Evapotranspiration (ET) is an essential parameter in the water cycle and surface energy balance. Accurate estimation of daytime or daily ET is of great significance for many activities in human economic and social development. This study aims to propose a novel method for estimating daytime average ET by using temporal measurements of land surface temperature (LST) and net surface shortwave radiation (NSSR), following a previous developed elliptical relationship between diurnal cycles of LST and NSSR under cloud-free days. The method was primarily developed from the simulated data of a physics-based Atmosphere–Land Exchange (ALEX) model under different underlying surfaces and atmospheric conditions. Based on the simulated data, the proposed method showed considerable accuracy with the overall coefficient of determination ( <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">R</i> <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sup> ) of 0.958 and the root mean square error (RMSE) of 25.3 Wm <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">-2</sup> . In addition, ground ET measurements at four Ameriflux sites (US-ARM, US-SRM, US-Whs, and US-Wkg) during the 2018 growing season were collected to assess the estimated daytime average ET. Results show an overall RMSE of 64.7 Wm <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">-2</sup> for the estimated ET at the four sites, and the US-Whs site reveals a best accuracy ( <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">R</i> <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sup> =0.825, RMSE=44.4 Wm <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">-2</sup> ). These results indicated a potential for generating daytime ET with geostationary satellite observations at regional scales in future development.
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