Rock Cycle Research Articles

The Carbon Isotopic Composition of Archean Kerogen and Its Resilience Through the Rock Cycle

The Archean rock record is limited and there is minimal organic matter available to understand the origin and evolution of life on early Earth. Low carbon isotope ratios have been measured in organic and reduced carbon phases in Archean rocks and have been invoked as biosignatures. However, it can be challenging to distinguish whether these low values reflect biotic formation, abiotic reactions, or post-depositional processes. To re-address this long-standing question, we compiled a comprehensive dataset of carbon isotope ratio measurements from organic carbon phases from Archean units that were analyzed using a variety of geochemical techniques. Our compilation also includes available descriptions and measurements of the stratigraphy, mineralogy, elemental ratios, and metamorphic grade for each data point. Our statistical analyses re-enforce a result that has been noted by prior compilations, that the carbon isotopic composition of Archean organic matter (OM) is broadly more 13C-deplete than the composition of Phanerozoic OM: The median δ13C values ( ±SD) of Archean total organic carbon and kerogen were −30.5±8‰ (n=2421) and −33.7±11.3‰ (n=556; Phanerozoic OM δ13C ±SD = −26.7±4.6‰ with n=449 from a prior compilation). Our study also identifies a previously unrecognized bimodality within the δ13C values of Archean OM that is observed even with subsampling of the data to account for geographic and stratigraphic sampling bias. We describe and model the isotopic and structural changes associated with the transformation of marine Type II kerogen from formation through diagenesis, catagenesis and metagenesis, and metamorphism, as described by trends on a van Krevelin diagram. Empirically, early maturation of organic matter during diagenesis results in shifts up to a few per-mille, which can occur in either direction depending on selective preservation and degradation of compounds. Thermal cracking that occurs during catagenesis can drive increases in δ13C of 5–12‰. At temperatures above greenschist metamorphism, carbon atoms exchange with other reactive carbon pools, driving increases in δ13C of up to 20‰. Together, our analyses suggest that the most metamorphosed graphitic samples from the earliest Archean are likely signatures of alteration, while low and multimodal ranges of δ13C values may preserve records of Archean ecology.

Calcium isotopic fractionation during aragonite and high-Mg calcite precipitation at methane seeps

The formation of authigenic carbonate in marine environments represents a process that buffers ocean chemistry and atmospheric carbon dioxide levels. The isotopic composition of calcium (δ44/40Ca) in authigenic carbonate can be used to investigate the calcium (Ca) cycle, seawater chemistry, and diagenesis of carbonate rocks, archiving key information on the evolution of the Earth's surface environments. Laboratory experiments have shown that Ca isotopic fractionation during carbonate precipitation – the basis of the δ44/40Ca proxy – is mainly determined by both mineral phase and precipitation rate. However, the precipitation rate of submarine authigenic carbonate is much lower than rates in laboratory experiments. This study investigated the Ca isotopic composition of pore water and carbonate nodules collected from two gravity piston cores and one push core from the Haima seeps in the northern South China Sea. Methane fluxes calculated for the three cores range from 12 to 134 µmol cm−2 yr−1. The core with intermediate methane flux showed evidence of aragonite precipitation, while high-Mg calcite was the dominant mineral phase in the other two cores as indicated by Mg/Ca and Sr/Ca ratios of pore water. Numerical modeling of pore water geochemistry revealed that: (1) precipitation rates of carbonate per unit reactive surface area range from 0.05 to 21 µmol m−2 h−1, which is one to three orders of magnitude lower than rates in precipitation experiments; (2) Ca isotopic fractionation for aragonite precipitation is –1.8 ± 0.3 ‰, close to the reported equilibrium isotopic fractionation in precipitation experiments; and (3) Ca isotopic fractionation for high-Mg calcite precipitation is similar for the two cores (−0.9 ± 0.3 ‰ and −0.8 ± 0.3 ‰), although the modeled precipitation rates differed by two orders of magnitude. These results indicate that mineralogy rather than precipitation rate is the primary control on Ca isotopic fractionation during carbonate precipitation at seeps, resulting in lower δ44/40Ca values of aragonite (0.91±0.06 ‰, N = 4) than of high-Mg calcite (1.41±0.04 ‰, N = 9) reported relative to NIST SRM915a. This study documents distinguishable Ca isotopic fractionation during the formation of methane-derived high-Mg calcite and aragonite, providing fundamental parameters for further exploration of the calcium isotopic composition of marine authigenic carbonates in the geological record.

