In this study, we investigate the 40Ar/39Ar systematics of nineteen diogenites thought to come from deep crustal levels of asteroid 4 Vesta. We applied both Electron Backscattered Diffraction (EBSD) and 40Ar/39Ar and methods to the unbrecciated diogenite LAP 031381. We obtained three plateau ages resulting in a combined weighted mean age of 4441 ± 15 Ma (P = 0.16). The EBSD analyses suggest that LAP 031381 displays minimal evidence of shock and, when combined with petrography observations, diffusion modelling and 40Ar/39Ar data, these results suggest that the crustal volume that initially contained this diogenite, reached a temperature of ca. 630 °C at ∼ 4.44 Ga. This corresponds to a linear cooling rate of ∼ 5 °C / Ma for a crystallization age of 4550 Ma. Independent thermal models suggest that these conditions were present at a depth of 60 to 65 km at 4.44 Ga.The other eighteen diogenites yielded 40Ar/39Ar results that indicate that they have been variously shocked by impact events and seven of them yielded plateau ages ranging from 2413 ± 189 Ma to 84 ± 162 Ma. We combined these results with 40Ar/39Ar ages from eucrites and howardites and propose that the HED (Howardite, Eucrite, Diogenite) meteorites recorded impact events at the surface of Vesta until ∼ 3.4 Ga when they were then ejected during a large collision. The eucrites, diogenites and howardites were then recombined into small rubble pile asteroids which probably make up a large part of the Vestoid family. After ejection, the K/Ar system in plagioclase crystals ceased in most cases to be fully reset by impact events as the temperature spikes reached during small impacts lack enough energy to trigger significant 40Ar* diffusion. On the other hand, ultra-transient and high-temperature – sensitive pyroxene crystals kept a more systematic record of small impacts until recent time. 38Arc cosmochron cosmogenic exposure ages on diogenites mostly range from 51 ± 7 Ma to 0 ± 1 Ma and when combined with other HED cosmochron ages, suggest that almost all the HED meteorites were continuously ejected from secondary rubble pile asteroids mostly between 50 Ma and present.