Crystal Modulator Research Articles

High-speed, low-voltage, low-bit-energy silicon photonic crystal slow-light modulator with impedance-engineered distributed electrodes

Silicon modulators in optical transceivers feature high-density integration and low manufacturing cost, but they also need to deliver high speed and low power consumption to meet the demands of future data centers and high-performance computing. This paper demonstrates a significantly improved 64 Gbps silicon Mach–Zehnder modulator incorporating photonic crystal slow-light phase shifters. By employing distributed electrodes and engineering their impedance, electro-optic phase matching and electrical impedance matching were obtained simultaneously, and the driving voltage was reduced to 0.87 V, which is compatible with fin-type field effect transistors and eliminates the need for additional electrical amplifiers. The bit energy of as low as 59 fJ/bit is comparable to that of microring modulators, while this modulator does not require temperature control like that used for microring modulators, due to its wide working spectrum of 6 nm. These results indicate the potential for addressing power issues in next-generation data infrastructures.

Algorithms for representations of quiver Yangian algebras

In this note, we aim to review algorithms for constructing crystal representations of quiver Yangians in detail. Quiver Yangians are believed to describe an action of the BPS algebra on BPS states in systems of D-branes wrapping toric Calabi-Yau three-folds. Crystal modules of these algebras originate from molten crystal models for Donaldson-Thomas invariants of respective three-folds. Despite the fact that this subject was originally at the crossroads of algebraic geometry with effective supersymmetric field theories, equivariant toric action simplifies applied calculations drastically. So the sole pre-requisite for this algorithm’s implementation is linear algebra. It can be easily taught to a machine with the help of any symbolic calculation system. Moreover, these algorithms may be generalized to toroidal and elliptic algebras and exploited in various numerical experiments with those algebras. We illustrate the work of the algorithms in applications to simple cases of Ysl2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ \ extrm{Y}\\left({\\mathfrak{sl}}_2\\right) $$\\end{document}, Ygl̂1\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ \ extrm{Y}\\left({\\hat{\\mathfrak{gl}}}_1\\right) $$\\end{document} and Ygl̂11\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ \ extrm{Y}\\left({\\hat{\\mathfrak{gl}}}_{\\left.1\\right|1}\\right) $$\\end{document}.

Modulation of electron transfer behavior on Fe2P-Co2P/NPC oxygen electrocatalyst by lattice cation substitution engineering and charge transport network design for rechargeable Zn-air batteries

Crystal structure modulation engineering on the lattice scale and charge transport network design on the micro/nano scale work together to endow oxygen electrocatalysts with high reactivity to fully release the capacity of Zn-air batteries (ZABs) as the next-generation green energy storage devices. Metal phosphide-based oxygen reduction reaction (ORR)/oxygen evolution reaction (OER) electrocatalysts with tunable electronic structures, variable valence states, and moderate overpotentials are recognized as the most promising and ideal candidates for air cathodes. The cation substitution strategy overcomes the drawback that single metal phosphides with fewer active sites and high adsorption barriers are not sufficient to achieve satisfactory electrocatalytic performance. In this paper, the Fe2P-Co2P/NPC oxygen electrocatalyst employing lattice cation site substitution engineering and three-dimensional (3D) conductive network encapsulation strategies are constructed to successfully ensure fast electron transfer behavior and safe charge/discharge energy storage. Noteworthy, the presence of Schottky barriers at the interface of the two materials hinders the electron reflux, which promotes a unidirectional flow of electrons, and increases the electron condensation in the OER and ORR processes. Relying on these features, the Fe2P-Co2P/NPC-assembled liquid ZABs achieved power densities, specific capacities, and energy densities of 175.18 mW cm-2, 805.75 mAh gZn-1, and 958.84 Wh kg-1, respectively, and importantly good rate performances and stability were exhibited even under high-current-density operation. The corresponding flexible solid-state ZABs also possesses superior electrochemical activity and mechanical flexibility. This work paves the way for the construction of bifunctional oxygen electrocatalysts with high-speed electron transfer channels, thus advancing the development of wearable electronic devices.

Research on Polarization Modulation of Electro-Optical Crystals for 3D Imaging Reconstruction.