On the crumpling and repaving of the North American continent

At perhaps the coarsest scale of consideration, the rock cycle operates through fluxes associated with tectonic uplift and erosion, which are generally balanced by subsidence/subduction and the burial of mineral materials that leads to volumetric balance among the principal rock reservoirs. At Earth’s surface, net rates of transfer are manifest as the reduction of areas of older rocks during erosional destruction as well as during burial by younger units. Because exposure of continental crust comprises some finite space, decrease of older rock area by erosion and/or burial must be largely balanced by an increase in area of new sedimentary and volcanic successions. Here, we examine relations between the lateral extents of rock units exposed across North America—their lithology, elevation, and the age of formation—to determine rates of geologic “repaving” that are recorded in the age and area of rocks making up the surface of the continent. Moreover, because deposition occurs at lower elevations, one might expect that subsequent episodes of uplift and/or burial would serve to increase the average elevation of currently exposed sedimentary lithosomes. Because plutonic and metamorphic rocks form at depth and are only exposed along orogenic belts and across shields after extended intervals of uplift and/or erosion, one might expect basement rocks to be initially exposed at higher elevations, and that subsequent erosion would decrease elevation with increasing age. Therefore, processes giving rise to associations between outcrop lithology, extent, and elevation may serve as measures of continent-scale rates of rock cycling. We combine data from the 1 arc-minute global relief model with data from the Geological Society of America’s 2005 Geologic Map of North America to assess the actuality and significance of first-order relations among the lithologies, areas, ages, and elevations of rock bodies now exposed across the North American continent and how these may shed light on deep-time rates of rock cycling. Areas of the 23,642 mapped North American lithosomes make up a lognormal frequency distribution (mode = 121 km2). This distribution reflects both natural (lateral extents of individual map units must be limited in space) and anthropogenic (cartographers must render map units within limited range of sizes) causes. Contiguous, lateral associations of the major rock types suggest that the spatial occurrence of volcanic and sedimentary rock bodies is largely independent of the proximity of other rock types, but exposures of plutonic and metamorphic lithosomes are intimately associated in space and thus comprise the “crystalline basement” exposed in cores of younger orogens and across the Canadian Shield. Unlike sedimentary and volcanic rocks that “attain their age” when formed at Earth’s surface, plutonic and metamorphic units are “born” at depth and therefore must have reached some antiquity prior to first exposure. As a result, the ages of volcanic and sedimentary exposures span the full range of ages represented by all lithologies, while those of plutonic and metamorphic suites are more abbreviated and older. Median ages of North American volcanic, sedimentary, plutonic, and metamorphic exposures are 482 Ma, 306 Ma, 1695 Ma, and 2467 Ma, respectively. Although the areal extent of sedimentary rock decreases with increasing age, elevation increases. This change is interpreted as reflecting progressive tectonic uplift from initial accumulation at lower elevations. In contrast, the surfaces of exposed volcanic, plutonic, and metamorphic lithosomes become lower in elevation with increasing age. This change reflects both the erosional lowering of lithosome surfaces as well as the progressive exhumation of larger areas of crystalline basement. Exposed rock area exhibits a power law decrease with increasing age. This change reflects the progressive destruction of older units and their burial by younger units. A simple “repaving” model in which 0.8% area is uplifted and eroded per million years is in good agreement with observed relations of map age versus area, the rate of which is equivalent to the resurfacing of the North American continent every 63 m.y. or ∼56 times over the past 3.5 Ga. The rate of decrease in map area of exposed rocks with increasing age evident in both geologic map data and repaving models is about three times the rate of decrease in total sediment volume as determined from stratigraphic data and repaving models. The decrease in the areas of exposed rock units is primarily the result of burial by younger units rather than erosive destruction.

Becoming-lithic: elemental utopian possibility in the contemporary ecocatastrophe

