In this paper, using Sullivan's approach to rational homotopy theory of simply-connected finite type CW complexes, we endow the $\mathbb{Q}$-vector space $\mathcal{E}xt_{C^{\ast}(X;\mathbb{Q})}(\mathbb{Q}, C^{\ast}(X;\mathbb{Q}))$ with a graded commutative algebra structure. This leads us to introduce the $\mathcal{E}xt$-version of higher (resp. module, homology) topological complexity of $X_0$, the rationalization of $X$ (resp. of $X$ over $\mathbb{Q}$). We then compare these invariants and their respective ordinary ones for Gorenstein spaces.
 We also highlight, in this context, the benefit of Adams-Hilton models over a field of odd characteristics especially through two cases, the first one when the space is a $2$-cell CW-complex and the second one when it is a suspension.
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