Cyclic Process Research Articles

Influence of NiCrAlY coating on anti-corrosion of M951 alloy

M951 alloy is a cast nickel-based super-alloy widely used in gas turbines and aircraft engines, thus a suitable high temperature protective coating must be applied on its surface to enhance the corrosion resistance. In this research, NiCrAlY coating was deposited on M951 by arc ion plating. TGA at 1100 °C, cyclic oxidation at 1000 °C and hot corrosion in molten Na2SO4+25 wt% K2SO4 salt at 850 °C of M951 bare alloy and NiCrAlY coating specimens were investigated respectively. After TGA and cyclic oxidation, mixed oxides of NiO, NiAl2O4, Nb2O5 and Al2O3 formed on M951 surface, which spalled seriously during cyclic oxidation process. Thin, continuous and adhesive α- Al2O3 formed on the surface of NiCrAlY coating after both oxidation process. In molten Na2SO4+25 wt%K2SO4 salt at 850 °C, catastrophic corrosion occurred for the M951 alloy only after 10 hours, while thin and continuous θ- Al2O3 film formed on the surface of the NiCrAlY coating. In a word, NiCrAlY coating greatly improved the high temperature oxidation and hot corrosion resistance of the M951 superalloy. This study will further refine the oxidation and corrosion behaviors of M951 superalloy under different high temperature protective coatings and provides theoretical and experimental basis for the application of M951 superalloy in corrosive environments.

Writing Effective Cover Letters: Do Undergraduates Have the Written Communication Skills to Achieve the Spirit of SDG4 Quality Education?

Introduction: This study investigates the impact of English language instructors’ intervention on the cover letter writing process for job applications among specific ESL learners enrolled in a workplace communication course at a public university in Malaysia. This study adopts an action research technique, incorporating content analysis conducted before and after the intervention. The goal of this action research is to identify inaccuracies or issues in the format and content of cover letters written by the selected learners and implement instructor intervention to resolve the identified problems or errors. Generally, the results of this study revealed that the effectiveness of the learners’ cover letters improved after receiving extra input and feedback from their language instructors. A lack of learner-readiness and job knowledge resulted in some learners experiencing difficulty in writing coherent cover letters. More importantly, the learners indicated that their writing experiences raised greater awareness of the many aspects of cover letters and enhanced their confidence in writing cover letters. Overall, this study contributes the initiative to enhance learners' understanding of the ever-changing employment market and develop not only their ability to write cover letters but also their self-confidence and proficiency in the English language. Most significantly, the written communication skills will provide them with lifelong learning opportunities that are taught in higher education as stipulated in the fourth goal (SDG4) of the United Nations’ Sustainable Development Goals, which emphasizes quality education. Objective: The objective of this study is to assess the learners' proficiency in writing cover letters by identifying their strengths and weaknesses. The aim is to evaluate the efficacy of the writing methods employed in cover letters and determine their appropriateness. Theoretical Framework: Kolb’s experiential learning theory (ELT) serves as the primary conceptual framework to define the sequence of activities in the research procedure. David Kolb's (1984) cycle of experiential learning stages perceives learning as a dynamic interaction between learners and their environment (Kolb, 2014). The Experiential Learning Theory (ELT) underscores a cyclical learning process that includes experiencing, reflecting, thinking, and experimenting (Kolb & Kolb, 2005). Method: This study adopts the action research methodology and employed a six-phase method, which comprises the first phase, the diagnostic test, the second phase, the evaluation of cover letters, the third phase, the pre-writing strategies, the fourth phase, the writing phase, the fifth phase, the instructor feedback phase, and the sixth phase is the re-writing phase. Results and Discussion: The results obtained revealed the necessity for graduating learners to possess enhanced skills and knowledge prior to entering the challenging work market. There is currently a strong demand for graduates to develop more modern and thorough tactics to successfully secure employment. The results of this study confirm the need for innovative methods in language acquisition, specifically grammar mastery. Research Implications: Learners need a helping hand with their language and should be guided closely beginning with the rudiments of writing and other integrated language skills that would help bolster their confidence in writing cover letters and improve their communication skills. They need to learn to be independent and proactive in the job-search process. As instructors empower learners with lifelong skills of writing cover letters, the learners themselves should constantly keep abreast of the changes in the dynamic job market. Originality/Value: This study helps learners comprehend the shifting job market, prepare cover letters, and improve their English and self-confidence. Most importantly, it will offer lifelong learning, as stated in the UN's fourth Sustainable Development Goal (SDG4).