A method for enhancing the resolution of 3D imaging reconstruction by employing the polarization modulation of electro-optical crystals is proposed. This technique utilizes two polarizers oriented perpendicular to each other along with an electro-optical modulation crystal to achieve high repetition frequency and narrow pulse width gating. By varying the modulation time series of the electro-optical crystal, three-dimensional gray images of the laser at different distances are acquired, and the three-dimensional information of the target is reconstructed using the range energy recovery algorithm. This 3D imaging system can be implemented with large area detectors, independent of the an Intensified Charge-Coupled Device (ICCD) manufacturing process, resulting in improved lateral resolution. Experimental results demonstrate that when imaging a target at the distance of 20 m, the lateral resolution within the region of interest is 2560 × 2160, with a root mean square error of 3.2 cm.

Broadband terahertz modulation in symmetric gate-controlled graphene photonic crystals

Innovative research in terahertz (THz) communications is urgently needed to meet the evolving demands of the industry. In the past, the absence of optoelectronic devices made it difficult to control THz waves effectively. In this study, a symmetric gate-controlled graphene photonic crystal (PC) is proposed, which achieves a modulation depth (MD) of more than 99 %, an ultralow insertion loss (IL) of 0.08, and a wide operation bandwidth (BW) simultaneously. Additionally, even in graphene samples with low carrier mobilities, the high-performance MD can be achieved with acceptable IL in the broadband THz range. Furthermore, our proposed one-dimensional graphene PC system enhances manufacturing convenience. Through the adoption of the proposed symmetric structure, highly efficient THz communications can be achieved through photonic systems that utilize graphene.

Oiling‐Out in Industrial Crystallization of Organic Small Molecules: Mechanisms, Characterization, Regulation, and Applications

AbstractOiling‐out is a common phenomenon in industrial crystallization processes that not only prolongs the total operating time but also leads to undesirable crystal morphology, making it challenging to control crystallization paths. This review provides a comprehensive overview of the oiling‐out phenomenon in organic small molecule crystallization. First, the formation mechanisms of oiling‐out are summarized from both thermodynamic and dynamic perspectives, providing the theoretical foundation for understanding the phenomenon. Then, the universal characterization methods for studying the oiling‐out phenomenon of organic small molecules are introduced in detail, covering both offline and online analytical tools. Moreover, the regulation strategy for oiling‐out, including solvents, impurities, seeding, temperature, and mixing methods are discussed. This paper also focuses on the application of oiling‐out in co‐assembly and crystal shape modulation. Finally, future opportunities and challenges are presented to address the current shortcomings and application bottlenecks in the study of organic small molecule oiling‐out phenomena. This review aims to provide valuable insights and guidance for researchers working on the crystallization of organic small molecules, particularly in the pharmaceutical industry, to better understand, control, and utilize the oiling‐out phenomenon.

Thermodynamic and Kinetic Modulation of Methylammonium Lead Bromide Crystallization Revealed by In Situ Monitoring

Thermodynamic and Kinetic Modulation of Methylammonium Lead Bromide Crystallization Revealed by In Situ Monitoring

Multifunctional gas safety monitoring and classification warning device

Due to the absence of automatic flameout and other essential functionalities in these devices, incidents such as gas leaks can easily lead to explosions. As a result, an autonomous safety monitoring and early warning device has been specifically developed for traditional gas stove equipment. This device is capable of activating a multi-tiered alarm and control mechanism when it reaches a predetermined threshold concentration. The main control of the Arduino Uno R3 microcontroller development board serves as the foundation for this device, which utilizes the MQ-5 gas sensor and 1602 liquid crystal display module to provide real-time gas concentration display. It also incorporates a sound and light alarm system that triggers when the concentration exceeds the predetermined threshold. Additionally, it employs a human infrared sensor and flame sensor as modules for fire detection and occupancy monitoring respectively. Any abnormal changes in these parameters will activate the sound and light alarm system. Equipped with an LED light and buzzer, this system provides real-time monitoring around gas stoves. Experimental results demonstrate excellent responsiveness under current conditions. Given its significant relevance in ensuring gas safety, this multifunctional gas safety monitoring device with classification early warning capabilities holds immense potential for market applications.

