Cryogenic Separation Research Articles

Construction of a Fluorinated-Anion Pillared Metal-Organic Framework Exhibiting Dual-Pore Architecture for Simultaneous Enhancement of C2H2 Adsorption Capacity and Selectivity.

Physisorption-based separation processes represents a promising alternative to the conventional thermally driven methods, such as cryogenic separation. However, a significant challenge lies in balancing the trade-off between adsorption capacity and selectivity of adsorbents. In this study, we introduce a novel fluorinated-anion pillared metal-organic frameworks (APMOFs) featuring a dual-pore architecture, constructed using a pyridine-oxazole bifunctional ligand. The inherent low symmetry of the ligand leads to significant distortion of the fluorinated-anion pillars, resulting in a distinctive type of APMOFs characterized by dual-pore architecture. On pore structure with constrict pore width is enriched with a high density of anion fluorinated pillars, offering numerous active sites advantageous for enhancing separation selectivity. Concurrently, the other pore structure exhibits larger dimensions, facilitating increased gas molecule accommodation and thereby augmenting adsorption capacity. Gas sorption studies reveal a substantial C2H2 adsorption capacity and a high C2H2/CO2 separation selectivity. Breakthrough experiments confirm its exceptional separation performance, while theoretical investigations elucidate a sequential adsorption process within these APMOFs, underscoring the efficacy of this strategy in overcoming trade-off limits in adsorbents.

Thermoeconomic modeling of new energy system based on biogas upgrading to multigenerational purpose

The following article outlines an integrated approach toward the valorization of biogas for energy, chilled water, hot water, freshwater, and liquid carbon dioxide production. The suggested system includes a biogas upgrading unit with a biomethane-fueled burner, a Kalian cycle, an LNG regasification process, and a multi-effect desalination unit that can provide CO2, electricity, cooling, and heating. The new ideas in the proposed system include a cryogenic biogas upgrading process that can be used in many industrial settings, the production of liquid carbon dioxide through biogas upgrading, and the use of biomethane in the integrated combustion process. Furthermore, the grey wolf optimization technique is applied in various multi-objective optimization contexts to achieve optimal operating conditions and preferred performance outcomes. In this simulation, the generation of electricity reaches a value of 755 kW. Attached to it is a cooling load of about 5102 kW, with a heating load of 4725 kW, freshwater capacity about 1.33 kg/s, production rate of liquid CO2 at 0.58 kg/s, and natural gas at 3.1 kg/s. Thermodynamic results reveal that the proposed multigeneration performance scheme providently enhances energy and exergy efficiencies up to 59.82 % and 5.74 %, respectively, compared to the condition of a single product. The performed exergy analysis shows that the overall irreversibility of the suggested configuration is equal to 18,047 kW while about 42.6 % of this value is contributed from the heat exchanger E-104. Moreover, the CO2 emission intensity of the process can be kept as 0.35 kg/kWh. Cryogenic separation can obtain about 88 % of CO2 in biogas and turn it into its liquid phase. The performed economic assessment has resulted in the following total cost rate as well as cost per unit exergy: 321.38 $/h and 83.06 $/GJ, respectively. Under optimal conditions, an exergy efficiency of 13.40 % and a net power output of 2034.39 kW are attained.

A novel numerical simulation approach for cryogenic CO2 frosting in binary mixture gas by integrating desublimation and gas-solid phase equilibrium models

Cryogenic CO2 separation from natural gas is a promising technology due to its environmental benefits and smaller spatial requirement. Nonetheless, the dynamics of CO2 desublimation and subsequent frost layer formation under cryogenic conditions for natural gas pre-treatment remain largely unexplored. Addressing this gap, this paper presents a novel numerical simulation approach by integrating desublimation phase change model and vapor-solid phase equilibrium model to investigate CO2 frost layer formation on the cold wall, revealing that both the cold wall temperature and the initial CO2 concentration significantly influence the thickness of the CO2 frost layer. Moreover, the study finds that the density of frost layer intensifies over time, with the highest density observed near the cold surface. Furthermore, increasing the cold wall temperature and the flow rate not only increases the average density of the CO2 frost layer but also affects the outlet CO2 concentration. To adhere to specific outlet CO2 concentration targets and desublimation duration, it is critical to adjust the cold wall temperature and the inlet flow velocity dynamically. Therefore, cryogenic CO2 removal methods, by reducing the spatial requirements of CO2 pre-treatment units, offer a practical and efficient solution for small-scale natural gas liquefaction plants. This approach not only facilitates operational efficiency but also contributes to the broader effort of mitigating greenhouse gas emissions, aligning with environmental sustainability objectives.