A Qualitative Study on Self-Regulated Learning of Chinese as a Second Language

The characteristics and challenges of learning Chinese as a second language (CSL) warrant a deeper understanding of the learning process from various perspectives to promote learning development. In the domain of second language acquisition research, the concept of self-regulated learning (SRL) has been gaining increased attention from researchers. SRL encompasses a broader and more profound connotation than previous models, as it emphasizes the strategic application of learning techniques to facilitate language development. This theoretical shift has yielded fruitful research results in the field. By investigating SRL, we can examine the dynamic and cyclical process of CSL learning from multiple dimensions and identify learning problems from the learners’ perspective, ultimately finding solutions. This study aims to conduct qualitative research on SRL among five CSL learners with different cultural and educational backgrounds, utilizing qualitative study methods. The research focuses on exploring the characteristics and patterns of SRL among CSL learners, offering insights for teaching practices. The study will employ semistructured interviews and reflective journals to gather in-depth data on the learners’ SRL processes. Key questions include how SRL impacts CSL learning outcomes, the distinctive characteristics of applying SRL theory to CSL learning, and the effective implementation of SRL strategies to enhance learning. By addressing these questions, the research aims to fill the gap in existing literature and provide practical insights for educators to support the development of autonomous, self-regulated Chinese language learners. This, in turn, will contribute to improving instructional methods and promoting better academic achievements in CSL learners.

Dietary Tributyrin Improves Growth Performance, Meat Quality, Muscle Oxidative Status, and Gut Microbiota in Taihe Silky Fowls under Cyclic Heat Stress.

Heat stress adversely affects poultry production and meat quality, leading to economic losses. This study aimed to investigate the effects of adding tributyrin on growth performance, meat quality, muscle oxidative status, and gut microbiota of Taihe silky fowls under cyclic heat stress (CHS) conditions. In this study, 120-day-old Taihe silky fowls (male) were randomly divided into six dietary treatments. These treatments included a normal control treatment (NC, fed a basal diet), a heat stress control treatment (HS, fed a basal diet), and HS control treatments supplemented with 0.04%, 0.08%, 0.16%, and 0.32% tributyrin, respectively. The NC treatment group was kept at 24 ± 1 °C, while the HS treatment birds were exposed to 34 ± 1 °C for 8 h/d for 4 weeks. Results showed that CHS decreased growth performance and compromised the meat quality of broilers (p < 0.05). However, tributyrin supplementation improved ADG and FCR in broilers exposed to CHS (p < 0.05). Additionally, tributyrin supplementation resulted in increased shear force value and GSH-Px activity, as well as a decrease in drip loss, ether extract content, and MDA content of the breast muscle in broilers under CHS (p < 0.05). Furthermore, tributyrin supplementation up-regulated the mRNA expressions of Nrf2, NQO1, HO-1, SOD, and GSH-Px of the breast muscle in broilers exposed to CHS (p < 0.05). Based on these positive effects, the study delved deeper to investigate the impact of 0.16% tributyrin supplementation (HS + 0.16%T) on the cecum microbiota. The HS + 0.16%T treatment showed an increase in the relative abundance of Rikenellaceae_RC9_gut_group (p < 0.05) and a trend towards an increase in Lactobacillus (p = 0.096) compared to the HS treatment. The results indicate that supplementation successfully improved the growth performance and meat quality of Taihe silky fowls. Furthermore, tributyrin supplementation, particularly at levels of 0.16%, improved meat quality by enhancing muscle antioxidant capacity, which is believed to be associated with activation of the Nrf2 signaling pathway.

An Investigation of the Effects of Flame Straightening Heating on the High-Strength Structural Steels Microstructure

AbstractIn this research, the effects of heating cycles that are performed correctly and excessively—well above the limitations given by the steel manufacturer—on flame straightening are assessed and analyzed. The paper focuses on the microstructural changes caused by the overheating during the flame straightening process. To create geometrical changes in a metal construction, a tiny section of the element or structure is heated to the straightening temperature during the flame straightening process. Strenx® 960 is typically produced through a combination of thermomechanical rolling and quenching and tempering, resulting in a fine-grained martensitic or bainitic microstructure. These processes are designed to achieve a balance of high strength and good toughness. The microstructural changes associated with different working conditions in the case of welding include HAZ softening and grain growth. The study aimed to highlight the influence of flame hardening on the microstructure of the material.