ABSTRACT This article explores an emerging cluster of ecocatastrophe narratives that locate utopian possibility within the Earth’s sub-crustal lithosphere. Texts such as N. K. Jemisin’s “Broken Earth” trilogy (2015–2017), J. G. Ballard’s The Crystal World (1966), Lars von Trier’s film Melancholia (2011), Irene Solà’s Catalan novel When I Sing, Mountains Dance (2019), and the first season of the Icelandic TV series Katla (Netflix, June 2021) uncover an inhuman ecology whose vibrant, lively agency can be discerned within the geologic temporalities of deep time. Unlike their “Hollow Earth” precursors (a late nineteenth-century subgenre of the literary utopia), in which human protagonists ventured below the Earth’s surface to discover rich worlds of utopian alterity, these contemporary lithic texts revoke their characters’ human sovereignty in images of encroaching human-lithic intimacy: a process that I call becoming-lithic. In conveying the lively potentialities of geological processes such as the rock cycle, plate tectonics, continental drift, orogenesis and subduction, igneous activity, these lithic texts encourage readers and viewers to reconsider our relationship between the geosphere and the biosphere. I trace their emerging elemental aesthetics, asking how we might parse their inhuman moments of possibility and, in the process, undertake the urgent task of decolonising utopian studies.

Entire Life Theoretical Model of Limestone under Unequal Cyclic Loading Based on the Expanding Theory of Thermodynamic System Analysis

Breakage, Helmholtz free energy, and nonlinearity are involved in many fundamental phenomena of complex systems across natural sciences. However, a mathematical equation that can express the entire life cycle of complex natural objects (such as rock-like quasi-brittle materials) is lacking. We expand the material body system to an isolated compound thermodynamic system to establish an innovative theoretical model induced by coupling nonlinear separation of Helmholtz free energy and breakage evolution that can be used to express the extreme entire life model of rock under unequal amplitude loading and unloading cycle. We gain crucial insights into the life essence of limestone, which is termed “Negative Dissipation.” This study first shows that the change in the mechanical properties of quasi-brittle materials caused by the timely evolution of breakage can be represented by the nonlinear separation of Helmholtz free energy and negative dissipation. An analytical solution to the nonlinear separation variables of Helmholtz free energy is provided by combining the method of solving nonlinear partial differential equations in mathematics and thermodynamic law. An analytical solution of Helmholtz free energy considering nonlinearity and breakage is proposed, and an equation that can reflect the constitutive mechanics law of the entire life cycle of rock in the theoretical model is presented. Theoretical results are consistent with the experimental data obtained from limestone samples with different prefabricated cracks. This original study provides a theoretical foundation for the life model of complex natural objects for nonlinear breakage and an early warning investigation of rocks under various unprecedented conditions.Practical ApplicationsThis study first found that the change in the mechanical properties of complex natural objects caused by the timely evolution of breakage can be represented by the nonlinear separation of Helmholtz free energy. We establish an innovative theoretical model induced by coupling nonlinear separation of Helmholtz free energy and breakage evolution. The innovative theory includes three parts: (1) an analytical solution to the nonlinear separation variables of Helmholtz free energy, (2) an analytical solution of Helmholtz free energy considering nonlinearity and breakage, and (3) an equation of the theoretical model that can reflect the constitutive mechanics’ law of the entire life of quasi-brittle rocks is presented for the first time. This original research result provides the foundation for a more in-depth life cycle of quasi-brittle rocks to develop the theoretical basis for the nonlinear breakage and early warning research of materials under various unprecedented conditions. We report a route to material microstructure composition, which may open an alternative pathway to quasi-brittle materials, which may, in turn, open a door into the mysterious world of science.

Milankovitch cycle of continental deep-water fine-grained sedimentary rocks in the lower submember of Es3 of Well FY1 in Dongying Sag and its significance for shale oil exploration

China has recently faced significant difficulties in the exploitation of its shale oil and gas resources. An essential geological obstacle preventing the breakthrough of Chinese shale oil exploration is the precise identification of productive oil and gas pools and ideal formation. Therefore, it is crucial to examine the properties of shale reservoirs. Deep-water fine-grained sedimentary rocks in the lower member of the Well FY1 in Dongying Sag are analyzed using the Milankovitch cycle based on core, geochemical analysis, and gamma logging data. The findings demonstrate that: (1) The entire Milankovitch cycle is preserved in the Es3x of Well FY1 in Dongying Sag, and that the long Eccentricity of 405 ka and the Precession cycle of 23.2 ka are the key controlling factors in the deposition. (2) The “three-end-member” method is used to divide eight different types of lithofacies. The main vertical changes in these lithofacies are from organic massive gray mudstone to organic lamellar callitic mudstone to organic massive gray mudstone to organic lamellar gray mudstone to organic lamellar gray mudstone and back again. From shallow to deep to deeper, the entire water depth fluctuated. (3) Each of the four lengthy Eccentricity cycles has a half-cycle of warm, humid weather and cold, dry weather. Analysis was done on how the lithofacies and organic matter concentration changed with high and small eccentricities. The enrichment of biological materials in warm, wet, dry, and cold climates was hypothesized by examining the response of fine-grain sedimentary rocks to eccentricities and Precession periods. Larger Eccentricity is thought to be more suitable for storing shale oil.

