Crustal Rocks Research Articles

ِA new occurrence of rift-related damtjernite (ultramafic) lamprophyre, Gebel Anweiyib area, Arabian Nubian shield: Insights from bulk rock geochemistry and remote sensing data analysis

The occurrence of lamprophyre dikes is being reported first time in the Gebel Anweiyib area, south Eastern Desert, Egypt. The investigation of the ultramafic lamprophyre (damtjernite) dikes intruded into the crustal younger granites and metasediments based on their spectral characteristics, mineralogical and geochemical compositions. Three multispectral sensors of Landsat-8, ASTER and S2 have been used to detect and characterize the lithologic units and the lamprophyre dikes. The reflectance and absorption signatures of the granitic rocks and lamprophyre dikes were the basis for detecting them from the remotely sensed data using the application of advanced image processing algorithms including FCC, BR, PCA, MNF, and DS. Geochemical studies inferred that the damtjernite dikes are under-saturated with SiO2 (<38.89 wt%), alkaline with total alkalis (avg. 4 wt%), metaluminous with A/CNK (0.22–0.51), and ultramafic with MgO (13.88–19.23 wt%). They exhibit unique geochemical characteristics of mantle (with high MgO, Ni, Cr, and Mg#) coupled with crustal (high Sr, Ba, Zr, Ga and REEs) sources, similar to global ultramafic lamprophyres. High TiO2 and highly fractionated REEs with low HREEs (avg. 23 ppm) relative to LREEs (avg. 354 ppm) contents, yielding residual garnet in melts. Low partial melting of primitive garnet lherzolite can account the obtained REEs in the ultramafic lamprophyres. These features signify their derivation from a deeper enriched asthenospheric (plume-type) magma like OIB, which is attested by the high Nb/La (avg. 1.32), Nb/U (avg. 102), La/Yb (avg. 43), and low Y/Nb < 0.52, Rb/Sr < 1, Rb/Ba (<0.14), and Sr/Ba (<0.9), suggesting their derivation from a mantle-derived source rather than crustal rocks. High concentrations of TiO2 and Fe2O3 in the ultramafic lamprophyres, reflecting their formation from a fertile peridotite by mantle plume-derived melts with K-residual phlogopite rather than amphibole as obtained by low Ba/Rb and high Rb/Sr ratios. The Anweiyib lamprophyres are anorogenic and confined to being derived from rifting regions, and their magma is not contaminated with crustal sources during emplacement.

OIB-like magma genesis at the modern Chiapanecan Volcanic Arc, southern Mexico

The Chapultenango trachybasalt, located in the modern Chiapanecan Volcanic Arc (CVA) in southern Mexico, is constituted by two mafic dykes. Dyke 1 shows relatively low Th/Nb and Pb/Nb ratios compared to other CVA rocks, and exhibits primitive chemical characteristics (e.g. #Mg >65, Ni > 200, Cr > 600) typical of Ocean Island Basalts (OIB). On the other hand, Dyke 2 is almost in touch with Dyke 1, is calc-alkaline, and more evolved than Dyke 1, similar to other rocks found in El Chichón volcano. Hence this work is mainly focused on Dyke 1 that represents the least differentiated melt observed so far in the Chiapanecan Volcanic Arc, and its composition helps in characterizing the mantle source in this region. Dyke 1 OIB-like magma was likely generated by a slab window resulting from the tearing of the Cocos slab along the Tehuantepec Ridge. This tearing was likely caused by differences in physical properties between the northern and southern segments of the Cocos plate, which can be attributed to their age difference (10 Ma) and velocity convergence. This configuration permits the ascent of OIB-like melts from an enriched and relatively deep mantle, which was metasomatized by subduction components (2–6%) and then underwent partial melting (∼5%), although contamination by crustal rocks (e.g., Chiapas Massif) could not be ruled out. The resulting primitive melt therefore would have ascended rapidly, carrying some phaneritic and gabbroic fragments that exhibit similar chemical characteristics to the Chiapanecan Volcanic Arc rocks.

Petrological and Geochemical Constraints on the Origin of Strongly Peraluminous Granitoids from the Triassic Guangtoushan Pluton in South Qinling

AbstractAs an important part of the early Mesozoic granites in the South Qinling tectonic belt (SQTB), the Guangtoushan pluton provides a material basis for research on the composition of magma sources and the effects of peritectic assemblage entrainment (PAE) on the changes in the granite composition. As shown by the results of LA‐ICP‐MS zircon U‐Pb dating, the Guangtoushan pluton was emplaced during the Late Triassic (214–212 Ma) and was formed in the post‐collision stage between the SQTB and the Yangtze plate. The collected samples had high SiO2 content and low Cr and Ni contents, indicating that the magmas did not undergo significant crust‐mantle mixing during their evolution. The Guangtoushan granitoids were distributed along the trend line of magmatic fractional crystallization in the F–An–Or diagram. This result, combined with the relatively homogeneous Sr‐Nd isotopic composition, implies that the Guangtoushan pluton underwent slight assimilation and contamination. As can be inferred from the comparison between the compositions of the Guangtoushan granitoids and various fluid‐absent experimental melts, the magma sources of the Guangtoushan granitoids contain a variety of materials, such as graywackes, pyroclastic graywackes, and pelites and are not derived from lower crustal mafic rocks. The correlation between the maficity and the major and trace elements further indicates that the strongly peraluminous granitoids from the Guangtoushan pluton was formed by the partial melting of biotite‐bearing crustal rocks and its magmatic evolution was accompanied by the entrainment of clinopyroxenes and accessory minerals.

