Curing Duration Research Articles

Optimization of Hybrid Microwave Curing Approach Based On the Performance of Metakaolin-Based Geopolymer Mortars

Geopolymer binders have been highlighted due to their low carbon emission during production and processing. While metakaolin and F-type fly ash are commonly used as raw materials for aluminosilicate-based geopolymers, the long heat-curing requirements for hardening and strength development still pose challenges. This paper investigates the possible use of a hybrid microwave curing technique to design a set-on-demand approach to reduce the duration of heat curing in metakaolin-based geopolymer. The experimental design was established for samples with three different molar ratios (MR; 1.3,1.5, and 1.7) containing metakaolin, fly ash, and silica fume. Samples were subjected to 3 different curing regimes: oven curing, microwave (MW) curing, and hybrid curing (a combination of optimized microwave and oven curing). The performance evaluation was based on compressive strength, dimensional stability, and alkali leaching (efflorescence). Implementing only MW curing resulted in a significant decrease in compressive strength compared to their counterpart oven-cured samples. The reduction of compressive strength was more pronounced at lower molar ratios. The design of a hybrid curing approach where a portion of oven curing was replaced by MW resulted in a higher strength development than those only cured with MW. Similarly, the efficiency of hybrid curing was more pronounced in samples having MR of 1.5 and 1.7. Using MW curing in the geopolymer binders did not affect the alkali leaching; however, it increased the material’s drying shrinkage. Results showed that replacing a portion of oven curing with microwave curing in a hybrid approach can increase the operation speed and the hardening rate without significantly decreasing compressive strength.

Performance evaluation and mix design of ambient-cured fly ash-phosphogypsum blended geopolymer paste and mortar

A practical mix design and performance metrics for fly ash-phosphogypsum blended geopolymer paste and mortar is lacking. This study focused on investigating the physico-chemo-mechanical performance and mix design of ambient-cured fly ash-phosphogypsum geopolymer paste (FPGP) and mortar (FPGM). The geopolymer was formed by reacting binary powder precursor (fly ash+phosphogypsum) and alkaline activator (NaOH+Na2SiO3). The fly ash was substituted with varying weight proportions of phosphogypsum (i.e., 10 %, 20 %, 30 %, 40 %, 50 %). Experimental testing and analysis were done based on ASTM standards, XRF, XRD, SEM-EDS, ANOVA, and Python. The workability, setting time, flexural strength, compressive strength, morphology, and mineralogy were studied. The multivariate regression approach was used to model the relationship between compressive strength and alkaline liquid/precursor. The optimum mixture conditions for FPGP and FPGM were 30 wt% phosphogypsum, alkaline liquid/precursor of 0.4, 10 M NaOH, Na2SiO3/NaOH of 1.5, and binder/aggregate of 1.0. The results showed that the workability of FPGP ranged from 185 mm to 112 mm while that of FPGM ranged from 145 mm to 100 mm. The FPGP and FPGM had considerably lower initial and final setting times of (18 – 37 min, 81 – 155 min) and (14 – 29 min, 67 – 142 min), respectively. The compressive strength of FPGP ranged from 7.3 MPa to 27.24 MPa while that of FPGM ranged from 9.5 MPa to 43.27 MPa. There was a strong connection between compressive and flexural strength giving R2 values > 0.8. Based on the adjusted R2 values and ANOVA, the proposed mix design models were statistically significant since the p-value (0.000) was less than the 0.05 significance level and the value of F (197.953) was greater than the critical value of 1. At high curing duration, the concentration of NaOH and alkaline liquid/precursor facilitated the dissolution of Ca2+ in phosphogypsum and Si4+and Al3+ in fly ash forming a C-(N)-A-S-H matrix crucial to the strength development of geopolymers. The statistical metrics implied a good performance accuracy and reliability of the proposed model equations and can find practical applications in construction materials design. For optimal results, it is recommended to use the prediction models within the specific input parameters employed in this study.

