Dacite Research Articles

Metals, Volatiles, and Lithostratigraphy of Brothers Submarine Volcano

AbstractRelatively fresh volcanic rocks have been sampled by a remotely operated vehicle in situ from the NE caldera wall of Brothers submarine volcano, associated with Seafloor Massive Sulfide‐SMS deposits. Here, we present the first complete stratigraphic column of the NE caldera wall, comprising at least 12 massive dacitic lava flows, up to 80 m‐thick intercalated with multiple volcaniclastic layers associated with tuffaceous sediment layers. Detailed petrographic and geochemical analyses from hand specimen to crystal to silicate melt scale show chemical variability with depth, correlating partly with an increase in pervasive alteration due to volatile degassing. Moreover, while sulfide saturation occurred prior to volatile exsolution—which sequestrated most chalcophile elements as confirmed by the low metal contents of melt inclusions (e.g., Cu ≤ 1.3 μg/g and Au ≤ 7.0 μg/g)—silicate glass records a Cu enrichment and Au loss with differentiation, with interstitial glass accounting for Cu = 4.2 μg/g and Au = 6.6 μg/g and matrix glass for Cu = 6.0 μg/g and Au = 2.8 μg/g, respectively. Our findings suggest multiple sources for metals compensating for the low initial metal contents: (a) from hydrothermal fluids and volatile percolation ensuing interaction with the host rock and thus also replacement and/or dissolution of pre‐existing magmatic sulfides, (b) directly from the magma, consistent with metal release during magma degassing of metal‐ and Cl‐, and S‐ rich volatiles, and (c) from fluid circulation within unusually metal‐rich andesitic volcaniclastic layers (Cu = 40 μg/g, Au = 1.5 ng/g, and Pt = 0.99 ng/g). Our results elucidate the capacity of such hybrid mineralizing submarine volcanic systems to effectively scavenge, transport, and concentrate metals.

Results of the CO2 diffuse degassing survey from the 2017 IAVCEI CCVG 13th volcanic gas workshop: Pululahua Dome Complex, Ecuador

Pululahua is a potentially active andesite and dacite lava dome complex. This paper presents the results of a survey focused on carbon dioxide (CO2) diffuse degassing at Pululahua, which was conducted during the 2017 International Association of Volcanology and Chemistry of the Earth's Interior (IAVCEI) Commission of the Chemistry of Volcanic Gases (CCVG) 13th Gas Workshop. Our objective was to conduct a comprehensive investigation of CO2 diffuse degassing by employing standard methods for measuring CO2 flux and temperature, and data processing. These methods were applied to map the spatial distribution of the measured parameters, investigate the origin of CO2, and quantify the volcanic CO2 output within the surveyed area of Pululahua. We carried out a total of 350 soil CO2 flux and 329 soil temperature measurements and collected 12 gas samples for carbon isotopic composition analysis, surrounding the three youngest domes in the complex. In addition, seventeen CO2 flux measurements over a thermal water pool were performed. Our findings indicate that the diffuse emission at Pululahua's crater floor is fed by both biogenic and volcanic CO2. Fluxes from each source are similar in magnitude, with approximately 90% of the measurements falling into an intermediate flux range. The occurrence of volcanic CO2 emissions is supported by the carbon isotopic composition. Diffuse degassing distribution highlights a CO2 anomaly surrounding the younger domes within the crater. We estimated the CO2 diffuse emission using both statistical and geostatistical approaches over area of 3.36 km2, resulting in values of 154.2 t d−1 and 126.2 t d−1 respectively. Based on the geostatistical quantification of the total CO2 emission from soil degassing, Pululahua's crater volcanic CO2 contribution is estimated between 59 and 97 t d−1. Finally, the potential hazards associated with the release of cold CO2 at Pululahua's crater are also discussed.

Magmatic sulfide oxidation drives crustal PGE mobilization: Implications for hydrothermal PGE mineralization

