in an Fe-Based Framework: Coexistence of Slow Magnetic Relaxation, Semiconductivity, and Redox Activity.

A 2-D coordination framework, (NEt4)2[Fe2(fan)3] (1·5(acetone); H2fan = 3,6-difluoro-2,5-dihydroxy-1,4-benzoquinone), was synthesized and structurally characterized. The compound is structurally analogous to a formerly elucidated framework, (NEt4)2[Fe2(can)3] (H2can = 3,6-dichloro-2,5-dihydroxy-1,4-benzoquinone), and adopts a 2-D (6,3) topology with the symmetrical stacking of [Fe2(fan)3]2- sheets that are held in position by the NEt4+ cations between the sheets. The investigation of the dc and ac magnetic properties of 1·5(acetone) revealed ferromagnetic ordering behavior and slow magnetization relaxation, as evinced from ac susceptibility measurements. Furthermore, the exposure of 1·5(acetone) to air led to the formation of a heptahydrate 1·7H2O which displayed distinct magnetic properties. The study of the redox state and extent of delocalization in 1·5(acetone) was undertaken via crystallography, in combination with Mössbauer and vis-NIR spectroscopy, to reveal the mixed-valence and delocalized nature of the as-synthesized material. As a result, the conductivity studies conducted on a pressed pellet showed a relatively high conductivity of 1.8 × 10-2 S cm-1 (300 K). In order to compare structurally related anilate-based structures, a relationship among the redox state, spectroscopic properties, and electronic properties was elucidated in this work. A preliminary investigation of 1·5(acetone) as a candidate anode material in lithium ion batteries revealed a high reversible capacity of 676.6 mAh g-1 and high capacity retention.

Probing the Griffiths like phase, unconventional dual glassy states, giant exchange bias effects and its correlation with its electronic structure in Pr2−xSrxCoMnO6

Crystal, electronic structure, dc and ac magnetization properties of the hole substituted (Sr2+) and partially B-site disordered double perovskite Pr2−xSrxCoMnO6 system have been investigated. The XRD pattern analysis showed a systematic decrease in the lattice parameters owing to the enhanced oxidation states of the Co/Mn ions. The electronic structure study by XPS measurements suggested the presence of mixed valence states of the B-site ions (Co2+ /Co3+ and Mn3+ /Mn4+) with significant enhancement of the average oxidation states due to hole doping. The mere absence of electronic states near the Fermi level in the valence band (VB) spectra for both pure (x = 0.0) and Sr doped (x = 0.5) systems indicated the insulating nature of the samples. Sr substitution is observed to increase the spectral weight near the Fermi level suggesting for an enhanced conductivity of the hole doped system. The dc magnetization data divulged a Griffiths like phase above the long-range ordering temperature. A typical re-entrant spin glass like phase driven by the inherent anti-site disorder (ASD) has been recognized by ac susceptibility study for both the pure and doped systems. Most interestingly, the emergence of a new cluster glass like phase (immediately below the magnetic ordering temperature and above the spin-glass transition temperature) solely driven by the Sr substitution has been unravelled by ac magnetization dynamics study. Observation of these dual glassy states in a single system is scarce and hence placed the present system amongst the rare materials. The isothermal magnetization measurements further probed the exhibition of the giant exchange bias effect originated from the interfacial exchange interactions due to existence of low temperature antiferromagnetic clusters embedded in the glassy matrix.

Magnetic Nanoparticle Systems for Nanomedicine—A Materials Science Perspective

Iron oxide nanoparticles are the basic components of the most promising magneto-responsive systems for nanomedicine, ranging from drug delivery and imaging to hyperthermia cancer treatment, as well as to rapid point-of-care diagnostic systems with magnetic nanoparticles. Advanced synthesis procedures of single- and multi-core iron-oxide nanoparticles with high magnetic moment and well-defined size and shape, being designed to simultaneously fulfill multiple biomedical functionalities, have been thoroughly evaluated. The review summarizes recent results in manufacturing novel magnetic nanoparticle systems, as well as the use of proper characterization methods that are relevant to the magneto-responsive nature, size range, surface chemistry, structuring behavior, and exploitation conditions of magnetic nanosystems. These refer to particle size, size distribution and aggregation characteristics, zeta potential/surface charge, surface coating, functionalization and catalytic activity, morphology (shape, surface area, surface topology, crystallinity), solubility and stability (e.g., solubility in biological fluids, stability on storage), as well as to DC and AC magnetic properties, particle agglomerates formation, and flow behavior under applied magnetic field (magnetorheology).