Effect of magnesium hydroxide on the properties of fireproof coatings for steel structure based on magnesium phosphate cement

Magnesium phosphate cement, renowned for its exceptional fire resistance, has been a key area of research in fireproof coatings for steel structures. This study introduces a significant amount of magnesium hydroxide to replace the dead-burned MgO in magnesium phosphate cement. The goal is to enhance fireproof performance by capitalizing on magnesium hydroxide's outstanding flame retardant and fire resistance properties. This paper primarily investigates the effects of substantial amounts of magnesium hydroxide on the compressive strength, dry density, and bonding strength of coatings and the quality, phase, and micro-morphology of coatings before and after flaming thermal shock. The findings indicate that when the substitution rate of magnesium hydroxide surpasses 50%, the coatings exhibit commendable performance characteristics. After a curing duration of 28 days, the coatings attain a compressive strength of 0.5MPa, a bonding strength exceeding 0.04MPa, and a dry density remaining below 650kg/m³. Furthermore, the coatings demonstrate remarkable resilience to thermal shock, maintaining structural integrity even under extreme flame thermal shocks exceeding 1000 °C, without any observable cracking or spalling. This noteworthy performance underscores the significant potential of this research in the industrial landscape.

Comprehensive Utilization of Industry By-Products in Precast Concrete: A Critical Review from the Perspective of Physicochemical Characteristics of Solid Waste and Steam Curing Conditions

Solid wastes have been widely used as a cement substitute in precast concrete. On the one hand, solid waste can effectively ameliorate a series of problems caused by steam curing. On the other hand, the use of solid waste can reduce the amount of cement used in the construction industry and reduce carbon emissions. However, due to the complexity of the steam curing system, the performance of precast concrete prepared under different steam curing conditions varies greatly. Moreover, there are a wide variety of solid wastes, and the differences in the physicochemical properties of different solid wastes are significant. Therefore, it is necessary to systematically determine the mechanism of action of commonly used solid wastes. In this paper, the steam curing system is introduced in detail, and the mechanism of action of solid waste in precast concrete is systematically summarized. It was found that an appropriate increase in the temperature and duration of steam curing facilitates the strength development of precast concrete. In addition, there is a difference in the effect of the addition of solid wastes on the early and late strength of precast concrete, which usually leads to a decrease in the demolding strength of precast concrete, but increases the late strength of precast concrete. This study provides a reference for rationally regulating steam curing systems and realizing the comprehensive utilization of solid wastes in precast concrete.

Temperature induced fast-setting of cement based mineral-impregnated carbon-fiber reinforcements for durable and lightweight construction with textile-reinforced concrete

Developing durable and sustainable mineral-impregnated carbon-fiber (MCF) reinforcement system is today an effective measure to solve common service issues of conventional steel or FRP reinforcement in building sector. This study introduces a novel methodology for the design and realization of fast-setting cement based MCF reinforcements via targeted thermal activation. The process involves impregnating continuous yarns with a micro-sized particle cement suspension utilizing custom-built manufacturing equipment. Subsequently, the impregnated yarns undergo controlled heating at moderate temperatures to accelerate the cure process and strength development. Flexural and tensile performance of the MCFs exhibits progressive improvements with longer curing durations (from 2 to 20 h) and higher temperatures (from 40 °C to 60 °C). Enhanced mechanical properties are attributed to advanced hydration reactions and microstructural densification, as proven by thermogravimetric analysis (TGA), mercury intrusion porosimetry (MIP), scanning electron microscopy, isothermal calorimetry and micro-computed tomography (μCT). When heating at 60 °C for 20 h, as-produced MCFs demonstrate optimal tensile strength of 2747 MPa and flexural strength of 482 MPa, with exceptional bond with concrete substrate, comparable to conventional FRPs. The proposed post-treatment shows promising potential for significantly enhancing the flexibility of mineral matrix composites, making them suitable for a wide range of industrial and field applications.