Platinum-group elements (PGEs) have a strong affinity for sulfur and tend to accumulate in the deep continental crust, either concentrated within magmatic Cu-Ni-PGE deposits or dispersed throughout disseminated sulfides. However, PGE enrichment in shallow magmatic-hydrothermal systems implies an obscure link to deep sulfide destabilization, which releases PGEs into ore-forming fluids. To bridge this gap, our study investigates the PGE composition of magmatic sulfides with oxidative textures in dacitic rocks from the southwestern Okinawa Trough. We identified three groups of magmatic sulfides, primarily precipitated as Cu-poor monosulfide solid solution (MSS), which formed at distinct stages of magma evolution from deep to shallow crustal levels. Group A sulfides manifest as small-sized inclusions (<30 μm) within most high-Mg olivines, whereas Group B and C sulfides are larger (50–500 μm) and occur within cognate xenoliths of mafic cumulate rocks and the groundmass of host dacites. Group B and C sulfides exhibit distinct oxidative textures and newly-formed mineral assemblages, including magnetite, hematite, goethite, and magnetite ± pyrite, alongside hydrothermal silicate minerals, respectively. We attribute the oxidation process to the infiltration of orthomagmatic fluids exsolved from mafic magma that had underplated the sulfide-bearing felsic magma reservoir, which was nearly solidified. By comparing the chemical compositions between pristine sulfides and their oxidative remnants, we observed extensive mobilization of Pd, Pt, Cu, Ag, Ni, and Co from the altered sulfides of Group B, while Au enrichment occurred as nanoparticles under high oxidation states. In contrast, Au was extracted along with other mobile metals from the altered sulfides of Group C, with Pt remaining in place under more reduced conditions. These distinct scenarios may lead to the formation of PGE-rich and Au-rich fluids, respectively. The formation of deep crustal MSS and subsequent hydrothermal oxidation under varying redox conditions thus provides a viable mechanism for trans-crustal PGE mobilization and inter-element fractionation, typical of PGE-rich magmatic-hydrothermal deposits.

Reconstruction of Hualca Hualca volcano (southern Peru) based on geomorphological and geological evidence and 40Ar/39Ar dating

The volcanic history of many of the western Central Andes volcanoes, including Hualca Hualca in the northern Ampato Volcanic Complex, remains poorly constrained. Based on an updated 1:50,000-scale geological map, new cross-sections of the Ampato Complex, a compilation of published dates, new geochemical data and 40Ar/39Ar ages, we present new insights into its volcanic evolution. Our study identifies 7 principal geological units (4 were not reported on the previous geologic map) and 8, mostly constructive, volcanic phases. The 40Ar/39Ar dating supports that Hualca Hualca began its formation during the Early Pleistocene (>1.6 Ma) with the establishment of an ancient stratovolcano. This volcano underwent a massive sector collapse to the north that created a U-shaped large amphitheater. This collapse likely resulted in the temporary damming of the Colca River, though no dates or associated deposits have been identified. Subsequent eruptions led to the formation of a smaller volcano along the amphitheater's scar that emplaced andesitic and dacitic lavas. This volcano dubbed modern Hualca Hualca holds the main summit. One of the longest lavas of this edifice reach the Colca valley and was previously dated at 610 ka. Sometime around 550 ka, volcanic activity migrated to the interior of the amphitheater forming the Nevado de Puye, Cruz del Condor, and Ahuashune domes that produced lavas of andesitic and dacitic composition. Around 164 ka a dacitic lava flow was emitted between Nevado del Puye and the base of the modern Hualca Hualca inside the horseshoe crater. The youngest known collapse of the Hualca Hualca complex involved parts of Nevado de Puye dome and the modern Hualca Hualca volcano, emplacing a debris avalanche that again dammed the Colca River and formed an upstream temporary lake that emplaced lacustrine and volcaniclastic deposits. After this collapse, no other volcanic deposit of the Hualca Hualca complex has been identified. Subsequently, glacial erosion during the local Last Glacial Maximum (17–16 ka) modified the volcanic landscape. Geochemical characteristics of Hualca Hualca suggest that their magmas were produced in a metasomatized mantle wedge and likely underwent crustal contamination during their ascent through the thick continental crust.

Stratigraphy, geochronology, geochemistry and Nd isotopes of the Ouarzazate Group, Anti-Atlas, Morocco: Evidence of a Late Neoproterozoic LIP in the northwestern part of the West African Craton