Molecular Structure and Properties of Resistant Dextrins from Potato Starch Prepared by Microwave Heating.

The dextrinization of potato starch was performed using a sophisticated single-mode microwave reactor with temperature and pressure control using 10 cycles of heating with stirring between cycles. Microwave power from 150 to 250 W, a cycle time from 15 to 25 s, and two types of vessels with different internal diameters (12 and 24 mm) and therefore different thicknesses of the heated starch layer were used in order to estimate the impact of vessel size used for microwave dextrinization. The characteristics of resistant dextrins (RD) including solubility in water, total dietary fiber (TDF) content, color parameters, the share of various glycosidic bonds, and pasting and rheological properties were carried out. The applied conditions allowed us to obtain RDs with water solubility up to 74% at 20 °C, as well as TDF content up to 47%, with a predominance of low-molecular-weight soluble fiber fraction, with increased content of non-starch glycosidic bonds, negligible viscosity, and a slightly beige color. The geometry of the reaction vessel influenced the properties of dextrins obtained under the same heating power, time, and repetition amounts. Among the conditions used, the most favorable conditions were heating 10 times for 20 s at 200 W in a 10 mL vessel and the least favorable were 15 s cycles.

Method and Verification of Liquid Cooling Heat Dissipation Based on Internal Heat Source of Airborne Long-Focus Aerial Camera

The traditional passive heat dissipation method has low heat dissipation efficiency, which is not suitable for the heat dissipation of the concentrated heat source inside the long-focal aerial camera, resulting in temperature level changes and temperature gradients in the optical system near the heat source, which seriously affect the imaging performance of the aerial camera. To solve this problem, an active heat dissipation method of liquid cooling cycle is proposed in this paper. To improve the solving efficiency and ensure simulation accuracy, a dynamic boundary information transfer method based on grid area weighting is proposed. The thermal simulation results show that the liquid cooling method reduces the heat source temperature by 70.12%, and the boundary temperature transfer error is 0.015%. The accuracy of thermal simulation is verified by thermal test, and the simulation error is less than 6.44%. In addition, the performance of the optical system is further analyzed, and the results show that the MTF of the optical system is increased from 0.077 to 0.194 under the proposed active liquid cooling cycle heat dissipation method.

Understanding Polyproline's Unusual Thermoresponsive Properties Using a Polyproline-Based Double Hydrophilic Block Copolymer.

Polyproline is a unique thermoresponsive polymer characterized by large thermal and conformational hysteresis. This article employs polyproline-based double hydrophilic block copolymers (PNIPAMn-b-PLPm) to gain insight into polyproline's thermoresponsive mechanism. The amine-terminated poly(N-isopropylacrylamide) (NH2-PNIPAMm) was used as the macroinitiator for ring-opening polymerization of proline-NCA monomers, resulting in various block copolymers (PNIPAMn-b-PLPm) with varying PLP block lengths. Block copolymers' thermal phase transitions were compared with their homopolymer counterparts using turbidimetry, variable-temperature NMR, dynamic light scattering, and circular dichroism spectroscopy. These experiments revealed that regardless of their compositions, all block copolymers exhibited a two-stage collapse (TCP(PLP) > TCP(PNIPAM)) during the heating cycle. In contrast, only one clearing temperature (TCL) was observed during cooling. The observed clearing temperature is closely correlated to the clearing temperature of PNIPAM blocks, suggesting the role of water-soluble PNIPAM blocks in resolving the PLP blocks. Moreover, thermal and conformational hysteresis related to the polyproline block is significantly suppressed in the presence of a PNIPAM block. Linking PNIPAM blocks has two significant effects on PLP segments' thermoresponsive behavior. For example, during the heating cycle, the precollapsed PNIPAM chains (as TCP(PNIPAM) < TCP(PLP)) prevent orderly aggregation within the PLP block. Meanwhile, during the cooling cycle below the clearing temperature of the PNIPAM block, the PNIPAM chains impart water solubility (as TCL(PNIPAM) > TCL(PLP)) to the collapsed PLP chains. Overall, the PNIPAM block imparts water solubility and perturbs PLP chains to form the native aggregate structure, suppressing the hysteresis effect. Accordingly, the large thermal and conformational hysteresis associated with native PLP chains appears to result from a noninterfering aggregation above the critical temperature.