Experimental study on the stabilization of marine soft clay as subgrade filler using binary blending of calcium carbide residue and fly ash

This study endeavors to realize the concurrent utilization of marine soft clay (MSC) and industrial waste, specifically calcium carbide residue (CCR) and fly ash (FA), through a series of experimental investigations. The optimal ratio between CCR and FA, as well as the efficacy of the composite agent (CF–1), were examined, and an empirical equation associating the unconfined compressive strength (qu) of stabilized MSC was developed through unconfined compressive strength (UCS) tests. Microscopic analyses, including X–ray diffraction (XRD), scanning electron microscopy (SEM), and energy–dispersive spectroscopy (EDS), were employed to unveil the intrinsic mechanisms underlying CF–1 stabilized MSC. Subsequently, the suitability of CF–1 solidified MSC as a roadbed filler was ascertained through laboratory tests. Results revealed the optimum CCR:FA ratio for CF–1 to be 4:1, demonstrating superior curing effects compared to individual components such as Portland cement (PC), CCR, and FA, with commendable environmental and economic benefits. The developed empirical equation exhibited effectiveness in predicting the qu of CF–1 solidified MSC under varying curing dates (T) and dosages (Wg) conditions. Characterization through XRD, SEM, and EDS identified the primary products formed within the stabilized MSC matrix with CF–1 as comprising calcium–silicate–hydrate (C–S–H) gel, calcium–aluminate–hydrate (C–A–H) gel, and a minor amount of calcite. As T and Wg increased, the reduction in pores between soil particles enhanced the structural integrity and macro–strength of the cured MSC. The failure pattern of CF–1–solidified MSC elementary samples depended on the CF–1 dosage and curing duration. The solidification mechanism of CF–1 on MSC involved pozzolanic, ion exchange, and carbonation reactions. CF–1 solidified MSC satisfied all the specified requirements for roadbed filler in the relevant code, demonstrating substantial potential for in–situ solidification projects involving MSC.

Synergistic effects of CO2 mixing and CO2 curing in CO2 uptake capacity of Portland cement

This study investigates the synergistic effects of CO2 mixing and CO2 curing on the CO2 uptake capacity of Portland cement. After a normal mixing or ten minutes of CO2 mixing, samples underwent 0.5, 1, or 3 days of CO2 curing at a 10 % CO2 concentration. Hydration and carbonation characteristics were assessed by means of a thermogravimetry analysis, reacted water and CO2 uptake measurements, pore solution analysis, X-ray diffractometry, and Rietveld-refinement-based quantification. The CO2-mixed samples displayed an escalating trend in terms of CO2 uptake with longer curing times and greater reaction degrees compared to normally mixed samples. In addition, extended CO2 curing durations resulted in decreased levels of portlandite and increased amounts of crystalline carbonates, alongside a reduction in the ratio of amorphous to crystalline carbonates. Subsequently, improvements in the compressive strength were noted with longer CO2 curing durations.

Thermal, electrical, and mechanical performances of ultrahigh-performance cementitious composites with multiwalled carbon nanotubes

This study examines the influence of multiwalled carbon nanotubes (MWCNTs) on cementitious composites, specifically focusing on the fabrication of multifunctional cementitious composites known as ultrahigh-performance cementitious (UHPC) composites. Key properties such as compressive strength, thermal performance, and electrical resistance were examined with varying MWCNT contents, curing methods, curing duration, and supply voltage. The effects of the incorporation of MWCNTs on the hydration reactions of the cementitious composites were analyzed using field-emission scanning electron microscopy, thermogravimetric analysis, and X-ray diffraction. The study revealed that MWCNT UHPC composites can achieve a maximum ultrahigh strength of 120.8 MPa. Additionally, the incorporation of MWCNTs enabled the composites to reach a maximum surface temperature of 90.6 °C during heating. Furthermore, the power consumption of MWCNT UHPC composites was found to be predictable based on the curing type and the duration of curing. Notably, the hydration reactions in MWCNT UHPC composites remained unaffected by the MWCNT content. The findings emphasize the potential of multifunctional MWCNT UHPC composites by offering exceptional strength, heating capabilities, and electrical performance in construction materials.