In the eastern and central Anti-Atlas of Morocco, the Late Neoproterozoic Ouarzazate Group (OG) forms a ∼ 2 km-thick section of volcano-sedimentary rocks deposited during intermittent magmatic activity, spanning a time period between 590 and 540 Ma. In the eastern Anti-Atlas, the stratigraphy of the OG, termed IMS (Imiter Mine succession), includes four units that reflect a gradual change from fluvial to lacustrine depositional sedimentary environments. In the central Anti-Atlas, the deposition of the OG occurs within a caldera environment, consisting of five units referred to as BMS (Bou Azzer Mine succession). UPb dating on zircon from the rhyolite lava flow at the top of the IMS constrains the latest lava flow of the IMS to 570.7 ± 2.1 Ma. In the Bou Azzer inlier, the stratigraphically correlated basal andesite and top dacite lava flows were emplaced at 590.6 ± 4.2 Ma and 555.9 ± 20.4 Ma, respectively, suggesting that the OG was constructed through successive pulses within a long-lived magmatic episode. The magmatic rocks display geochemical signatures typical of continental arc magmas, including high-K calc-alkaline to shoshonite composition, enrichment in LILE, and negative Nb, Sr, Ti and P anomalies. Nd isotopes indicate that magmas supplying the plumbing systems of the IMS and BMS constitute transitional products resulting from a combination of orogenic and intraplate volcanism, involving deep crustal recycling. The compositions of these magmas evolved through processes of crustal contamination, bulk assimilation, and minor fractional crystallization of the parent melt. High εNd values of the BMS rocks argue for a juvenile origin, whereas lower εNdt recorded in the IMS likely reflect old crustal protoliths and an overall less contribution of juvenile material in their source. The magmatic rocks of the OG are interpreted as products of a large igneous province (LIP) developed by a post-collisional delamination model that initiated tens of millions of years after the subduction-collision process stage of the Pan-African orogeny in the northwestern part of the West African Craton (WAC).

Iron–Titanium Oxide–Apatite–Sulfide–Sulfate Microinclusions in Gabbro and Adakite from the Russian Far East Indicate Possible Magmatic Links to Iron Oxide–Apatite and Iron Oxide–Copper–Gold Deposits

Mesozoic gabbro from the Stanovoy convergent margin and adakitic dacite lava from the Pliocene–Quaternary Bakening volcano in Kamchatka contain iron–titanium oxide–apatite–sulfide–sulfate (ITOASS) microinclusions along with abundant isolated iron–titanium minerals, sulfides and halides of base and precious metals. Iron–titanium minerals include magnetite, ilmenite and rutile; sulfides include chalcopyrite, pyrite and pyrrhotite; sulfates are represented by barite; and halides are predominantly composed of copper and silver chlorides. Apatite in both gabbro and adakitic dacite frequently contains elevated chlorine concentrations (up to 1.7 wt.%). Mineral thermobarometry suggests that the ITOASS microinclusions and associated Fe-Ti minerals and sulfides crystallized from subduction-related metal-rich melts in mid-crustal magmatic conduits at depths of 10 to 20 km below the surface under almost neutral redox conditions (from the unit below to the unit above the QFM buffer). The ITOASS microinclusions in gabbro and adakite from the Russian Far East provide possible magmatic links to iron oxide–apatite (IOA) and iron oxide–copper–gold (IOCG) deposits and offer valuable insights into the early magmatic (pre-metasomatic) evolution of the IOA and ICOG mineralized systems in paleo-subduction- and collision-related geodynamic environments.

Recently-discovered Bahçecik Au±Ag mineralization in the Eastern Pontides, Gümüşhane-NE Türkiye: geological and geochemical implications on the intermediate sulfidation epithermal deposit

ABSTRACT Intermediate sulfidation epithermal deposits represent significant reservoirs of precious metals, playing a crucial role in global mining operations. The Anatolian Peninsula, predominantly characterized by relatively young (Tertiary) lithologies, hosts numerous occurrences of epithermal base and precious metal mineralization. Within the realm of research in Northeastern Anatolia, several hydrothermal alteration zones have emerged as indicators of concealed epithermal mineralization, with the Bahçecik mineralization standing out as a recent focal point. The Bahçecik mineralization represents an intermediate sulfidation epithermal Au-Ag system, hosted by Late Cretaceous andesitic rocks, as well as Eocene dacitic lava and tuffs. Employing U-Pb LA-ICP-MS zircon dating of the dacitic host rocks, the mineralization is estimated to have occurred during the Lutetian epoch (43.61 ± 0.35 Ma) or later. The genesis of the Bahçecik deposit is believed to be linked to postcollisional regional extensional tectonics, primarily controlling its structural arrangement. Comprising pyrite, chalcopyrite, low-Fe sphalerite, galena, tetrahedrite/tennantite, enargite-luzonite, and gold-silver minerals, the deposit is accompanied by prominent gangue minerals such as Mn- and Ca-carbonates, quartz, and barite. Microprobe measurements have identified a majority of Au-Ag minerals (krennerite, buckhornite, and nagyagite) closely associated with sulphide minerals. Fluid inclusion data reveal that mineralization and fluid transportation occurred at temperatures ranging from 153 to 327°C, with solutions exhibiting salinity levels consistent with those of intermediate sulfidation deposits (1.7–7.3 wt.% NaCl). This study unequivocally classifies the Bahçecik mineralization as an intermediate sulfidation deposit, contrary to the conclusions drawn in previous research. Moreover, our investigation has unveiled the presence of a substantial ore resource, totalling 7.84 million tons, featuring 1.76 g/t Au and 2.24 g/t Ag. As an intermediate-type deposit, it shares characteristics with other subtypes within the epithermal class, bridging the realms of both high and low sulfidation systems.

