The polymer solar cells (PSCs) have been developed as a promising low-cost renewable energy. The best PSC is composed of a polymer donor layer and a fullerene acceptor bulk-heterojunction (BHJ) composite sandwiched between a transparent conductive oxide, and a metal electrode. In this manuscript we report on the integration of the electrodeposited ZnO and CuSCN in PSCs as electron (ETL) and hole (HTL) transporting layers. We developed inverted polymeric photovoltaic devices based on electrodeposited ZnO ETL with power conversion efficiency (PCE) of 3.3% on glass substrates and remarkably good stability under AM1.5 illumination for an active surface area of 0.28 cm2. Electrodeposited CuSCN nanowires are proposed as new HTL in conventional PSCs and a PCE of 5.1% with low-bandgap polymer active layer was obtained. The appropriate selection of the ETL and the HTL and the method for their preparation is crucial to obtain high-performance of PSCs.