Exploring the curing kinetics of Acrolein-Pentaerythritol resin: Impact of molecular weight and molecular weight distribution on cure behavior

Curing kinetics are crucial for designing and optimizing the process parameters of a resin. This study examines the non-isothermal curing kinetics of acrolein-pentaerythritol (APE) resins, focusing on the impact of molecular weight (MW) and molecular weight distribution (MWD) on their cure behavior. Kinetic parameters were determined using isoconversional and combined kinetic analysis methods through microcalorimeter measurements. The findings suggest that the cure process follows the nucleation and growth models (Avrami−Erofeev equation), with an activation energy of 72.2 kJ/mol. A comparison of two APE resins with different molecular weights and molecular weight distributions reveals that higher MW components expedite the initial curing reaction but impede the main curing process, leading to extended curing durations. This study provides valuable insights into the curing kinetics of APE resin and the influence of MW and MWD, contributing to the reliable and reproducible production of composite parts.

Study on High-Ductility Geopolymer Concrete: The Influence of Oven Heat Curing Conditions on Mechanical Properties and Microstructural Development.

Low carbon and high performance have become key trends in the development of construction materials. Understanding the mechanism by which curing conditions affect the mechanical properties of high-ductility geopolymer concrete (HDGC) is of significant importance. This study investigated three sealing curing temperatures (room temperature, 45 °C, and 60 °C) and four curing durations (1 day, 3 days, 5 days, and 7 days), while considering two final curing ages (7 days and 28 days) to explore their effects on the axial tensile and compressive properties of HDGC. The results showed that both 45 °C and 60 °C could improve the brittle failure of HDGC under axial compressive loading. However, curing at 60 °C and for durations longer than 1 day in an oven would catalyze the formation of eight-faced zeolite crystals within the slag-fly ash geopolymer matrix, and it could weaken the matrix's pore structure and subsequently affect the material's later strength development. Nevertheless, oven heat curing enhanced the bridging effect between the fibers and the matrix, partially compensating for the reduction in the initial tensile strength of HDGC. This follows the pseudo-strain-hardening material's saturation cracking criterion to enhance the strain-hardening behavior of HDGC and improve its tensile energy absorption capacity. A curing condition of 45 °C for 5 days is recommended to maximize the ductility of HDGC. This study provides important theoretical support for the design and promotion of green, low-carbon, high-ductility composite materials.

Effect of waste travertine powder on properties of rhyolitic tuff-based geopolymer

This investigation explores the potential of geopolymer technology as an eco-friendly substitute for conventional construction materials by emphasizing the innovative use of naturally occurring green rhyolitic tuff and repurposed travertine powder in geopolymer paste formulations. Replacement levels of tuff with travertine at 40 %, 45 %, and 50 %, along with an alkaline solution with a NaOH molarity range of 8.2 M–22.1 M, have been analyzed for their impact on flowability, water absorption, porosity, compressive strength, and unit weight of the geopolymers over curing periods of 2, 28, and 90 days. The flowability measurements show that adding 40 %, 45 %, and 50 % travertine leads to approximately 7 %, 31 %, and 31 % reductions in the flowability of the geopolymer, respectively. It is demonstrated that adding 40 % travertine significantly improves the geopolymers’ compressive strength with an 11.5 M NaOH concentration, showing substantial increases of approximately 15.5, 9.0, and 2.4 times at the curing duration of 2, 28, and 90 days, respectively, relative to the geopolymer without travertine. As an optimum points, an 18.5 M NaOH and an 0.7 solution-to-powder ratio decrease the long-term apparent porosity and water absorption of the geopolymer without travertine by about 14 % and 19 % compared to those at the same solution-to-powder ratio with 11.5 M NaOH, respectively. Microscopic examinations were employed to validate the development of sodium aluminosilicate hydrate, calcium aluminosilicate hydrate, and calcium silicate hydrate gels, underscoring the advantageous contribution of the elevated CaO content in the travertine to the geopolymer matrix. This research not only highlights the environmental benefits of repurposing waste materials but also contributes to the development of more sustainable and durable geopolymer pastes, offering a promising approach to enhancing environmental stewardship in material science practices.