New U-Pb zircon geochronological data for Takestan magmatic rocks (Western Alborz) and their significance for the interpretation of Paleogene magmatism in Iran

ABSTRACT The Takestan area is in the western part of the Alborz magmatic arc. Magmatic rocks of the area consist of plutonic rocks (e.g. granitoids), effusive volcanic, and pyroclastic rocks. Using U-Pb zircon LA ICP-MS dating, we conclude that major parts of Takestan plutonic rocks were emplaced at 41–39 Ma (Late Eocene, Bartonian), but a small part of these rocks have ages of ~37 Ma (Late Eocene, Priabonian). The dacitic rocks have an age of ~39 Ma (Late Eocene, Bartonian) and the rhyolitic rocks are the youngest part of the magmatic rocks of the region with ages of 37–35 Ma (Late Eocene, Priabonian). Old zircons are present in all of granitoid and volcanic samples, except for a dacitic sample. They are interpreted both as earlier components in a long-lived magma chamber and inherited zircons from older continental crust. The age of magmatic rocks in the western part of the Alborz magmatic arc decreases from east to west, but the ages of the majority of them are limited to Palaeogene. The studied rocks like other Palaeogene magmatic rocks of Iran were possibly formed in a subduction related tectonic environment. Indeed, the Palaeogene magmatism of Iran is akin to geodynamic events related to Neotethyan subduction beneath Iranian micro-continent at the southern part of Eurasia.

Petrological and geochemical evidence for a hot crystallization path and a recharge filtering bypass at Antimilos, Milos volcanic field, Greece

Antimilos volcano in the South Aegean Volcanic Arc, Greece, comprises an andesite–dacite suite that follows a distinct evolutionary path than the main edifice of the Milos volcanic field, despite their proximity. Petrographic and geochemical analyses reveal that basaltic andesite to low-Si dacite lavas have similar phenocryst assemblages that indicate crystallization from hot, relatively dry magmas in an upper crustal storage region. Rare antecrystic high-Mg# clinopyroxene cores with low Y, low Dy, and high Sr contents record the cryptic involvement of amphibole, a phase nominally absent from the erupted products, in the deeper parts of the plumbing system. Low temperature antecrysts with textures recording various degrees of disequilibrium suggest a protracted history of interaction between the upper crustal reservoir and deeper mafic melts, forming mobile hybrid magmas that consequently erupt as highly mingled, crystal-rich lava domes. Antimilos magmas seem to have escaped recharge filtering in the upper crust and prolonged stalling, which is the process that is probably responsible for the paucity of mafic eruptions in the rest of the Milos volcanic system. Large extensional structures offshore of Antimilos promote rapid ascent of mafic melts, inhibiting prolonged stalling and interaction with the arc crust. This model highlights the dominant role of the regional stress field in generating petrologically distinct suites in the marginal parts of some volcanic fields.

