Optimal fiber path configurations that minimize the sum of the coefficients of thermal expansion (CTE) values along the principal material directions for a class of laminates are presented. Previous studies suggest that balanced, symmetric, angle ply laminates exhibit negative CTE values along the principal directions. Using the sum of the CTE values along the principal material directions as an effective measure of the coefficient of thermal expansion (CTE eff ), we have shown and provided a proof that the smallest value of CTE eff is rendered by straight fiber path configurations. The laminates considered are sufficiently thin so as to neglect the thermal stresses induced through the thickness of the laminate. It is found that the minimal CTE eff values occur for [+45/−45] ns lay-ups. This result is supported by numerical studies that consider curvilinear fiber paths. The possibility of obtaining zero CTE values along both principal material directions and the conditions that render this situation are also examined.