Radiative heat transfer to enhance the performance of liquid metal-based phase change heat sink under natural convection condition

Liquid metal phase change materials have the advantages of high thermal conductivity and high volumetric latent heat, which are expected to address the growing challenges of thermal management of advanced electronics. In previous studies, the effect of radiative heat transfer from fins of a phase change heat sink on thermal management performance has rarely been considered. In this study, radiative coating materials with high emissivity were prepared and coated on the fins of the liquid metal phase change heat sink. The effect of radiative heat transfer on the performance of liquid metal phase change heat sink was investigated. The experimental results of continuous heating under natural convection conditions show that the introduction of the radiative coating with an emissivity of 0.9298 can extend the time for the surface temperature of the heat source to reach 100 °C by 9.4%, while shortening the recovery time of the phase change heat sink by 14.9%. The results of high-power cyclic heating indicate that the high emissivity coating can reduce the peak temperature by 16.6 °C in the tenth working cycle. A simplified numerical model was subsequently developed and validated to determine the specific effects of phase change and radiative heat transfer on the overall thermal control performance. The radiation-enhanced liquid metal phase change heat sink proposed in this study is simple and maintenance-free. It is expected to address the thermal management issues of electronic devices that cannot use active cooling or operate in thin-air environments.

Semi-Closed Oxy-Combustion Combined Cycles for Combined Heat and Power Applications

Abstract This study focuses on the design and comparison of three utility-scale combined heat and power (CHP) cycles with carbon capture and storage (CCS): (i) a CHP semi-closed oxy-combustion combined cycle (SCOC-CC), (ii) a CHP natural gas combined cycle (NGCC) with postcombustion CCS, and (iii) a CHP NGCC with postcombustion CCS and supplementary firing. Performance evaluations are conducted at the design point and partial load (gas turbine at 30%) for different exports of high-temperature pressurized steam. The comparison is extended against two reference separate production systems with CCS, one based on postcombustion technologies, and another based on oxy-combustion. Simulations of the H-class gas turbines are performed using gas steam (GS), a specific in-house validated software, while the heat recovery steam cycle is modeled using Thermoflex. The CO2 capture processes employ validated models in Aspen Plus. The results highlight the suitability of the SCOC-CC for CHP applications, demonstrating superior performance and flexibility compared to CHP postcombustion technologies at both nominal and minimum loads. The SCOC cycle achieves a maximum first-law efficiency of 65.95%, outperforming CCS technologies that generate electricity and heat separately and enabling fuel savings up to 9.2%.

간호대학 교수의 이직의도 극복 경험

Objectives This study is to understand the experience of nursing professors overcoming turnover intention and to clarify the meaning and structure of the experience. Specifically, it is to derive a general structure by grasping from their perspective how nursing professors overcome the turnover situation. Methods This study is a qualitative study applying Giorgi(2009)'s phenomenological research method. The study participants are professors of nursing department who have worked as full-time professors for more than 5 years, and a total of 5 people understood the purpose of this study and voluntarily agreed to participate. Data collection was collected through individual in-depth interviews and observations from March 1, 2024 to May 18, 2024. The number of interviews for each participant was 2-4, and interviews were conducted at a place the participant wanted, and the time required for one interview was about 1 hour. Purposeful sampling was performed to select participants. The collected data went through a cyclical repetitive process of data collection and analysis based on the phenomenological research method developed by Giorgi(2009). Results The general structure of the experience of nursing professors overcoming the intention to turnover derived from the results of this study was ‘extreme situation that is difficult to endure’, ‘confirm reality’, ‘promoting stability’, ‘growth’, and ‘construction of place’, and a total of 5 upper themes, 8 lower themes, and 40 semantic units were derived. Conclusions Their experience was a series of processes in which they began to consider turnover through physical and psychological difficulties, confusion, and conflict while starting a nursing professor, but they identified their reality and promoted stability to build a position as their growth took place. Problems related to turnover of nursing professors are not limited to individual professors' problems, but it is necessary to carefully recognize experiences and difficulties at various levels. However, since coping with turnover is carried out on a personal level, it is desirable to seek systematic and concrete solutions at the formal level. This study walks the overall understanding of nursing professors who have overcome turnover by looking at the nursing professor's experience of overcoming turnover intention and provides evidence to understand the experience of nursing professors who have overcome turnover intention from a phenomenological point of view based on this result. It aims to contribute to improving the quality of nursing education for nursing students by allowing nursing professors to focus on nursing education without changing jobs.

