Cu-Cr pseudobinary alloys have excellent electrical properties and are widely used in many industries. Laser additive manufacturing can effectively avoid the shortcomings of traditional methods for preparing Cu-Cr alloys. However, the high reflection of Cu powder to laser energy brings difficulties to industrial practice. The assembled Cu powder is used as raw material to absorb more laser energy through the outer layer of Cr powder, thereby improving the melting efficiency of the powder and the quality of the molten pool. Laser remelting of unmelted Cr powder can inhibit the uneven nucleation and growth of precipitated Cr, and improve the uniformity of electrical conductivity and element distribution. This study provides a new idea for the preparation of high-performance Cu alloys.