AbstractSoil moisture (SM) information is invaluable for a wide range of applications, including weather forecasting, hydrological and land surface modeling, and agricultural production. However, there is still a lack of sensing information that adequately represents root‐zone SM for longer periods and larger spatial scales. One option for root‐zone SM observation is terrestrial gamma radiation (TGR), as it is inversely related to SM. Hence, the near real‐time data of more than 5000 environmental gamma radiation (EGR) monitoring stations archived by the EUropean Radiological Data Exchange Platform (EURDEP) is a potential source to develop a root‐zone SM product for Europe without extra investments in SM sensors. This study aims to investigate to what extent the EURDEP data can be used for SM estimation. For this, two EGR monitoring stations were equipped with in situ SM sensors to measure reference SM. The terrestrial component of EGR was extracted after eliminating the contributions of rain washout and secondary cosmic radiation, and used to obtain a functional relationship with SM. We predicted the weekly volumetric SM with a root mean square error of 7%–9% from TGR measurements. Nevertheless, we believe that this technique, due to its greater penetration depth and long data legacy, can provide useful data complementary to satellite‐based remote sensing techniques to estimate root‐zone SM at the continental scale.