Device Model for a Solid‐State Barocaloric Refrigerator

Solid‐state refrigeration represents a promising alternative to vapor compression cooling systems. Solid‐state devices based on magnetocaloric, electrocaloric, and elastocaloric effects have demonstrated the ability to achieve high‐efficiency, reliable, and environment‐friendly refrigeration. Cooling devices based on the barocaloric (BC) effect—entropy change due to applied hydrostatic pressure, however, has not yet been realized despite the significant promise shown in material‐level studies. As a step toward demonstrating a practical cooling system, this work presents a thermodynamic and heat transfer model for a BC refrigerator The model simulates transient thermal transport within the solid refrigerant and heat exchange with hot and cold thermal reservoirs during reversed Brayton refrigeration cycle operation. The model is used to evaluate the specific cooling power (SCP) and coefficient of performance (COP) of the device comprising nitrile butadiene rubber (NBR) as a representative BC refrigerant. Experimentally validated BC properties of NBR are used to quantify the contribution of different operating parameters including cycle frequency, applied pressure, operating temperatures, and heat transfer coefficient. The results show that a BC refrigerator operating with a temperature span of 2.4 K and 0.1 GPa applied pressure can achieve an SCP of 0.024 W g−1 at 10 mHz cycle frequency and a COP as high as 5.5 at 1 mHz cycle frequency—exceeding that of conventional vapor compression refrigerators. In addition, to identify key refrigerant properties, the effect of bulk modulus, thermal expansion coefficient, heat capacity, and thermal conductivity on device performance are quantified. The results highlight the trade‐off between different material properties to maximize the BC response, while minimizing mechanical work and improving thermal transport. This work demonstrates the promise of solid‐state cooling devices based on soft BC materials and provides a framework to quantify its performance at the device‐level.

Thermal performance of a novel composite phase change material for solar-assisted air source heat pump packed bed thermal energy storage application

The thermal properties of the heat storage medium in the solar-assisted air source heat pump (SAASHP) systems must be aligned with the system’s heat generation temperature while satisfying the heat demand. In this study, a novel composite phase change material (CPCM) for efficient heat storage in SAASHP systems was developed. Our investigation revealed that the incorporation of 8 wt% KNO3, 1.5 wt% thickener, and 1.0 wt% Al2O3 nanoparticles into sodium acetate trihydrate resulted in the manifestation of desirable properties suitable for SAASHP systems. The compound exhibited a suitable melting point of 48.66 °C, high latent heat of 235.97 kJ/kg, low supercooling degree of 2.25 °C, and good thermal conductivity of 0.905 W/(m·K). Furthermore, the novel CPCM demonstrated exceptional thermal stability, with only an 8.64 % loss of latent heat after undergoing 200 cycles, while maintaining a supercooling degree within a range of 6 °C for each cycle. Moreover, molecular dynamics simulation results further indicated that the presence of KNO3 weakened the interaction between CH3COONa molecules and water molecules, leading to a reduction of the melting point. Additionally, numerical analysis revealed that the total heat storage capacity and exergy storage capacity of the packed bed thermal energy storage (PBTES) system filled with the novel CPCM are 358.8 MJ and 25.1 MJ, respectively. With an increase in the heating power of the SAASHP system from 10 kW to 30 kW, the cycle heat storage time of the PBTES system can decrease by 38.8 %, while an increase in the flow rate from 2 m3/h to 6 m3/h can reduce the time by 26.3 %. These findings have significant implications for the selection and composition design of thermal storage materials in SAASHP systems.

An Overview of Microorganisms Immobilized in a Gel Structure for the Production of Precursors, Antibiotics, and Valuable Products.