Low-emissions hydrogen from MCH dehydrogenation: Integration with LNG regasification

Methylcyclohexane (MCH) is a promising organic hydride carrier for hydrogen transport and storage. Recovering hydrogen from MCH is an energy intensive process. An innovative idea of integrating this process with liquified natural gas (LNG) regasification is proposed in this study and demonstrated via modelling and simulation to substantially reduce external energy use. The synergistic benefits are twofold. In addition to providing a cold energy source for an effective high recovery cryogenic flash separation, the organic Rankine cycle based electrical power generation potential from LNG cold energy is fully exploited to reduce/eliminate external electricity demand for hydrogen compression to the high (end use) pressure. The results is a major reduction in carbon dioxide emissions. The proposed design for an integrated LNG-H2terminal can supply (1) 99.99 mol% pure hydrogen to a Combined Cycle Gas Turbine (CCGT) power plant and (2) commercial-grade natural gas to a gas-grid, both at the desired pressures and temperatures. Subsequently, rigorous simulation-based optimization was performed to minimize external energy inputs.A case study with 100 tph MCH and 100 tph LNG showed that integrating regasification with dehydrogenation produced 6.2 tph of hydrogen while gasifying LNG with a net power generation of 310 kW and a hydrogen recovery cost of 0.282 $/kg H2. Up to 7.3 tonnes of hydrogen can be produced per 100 tonnes of LNG without the use of external power. On the other hand, using external power, up to 11.3 tonnes of hydrogen can be produced per 100 tonnes of LNG without any external refrigeration. Overall, the superstructure proposed in this manuscript provides a generic initial approach for future MCH hydrogen supply chain projects, when considering integrations with LNG regasification plants.

Benchmarking Performance Indices of Electrochemical CO2 Reduction to Ethylene Based on Prospective Life Cycle Assessment for Negative Emissions.

To mitigate global warming to the most ambitious targets, it is necessary to remove CO2 from the atmosphere and reduce fossil fuels use. The electrochemical conversion of CO2 to ethylene (C2H4) as a basic chemical is a promising technology that meets both requirements; however, its life cycle CO2 emissions remain inconclusive because of varying assumptions in the performance indices. This study aimed to set benchmarks for the four most sensitive indices to achieve -0.5 t-CO2/t-C2H4 by calculating net greenhouse gas (GHG) emissions through a prospective life cycle assessment of a model system including CO2 capture, CO2 enrichment, electrochemical conversion, CO2 recycling, and cryogenic separation. As a result, the electrochemical conversion process was the hotspot of life cycle emissions, and representative benchmarks were determined as follows: cell voltage, 3.5 V; C2H4 Faraday efficiency, 70%; conversion rate, 20%; and electrochemical CO2 recycling energy, 2.2 GJ/t-CO2. The gaps between the benchmarks and current top data of cell voltage and Faraday efficiency were <10%, and suppressing the performance degradation for up to one year was found to be a critical requirement. These results can direct research towards the development of a year-round stable system, rather than further improving the performance indices.

Stepwise tuning carbon slits at sub-angstrom scale for dynamical separation of hydrogen isotope

Heavier hydrogen isotope is indispensable for many applications such as isotope tracing and labeling, neutron scattering, and nuclear fusion reaction. Thus it calls for efficient hydrogen isotope separation. Cryogenic adsorptive separation is an energy-efficient way for deuterium/protium (D2/H2) separation, requiring nanopores with precisely tuned pore size and suitable geometry to induce the quantum sieving effect. Herein, we report on the stepwise tuned slit-shaped ultramicropores at sub-angstrom (Å) scale for highly efficient D2/H2 separation. The opening width of carbon nanoslits was precisely tuned by the devised thermal-induced molecularly imprinting method. The adsorbent with 4.0 Å centered nanoslits showed an excellent D2/H2 uptake ratio of 1.9 with a high D2 uptake of 10.1mmol/g at 40 K and 100 kPa. Column breakthrough experiments revealed a high D2/H2 selectivity of 10.1 at 40 K. It evidenced that the 4.0 Å centered slits enable an optimal balance between the barrier induced by zero-point energy and the adsorption potential at 40 K, thereby reaching a selectively quantized configurational diffusion of D2/H2. Programmed thermal desorption experiments indicated that a 0.1 Å alteration of the slit size enhanced the quantum sieving effect of D2/H2 by 180 %. These results would benefit the understanding of D2/H2 separation behavior, and the design principle may inspire other isotope separations.