Compact hundred-watt level picosecond laser system based on tapered double cladding fiber-single crystal fiber hybrid amplifier

This paper introduces a compact picosecond laser system using tapered double cladding fiber-single crystal fiber hybrid amplification technology for the first time. By modifying the Ginzburg-Landau equation, we established a simulation model and designed a passive mode-locked picosecond oscillator based on a semiconductor saturable absorber mirror. The oscillator outputs laser with a pulse width of 7.75 ps, a center wavelength of 1030.55 nm, and a spectrum width of 0.58 nm. The seed laser is stretched and amplified by the all-fiber front stage, and then injected into the tapered double cladding fiber-single crystal fiber hybrid amplifier. The laser power is amplified from 820 mw to 103.1 W, obtaining a gain of 21 dB. We used zero-phonon line pumping technology in single crystal fiber amplifier to reduce the thermal effects caused by quantum loss, thereby increasing the length of the crystal and increasing the power loading capacity. We designed a single crystal fiber amplification module using Yb:YAG with 60 mm long, 1 mm diameter and a 1 at.% doping rate for the first time. Finally, a hundred-watt level picosecond laser output with a repetition frequency of 26.33 MHz, an average power of 103.1 W, a pulse width of 244.72 ps, a spectrum width of 1.16 nm, and a beam quality of M2 x = 1.368 and M2 y = 1.511 was obtained. To the best of our knowledge, this is the highest picosecond laser output power for an all-fiber front-stage combined with a single-stage single crystal fiber amplifier.

Dual-Site Doping in Transition Metal Oxide Cathode Enables High-Voltage Stability of Na-Ion Batteries.

Designing cathode materials that effectively enhancing structural stability under high voltage is paramount for rationally enhancing energy density and safety of Na-ion batteries. This study introduces a novel P2-Na0.73K0.03Ni0.23Li0.1Mn0.67O2 (KLi-NaNMO) cathode through dual-site synergistic doping of K and Li in Na and transition metal (TM) layers. Combining theoretical and experimental studies, this study discovers that Li doping significantly strengthens the orbital overlap of Ni (3d) and O (2p) near the Fermi level, thereby regulates the phase transition and charge compensation processes with synchronized Ni and O redox. The introduction of K further adjusts the ratio of Nae and Naf sites at Na layer with enhanced structural stability and extended lattice space distance, enabling the suppression of TM dissolution, achieving a single-phase transition reaction even at a high voltage of 4.4V, and improving reaction kinetics. Consequently, KLi-NaNMO exhibits a high capacity (105 and 120 mAh g-1 in the voltage of 2-4.2V and 2-4.4V at 0.1 C, respectively) and outstanding cycling performance over 300 cycles under 4.2 and 4.4V. This work provides a dual-site doping strategy to employ synchronized TM and O redox with improved capacity and high structural stability via electronic and crystal structure modulation.

Highly Oriented FAPbI3 via 2D Ruddlesden Popper Perovskite Template Growth

Abstract2D perovskites are demonstrated as the growth template for the modulation of phase transition and crystallization of formamidinium lead triiodide (FAPbI3). However, it is challenging to obtain highly oriented α‐FAPbI3 and regulate crystallization at the bottom of the FAPbI3 film. Here, a 2D (BA)2PbI4 layer with preferred orientation is introduced to perform as the bottom template for the quasi‐epitaxial growth of FAPbI3, which triggers the α‐FAPbI3 perovskite formation. Owing to the assembly of [PbI6]4− octahedral on the 2D template, the highly (100) oriented FAPbI3 perovskites from the bottom to the top are attained. At the optimum concentration, 2D perovskites gradually vanish due to the extrusion of BA+ cation from the template, which guarantees the charge transport at the bottom. Consequently, the strategy effectively promotes film quality and suppresses non‐radiative recombination. The efficiency of perovskite solar cells (PSCs) is promoted from 23.06% to 24.78%.

Mixed-crystalline-phase molybdenum disulfide-based adsorbents with high selectivity for Pb(II) capture: Crystal surface growth modulation and selectivity mechanisms

It was a challenge to prepare an adsorbent with excellent selectivity for target heavy metals, especially when treating real wastewater contaminated with various heavy metals. In the present study, MoS2 with a specific binding capacity for Pb, was selected as the substrate material. And alkaline earth metal doped SM(Sr-MoS2) adsorbent was synthesized via a simple one-step hydrothermal method. The morphology and structure of SM were characterized and the results confirmed that Sr was successfully anchored to MoS2. In addition, it indicated that Sr played a role in expanding the MoS2 spacing, increasing the ratio of 1 T phrases, and modifying the crystal growth (such as the growth direction and growth rate). Therefore, it suggested that SM had a high selectivity factor (171.26) and partition coefficient Kd (31.34 L g-1). More importantly, SM maintained good adsorption performance (∼90 % removal) after six adsorption–desorption cycles, using NaOH or Na2-EDTA as desorbent. Therefore, this work provided a new idea for the preparation of selective adsorbents based on MoS2, which was expected to be used for the remediation of Pb2+-contaminated wastewater.