Using free microorganisms for industrial processes has some limitations, such as the extensive consumption of substrates for growth, significant sensitivity to the microenvironment, and the necessity of separation from the product and, therefore, the cyclic process. It is widely acknowledged that confining or immobilizing cells in a matrix or support structure enhances enzyme stability, facilitates recycling, enhances rheological resilience, lowers bioprocess costs, and serves as a fundamental prerequisite for large-scale applications. This report summarizes the various cell immobilization methods, including several synthetic (polyvinylalcohol, polyethylenimine, polyacrylates, and Eudragit) and natural (gelatin, chitosan, alginate, cellulose, agar-agar, carboxymethylcellulose, and other polysaccharides) polymeric materials in the form of thin films, hydrogels, and cryogels. Advancements in the production of well-known antibiotics like penicillin and cephalosporin by various strains were discussed. Additionally, we highlighted cutting-edge research related to strain producers of peptide-based antibiotics (polymyxin B, Subtilin, Tyrothricin, varigomycin, gramicidin S, friulimicin, and bacteriocin), glusoseamines, and polyene derivatives. Crosslinking agents, especially covalent linkers, significantly affect the activity and stability of biocatalysts (penicillin G acylase, penicillinase, deacetoxycephalosporinase, L-asparaginase, β-glucosidase, Xylanase, and urease). The molecular weight of polymers is an important parameter influencing oxygen and nutrient diffusion, the kinetics of hydrogel formation, rigidity, rheology, elastic moduli, and other mechanical properties crucial for long-term utilization. A comparison of stability and enzymatic activity between immobilized enzymes and their free native counterparts was explored. The discussion was not limited to recent advancements in the biopharmaceutical field, such as microorganism or enzyme immobilization, but also extended to methods used in sensor and biosensor applications. In this study, we present data on the advantages of cell and enzyme immobilization over microorganism (bacteria and fungi) suspension states to produce various bioproducts and metabolites-such as antibiotics, enzymes, and precursors-and determine the efficiency of immobilization processes and the optimal conditions and process parameters to maximize the yield of the target products.

Plasma-enhanced atomic layer deposition of carbon films employing a cyclic process of N2/H2 plasma and α, α’-dichloro-p-xylene as a precursor

A novel concept and process were proposed for the plasma-enhanced atomic layer deposition (PE-ALD) of carbon films. α, α’-dichloro-p-xylene (DCX) was used to form the adsorption layer, which was modified using nitrogen/hydrogen (N2/H2) plasma. Through iterative molecular chemisorption and end-group substitution processes, the selective and precise control of carbon deposition by PE-ALD was achieved. The growth per cycle of this process was estimated to be 0.02–0.05 nm/cycle. To determine the chemical reactions that occurred during the PE-ALD process, the IR spectra observed using in-situ Fourier transform infrared spectroscopy were analyzed. The decrease in the Si-OH bond at 3740 cm−1 and the saturation of the increase in CH bending at 1250 cm−1 revealed that the deposition of a DCX monolayer via a dehydrochlorination reaction with isolated OH bonding on SiO2 has been successfully achieved. The change in N(−H)x stretching during the N2/H2 plasma treatment indicated the substitution of exposed C-Cl bonding with C-NH2 bonding on the chemisorbed DCX monolayer surface. Additionally, the composition of the carbon films after 200-cycle PE-ALD was analyzed. Finally, the realization of the concept for PE-ALD of carbon film was confirmed by surface analysis.

Accelerated failure behavior of Zr702 in boiling nitric acid solutions under constant stress loading

The constant stress tensile deformation behavior of commercial Zr702, used in spent fuel reprocessing industry, was investigated in 108 °C/200 MPa nitric acid solutions and non-corrosive silicone oil. Microscopic characterization of surface as well as cross-section of deformed Zr702 was carried out. In silicone oil, there were minimal cracks observed on the sample's surface. However, a significant number of cracks appeared on the sample's surface in nitric acid solutions. In nitric acid solutions, at the interface between the oxide layer and the matrix, cracks occurred, extended, the oxide film fractured, cracks further expanded, and the stress concentration at the cracks tip led to the formation of new cracks. This cyclic process resulted in the strength of the material decreasing and accelerated failure.

Methodological path of an action research project in Brazil’s unified health system research program

ABSTRACT This paper analyzes the cyclical process of an action research project conducted by a group of academics, policy advocates, and humanization supporters under the aegis of Brazil’s Unified Health System Research Program. The project uses a qualitative approach, based on Institutional Analysis and Intervention Research principles. As nested cycles often pass through reflection-action moments, the findings are presented according to several such moments: method construction, participation type, search for theories, and cyclical action research process. They suggest that AR’s cyclical nature can enrich knowledge production and transform healthcare practices, and that well-qualified advocates and humanization supporters can contribute to this by understanding local health needs and providing valuable suggestions to enhance administrative and healthcare actions. These findings underscore the importance of the cyclical nature of action research, which constantly deepens and adds flexibility to participation, knowledge and data production, thereby providing a crucial element which enables research to continue, despite adverse conditions, such as the COVID-19 pandemic.