Preparation and characterisation of soft magnetic composites based on Fe fibres

This paper presents the preparation and characterisation of a new type of soft magnetic composites that are prepared from long Fe fibres instead of ferromagnetic particles. The Fe fibres were coated with a polymeric layer and compacted in toroidal shapes. The influence of polymer content and compaction pressure on the AC and DC magnetic properties of the compacts was investigated. The AC magnetic properties of the compacts were determined in the frequency range from 50 to 10 kHz at the flux densities of 0.1 T. It was found that 1 wt% of polymer ensures proper insulation of the fibres, hindering the development of eddy currents. Also, in order to have good magnetic properties, the compaction pressure should not be lower than 600 MPa. The comparison between the fibre-based soft magnetic composite and powder-based soft magnetic composite evidenced the superior magnetic properties of this new class of composites. For example, in the frequency range of 50 Hz–10 kHz, the initial relative permeability of the fibre-based compact is two times larger than the initial relative permeability of the powder-based compacts.

Effect of Winding Stress on DC Magnetic Properties of Ring Sample

Effect of Winding Stress on DC Magnetic Properties of Ring Sample

Slow Magnetic Relaxation of Co(II) Single Chains Embedded within Metal-Organic Superstructures.

Two coordination polymers of the type Co(BPDC)(N-ox), with BPDC being 4,4'-biphenyldicarboxylate and N-ox being pyridine N-oxide (PNO) or isoquinoline N-oxide (IQNO), have been synthesized and characterized. The compounds feature 2D and 3D metal-organic networks that encapsulate Co(II)-based chains in a rigid superstructure. The dc and ac magnetic properties of these Co(BPDC)(N-ox) materials have been investigated alongside those of a related Co(BDC)(PNO) compound (where BDC is 1,4-benzenedicarboxylate), which contains a smaller dicarboxylate linker. These Co(II)-containing coordination polymers exhibit slow magnetic relaxation, as observed by ac susceptibility measurements. The observed magnetic behavior of all compounds is consistent with an antiferromagnetic interaction between canted Co spins along the 1D skeleton, resulting in single-chain magnet behavior. In the case of Co(BPDC)(IQNO), weak interchain magnetic interactions yield 3D antiferromagnetic order while the inherent magnetic behavior stemming from the chain component is maintained. The combination of these effects in this material puts it at the frontier between single-chain magnets and classical bulk antiferromagnets. This work contributes to the limited group of materials featuring the organization of single-chain magnets within a coordination polymer superstructure.

Field-induced slow magnetic relaxation in pseudooctahedral cobalt(ii) complexes with positive axial and large rhombic anisotropy.

The preparation, X-ray crystal structure, spectroscopic and variable-temperature dc and ac magnetic properties of two six-coordinate cobalt(ii) complexes of formula [Co(bim)4(tcm)2] (1) and [Co(bmim)4(tcm)2] (2) (bim = 1-benzylimidazole, bmim = 1-benzyl-2-methylbenzimidazole and tcm- = tricyanomethanide ion) are reported. 1 and 2 crystallize in the monoclinic P21/n and C2/c space groups with the asymmetric units composed of one tcm- ion and half the [Co(bim)4]2+ and [Co(bmim)4]2+ complex cations, respectively. Their cobalt atoms are in compressed (1)/rhombic (2) CoN6 octahedral environments, the axial positions being occupied by monodentate tricyanomethanide anions. The neutral molecules in 1 are linked through weak C-HN type interactions into supramolecular chains, which are further interconnected into supramolecular 2D motifs by C-Hπ stacking. No short intermolecular interactions occur in 2. The values of the shortest intermolecular cobalt-cobalt separation are 10.901(1) (1) and 10.577(3) Å (2). Detailed ac and dc magnetic studies indicate that 1 and 2 are field-induced single-ion magnets (SIMs) with D = +46.1 (1)/+80.1 cm-1 (2) thus presenting new examples of SIMs with transversal magnetic anisotropy. Theoretical calculations by CASSCF/NEVPT2 support these results and suggest that the relaxation of the magnetization occurs in the ground state under applied fields through two Orbach processes possibly bound to low-lying vibrational modes. Q-band EPR study for polycrystalline samples 1 and 2 at low temperatures confirms the positive sign of D, allows the rough estimation of the E/D ratio [0.144 (1) and 0.180 (2)] and reveals the occurrence of a strong asymmetry in the g-tensors. The values found for the spin-reversal barrier, Ea ≈ 28 and 11 cm-1 (1) and 20 and 9 cm-1 (2), are within the range of those found in other cobalt(ii) field-induced SIMs with a pseudooctahedral trans-CoN4N'2 chromophore.