Simultaneous size and defect control of metal-organic framework by deep eutectic solvent for efficient perfluoroalkyl substances adsorption: Delving into mechanism

This study reports an environment-friendly protocol to prepare a metal–organic framework (MOF) with simultaneously controlled particle size and open metal site for adsorption removal of perfluoroalkyl substances (PFASs). The successful preparation of UiO-66 with defect and crystal size modulation was achieved using a green and straightforward method, adjusting the components and molar ratios of ammonium salt/glycolic acid deep eutectic solvents (DESs). The corresponding modulation mechanism primarily relied on the combined regulation of the deprotonation and competitive coordination abilities of the eutectic solvent components. The adsorption process was thoroughly examined using spectral analyses, adsorption behavior profiling, and ab initio molecular dynamics simulations. The results revealed that PFAS adsorption is driven by combined capturing effects, such as CF–π, acid/base coordination, C–F⋯Zr, hydrogen bonding, and hydrophobic interactions. Our findings were not thus that the smaller the crystal size of MOF and the higher the defect concentration in the material, the better the PFAS adsorption performance. The result demonstrated the combined effect of these adsorbent features on PFAS mixtures. Furthermore, they revealed unique differences in sorption properties between these targets with different carbon chain lengths. Extensive defects in DES-based UiO-66 led to larger pores, increasing the availability of many adsorption sites and aiding in PFAS adsorption and diffusion. Nevertheless, the surplus of larger pores in the substance increased the competitive adsorption, reducing the total quantity of PFASs absorbed. Furthermore, various interactions and a less restrictive configuration increased the contact of functional groups with adsorbates, substantially enhancing the adsorption. This study investigates the basic questions about how PFAS molecules are adsorbed on DES-based MOFs and the relationship among the structure, properties, and performance to improve the efficiency of this novel adsorbent.

Structural and interfacial microenvironment modulation of two-dimensional layered niobium phosphate to enhance uranium adsorption

To address the environmental and resource challenges arising from the advancement of the nuclear power industry, it becomes imperative to foster the development of efficient and expeditious materials for uranium adsorption. Here, for the first time, a kind of niobium phosphate with improvement of interlayer spacing and hydrophilicity (NbP-8) is employed by crystal phase modulation for uranium adsorption, which synergistically realizes structural and interfacial microenvironment modulation. Characterizations demonstrate that the expanded interlayer spacing contributes to accommodation of uranyl which increases adsorption capacity, and the enhanced hydrophilicity reduces infiltration time and greatly accelerates the adsorption rate. Consequently, NbP-8 possesses exceptional adsorption capacity of 1470.4 mg g−1, ultra-fast adsorption rate with an equilibrium time of 1 min and high selectivity, delivering one of the best phosphate uranium adsorbents. Moreover, this work opens a new venue for optimizing performance of phosphate by changing the crystal phase to modulate structure and interfacial microenvironment for uranium adsorption.

Environmentally friendly additives for crystal surface modulation and suppression of dendrites for aqueous zinc-ion batteries

Aqueous zinc-ion batteries (AZIBs) as promising energy storage devices provide synergistic advantages of high safety, low cost and high energy density. However, it has been observed that underestimated but not negligible dendrites of Zn and H2 production affect battery performance and limit applications of AZIBs. In this work, a functional electrolyte strategy is reported by adding polyhydroxy chlorinated organic compound-sucralose (SCL), which can improve the lifetime of battery. A combination of experimental and theoretical research reveals that SCL could induce the deposition behavior of Zn2+, i.e. the preferential deposition of Zn2+ on the (002) crystal plane, which is conducive to suppress dendrite formation. In the presence of 0.5 mA cm−2 and 1.0 mAh cm−2, compared with pure ZnSO4 electrolyte, the electrolyte with SCL significantly improves the cycle lifespan of Zn||Zn symmetrical cells (3200 h compared to 125 h). To validate the feasibility of SCL, we assemble Zn||MnO2 full cells, which exhibit excellent specific capacity (149 mAh g−1) and capacity retention (89 %) over 2000 cycles at 1.0 A g−1.