KARAKTERISTIK MINERALOGI PADA VEIN TEMBAGA KLUWIH, PACITAN, JAWA TIMUR

The southern mountains of Java are a path of copper-gold mineralization that has proven to have high economic value. Pacitan is part of the geological system and mineralization of the southern mountains, which are part of the Sunda Arc magmatism. The research area is located in the copper mining location in Kluwih village, Tulakan, Pacitan, East Java. The presence of copper mineralization in the form of massive sulfide/sulfosalt veins in the Kluwih area is evidence of an epithermal mineralization system which is rare and has not been studied intensively. This study intends to carry out mineralogical tests both physically and chemically for the characteristics and mineralogical composition of vein in the Kluwih area. The research was conducted using geological mapping methods in mine tunnels, rock sampling, laboratory analysis using petrographic methods, ore microscopy, rock geochemistry using ICP OES/MS – XRF – AAS, mineralogy using SWIR and XRD spectral analysis. The geomorphology of the Kluwih area and its surroundings consists of the morphology of alluvial plains and intrusive hills. Lithology is composed of volcanic–subvolcanic rocks in the form of porphyry dacite, dacite, dacite breccia, and alluvium. Mineralization forms in structural openings that cut and alter dacite rocks and dacite breccias. The alteration that develops in the Kluwih area, especially in the area around the mine (tunnel) is dominated by kaolinite-illite, pyrophyllite-little-sericite, chloritization, and mineralization found in the form of veins that have massive sulphide composition with the dominant internal texture being breccia. The texture or structure of the mineralization is in the form of brecciation (hydrothermal breccia), sulfide-pyrophyllite-kaolinite, quartz- sulfide/sulfosalt, and massif sulfide/sulfosalt. The results showed that the ore had a density of 4.65 gr/cm3 while the highly argillic altered side rocks had a density of 2.54 gr/cm3. In the ore, visible massive sulfide/sulfosalt minerals consist of mosaic bonds and intergrowth between similar or different minerals. The detected ore minerals are pyrite, enargite, covellite, chalcopyrite, and bornite. Enargite and pyrite are the dominant metallic minerals found in ores. Enargite crystals appear to have a size of 56 - 160µm, pyrite accumulates in anhedral crystal forms with a size of 120 - 900µm and inclusions in enargite measuring 50 - 140µm, along with covellite-chalcopyrite ± bornite minerals with a fine size of 5 - 20µm. The geochemistry of the ore is seen as sulfide filling, as evidenced by the SiO2 value of only 4.5% followed by metal enrichment in the form of 27.6% Fe, 12.6% Cu, 4.15% As, and 46.2% S. Alteration minerals which is present is probably a mica group such as phengite with a marked presence of elements of 0.7% MgO and 1.9% Al2O3. The geochemistry of the side rock is seen to have a high SiO2 value of 71.7%, followed by a high alkaline element forming alteration minerals such as pyrophyllite with an Al2O3 value of 15.3% with a low total Ca-Na-K value of 0.25%, and there is residual TiO2 by 0.38%. Terraspectral analysis and XRD confirmed that the main peaks were pyrophilite-phengite, followed by the minerals enargite and pyrite. The Kluwih vein is a copper vein associated with advanced argillic alteration, as part of a rich high sulfidation epithermal system with Cu-Au-As-Sb mineralization.

Interpretasi Struktur Bawah Permukaan Menggunakan Data Anomali Medan Magnet Daerah Manifestasi Panas Bumi Sampuraga Kabupaten Mandailing Natal

This research was conducted to identify the distribution of magnetic field anomalies to determine the subsurface structure of the area around Sampuraga hot springs. Magnetic field data was measured using a magnetometer in an area with dimensions of 1400 m x 1100 m with 154 points. The measurement data is a total magnetic field, and to obtain magnetic field anomaly values, corrections are made for diurnal variation and IGRF correction. Magnetic field anomaly values range from 353,1 nT to 7622,0 nT. Magnetic field anomaly data were processed using the Oasis Montaj software by reducing to the poles, upward continuation, and 2D modeling. The 2D modeling results show three layers of soil in the study area. The upper part (first and second layers) is interpreted as a caprock. This layer consists of sedimentary rock types of sandstone and clay and igneous rock in the form of granite at a depth of up to 1700 m. The lower part (third layer) is interpreted as a reservoir. This layer consists of metasedimentary volcanic rock, clay alteration, andesitic lava, and dacitic lava with a depth of up to 2030 m from the ground surface. The results of this model also interpret the fault zone as an outflow zone so that it forms manifestations on the surface. These three geothermal system components show that the Sampuraga area can be further developed and explored.

Slope Stability Analysis of Alterated Dasit Rock on Ponorogo Pacitan Road Using Hoek-Brown Failure Criteria

To mitigate landslide on rock slopes the information on adequate safety factors is needed. The strength of rock and soil is one of the important parameters on a slope stability analysis. This paper discussed the stability of the altered and dissected dacite rock. To make it easier to determine the Hoek-Brown failure criteria, the GSI rock mass classification is used. By using the Hoek-Brown failure criterion and supporting by the Rocsience software the analysis of safety factor of rockslide has been conducted. From field and laboratory observations of the rock masses that make up the slopes at the study site, a Geological Strength Index value of 25 was obtained. Base on GSI and some field condition can be obtained the Hoek-Brown parameter are γ = 2.6 t/m3, mi = 25, Disturbance Factor (D) = 1.0, mb = 0.118, s = 3.73e-6, 𝑎 = 0.531. The rock mass strength of the sample was brittle so that it can easily collapse. The purpose of this analysis is to do further study to overcome the problems that occur in most rocks, especially those related to transportation routes next to the slope.

