An anisotropic visco-hyperelastic constitutive model for rate-temperature-dependent deformation during one-step hot stamping forming simulation of unidirectional (UD) CF/PEEK prepregs is presented. This constitutive model is based on strain energy decomposition and a multiplicative decomposition of the deformation gradient. Two simple Maxwell models are used to characterize the viscoelastic behavior of the melted PEEK matrix and longitudinal shear deformation, respectively, and a shear invariant of [Formula: see text] is proposed to calculate the shear deformation. Moreover, the fiber stretching deformation is modeled by an anisotropic hyperelastic model. To obtain the model parameters, tensile tests at different strain rates and temperatures above the melt temperature of PEEK are performed on [Formula: see text], [Formula: see text], and [Formula: see text] CF/PEEK prepreg specimens, respectively. In parallel, the [0]8 and [45]8 curved beam specimens are experimentally fabricated to validate the constitutive model. The VUMAT subroutine is developed according to the proposed constitutive model and applied for a [Formula: see text] off-axis tensile simulation and hot-stamping forming simulation of CF/PEEK prepregs. The experimental and simulation results show that the materials flow, distribution of strain and stress, forming defects (wrinkles and overlap) of CF/PEEK curved beam can be captured by the proposed model.