Incorporation of High Volume Ground Granulated Slag From Blast Furnaces in Pavement Quality Concrete

Supplementary cementitious materials (SCMs) are commonly introduced into the concrete mix to increase their properties, addressing the current need for durable and robust pavements. With every ton of Ordinary Portland Cement (OPC) produced through processes such as fossil fuel combustion and limestone fermentation, carbon dioxide is released into the atmosphere. Conversely, Ground Granulated Blast-furnace Slag (GGBS), being abundantly available, presents a viable more environmentally friendly alternative to cement for various concrete applications. This work studies the influence of GGBS, in combination with chemical admixtures, on M40 grade binary blended concrete mixtures. The aim of the study was to improve the strength characteristics at various stages of concrete curing. The results indicated that the GGBS-incorporated concretes (replacing 60%, 65%, and 70% of the cement) exhibited an increase in compressive strength after prolonged curing. The average density of fresh concrete mixes containing GGBS did not exhibited a noticeable increase. A marginal disparity in air content was observed in the replacement mix. Minimal length changes were observed in the drying shrinkage test after a curing duration of 360 days compared to conventional concrete mixtures.

Integrating PZT-based WP and EMI techniques with multi-criteria analysis for monitoring and assessment of mechanical properties of structural adhesives under curing

Structural adhesives are commonly employed as bonding agents in FRP strengthening systems. Measuring and assessing the mechanical properties of adhesives during the curing process is essential, as these properties directly influence the overall effectiveness of the strengthening system. This study investigated the development of mechanical properties in structural adhesives at various curing times using two PZT-based monitoring techniques, specifically wave propagation (WP) and electromechanical impedance (EMI) techniques. Two types of structural adhesives and two distinct curing temperatures (ambient temperature and mild temperature) were selected for examination. Throughout the adhesive curing process, both methods were utilized for monitoring. Subsequently, tensile tests were conducted to obtain the mechanical properties at different curing durations. The results demonstrate that monitoring indicators from both PZT-based techniques effectively captured the enhancement in adhesive performance during the curing process. Moreover, the tensile strength of the Sika and Carbon adhesives reached stability at ambient temperature after five and three days, respectively, while elevated temperatures accelerated the curing process. Furthermore, two Multi-Criteria Decision Making (MCDM) methods were employed to select monitoring indicators with the least deviation and the closest correlations with mechanical properties. These indicators have the potential to predict mechanical properties, potentially reducing the need for tensile tests.

Study on the Repair Effect of Self-Healing Cementitious Material with Urea-Formaldehyde Resin/Epoxy Resin Microcapsule

Recent studies on microencapsulated self-healing cementitious materials have primarily focused on the particle size and preparation methods of the microcapsules. However, there has been limited attention paid to the microscopic aspects, such as the selection of curing agents and the curing duration of these materials. In this study, urea-formaldehyde resin/epoxy resin E-51 microcapsules were synthesized through in situ polymerization. This research investigates the feasibility of self-healing from a molecular mechanism perspective and evaluates the repair performance of microencapsulated self-healing cement mortar with varying microcapsule concentrations, curing agent types, and curing ages. The findings demonstrate that the microcapsule shells bond effectively with the cementitious matrix, with radial distribution function peaks all located within 3.5 Å. The incorporation of microcapsules enhanced the tensile strength of the modified cement mortar by 116.83% and increased the failure strain by 110%, indicating improved adhesion and mechanical properties. The restorative agent released from the microcapsule core provided greater strength after curing compared to the uncured state. Although the overall strength of the microencapsulated self-healing cement mortar decreased with higher microcapsule concentrations, the repair efficiency improved. The strength recovery rate of 28-day aged modified cement mortar had a significant improvement with the addition of X and Y curing agents, respectively.

Kinetic Study and Catalytic Activity of Cr3+ Catalyst Supported on Calcium Silicate Hydrates for VOC Oxidation.