The physical volcanology of large-scale effusive and explosive silicic eruptions in southeastern Saurashtra, Deccan Traps

AbstractSilicic magmatism, minor overall in the ∼65.5 Ma Deccan Traps continental flood basalt (CFB) province of India, was widespread in the Saurashtra region. We describe the physical volcanology of silicic volcanics and dykes exposed around Rajula–Savarkundla–Gariyadhar–Talaja towns in southeastern Saurashtra. The silicic volcanics conformably overlie basaltic lavas, suggesting rapid subaerial volcanism, and the sequence shows gentle tectonic dips (∼15°) towards the Arabian Sea. Rhyolites and dacites with preserved thicknesses of tens of metres show intense internal rheomorphic deformation, and a dacite shows a well-formed basal autobreccia. The rheomorphic rhyolites, and vitrophyres which often underlie them, lack vitroclasts (glass shards and pumice clasts). They have very similar mineral assemblages (quartz and alkali feldspar phenocrysts, and crystal cargoes dominated by calcic plagioclase and clinopyroxene or orthopyroxene, sometimes with olivine). The rheomorphic units are thus flood rhyolite and dacite lavas, apparently common in the northern-northwestern Deccan, and the vitrophyres their basal chilled parts. Tuffs (including crystal-vitric Plinian fallout ash) and eutaxitic ignimbrites formed from pyroclastic density currents; one tuff contains extraordinary numbers of lithophysae. Ridges of rhyolitic tuff breccias with pervasive secondary silicification and ferruginization represent pyroclastic eruptive fissures. The area thus records large-scale effusive and explosive silicic eruptions. Mafic and silicic dykes intrude the basaltic lavas and rarely the silicic volcanics. Mafic enclaves in several silicic dykes and some volcanics indicate magma mingling as a common phenomenon. The seaward-dipping volcanic units define a regional-scale flexure comparable to coastal flexures in CFB provinces worldwide, suggesting extensive block-faulting of this classical volcanic rifted margin.

Identification of Rock Resistivity and Slip Surface in the Ambon Volcanic Rock in the Kayu Putih Area of Ambon City

Research on rock resistivity and slip surface in the Ambon Volcanic Rock formation has been carried out through geoelectric mapping with the Wenner-Schlumberger configuration in the Kayu Putih area, Ambon City as one of the areas prone to landslides. Measurement of rock resistivity by Mapping was carried out on two tracks each 120 m long and 70 m long intersecting each other. The results showed that the resistivity values ​​of the rocks ranged from 185 Ωm to 4,128 Ωm consisting of Top Soil, Unsaturated Landfill, and Loose Sand as the cover layer followed by Dry Sandy Soil and Gravel, and Breccia Dacite and Tuff at the bottom layer. Breccia Dacite rocks with a resistivity of greater than 2,000 Ωm are found at a depth of 11 – 13 m below the soil surface functioning as slip surface for the sand layer above them. The movement of the soil mass over the slip surface causes cracks in the surface of the road and houses.

Laboratory Simulation of Earthquake-Induced Damage in Lava Dome Rocks

Earthquakes can impart varying degrees of damage and permanent, inelastic strain on materials, potentially resulting in ruptures that may promote hazards such as landslides and other collapse events. However, the accumulation of damage in rocks under the frequency and amplitude of shaking experienced during earthquake events is rarely systematically measured due to technical limitations. Here, we characterize damage evolution during laboratory experiments on a suite of dacitic rocks from Unzen volcano, Japan, to help resolve accumulated damage and landslide susceptibility of lava domes during regional earthquake events. Damage was imparted during slow (time-dependent creep) and fast (stress-oscillation earthquake simulations) uniaxial loading in compression and tension. Damage evolution is approximated from strain during experiments; all samples accumulate strain during earthquake events, but microfracture-dominated samples tend to be more susceptible to damage than vesicle-dominated samples. The orientation of existing fabrics with respect to loading direction dictates the magnitude of strain accumulation under load oscillations. During each “earthquake” experiment of multiple dynamic stress-oscillations, samples accumulate inelastic strain. The strain imparted during each successive event is initially high and then reduces after 5-7 events, except when stressing results in failure. The strain rate during phases of intermittent stressing tends to be higher than prior to them. Understanding the accumulation of damage and the potential for brittle failure of rocks subjected to earthquakes can help define the origin and timing of certain landslides, rockfalls, lava dome collapses, and other failure events.