Cryogenic-membrane separation process for helium extraction and ethane co-production from natural gas

In order to address the defects of high energy consumption and low efficiency in the single cryogenic separation process for helium extraction, this paper integrate post-expansion nitrogen cycle refrigeration with membrane separation to establish a novel natural gas cryogenic-membrane helium recovery process. Based on four mainstream processes for ethane recovery from natural gas, an optimal ethane recovery method is selected and incorporated into the proposed cryogenic-membrane helium recovery process. The process is then simulated using ASPEN HYSYS software. The effects of operating parameters on critical equipment energy consumption, helium product concentration and ethane recovery were evaluated. The simulation results indicate that in the proposed helium recovery process, the concentration of refined helium reaches 99.6 %, and the ethane recovery rate is 90.13 %. Compared to the single helium extraction process, the total compressor energy consumption in our process is reduced by 23.10 %, and the integrated energy consumption is reduced by 20.4 %.

A Comprehensive Review on Biomethane Production from Biogas Separation and its Techno-Economic Assessments.

Biogas offers significant benefits as a renewable energy source, contributing to decarbonization, waste management, and economic development. This comprehensive review examines the historical, technological, economic, and global aspects of biomethane production, focusing on the key players such as China, the European Union, and North America, and associated opportunities and challenges as well as future prospects from an Australia perspective. The review begins with an introduction to biogas, detailing its composition, feedstock sources, historical development, and anaerobic digestion (AD) process. Subsequently, it delves into major biomethane production technologies, including physicochemical absorption, high-pressure water scrubbing (HPWS), amine scrubbing (AS), pressure swing adsorption (PSA), membrane permeation/separation (MP), and other technologies including organic solvent scrubbing and cryogenic separation. The study also discusses general guidelines of techno-economic assessments (TEAs) regarding biomethane production, outlining the methodologies, inventory analysis, environmental life cycle assessment (LCA), and estimated production costs. Challenges and opportunities of biogas utilization in Australia are explored, highlighting and referencing global projections, polarization in production approaches, circularity in waste management, and specific considerations for Australia. The review concludes discussing future perspectives for biomethane, emphasizing the importance of technological advancements, policy support, and investment in realizing its full potential for sustainable energy and waste management solutions.

CARBON DIOXIDE CAPTURE BY USING HYBRID SYSTEM. PARAMETRIC SENSITIVITY ANALYSIS AND ENVIRONMENTAL AND ENERGY EVALUATION

Global warming is mainly caused by carbon dioxide (CO2). For natural gas streams that contain high lev-els of CO2, combining different technologies, such as absorption, adsorption, membrane, and cryogenic separation, may be more convenient for separating acid gas. This study focuses on a gas stream that con-tains 81.14 mole% of CO2. Two hybrid processes, membrane-absorption with amines and cryogenic-membrane, were evaluated for their capital cost, en-ergy and water consumption, and greenhouse gas (GHG) emissions under different operational condi-tions using ASPEN HYSYS V.12. The membrane-absorption system has the lowest CH4 losses, while the hybrid cryogenic-membrane system has lower energy and water requirements and 69% less GHG emissions than the membrane-amine hybrid system. The cryo-genic-membrane system is suitable for enhanced oil recovery (EOR) due to its high carbon dioxide purity and 30% lower operative costs, but requires a slightly higher initial investment.

Solar Energy Driven Chemical Looping Air Separation

Chemical looping is emerging as a feasible alternative to carry out reduction and oxidation processes under different process conditions. This technology proves especially useful when reduction and oxidation processes proceed with different time constants. With the possibility of incorporation of solar energy to the endothermic end of the process, chemical looping technology has recently become more popular. Chemical looping air separation (CLAS) is an alternative to cryogenic separation, by utilizing solar thermal energy. In this process a reducible metal oxide is heated to a temperature such that the metal releases its lattice oxygen. In the second step, the metal oxide is exposed to air and oxygen is captured by the oxide while pure nitrogen is released at the outlet and the loop is closed. Mn2O3 is selected as the oxygen carrier to perform chemical looping cycles. Oxygen mobility of the metal oxide and reversibility through redox cycles are tested with thermogravimetric analysis (TGA). The redox cycles are designed such that the air oxidizes, and the steam reduces the material. The reduction behavior of manganese (III) oxide under inert atmosphere is tested in TGA. It is proved that steam acts as an inert gas under the reaction conditions. The use of steam at the reduction stage results in a more convenient separation of the sweep gas (steam) from the oxygen released from the oxide. It is demonstrated that a redox cycle between Mn2O3 and Mn3O4 can be performed isothermally. The capability of the system to be coupled with solar energy makes it more alluring for environmentally friendly option seekers. The use of solar irradiation is tested with parabolic mirrors to observe the power output. Overall, CLAS process works on milder conditions which is crucial in reducing the energy and equipment costs, and its advantages regarding energy efficiency increase even more when solar energy is incorporated into the system.