Facile preparation of photothermal and superhydrophobic melamine sponge for oil/water separation and anti-icing

The preparation of superhydrophobic sponges with excellent physiochemical performance, affordability, and versatility is still a big challenge. Herein, a photothermal and superhydrophobic melamine sponge has been successfully achieved by decorating lignin particles (LPs)@MXene composite onto the skeletons of melamine sponge (MS) via the self-polymerization of dopamine. The obtained superhydrophobic MS (labeled as MS@PDA/LPs@MXene) shows a water contact angle of 153.7°, and maintains surface superhydrophobicity under harsh conditions (i.e., acidic, alkaline environments, high temperatures, frictional damage, and icing/de-icing cycles). Notably, the MS@PDA/LPs@MXene exhibits an exceptional oil adsorption capacity of carbon tetrachloride up to 143.6 times of its own weight, a high separation efficiency of 99.3 %, and a retained separation efficiency of 98.9 % after 15 cyclic adsorption processes, respectively. Owing to a synergistic photothermal effect of PDA and LPs@MXene, the MS@PDA/LPs@MXene possesses a maximum surface temperature of 62.8 °C under solar irradiation (1.0 kW/m2, 1 sun), and realizes the ice-free property at a low temperature of −17.9 °C (relative humidity, 90 %) on a continuous cooling stage under solar irradiation (0.5 sun). Furthermore, the LPs@MXene composite coating can be applied on various substrates (i.e., Al sheet, Cu sheet, filter paper, carbon cloth, steel mesh and NdFeB magnet) to obtain surface superhydrophobicity, showing excellent anti-corrosion property for the permanent NdFeB magnet. Thus, this paper proposes a facile and cost-effective strategy to prepare superhydrophobic melamine sponge with multifunctional properties, and provides new insights into the rational design of high-performance superhydrophobic sponges for their applications in oil/water separation and anti-icing.

Experimental and DFT studies of mercury adsorption and oxidation on CuCo2O4(110) surface

Elemental mercury (Hg0) is a typical toxic pollutant in flue gas from coal-fired power plants. The specific role of oxygen transfer on Hg0 oxidation over CuCo2O4 oxygen carrier and the involved reaction mechanisms were systematically studied by experimental and theoretical methods. In this study, the CuCo2O4 oxygen carrier with spinel-structure was prepared with salt-assisted combustion method. To reduce the grain size and increase the specific surface area of the oxygen carrier, the optimal KCl: CuCo2O4 ratio of 1:1 was obtained. Oxygen uncoupling ability of CuCo2O4 oxygen carrier was very strong, and the oxygen-releasing performance was slightly decreased after ten cyclic processes. Simulation based on density functional theory (DFT) shows that CuCo2O4 has relative low oxygen vacancy formation energy and oxygen transport energy barrier, and the oxygen vacancy is the preferred O2 adsorption site. Hg0 removal experiments show that CuCo2O4 has a strong ability to remove Hg0. The proportion of Hg2+ increases with the temperature, and the proportion of HgP decreases accordingly. Simulation shows that the 3-Co site on the surface of the CuCo2O4 oxygen carrier is the optimum Hg0 adsorption site. CuCo2O4 is found as a strong oxygen-releasing oxygen carrier, which can effectively promote the oxidation of Hg0.

Bounded Rational Decision Networks with Belief Propagation.

Complex information processing systems that are capable of a wide variety of tasks, such as the human brain, are composed of specialized units that collaborate and communicate with each other. An important property of such information processing networks is locality: there is no single global unit controlling the modules, but information is exchanged locally. Here, we consider a decision-theoretic approach to study networks of bounded rational decision makers that are allowed to specialize and communicate with each other. In contrast to previous work that has focused on feedforward communication between decision-making agents, we consider cyclical information processing paths allowing for back-and-forth communication. We adapt message-passing algorithms to suit this purpose, essentially allowing for local information flow between units and thus enabling circular dependency structures. We provide examples that show how repeated communication can increase performance given that each unit's information processing capability is limited and that decision-making systems with too few or too many connections and feedback loops achieve suboptimal utility.