Volatile organic compounds (VOCs) are pollutants that pose significant health and environmental risks, necessitating effective mitigation strategies. Catalytic oxidation emerges as a viable method for converting VOCs into non-toxic end products. This study focuses on synthesizing a catalyst based on calcium silicate hydrates with chromium ions in the CaO-SiO2-Cr(NO3)3-H2O system under hydrothermal conditions and evaluating its thermal stability and catalytic performance. A catalyst with varying concentrations of chromium ions (10, 25, 50, 100 mg/g Cr3+) was synthesized in unstirred suspensions under saturated steam pressure at a temperature of 220 °C. Isothermal curing durations were 8 h, 16 h, and 48 h. Results of X-ray diffraction and atomic absorption spectroscopy showed that hydrothermal synthesis is effective for incorporating up to 100 mg/g Cr3+ into calcium silicate hydrates. The catalyst with Cr3+ ions (50 mg/g) remained stable up to 550 °C, beyond which chromatite was formed. Catalytic oxidation experiments with propanol and propyl acetate revealed that the Cr3+ catalyst supported on calcium silicate hydrates enhances oxygen exchange during the heterogeneous oxidation process. Kinetic calculations indicated that the synthesized catalyst is active, with an activation energy lower than 65 kJ/mol. This study highlights the potential of Cr3+-intercalated calcium silicate hydrates as efficient catalysts for VOC oxidation.

Leaching behavior and compressive strength in the immobilization of Cs-137 contaminated electric arc furnace dust via doping with activated carbon

This study evaluated the potential of an immobilization technique to inhibit the migration and dispersion of Cs-137 contaminated electric arc furnace dust (EAFD) into the environment, by investigating its compressive strength and leaching characteristics. The EAFD was employed to replace ordinary Portland cement (OPC) in varied ratios, ranging from 0 % to 50 % by weight. The replacement was done using various water-binder ratios of 0.35, 0.40, 0.45, and 0.50. Furthermore, the use of activated carbon (AC) has been shown to minimize radionuclide and heavy metal discharge related to its high porosity. AC was added at weight concentrations of 0.5 %, 1.0 %, 1.5 %, and 2.0 %. Compressive strength and leaching tests are used to assess the long-term stability of waste forms and the effectiveness of immobilizing radioactive wastes, which is beneficial for storing and disposing of radioactive waste. The compressive strength is affected by the amount of EAFD, water-to-binder ratios, the addition of AC, and the duration of curing. Measurements of specific surface area, pore size, pore volume, and porosity were also carried out under various conditions. The research results indicate that the addition of AC improves the compressive strength and decreases the release of Cs-137 and heavy metals from the specimen. The mixture of 45 % EAFD and 1.5 % AC is appropriate for efficiently immobilizing Cs-137 contaminated EAFD.

Short- and long-term mechanical performances of damaged porous asphalt mixture treated with asphalt emulsion

Porous asphalt (PA) pavement usually has a short service life due to the ravelling distress. Spraying surface treatment (ST) asphalt emulsion could alleviate it. However, the effects of ST on the short- and long-term mechanical performances of PA mixture are unclear. Therefore, this study used repeated axial load test, indirect tensile fatigue test and indirect tensile cracking test to evaluate the rutting, fatigue and cracking resistances of damaged PA under different curing durations, respectively. Two curing temperatures, 25 and 60°C, were considered here. Results showed that the mechanical properties of ST treated PA were significantly improved in short-term. The durability of mechanical properties is good based on long-term observation data. The rutting resistance of treated PA was not compromised if the application rate of ST is well controlled. A high curing temperature could expedite recovery efficiency of damaged PA, but it was accompanied by faster aging, which cannot be ignored.

Influences of pretreatment methods on the mechanical and environmental behaviors of PG-GGBS-LM ternary stabilizer.