Novel Study on Cryogenic Distillation Process and Application by Using CHEMCAD Simulation.

The purpose of this study was to examine the cryogenic separation process used in air separation plants with the CHEMCAD simulation program. A preliminary analysis was carried out with the literature about the operation of the process. In light of the technical information, the simulation of the cryogenic separation process was utilized with the program. While no changes were analyzed in the basic parts of the process, the filtration of the air and separation from moisture and carbon dioxide were not included in the simulation. The simulation showed the three basic components of air, nitrogen, oxygen, and argon obtained as a product of the desired purity rather than a one-to-one demonstration of the applications in the industry. In addition, the low-temperature separation process of an air separation unit was studied to obtain high-purity products (99.49-99.99%) achieving the expected separation efficiency. As a result, the production of all three substances in desired purity was achieved successfully.

Novel ethane recovery process from natural gas using ZIF-8/water–glycol slurry: Techno-economic and energy consumption evaluation

Ethane recovery is a vital step in natural gas processing and can provide raw material for ethylene production. The widely used cryogenic separation process is energy intensive, and the absorption-adsorption coupling process based on porous ZIF-8 slurry (SorbPro I) has been proven to be more energy-efficient. To further reduce energy consumption, this paper proposes a novel process with two absorption-adsorption columns (SorbPro II) and establishes its mathematical model by equilibrium stage method. Taking the natural gas with an ethane content of 6.19 mol% at 300,000 Nm3/d as a case study, the operating parameters of SorbPro I and SorbPro II are optimized by sensitivity analysis, and ethane recovery ratio of both processes can reach 90 %. The techno-economic/energy consumption evaluations of the two processes are conducted. Results show that the total annualized cost and the energy consumption per Nm3 feed gas of SorbPro II are 41.7 % and 47.7 % lower than those of SorbPro I, respectively. It indicates that SorbPro II has the same separation performance as SorbPro I, but is more economical.

From Biogas to Biomethane: An In-Depth Review of Upgrading Technologies That Enhance Sustainability and Reduce Greenhouse Gas Emissions

Renewable energies present an opportunity to enhance energy security, reduce dependence on imports, and lower greenhouse gas emissions. Natural gas, viewed as a transitional fuel from coal to renewables, lacks reliable environmental sustainability and does not contribute to EU energy independence. Recently, biomethane has been gaining attention as an alternative to natural gas. Obtained from purified or “upgraded” biogas, it offers environmental and economic advantages. Several developed technologies, including absorption, adsorption, membrane separation, and cryogenic separation, are commercially available. However, those are energy- and resource-intensive. In this context, this review aims to examine the recent advancements in biogas upgrading, particularly in physical, chemical, and biological pathways. It focuses on CO2 removal and/or conversion to methane, offering an updated overview for future studies. The technologies are classified based on the separation method (by phase addition, by solid agent, by phase creation, and by biological process), and an analysis of each category is conducted. The discussion covers the economic and environmental characteristics, process complexity, and future research prospects in sustainable technologies. This review highlights the potential of biogas upgrading technologies in contributing to sustainable development, increasing energy security, and achieving greenhouse gas reduction goals that are aligned with EU targets.