Extremely rapid up-and-down motions of island arc crust during arc-continent collision

Mountain building and the rock cycle often involve large vertical crustal motions, but their rates and timescales in unmetamorphosed rocks remain poorly understood. We utilize high-resolution magneto-biostratigraphy and backstripping analysis of marine deposits in an active arc-continent suture zone of eastern Taiwan to document short cycles of vertical crustal oscillations. A basal unconformity formed on Miocene volcanic arc crust in an uplifting forebulge starting ~6 Ma, followed by rapid foredeep subsidence at 2.3–3.2 mm yr−1 (~3.4–0.5 Ma) in response to oceanward-migrating flexural wave. Since ~0.8–0.5 Ma, arc crust has undergone extremely rapid (~9.0–14.4 mm yr−1) uplift to form the modern Coastal Range during transpressional strain. The northern sector may have recently entered another phase of subsidence related to a subduction polarity reversal. These transient vertical crustal motions are under-detected by thermochronologic methods, but are likely characteristic of continental growth by arc accretion over geologic timescales.

Trace element fingerprints of Ni–Fe–S–As minerals in subduction channel serpentinites

A variety of base-metal minerals (BMM) may form during hydration-dehydration of ultramafic rocks within subduction zones. However, the trace element fingerprints of these minerals and their relation to different stages of the subduction cycle are still unexplored. Here, we present the first comprehensive in situ analysis by Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) of (semi)-metals (Ni, Fe, As, Sb, Co, Bi, Te, Pb, Cd, Se, Cu, Zn, and Mn) and precious metals (Os, Ir, Rh, Pt, Pd, Au, and Ag) for Ni–Fe–S–As minerals in subducted serpentinites from the La Cabaña area (South-Central Chile). The targeted rocks are medium- and high-pressure serpentinites recording the entire cycle of burial-exhumation within a subduction zone. A first stage of hydration of upper mantle peridotites within the mantle wedge led to formation of lizardite after magmatic olivine at ~300 °C. This stage was followed by prograde hydration (i.e., antigoritization at ~320–400 °C; <1GPa) and subsequent partial dehydration (formation of prograde olivine at ~600 °C and 1.1 GPa) within the subduction channel, and final exhumation of the serpentinites and incorporation in the accretionary prism still in the stability field of antigorite (>300 °C). The Ni–Fe–S–As minerals in these serpentinites include Ni-Fe-rich sulfides [pentlandite (Ni,Fe)9S8), smythite (Fe9S11), heazlewoodite (Ni3S2), millerite (NiS)], arsenides [orcelite (Ni5-xAs2), nickeline (NiAs) and maucherite (Ni11As8)] and, to a lesser extent, alloy (awaruite, Ni3Fe) and sulfarsenides (gerdorffite, NiAsS). Their abundance, morphology and chemistry strongly vary with the degree of serpentinization and style of deformation of the host rock. Thus, euhedral grains of heazlewoodite ± awaruite ± magnetite formed in equilibrium with lizardite when magmatic olivine was hydrated within the mantle wedge. Once the lizardite-olivine serpentinites were incorporated into the subduction serpentinite channel, the infiltration of hotter (S-As-Sb)-bearing fluids promoted antigoritization under static regime and precipitation of orcelite and pentlandite in equilibrium with antigorite. Channelling of fluids in zones of focussed strain enhanced further antigoritization in some schistose serpentinites at decreasing fO2 and fS2, resulting in the transformation of pentlandite into a second generation of heazlewoodite–awaruite–magnetite. After relic olivine exhaustion, fO2 and fS2 increased promoting the replacement of the secondary heazlewoodite to millerite. No significant variations in terms of trace elements were observed during these mineral replacements associated to hydration upon prograde metamorphism and/or increasing of strain. In contrast, partial dehydration of serpentinites under high-pressure conditions (> 1GPa) generated Ni-rich awaruite in equilibrium with the prograde assemblage antigorite-metamorphic olivine. These awaruites are depleted in trace elements, indicating substantial (semi)-metal and precious metal mobility during high P-T metamorphism within the subduction channel. During the final stage of deformation linked to exhumation inside the accretionary prism some orcelite grains formed during early antigoritization recrystallized without substantial change in trace element concentration. At this stage, nickeline singularly enriched in gold formed in equilibrium with the recrystallizing orcelite. These results demonstrate that Ni–Fe–S–As minerals formed or modified during the entire subduction cycle of upper mantle rocks have their own characteristic trace element signature (i.e., depletion in precious metals and enrichment in As, Sb, Te, Bi and Pb) that distinguish them from magmatic counterparts.