Phosphogypsum is a kind of acidic industrial byproducts with high content of soluble phosphorus and fluorine pollutants, which requires to be pretreated when used as cementitious material to (partial) replace traditional Portland cement. In this study, five different pretreatment methods were proposed for comparative analysis to examine the pretreatment effect on the mechanical and environmental behaviors of ternary phosphogypsum (PG), ground granulated blast-furnace slag (GGBS), and lime (LM) mixed stabilizer. Series laboratory tests, including unconfined compressive strength (UCS), pH, phosphorus (P)/fluorine (F) leaching, scanning electron microscopy (SEM), and X-ray diffraction (XRD) tests, were conducted to comprehend the macro- and microscopic mechanism. The results show that it is essential to grind raw PG to finer powdered state, so that it reacts more easily and quickly with LM and water. In addition, it was noticed that the UCS and P/F leaching concentration are not only affected by the mixing proportion of the PG-GGBS-LM ternary stabilizer, but also by the curing duration. The UCS increases rapidly from initial curing period and then grows slowly after 28days of curing. From the perspective of strength evolution, mixing proportion of PG: GGBS: LM = 15:80:5 is optimal, but considering the economy and environmental related issues, PG: GGBS: LM = 30:65:5 was regarded as a more attractive choice. The findings can provide a reference for the selection of pretreatment methods and design of PG-based cementitious materials suited for stabilized soils.

Effects of post-curing duration on the mechanical properties of complex 3D printed geometrical parts

This study aims to assess the efficacy of post-curing guidance supplied by 3D printing resin manufacturers. Current guidance applies generically to all geometries with the caveat that post-curing should be extended for ‘large’ or ‘complex’ geometries but specific guidance is not provided.Two vat-polymerisation 3D printers (Form3B, Figure 4 Standalone) were used to print test models in 6 biocompatible resins (Pro Black, Med White, Med Amber, Biomed Black, Biomed White, Biomed Amber). The test model is of a complex geometry whilst also housing ISO 527 test specimens in concentric layers. Two separate intervals of curing were applied (100%, 500% stated guidance) creating different curing treatments of the specimens throughout the model. Post processed test models were disassembled and pull testing performed on each of the specimens to assess the mechanical properties.The analysis showed that extending the curing duration had significant effects on the mechanical properties of some materials but not all. The layers of the model had a significant effect except for elongation at break for the Med Amber material.This research demonstrates that generic post-curing guidance regarding UV exposures is not sufficient to achieve homogenous material strength properties for complex geometries. Large variations in mechanical properties throughout the models suggest some material was not fully-cured. This raises a query if such materials as originally marketed as biocompatible are fully cured and therefore safe to use for medical applications involving complex geometries.

A novel approach to heavy metal immobilization in municipal solid waste incineration fly ash: Investigating the use of chicken eggshell waste and CaO addition

Municipal solid waste incineration (MSWI) fly ash is a significant byproduct of waste-to-energy processes, and poses substantial environmental and health hazards if not treated properly. The process of Stabilization/Solidification (S/S) efficiently immobilizes hazardous elements present in the fly ash through a combination of physical and chemical mechanisms. The objective of this research is to thoroughly examine the feasibility of using chicken eggshell waste powder as a stabilizing agent for heavy metals, specifically targeting Pb, in MSWI fly ash. Experimental analysis involved varying eggshell waste to fly ash weight proportions, extending from 0.0 (control group), 7:3 up to 9.5:0.5 ratio, with designated curing durations of 2 and 72 hours, and maintaining a liquid-to-solid (L/S) ratio at 1.0 mL/g. In the two-hour curing period, the immobilization efficiency of Pb reached 100% with the addition of only 1.5% eggshell waste. Optimal ratios for Pb stabilization in MSWI fly ash were identified: maximum 2% eggshell waste for 2-hour curing and 1.5% for 72 hours due to elevated Pb and Cd levels of 7:3 ratio. Adding CaO mitigated these levels, enhancing stabilization and compliance with landfill criteria. The results demonstrated that the addition of CaO led to efficient immobilization of Pb, achieving approximately 99%. In addition, the observed enhancement in compressive strength resulting from the incorporation of CaO highlights its effectiveness in enhancing the stabilizing process of MSWI fly ash. By demonstrating the effectiveness of eggshell waste and CaO in stabilizing hazardous elements, this study advocates for scalable solutions and further research on long-term stability and environmental impacts.