Porosity in Sr1−xCaxFeO3-δ oxygen carriers: The role of surface area and pretreatment on storage activity

Perovskite oxides have generated interest as robust, low-temperature oxygen carrier materials for a variety of clean energy applications, including chemical looping gasification and air separations. Methods to improve O2 desorption kinetics are vital to allow these carriers to compete economically with traditional metal oxide carriers or cryogenic separations. Herein, we investigated the cumulative roles that surface area, pretreatment, and elemental composition have on the oxygen storage properties of a state-of-the-art carrier system, Sr1−xCaxFeO3-δ (x = 0.20, 0.25, 0.30) synthesized using multiple methods. Porous materials synthesized by the Pechini, or citrate, method had their surface area controlled using the synthesis temperature. The high surface area of the Sr0.7Ca0.3FeO3-δ materials is most beneficial at low operating temperatures, such as 350 and 400 °C, as their reduction rates are twice as fast as those obtained with their bulk counterparts. These effects are observed at higher operating temperatures and within a single composition, but temperature tunability using variable Ca2+ substitution in the Sr1−xCaxFeO3-δ overshadows the improvements gained from higher surface areas. Additionally, we establish that pretreatment in N2 at an elevated temperature is necessary to enhance kinetics further. For maximum efficiency, pretreatment at the synthesis temperature is suggested for the Pechini method-synthesized systems, whereas 800 °C is adequate for bulk materials.

Enhanced azeotropic C2ClF5/C3F8 separation by TMA+ exchanged MFI zeolites for ultrapure fluorine electronic gas

AbstractThe demand for the azeotropic C2ClF5/C3F8 separation continues to rise owing to the significance of ultrapure fluoride gases for the electronic industry. With a boiling point differential of 1.1 K, separating an azeotropic mixture of C2ClF5/C3F8 through sorption‐based processes under ambient conditions is a preferable alternative to the current energy‐intensive cryogenic separation method. Here, we report the highly efficient C2ClF5/C3F8 adsorption separation in quaternary alkylammonium ions modified MFI type zeolites with interlaced channels which provide a cooperative effect conferred by specific interaction sites and optimal pore size. A path‐regulatory mechanism was proposed, whereby TMA+ cations located at intersections resembling “train turnouts” force gas molecules to switch traffic channels to confined sinusoidal channels affecting the C2ClF5/C3F8 recognition sites and diffusion behavior. Molecular simulations were conducted to reveal the separation mechanism, and the breakthrough experiment validated the effectiveness of this adsorbent at 298 K outperforming conventional adsorbents for the challenging azeotropic separation.

Sustainable development and multi-aspect analysis of a novel polygeneration system using biogas upgrading and LNG regasification processes, producing power, heating, fresh water and liquid CO2

Considering biogas upgrading to feed energy systems and its significant impact on the biogas energy density, a novel polygeneration system utilizing biogas from landfill waste is designed, simulated, and studied in this paper. The primary innovation is to design a biogas upgrading technology for a novel multigeneration system using a thermal matching approach. This system is capable of simultaneously generating power, providing heating, producing fresh water, and extracting liquid carbon dioxide in an environmentally sustainable manner, thus resulting in reduced environmental impacts. For this purpose, a cryogenic separation system based on liquefied natural gas cold utilization is employed for biogas upgrading and biomethane separation. The proposed process also consists of a Kalina cycle, an organic Rankine cycle, a multi-effect desalination technology, and a heating provider unit. This system is simulated within the Aspen HYSYS software and is undergone a comprehensive analysis from the viewpoints of energy, exergy, environmental, and economic. The results indicate that the proposed structure achieves energy and exergy efficiencies of 80.91% and 43.76%, respectively. Environmental assessment reveals that the emission intensity is 90.43% lower in polygeneration mode compared to power generation mode, and the system’s net emission is equal to 23,041.51 kg/h. The economic evaluation demonstrates that the total unit cost of products is minimized in polygeneration operation (1.84 $/GJ), while it is highest in power generation condition (7.564 $/GJ). The investigations show that when a system is modified from a single generation to polygeneration, all thermodynamic, economic, and environmental indicators face an improvement.

Techno-economic analysis of CO2 cryogenic distillation from high CO2 content gas field: A case study in Indonesia

Indonesia has natural gas reservoirs with high CO2 content, such as Natuna and Bojonegoro gas fields. Various technologies have been developed, including cryogenic distillation separation technology suitable for application to gas wells with high CO2 content. Cryogenic distillation separates CO2 with high purity according to the operating conditions and the CO2 dew point. Cryogenic distillation was simulated in this study to determine the purity of the CO2 and to compare the economic potential of each approach. The highest CO2 purity using CFZ technology is 98.72% in the Natuna, while the highest purity of CH4 using Pellegrini Distillation technology is 99.95% in the Bojonegoro. Economically, the Natuna and Bojonegoro estimates using the CFZ technology have a lower total annual cost than the Pelegrini distillation. However, CFZ technology has a lower CO2 capture cost than Pellegrini Distillation technology, 7.9 USD/tonne CO2 and 10.26 USD/tonne CO2. In other words, separation using the CFZ technology is more effective for gas fields with higher CO2.