Steno and the rock cycle

Geologists categorize the basic types of rock according to their origin – igneous, sedimentary, or metamorphic -- rather than by their physical properties. This is expressed dynamically by the fundamental concept of the rock cycle, which describes how the basic rock types are derived from one another within the Earth system as a result of ongoing cyclic geologic processes. In Nicolaus Steno’s published geological work, particularly De Solido, he takes a similar approach, outlining how a substance can be examined “to disclose the place and manner of its production”. Steno also recognizes the roles of erosion, transport, and deposition in the production of sedimentary strata from pre-existing earth materials. His description and diagrams of the geological evolution of Tuscany also show a clear cyclicity of process. While the modern concept of the rock cycle did not emerge until the 19th century, Steno’s work contains key elements of this important concept.

Rapid endogenic rock recycling in magmatic arcs

In subduction zones, materials on Earth’s surface can be transported to the deep crust or mantle, but the exact mechanisms and the nature of the recycled materials are not fully understood. Here, we report a set of migmatites from western Yangtze Block, China. These migmatites have similar bulk compositions as forearc sediments. Zircon age distributions and Hf–O isotopes indicate that the precursors of the sediments were predominantly derived from juvenile arc crust itself. Using phase equilibria modeling, we show that the sediments experienced high temperature-to-pressure ratio metamorphism and were most likely transported to deep arc crust by intracrustal thrust faults. By dating the magmatic zircon cores and overgrowth rims, we find that the entire rock cycle, from arc magmatism, to weathering at the surface, then to burial and remelting in the deep crust, took place within ~10 Myr. Our findings highlight thrust faults as an efficient recycling channel in compressional arcs and endogenic recycling as an important mechanism driving internal redistribution and differentiation of arc crust.

The largest negative carbon isotope excursions in Neoproterozoic carbonates caused by recycled carbonatite volcanic ash

The late Ediacaran Shuram Excursion (SE) records the most prominent negative δ13C excursions (δ13C = −12‰) during Earth’s history. It has been hypothesized to have resulted from oxidation of dissolved organic matter, diagenetic or authigenic precipitates. However, the origin of the SE remains enigmatic; current models face challenges regarding the significant amount of atmospheric oxygen needed to balance such extensive oxidation and sustained inputs of light carbon with extremely negative C isotope compositions. Here, we show that the Doushantuo Formation at the Jiulongwan section in South China, a key stratum recording the SE event, contains mineralogical and geochemical signatures related to igneous processes. Both the occurrence of ankerite, feldspar, moissanite and euhedral quartz in the SE samples and the relatively consistent Ce anomalies of carbonate and O isotopes of quartz indicate a contribution from an igneous source. In particular, the SE samples have trace element and C isotope compositions similar to those of recycled carbonatites formed by decarbonation and melting of sedimentary carbonate rocks. These observations suggest that the deep cycle of ancient carbonate rocks, which were subjected to decarbonation during subduction, melting and eruption related to the breakup of the Rodinia supercontinent, contributed to the SE. This igneous model for the SE may provide a connection between the deep and shallow carbon cycles of the Earth.

Carbon cycle evolution before and after the Great Oxidation of the atmosphere

The rock record of organic carbon abundance and its isotopic composition is consistent with the evolution of life more than 3800 million years ago (Ma). Despite this, there are very few insights as to the ecology of this ancient biosphere or to its level of activity. One possible insight, however, comes from the isotopic composition of inorganic and organic carbon in ancient rocks. This isotope record can be used, in principle, to determine the proportion of inorganic carbon entering the oceans that was buried in sediments as organic matter, and thus it helps constrain the activity level of the ancient biosphere. A quantitative analysis of this isotope record, however, requires that we understand how the Earth-surface carbon reservoir has evolved over time, as burial rates of organic matter in marine sediments depend on the input rates of carbon to the oceans. We must also know how organic matter is weathered as a function of atmospheric oxygen concentrations, thus indicating how much of the organic matter in sediments is newly formed or recycled. To explore these issues, a carbon cycle model is developed here that includes an evolving Earth-surface carbon reservoir as well as the oxygen dependency of the organic matter weathering in rocks. The model also allows for the release of CO₂ from organic matter during metamorphism and it contains a rock cycle with young and old reservoirs with appropriate transfer fluxes between them. The model shows that before the Great Oxidation Event (GOE) about 2400 Ma, only about 5 percent to 10 percent as much organic matter was buried into marine sediments as compared with today. Such low rates of organic matter burial would be consistent with a subdued marine biosphere. Such a subdued biosphere could possibly be consistent with primary production driven by anoxygenic photosynthesis coupled to an iron cycle. In association with, and in the aftermath of, the GOE, the biosphere likely increased its activity level by an order of magnitude. This large increase would have completely transformed the biology of the Earth and could have resulted from either the evolution and/or expansion of oxygen-producing cyanobacteria or a dramatic increase in the availability of nutrients to fuel oxygenic phototrophs.