Surface potential-adjusted surface states in 3D topological photonic crystals

Surface potential in a topological matter could unprecedentedly localize the waves. However, this surface potential is yet to be exploited in topological photonic systems. Here, we demonstrate that photonic surface states can be induced and controlled by the surface potential in a dielectric double gyroid (DG) photonic crystal. The basis translation in a unit cell enables tuning of the surface potential, which in turn regulates the degree of wave localization. The gradual modulation of DG photonic crystals enables the generation of a pseudomagnetic field. Overall, this study shows the interplay between surface potential and pseudomagnetic field regarding the surface states. The physical consequences outlined herein not only widen the scope of surface states in 3D photonic crystals but also highlight the importance of surface treatments in a photonic system.

Broadband High-Precision Faraday Rotation Spectroscopy with Uniaxial Single Crystal CeF3 Modulator

We present a low-noise (<10 µrad/Hz) broadband Faraday Rotation Spectroscopy method which is feasible for near-ultraviolet through near-infrared wavelengths. We demonstrate this in the context of a high-precision spectroscopy experiment using a heated Pb vapor cell and two different lasers, one in the UV (368 nm) and a second in the IR (1279 nm). A key element of the experimental technique is the use of a uniaxial single crystal CeF3 Faraday modulator with excellent transmission and optical rotation properties across the aforementioned wavelength range. Polarimeter performance is assessed as a function of crystal orientation and alignment, AC modulation amplitude, laser power, and laser wavelength. Crystal-induced distortion of the (6p2)3P0→(6p2)3P1 (1279 nm) and (6p2)3P1→(6p7s)3P0 (368 nm) spectral lines due to misalignment-induced birefringence is discussed and modeled using the Jones calculus.

Evaluation of the performance of a CdZnTe-based soft γ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\gamma $$\\end{document}-ray detector for CubeSat payloads

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Broadband nonlinear modulation of incoherent light using a transparent optoelectronic neuron array

Nonlinear optical processing of ambient natural light is highly desired for computational imaging and sensing. Strong optical nonlinear response under weak broadband incoherent light is essential for this purpose. By merging 2D transparent phototransistors (TPTs) with liquid crystal (LC) modulators, we create an optoelectronic neuron array that allows self-amplitude modulation of spatially incoherent light, achieving a large nonlinear contrast over a broad spectrum at orders-of-magnitude lower intensity than achievable in most optical nonlinear materials. We fabricated a 10,000-pixel array of optoelectronic neurons, and experimentally demonstrated an intelligent imaging system that instantly attenuates intense glares while retaining the weaker-intensity objects captured by a cellphone camera. This intelligent glare-reduction is important for various imaging applications, including autonomous driving, machine vision, and security cameras. The rapid nonlinear processing of incoherent broadband light might also find applications in optical computing, where nonlinear activation functions for ambient light conditions are highly sought.

Toward high stability of O3‐type NaNi1/3Fe1/3Mn1/3O2 cathode material with zirconium substitution for advanced sodium‐ion batteries

AbstractWe successfully synthesized a series of O3‐type NaNi1/3Fe1/3Mn1/3−xZrxO2 (x = 0, 0.01, 0.02, 0.04) cathode materials by the solid‐state reaction method. Energy dispersion spectroscopy, X‐ray diffraction (XRD), and X‐ray photoelectron spectroscopy results confirmed the successful incorporation of Zr elements into the lattice to substitute Mn. Due to the introduction of Zr4+, the crystal structure modulation of O3‐NaNi1/3Fe1/3Mn1/3O2 has been realized. By increasing the Zr4+ content, the width of the sodium diffusion layer expands, thereby facilitating the diffusion of sodium ions. Consequently, the material exhibits a remarkable enhancement in high‐rate capability. At the same time, increasing the Zr4+ content results in a notable decrease in both the average bond length of TM−O and the thickness of the TMO6 octahedron in the transition metal layer, resulting in a significant improvement in the cycling performance and structural stability of the cathode material. Additionally, the in‐situ XRD results demonstrate that the optimized cathode composition of O3‐NaNi1/3Fe1/3Mn1/3–0.02Zr0.02O2 (NFMZ2) undergoes a reversible phase transition of O3 → O3 + P3 → P3 → O3 + P3 → O3 during the charge–discharge process.