A Thermodynamics Model for the Assessment and Optimisation of Onboard Natural Gas Reforming and Carbon Capture

The paper examines pre-combustion carbon capture technology (PreCCS) for liquefied natural gas (LNG) propelled shipping from thermodynamics and energy efficiency perspectives. Various types of LNG reformers and CCS units are considered. The steam methane reformer (SMR) was found to be 20% more energy efficient than autothermal (ATR) and methane pyrolysis (MPR) reactors. Pressure swing adsorption (PSA) had a lower energy requirement than membrane separation (MEM), cryogenic separation (CS), and amine absorption (AA) in pre-combustion carbon capture, with PSA needing 0.18 kWh/kg CO2. An integrated system combining SMR and PSA was proposed using waste heat recovery (WHR) from the engine, assuming similar efficiency for LNG and H2 operation, and cooling and liquefying of the CO2 by the LNG. The SMR-PSA system without WHR had an overall efficiency of 33.4% (defined as work at the propeller divided by the total LNG energy consumption). This was improved to 41.7% with WHR and gave a 65% CO2 emission reduction. For a higher CO2 reduction, CCS from the SMR heater could additionally be employed, giving a maximum CO2 removal rate of 86.2% with 39% overall energy efficiency. By comparison, an amine-based post-engine CCS system without reforming could reach similar CO2 removal rates but with 36.6% overall efficiency. The advantages and disadvantages and technology readiness level of PreCCS for onboard operation are discussed. This study offers evidence that pre-combustion CCS can be a serious contender for maritime propulsion decarbonization.Graphical

Technoeconomic evaluation of post-combustion carbon capture technologies on-board a medium range tanker

The international maritime organization has recently set targets and timelines for reducing global greenhouse gas emissions from the maritime industry, which currently stand at 1.1 Gt/year and make 3 % of the global emissions. Reducing emissions by increasing engine efficacy is the immediate target, but there is a limit to how much this path can achieve. Onboard post-combustion carbon capture and concentration in large marine vessels is emerging as an interim approach to reduce maritime emissions until large-scale deployment of low/zero emission fuels become viable. In this paper, we evaluate three carbon capture technologies (chemical absorption using either aqueous MEA or aqueous NH3 as the solvent, cryogenic separation, and membrane separation) for a medium-range tanker for two fuels, namely heavy fuel oil and liquefied natural gas. The capture cost per tonne of CO2 (recovery>90 %, purity>95 %) was considered as the assessment criterion, with simultaneous evaluation of other aspects such as energy and space demands. The simulations were carried out using MATLAB and ASPEN V12. For rate-based models, the adjustable parameters for the model were tuned using pilot plant data. Additionally, options for hot and cold energy integration were also assessed and implemented. Based on the reference ship conditions and assessment criteria, the simulation studies show that amine-based absorption is the best prospect for on-board capture by a clear margin.

Performance analysis of a hybrid system combining cryogenic separation carbon capture and liquid air energy storage (CS-LAES)

Cryogenic separation carbon capture is a promising green carbon emission reduction approach, which is rarely applied due to its high cold energy requirement. This work proposes a hybrid system combining cryogenic separation carbon capture and liquid air energy storage (CS-LAES), comprehensively utilizing low-temperature and high-pressure conditions of LAES to reduce the energy consumption of cryogenic CO2 separation. Flue gas with higher carbon dioxide (CO2) concentrations from coal-fired power plants is compressed in the charging process of CS-LAES instead of air. The CO2 is captured, and the CO2-free air is liquefied and stored for later use. The results demonstrate that the carbon capture energy consumption of the CS-LAES system is 1.12 GJ/ton, which is 0.68 GJ/ton lower than that of conventional cryogenic capture technology (1.80 GJ/ton). The CO2 capture rate of 99.97 % is higher than that of most existing cryogenic CO2 capture technologies. Moreover, the standalone total exergy efficiency (S_TEE) for energy storage of the CS-LAES system was 63.40 %, which is 5.22 % higher than the baseline LAES. Meanwhile, the dynamic payback period of the CS-LAES system is 5.82 years, which is more economical than that of baseline LAES (12.89 years) due to avoiding expensive carbon tax.