Garnet sand reveals rock recycling processes in the youngest exhumed high- and ultrahigh-pressure terrane on Earth

Rock recycling within the forearcs of subduction zones involves subduction of sediments and hydrated lithosphere into the upper mantle, exhumation of rocks to the surface, and erosion to form new sediment. The compositions of, and inclusions within detrital minerals revealed by electron microprobe analysis and Raman spectroscopy preserve petrogenetic clues that can be related to transit through the rock cycle. We report the discovery of the ultrahigh-pressure (UHP) indicator mineral coesite as inclusions in detrital garnet from a modern placer deposit in the actively exhuming Late Miocene-Recent high- and ultrahigh-pressure ((U)HP) metamorphic terrane of eastern Papua New Guinea. Garnet compositions indicate the coesite-bearing detrital garnets are sourced from felsic protoliths. Carbonate, graphite, and CO2 inclusions also provide observational constraints for geochemical cycling of carbon and volatiles during subduction. Additional discoveries include polyphase inclusions of metastable polymorphs of SiO2 (cristobalite) and K-feldspar (kokchetavite) that we interpret as rapidly cooled former melt inclusions. Application of elastic thermobarometry on coexisting quartz and zircon inclusions in six detrital garnets indicates elastic equilibration during exhumation at granulite and amphibolite facies conditions. The garnet placer deposit preserves a record of the complete rock cycle, operative on <10-My geologic timescales, including subduction of sedimentary protoliths to UHP conditions, rapid exhumation, surface uplift, and erosion. Detrital garnet geochemistry and inclusion suites from both modern sediments and stratigraphic sections can be used to decipher the petrologic evolution of plate boundary zones and reveal recycling processes throughout Earth's history.

Triple Oxygen Isotopes in Evolving Continental Crust, Granites, and Clastic Sediments

