The direct electrochemical conversion of CO2 to multi-carbon products offers a promising pathway for producing value-added chemicals using renewable electricity. However, producing ethanol remains a challenge because of the competitive ethylene formation and hydrogen evolution reactions. Herein, we propose an active hydrogen (*H)-intermediate-mediating strategy for ethanol electroproduction on a layered precursor-derived CuAl2 O4 /CuO catalyst. The catalyst delivered a Faradaic efficiency of 70 % for multi-carbon products and 41 % for ethanol at current density of 200 mA cm-2 and exhibited a continuous 150 h durability in a flow cell. The intensive spectroscopic studies combined with theoretical calculations revealed that the in situ generated CuAl2 O4 could tailor *H intermediate coverage and the elevated *H coverage favors the hydrogenation of the *HCCOH intermediate, accounting for the increased yield of ethanol. This work directs a pathway for enhancing ethanol electroproduction from CO2 reduction by tailoring *H intermediate coverage.
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