Developing an integrated approach based on geographic object-based image analysis and convolutional neural network for volcanic and glacial landforms mapping.

Rapid detection and mapping of landforms are crucially important to improve our understanding of past and presently active processes across the earth, especially, in complex and dynamic volcanoes. Traditional landform modeling approaches are labor-intensive and time-consuming. In recent years, landform mapping has increasingly been digitized. This study conducted an in-depth analysis of convolutional neural networks (CNN) in combination with geographic object-based image analysis (GEOBIA), for mapping volcanic and glacial landforms. Sentinel-2 image, as well as predisposing variables (DEM and its derivatives, e.g., slope, aspect, curvature and flow accumulation), were segmented using a multi-resolution segmentation algorithm, and relevant features were selected to define segmentation scales for each landform category. A set of object-based features was developed based on spectral (e.g., brightness), geometrical (e.g., shape index), and textural (grey level co-occurrence matrix) information. The landform modelling networks were then trained and tested based on labelled objects generated using GEOBIA and ground control points. Our results show that an integrated approach of GEOBIA and CNN achieved an ACC of 0.9685, 0.9780, 0.9614, 0.9767, 0.9675, 0.9718, 0.9600, and 0.9778 for dacite lava, caldera, andesite lava, volcanic cone, volcanic tuff, glacial circus, glacial valley, and suspended valley, respectively. The quantitative evaluation shows the highest performance (Accuracy > 0.9600 and cross-validation accuracy > 0.9400) for volcanic and glacial landforms and; therefore, is recommended for regional and large-scale landform mapping. Our results and the provided automatic workflow emphasize the potential of integrated GEOBIA and CNN for fast and efficient landform mapping as a first step in the earth's surface management.

The Origin of Magmas and Metals at the Submarine Brothers Volcano, Kermadec Arc, New Zealand

Abstract International Ocean Discovery Program (IODP) Expedition 376 cored the submarine Brothers volcano of the Kermadec arc to provide insights into the third dimension and the evolution of the volcano and its associated ore-forming systems. We present new petrological and geochemical data on dacitic rocks drilled from Brothers as well as mafic rocks collected at two adjacent ridges. These data include major and trace element compositions of whole rocks, including many economically important metals and metalloids such as Cu, Ag, Pt, Au, Mo, As, Sb, Tl, and Bi, plus Sr-Nd-Pb isotope compositions as well as in situ analyses of glasses and minerals. We show that the basalts and basaltic andesites erupted at the volcanic ridges near Brothers represent potential mafic analogues to the dacites that make up Brothers volcano. Mantle melting and ore potential of the associated magmas are locally enhanced by raised mantle potential temperatures and a high flux of subducted components originating from the partially subducted Hikurangi Plateau. As a result, the parental melts at Brothers are enriched in ore metals and metalloids relative to mid-ocean ridge basalts (MORBs), and a high melt oxidation state (Δ log fO2 of +1.5 fayalite-magnetite-quartz [FMQ]) suppresses early sulfide saturation. However, solid sulfide crystallization occurs late during magma differentiation, with the result that the dacitic lavas at Brothers volcano are strongly depleted in Cu but only moderately depleted in Ag and Au. The dacites at Brothers thus have a high fertility for many metals and metalloids (e.g., As, Sb, Bi), and fluids exsolving from the cooling magma have a high ore-forming potential.

40Ar–39 Ar dating, whole-rock and Sr-Nd isotope geochemistry of the Middle Eocene calc-alkaline volcanic rocks in the Bayburt area, Eastern Pontides (NE Turkey): Implications for magma evolution in an extension-related setting