Влияние токового отжига на температурные зависимости магнитоимпеданса в аморфных микропроводах

Miniaturization of material’s size is the key feature in many technological applications, in particular, in sensor systems. To achieve this goal, Taylor-Ulitovski technique was employed to produce microwires with very small (from 0.2 up to 100 µm) diameters. Ferromagnetic amorphous microwires exhibit giant magnetoimpedance effect (GMI) which is useful to develop high performance magnetic sensors. Since the discovery of GMI, a considerable amount of interest was devoted to enhancing sensitivity with respect to various external stimuli (magnetic field, stress, temperature). On the other hand, GMI sensing elements should have high environment stability. In the present work, a comprehensive study of the temperature effects on the magnetoimpedance behavior in amorphous microwires is conducted. The wires under investigations of the composition Co60.51Fe3.99Cr12.13B13.53Si9.84 have a relatively high Curie temperature (&gt;300 ℃) but may demonstrate considerable temperature dependence in the intermediate temperature range (&lt;100 ℃) of dc and ac magnetic properties. We showed that the as-casted wires exhibited a notable change in magnetic anisotropy, from circumferential to an axial anisotropy, owing to the internal stress relaxation. This is accompanied by huge variation in the magnetoimpedance behavior: the impedance vs magnetic- field plots change shape: from two symmetrical peaks to a single central peak. Current annealing (dc current of 25 mA magnitude for 60 min) was proposed to achieve a thermal stabilization of the magnetization processes and magnetoimpedance in glass-coated amorphous wires.

Ferromagnetic resonance in coupled magnetic nanostructured arrays

The modulated field sweep ferromagnetic resonance (FMR) spectroscopy was used to study the magnetization dynamics in large arrays of interacting cubic nanomagnets. A 60nm thick permalloy (Ni80Fe20) thin films were patterned using a lift-off process into several large arrays of 60 x 60 nm2 nanostructures where the spacing between the magnetic nanocubes was varied to control the strength of dipolar coupling. Electron beam lithography was used for device patterning using lift-off. The permalloy films were deposited using magnetron sputtering. DC magnetic properties were evaluated using alternating gradient force magnetometer (AGFM). In the FMR measurements, the orientation of DC bias magnetic field was varied from the in-plane to out-of-plane with respect to the 2D plane of the arrays. The FMR peak splitting and multiple FMR modes were observed in the evolution of the FMR spectra as the function of the bias field orientation, and were strongly influenced by the nanomagnet geometry and the spacing between the nanomagnets. Two resonance modes, shape and lattice, were particularly well pronounced in the observed FMR spectra. These modes are characterized by effective demagnetizing factors representing different symmetries of the system of interacting nanomagnets. Micromagnetic modeling suggest that micromagnetic texture within the nanomagnets modulated by the stray fields from the neighbors correlates with the FMR spectra.

Dc magnetometry of niobium thin film superconductors deposited using high power impulse magnetron sputtering

We performed a systematic investigation of the dc magnetic properties of superconducting niobium thin films deposited by high power impulse magnetron sputtering (HiPIMS) as a function of the main deposition parameters: the temperature, T, of the heated substrate and the applied dc bias voltage, V, during the sputtering process. The measured dc magnetization curves between 0 and 1000 mT were used to calculate the relative volume of each sample into which the applied magnetic field had penetrated, ðΔV=VÞM. The sample deposited at 700°C with −80 V biased substrate exhibited the least penetration by the magnetic field. ðΔV=VÞM appeared to be highly dependent on the bias voltage at both room temperature and 500°C; however, a broad range of bias voltages showed comparatively similar results at increased temperatures of 700°C. Samples deposited at 700°C exhibit smaller upper critical fields, HC2, than samples deposited at room temperature and 500°C, with the lower temperatures exhibiting a greater dependency on the applied bias. The films deposited at 700°C also display a more stable magnetization curve suggesting that an enhanced flux pinning was achieved when compared to lower temperatures. Consequently, films with stable pinning were found to have the most repeatable dc magnetic behavior. Our results are particularly relevant to the superconducting radio-frequency accelerator scientific community where thin films have been suggested as a technology which may ultimately surpass the performance of bulk niobium. They are also relevant to the fundamental area of superconducting thin films and any applied area where thin films produced by HiPIMS are used, such as superconducting electronics.

Evidence of large magnetic cooling power and double glass transition in Tb5Pd2

We report a detailed dc magnetization, ac susceptibility and magnetocaloric properties of a binary intermetallic compound Tb5Pd2. Our dc magnetization and heat capacity results reveal the absence of long range ordering in this compound. Two distinct frequency dependent peaks (Tf1∼60 K and Tf2∼21 K) had been observed in the ac-susceptibility. Analysis of these frequency dependent peaks by Mydosh parameter, power and Vogel-Fulcher law reveals that around Tf1 the compound is at the boundary of spin glass (SG) like-cluster glass (CG) like state and it undergoes a cluster glass-like freezing below Tf2. Zero field cooled memory effect and non-linear dc susceptibility also confirmed the presence of two glassy transitions in this compound. The transformation from SG/CG boundary to CG phase was also confirmed by the magnetic relaxation measurement and Arrott plots study. Remarkably, a significant magnetic entropy change was also observed in the temperature range of 60–120 K. Additionally a large relative cooling power also observed in this compound. The observed value is comparable to those of promising refrigerant material in this temperature range and is quite notable as in this compound magnetic hysteresis was absent in this temperature range. It was noted that in this compound short-range interactions persist up to a higher temperature above Tf1 and this is responsible for the observation of significant MCE over a wide temperature range. Our studies suggest that this compound is an example of a glassy magnetic compound which shows large magnetocaloric effect.