Cyclopentadienyliron Dicarbonyl Research Articles

Organoselenium derivatives of metal carbonyls. Part II. Dimeric and monomeric derivatives of iron carbonyl

Dodecarbonyltri-iron reacts with dimethyl and diethyl diselenides and with the corresponding bisperfluoroalkyl diselenides to afford the respective selenoalkyl and perfluoroalkyl iron tricarbonyl dimers, [Fe(CO)3Se(R)]2(R = CH3, C2H5, CF3, or C2F5), while the i-C3H7 derivative is obtained by the reaction of the same iron carbonyl with perfluoroisopropylselenol. The two compounds of the type [(C5H5)Fe(CO)Se(R)]2(R = C2H5 or n-C3H7) resulted from the reaction between the cyclopentadienyl iron dicarbonyl dimer, [(C5H5)Fe(CO)2]2, and the appropriate dialkyl diselenide.The only monomeric derivatives in this group of compounds, (C5H5)Fe(CO)2Se(RF)(RF= CF3, C2F5, or C3F7), were obtained by the reaction of cyclopentadienyl iron dicarbonyl dimer and the respective bisperfluoroalkyl diselenide.The mechanism of the above reactions is discussed and the properties of the new compounds are described.

Organic syntheses by means of metal complexes —VIII : Reactions of methyl trichloroacetate with olefins catalyzed by metal carbonyls

Reactions of methyl trichloroacetate with olefins catalyzed by dicobalt octacarbonyl, cyclopentadienylmolybdenum tricarbonyl dimer and cyclopentadienyliron dicarbonyl dimer have been studied. Products varied depending on catalyst nature. Methyl-4-alkyl-2,2,4-trichlorobutyrate was obtained by the cobalt catalyst. 4-Alkyl-2,2-dichloro-γ-butyrolactone was the main product by the molybdenum and iron catalysts.

Reaction of the dimer of cyclopentadienyliron dicarbonyl with?-diketones

Aβ-diketone in the reaction with the dimer of cyclopentadienyliron dicarbonyl cleaves the Fe-Fe bond, displaces both of the carbonyl groups, and forms compounds that contain twoβ-diketonate and one cyclopentadienyl ligands.

Iron(II)- and manganese(I)-carborane complexes formed through metal-carbon .sigma. bonds

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIron(II)- and manganese(I)-carborane complexes formed through metal-carbon .sigma. bondsM. Frederick Hawthorne, David A. Owen, James C. Smart, and Philip M. GarrettCite this: J. Am. Chem. Soc. 1971, 93, 6, 1362–1368Publication Date (Print):March 1, 1971Publication History Published online1 May 2002Published inissue 1 March 1971https://doi.org/10.1021/ja00735a008RIGHTS & PERMISSIONSArticle Views155Altmetric-Citations26LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (837 KB) Get e-Alerts Get e-Alerts

Organic Syntheses by Means of Metal Complexes. II. Oxo Reaction Catalyzed by Cyclopentadienyliron Dicarbonyl Dimer

Abstract It was found that cyclopentadienyliron dicarbonyl dimer is an active catalyst for oxo reaction and the characteristic features of the catalysis have been studied.

Complexes of trivalent phosphorus derivatives. V. Photochemical reactions of silicon and tin derivatives of cyclopentadienyliron dicarbonyl with trivalent phosphorus ligands

Complexes of trivalent phosphorus derivatives. V. Photochemical reactions of silicon and tin derivatives of cyclopentadienyliron dicarbonyl with trivalent phosphorus ligands

The crystal and molecular structure of a new ?-complex: The reaction product of ?-(?-acetylvinyl)-?-cyclopenta dienyliron-dicarbonyl with iron nonacarbonyl

The crystal and molecular structure of a new ?-complex: The reaction product of ?-(?-acetylvinyl)-?-cyclopenta dienyliron-dicarbonyl with iron nonacarbonyl

Kinetics studies of carbon monoxide insertion reactions. Reactions of cyclopentadienyl(methyl)iron dicarbonyl and cyclopentadienyl(methyl) molybdenum tricarbonyl with phosphines and phosphites

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTKinetics studies of carbon monoxide insertion reactions. Reactions of cyclopentadienyl(methyl)iron dicarbonyl and cyclopentadienyl(methyl) molybdenum tricarbonyl with phosphines and phosphitesIan Sydney Butler, Fred Basolo, and Ralph G. PearsonCite this: Inorg. Chem. 1967, 6, 11, 2074–2079Publication Date (Print):November 1, 1967Publication History Published online1 May 2002Published inissue 1 November 1967https://doi.org/10.1021/ic50057a032RIGHTS & PERMISSIONSArticle Views546Altmetric-Citations85LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (670 KB) Get e-Alerts Get e-Alerts

Cyclopentadieneiron tricarbonyl

Cyclopentadieneiron tricarbonyl has been prepared through the reaction of cyclopentadiene and diiron nonacarbonyl. The complex undergoes slow decomposition at 140° to afford the dimer of cyclopentadienyliron dicarbonyl. Abstraction of a hydride ion from cyclopentadieneiron tricarbonyl yields the cyclopentadienyliron tricarbonyl cation.

Hydrocarbon metal sulphide complexes : I. Cyclopentadienylcarbonyliron mercaptides

Stable monomeric cyclopentadienyl dicarbonyliron alkyl(aryl)mercaptide complexes have been isolated and the controlled decompositions of these into pairs of isomeric binuclear di-μ-mercaptido-bis(carbonylcyclopentadienyliron) complexes studied. Specific methods are described for the kinetic or thermodynamic control of these decompositions. Improved procedures for the preparation of di-μ-mercaptido-bis(carbonylcyclopentadienyliron) are described. The stereochemistry of these complexes are discussed in relation to IR and PMR spectra.

Reactions of Cyclopentadienyl (methyl) iron Dicarbonyl with Various Ligands. Cyclopentadienyl(acetyl)iron Carbonyl Phosphine and Phosphite Complexes

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReactions of Cyclopentadienyl (methyl) iron Dicarbonyl with Various Ligands. Cyclopentadienyl(acetyl)iron Carbonyl Phosphine and Phosphite ComplexesJane P. Bibler and Andrew WojcickiCite this: Inorg. Chem. 1966, 5, 5, 889–892Publication Date (Print):May 1, 1966Publication History Published online1 May 2002Published inissue 1 May 1966https://doi.org/10.1021/ic50039a037RIGHTS & PERMISSIONSArticle Views1188Altmetric-Citations115LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (497 KB) Get e-Alerts Get e-Alerts

Reactions of Alkali Metal Derivatives of Metal Carbonyls. II. Reactions between Acid Chloride Derivatives and the Sodium Derivative of Cyclopentadienyliron Dicarbonyl

<b>Reactions of Alkali Metal Derivatives of Metal Carbonyls. II. Reactions between Acid Chloride Derivatives and the Sodium Derivative of Cyclopentadienyliron Dicarbonyl</b>