Discussions continue about whether Middle Eocene magmatism in the Eastern Pontides is associated with collision or subduction. This paper presents new whole-rock geochemistry, Sr-Nd isotopic and 40Ar-39Ar age data for Middle Eocene volcanic rocks from the Bayburt area of the Eastern Pontides (NE Turkey) to investigate their sources and evolutionary history. The new 40Ar–39Ar ages reveal that these volcanic rocks erupted between 44.6 ± 0.1 Ma and 43.5 ± 0.1 Ma, within the Lutetian (Middle Eocene). The studied volcanic rocks are composed of basalt, andesite, basaltic andesite and minor dacite lava and pyroclastic rocks. These rocks consist of plagioclase, amphibole, pyroxene, olivine, biotite, sanidine and minor quartz phenocrysts with Fe-Ti oxides. They have microlithic, hyalo-microlithic, porphyritic and rarely glomeroporphyritic textures. The volcanic rocks have low to high-K calc-alkaline affinities. They display enrichment in large-ion lithophile elements and depletion in high-field strength elements with high Th/Yb ratios, which indicate that the magmas forming the volcanic rocks were derived from lithospheric mantle sources enriched by mostly slab-derived fluids in the spinel stability field. 87Sr/86Sr(i) values vary between 0.70485 and 0.70551 and 143Nd/144Nd(i) values vary between 0.51255 and 0.51267. These data correspond to the mantle array on the isotope ratio diagram. The main solidification processes consist of fractional crystallization with minor assimilation. In light of the data obtained in this study together with data from previous studies, petrogenetic character of the Middle Eocene magmas from the southern parts of the Eastern Pontides may be explained by melting of an enriched lithospheric mantle source initially metasomatized by subduction fluids in a post-collisional extensional-related tectonic setting.

A Showcase of Igneous Processes in the Urumieh-Dokhtar Magmatic Arc: the Miocene-Quaternary Collisional Magmatism of the Bijar-Qorveh Area, Northwest Iran

Abstract The Cenozoic Arabia–Iran continental collision was associated with emplacement of a large variety of magmatic rock types. This aspect is particularly evident in the Bijar-Qorveh area of NW Iran, where Miocene andesitic to rhyolitic rocks and Quaternary basic alkaline rocks crop out. The Miocene intermediate to acid products show radiogenic Sr and Pb isotopic compositions (87Sr/86Sri 0.70531–0.71109, 206Pb/204Pb 18.71–19.01, 207Pb/204Pb 15.66–15.73, 208Pb/204Pb 38.76–39.14), coupled with unradiogenic Nd isotopic ratios (143Nd/144Ndi 0.51223–0.51265). These characteristics, together with primitive mantle-normalised multielemental patterns resembling ‘subduction-related’ geochemical fingerprints, are considered ultimately derived from the Iranian plate mantle wedge, metasomatised during previous NE-directed Neothetyan Ocean subduction. The alkali-rich andesitic and dacitic rocks evidence both closed- and open-system differentiation, as typically observed for collisional settings in general. Both rock types display a high Sr/Y (37–100) and La/Yb (29–74) ‘adakitic’ signature that it is interpreted here with plagioclase (± amphibole) accumulation or melting of local mafic crustal rocks. Open-system processes involve recycling of crustal cumulates for pyroxene-rich andesite and biotite-rich dacite varieties and low-degree partial melting of the local crust for rhyolites. A radical change occurred during the Quaternary, when SiO2-understaturated to SiO2-saturated poorly evolved rocks (basanites, tephrites, alkaline and subalkaline basalts) were emplaced. The complete change of mantle sources suggests a phase of local extensional tectonics related with WNW-ESE right-transcurrent faults. The major oxide, as well as incompatible trace element and Sr-Nd-Pb isotopic fingerprint of these younger rocks is more akin to that of intraplate magmas, but still bearing some evidences for a variable contribution from a ‘subduction-modified’ mantle source. The NW-trend of increasing involvement of this subduction component is indicative of the strong tectonic control on magmatism. Additional lithotypes indicate the presence of open-system differentiation and remelting processes in the youngest phase of magmatic activity.

Semi Quantitative and Quantitative Analysis of Rockslides at Ponorogo – Pacitan Road Km 226

Rock avalanches is one of the problems that is often faced along the Ponorogo - Pacitan road. The research location was at KM 226 which is located at coordinates 111°22'14.39" East Longitude and 08°01'14.73" South Latitude. Semi quantitative analysis was conducted by using Geology Strength Index method, that is based on field identification. The quantitative slope stability analysis was used Rocscience software consisting of Roclab and Rocplane used the Hoek and Brown method. The classification results of  rock mass GSI obtained value of 25 and was dacite rock type. The slope had angle of 75o and  height of 12 meters, safety factor (FK) of 1.065 was obtained which made the slope unstable, so prevention was done by changing the slope angle geometry based on variations of 75 o - 35 o, so that (FK) 35o = 1.52