This Chapter considers triple oxygen isotope variations and their 4 Gyr temporal evolution in bulk siliciclastic sedimentary rocks and in granites. The d18O and D'17O values provide new insights into weathering in the modern and ancient hydrosphere and coeval crustal petrogenesis. We make use of the known geological events and processes that affect the rock cycle: supercontinent assembly and breakup that influence continent-scale and global climate, the fraction of the exposed crust undergoing weathering, and isotopic values of precipitation. New data from a 5000 m Texas drillhole into the Oligocene Frio Formation demonstrate minimal isotopic shifts from mudrocks to shales during diagenesis, mostly related to expulsion of water from smectite-rich loosely cemented sediment and its conversion to illite-rich shale. Inversion of triple oxygen isotope fractionations return isotopic values and temperatures along the hole depth that are more consistent with weathering conditions in the Oligocene and modern North America (d18O = -7 to -15‰, and T of +15 to +45°C) rather than d18O from 8 to 10‰ diagenetic water in the drill hole at 175-195°C. More precise T and d18Owater are obtained where the chemical index of alteration (CIA) based detrital contribution is subtracted from these sediments. Triple oxygen isotopes from suspended sediments in major world rivers record conditions (T and d18Ow) of their watersheds, and not the composition of bedrock because weathering is water-dominated. In parallel, the Chapter presents new analyses of 100 granites, orthogneisses, migmatites, tonalite-trondhjemite-granodiorite (TTG), and large-volume ignimbrites from around the world that range in age from 4 Ga to modern. Most studied granites are orogenic and anatectic in origin and represent large volume remelting/assimilation of shales and other metasediments; the most crustal and high-d18O of these are thus reflect and record the average composition of evolving continental crust. Granites also develop a significant progressive increase in d18O values from 6-7‰ (4-2.5 Ga) to 10-13‰ (~1.8-1.2 Ga) after which d18O stays constant or even decreases. More importantly, we observe a moderate -0.03‰ step-wise decrease in D'17O between 2.1 and 2.5 Ga, which is about half of the step-wise decrease observed in shales over this time interval. We suggest that granites, as well as shales, record the significant advent and greater volumetric appearance of low-D'17O, high-d18O weathering products (shales) altered by meteoric waters upon rapid emergence of large land masses at ~2.4 Ga, although consider alternative interpretations. These weathering products were incorporated into abundant 2.0-1.8 Ga orogens around the world, where upon remelting, they passed their isotopic signature to the granites. We further observe the dichotomy of high-D'17O Archean shales, and unusually low-D'17O Archean granites. We attribute this to greater contribution from shallow crustal hydrothermal contribution to shales in greenstone belts, while granites in the earliest 3.0-4.0 Ga crust and TTGs require involvement of hydrothermal products with lower-D'17O signatures at moderately high-d18O, which we attribute to secondary silicification of their protoliths before partial melting. The Chapter further discusses evolution of the shale record through geologic history and discusses the step-wise change in d18O and D'17O values at Archean/Proterozoic transition. Denser coverage for shales in the past 1 billion years permits investigation of the rocks and their weathering in the last supercontinent cycle, with observed lighter d18O values, characteristic for the mid-Phanerozoic at the initiation of Gondwana breakup. The continuing increase in d18O values of the shales since 4 Ga is interpreted to reflect accumulation of weathering products via shale accretion to continents, as low-density and buoyant shales tend to not subduct back into the mantle. The rock cycle passes triple oxygen isotopic signatures from precipitation to sedimentary, metasedimentary, and finally to anatectic igneous rocks. Continental crust became progressively heavier in d18O, lighter in D'17O due to incremental accumulation of high-d18O sediments in accretionary wedges. Second-order trends in d18O and D'17O are due to supercontinent cycles and glacial episodes.

Orogenic andesites and their link to the continental rock cycle

Continents are created and destroyed at convergent margins but understanding the interconnectedness of this system—a complex interplay of subaerial and tectonic erosion, volatile exchange and metamorphism, partial fusion and melt evolution—is far from complete. Here we use geochemical data from the Mexican convergent margin to reveal a strong connectivity between subducted materials and typical orogenic andesites. We find that the along-strike isotopic variations of andesitic stratovolcanoes in Mexico are mirrored by those of riverine sediments sampled along the continental margin, which presumably represent the compositions of tectonically ablated forearc crust entering the subduction zone. Isotopic modelling further indicates that the Mexican andesites represent partial melts of subduction mélanges, constituted by mixtures of altered subducted ocean crust, forearc debris and mantle peridotite in similar proportions. Remarkably, the concentrations and ratios of incompatible trace elements in the volcanoes also correlate with the major element compositions of their corresponding forearc sediments. This suggests that the modal contents of key mineral phases in the partially molten mélanges control the trace element abundances of the andesitic magmas. These findings demonstrate that a significant proportion of tectonically eroded subducted crust is not lost to the deep mantle, but effectively reincorporated into arc magmas in a closely interlaced continental rock cycle.

Global zircon analysis records a gradual rise of continental crust throughout the Neoarchean

Determining when continental masses emerged above the global ocean is crucial to understanding secular changes in crustal and Earth-surface processes. The emergence of continents above sea level provided important sinks for atmospheric CO2, a source of bioavailable P2O5, and initiated the erosional component of the rock cycle. Previous estimates for continental emergence vary widely and depend on complex geochemical proxies. Here, we formulate a testable hypothesis for the behavior of sedimentary systems in a world with flooded vs. emergent continents and employ a simple sample-based analysis of the global detrital-zircon record. Our analysis filters the total detrital zircon database from >600,000 analyses to ∼450,000 analyses, then calculates age distribution metrics for each rock sample containing >40 individual zircon analyses. We show that watersheds with inferred sizes, relative to their host continents, similar to modern ones became common ∼2.8 billion years ago, and that consistent crustal recycling occurred at least since the Neoarchean. In light of the extant geologic record, this analysis suggests that widespread continental emergence began at the end of the Mesoarchean and progressed throughout the Neoarchean. Our analysis therefore provides a novel chronometer to track the emergence of continental-crust throughout Earth's history.

