This paper deals with the following critical elliptic systems of Hamiltonian type, which are variants of the critical Lane-Emden systems and analogous to the prescribed curvature problem:{−Δu1=K1(y)u2p,y∈RN,−Δu2=K2(y)u1q,y∈RN,u1,u2>0, where N≥5,p,q∈(1,∞) with 1p+1+1q+1=N−2N, K1(y) and K2(y) are positive radial potentials.At first, under suitable conditions on K1,K2 and the certain range of the exponents p,q, we construct an unbounded sequence of non-radial positive vector solutions, whose energy can be made arbitrarily large. Moreover, we prove a type of non-degeneracy result by use of various Pohozaev identities, which is of great interest independently. The indefinite linear operator and strongly coupled nonlinearities make the Hamiltonian-type systems in stark contrast both to the systems of Gradient type and to the single critical elliptic equations in the study of the prescribed curvature problems. It is worth noting that, in higher-dimensional cases (N≥5), there have been no results on the existence of infinitely many bubbling solutions to critical elliptic systems, either of Hamiltonian or Gradient type.