Eruption Cycle of Volcanic Rocks Based on Virtual Reality Technology

The eruption cycle of volcanic rocks based on virtual reality technology is studied to reveal the spatial distribution of volcanic rocks and the genetic relationship between different lithologic assemblages, and effectively guide volcanic exploration. Taking Xujiaweizi fault depression and Yingshan depression in Songliao Basin as the research area, the monocular vision method of virtual reality technology is used to collect data from the study area. Then, the three-dimensional dynamic scene of the study area was constructed. Based on this, combined with the research steps and division basis of the volcanic eruption cycle, the eruption cycle of the volcanic region in the study area is studied. According to the characteristics of volcanic activity, volcanic facies sequence, and rock rhythm combination in Xujiaweizi fault depression, the first and three sections of Yingcheng formation are divided into three eruption periods according to the contact relationship between sedimentary strata and volcanic rocks in the eruptive intermittent period. Y1C1, Y1C2, Y1C3, Y3C1, Y3C2, and Y3C3 are respectively from bottom to top. Yingshan volcanic rocks in Yingshan depression are divided into three cycles and six periods. Each stage has significant stages and differences, and the eruption intensity is different. The overall performance is gradually enhanced, and the internal cycle is characterized by the first strong and then weak.

Physical and mechanical characteristics of saturated tuff under the freeze–thaw cycle

The freeze–thaw cycle of rocks is a research hotspot in the field of geotechnical engineering, and it significantly affects the eastern part of the Zhejiang Province in China. In this study, we test 40 occurrences of freeze–thaw cycles on tuff from the Ningbo area and investigate the variation of the physical and mechanical properties. The results show that only a small amount of debris falls off the saturated tuff samples during the freeze–thaw cycle. The overall quality of the rock sample gradually decreases with the increase in the number of freeze–thaw cycles. However, the average loss rate of the quality is extremely low, accounting for only 0.07% of the rock sample quality. The wave velocity of the rock sample gradually decreases, and the extent of reduction decreases when the number of cycles increases. In the uniaxial compression test, a failure surface appears for the rock samples with low freeze-thaw cycles. The complete failure surface of the samples gradually disappears. Moreover, the compressive strength of the samples progressively decreases with the increase of the number of freeze–thaw cycles.

Advanced comminution modelling: Part 2 - Mills

This second part paper explores rock breakage mechanisms, the life cycle of rocks in mills and the strong influence of end walls on charge motion within mills. We present recent advances in particle-based modelling of mills for comminution focused around wear and the effect of slurry and slurry phase grinding. Three mill scenarios are considered:1.Media flow and the resulting wear evolution of the belly and end wall liners and the resulting change in mill performance for a full industrial scale dry ball mill (modelled using DEM)2.Axial slurry transport and mixing in a wet overflow industrial scale ball mill (modelled using fully coupled DEM and SPH)3.Effect of mill speed on slurry and solid charge motion and the resulting grinding of fine particles in a 1.8 m diameter wet Hardinge pilot mill (modelled using fully coupled DEM and SPH with advection-diffusion-population balance equations solved for the slurry size distribution for each SPH particle)These demonstrate the nature and level of fidelity that is now possible to include in particle-scale comminution models. They provide insights into the critical importance of curtain flows generated by the end walls of tumbling mills, on wear behaviour on liners, on the structure of slurry pools and mill discharge and on the adverse effect on grinding of increasing mill speed.

Lugares geoeducativos da cidade de Caçapava do Sul (RS) para estudo de Geologia no ensino médio

Este artigo tem como objetivo descrever vivências obtidas a partir de atividades práticas envolvendo educandos do Ensino Médio, discentes do Curso de Geologia e seus educadores. O objetivo principal dessas atividades foi a seleção e investigação de lugares de interesse geológico com fins didáticos na cidade de Caçapava do Sul, RS, como proposta de ensino-aprendizagem. A observação e seleção dos lugares iniciou com a combinação de desenvolver debates sobre Geologia e cotidiano. Foram selecionados aqueles que estivessem próximos da escola para facilitar a mobilidade das turmas, segurança dos envolvidos e disponibilidade de tempo. Após cinco encontros, onde foi dialogado sobre o ciclo das rochas, Geologia da cidade, cotidiano e técnicas de registro digital e escrito. A participação e envolvimento efetivo dos educandos foi bem distribuída ao longo dos encontros. O engajamento durante as atividades foi positivo, o aprimoramento do aprender a conhecer, a fazer, a viver e a ser dos educandos nas atividades propostas.