Helium - Relationships to other reservoir gases and some implications for exploration: The New Mexico Example

Helium (He) is the second most abundant element in the universe after hydrogen but is relatively rare on earth. He occurs as two stable isotopes, 3He and 4He. 4He is the dominant isotope in crustal gases and is a radiogenic decay product of uranium and thorium mainly in granitic basement rocks. 3He is dominantly primordial and primarily originates from the earth’s mantle. 3He may also be formed by radiogenic decay of 6Li (Lithium) which may be found in argillaceous sediments deposited in evaporitic settings. Although He occurs in most natural gases, it almost always occurs in extremely low, subeconomic concentrations, less than 0.1%. It is rare in concentrations more than 1%. A very few small reservoirs have gases with more than 7% He. Other gases that constitute the dominant components of helium-bearing natural gases are nitrogen (N2), carbon dioxide (CO2), and methane (CH4). The highest He concentrations occur where the dominant gas is N2 but most He has historically been produced as a byproduct of gases that are hydrocarbons. Hydrocarbons are generated from petroleum source rocks. Their presence in a reservoir is dependent upon the presence of a mature source rock in the basin and a migration path between the source rock and the reservoir. Large accumulations of CO2 in the southwestern U.S. resulted from the degassing of rising Tertiary magmas and subsequent migration of the gases into crustal reservoirs. N2 appears to originate mostly from degassing of the mantle but may also be formed in some strata by the thermal maturation of kerogens or by diagenetic alteration of clays or organic compounds in red bed sequences. The presence of economic concentrations of He in reservoir gases is dependent not only on an adequate source of 4He generated from granitic basement rocks but also on accommodating flux rates of N2, CO2, and CH4. These gases differ in their origins, places of generation and rates of generation, migration and emplacement. While basement-derived 4He and N2 enter reservoirs at slow rates over long periods of geologic time, hydrocarbons and CO2 enter the reservoir over much shorter time periods and dilute the 4He and N2. Basement-derived gases may be characterized by differing N2:He ratios which may indicate greater rates of He production within the crust in some areas. Exploratory drilling for He on Chupadera Mesa in the late 1990’s and early 2000’s encountered He-rich gases in Lower Permian strata. Isotopic analyses suggest that 93% of Chupadera Mesa He originated from radiogenic decay in crustal rocks while 7% is derived from the mantle or with a possible contribution by evaporitic Permian shales. Marked differences in the CO2 concentrations in different strata indicate that some strata acted as carrier beds for magmatically-derived CO2 while strata with N2-rich and CO2-poor gases were isolated from CO2 sources.

Thermomechanics of ferri-antiferromagnetic phase transition in finitely-strained rocks towards paleomagnetism

The thermodynamic model of visco-elastic deformable magnetic materials at finite strains is formulated in a fully Eulerian way in rates with the aim to describe thermoremanent paleomagnetism in crustal rocks. The Landau theory applied to a ferro-to-para-magnetic phase transition, the gradient theory for magnetization (leading to exchange energy) with general mechanically dependent coefficient, hysteresis in magnetization evolution by Gilbert equation involving objective corotational time derivative of magnetization, and demagnetizing field are considered in the model. The Jeffreys viscoelastic rheology is used with temperature-dependent creep to model solidification or melting transition. The model complies with energy conservation and the Clausius-Duhem entropy inequality.

Petrological insights into connections between the S- and I-type magmatic associations in metamorphic core complexes: a case study of the Çataldağ metamorphic core complex (NW Turkey)

As one of the Cordilleran-type metamorphic core complexes in the western Anatolian extensional province and the broader Aegean region, the Çataldağ metamorphic core complex is composed of a granite-gneiss-migmatite complex and a synkinematic pluton, bounded by a detachment fault zone. The plutonic rocks within the footwall of the Çataldağ metamorphic core complex consist of Eo-Oligocene anatectic S-type leucogranites associated with gneiss-migmatite complex forming the core rocks and an I-type synkinematic pluton that emplaced into the core rocks in the Early Miocene. This paper presents the petrography, mineral chemistry, major-trace element geochemistry, and Sr-Nd-Pb isotope compositions of the Çataldağ I-type synkinematic pluton. It discusses the magma source evolution from the Eo-Oligocene to the Early Miocene and their relations to the Çataldağ metamorphic core complex formation by comparing two contrasting granitic associations from a petrological perspective. The Çataldağ I-type synkinematic pluton primarily comprises porphyritic granodiorite, granite, and peripheral rocks including evolved granite and pegmatite dikes. Thermobarometry calculations estimate crystallisation conditions of approximately 795 °C at 1–2 kbar (averaging 1.5 kbar), corresponding to a shallow crustal magma chamber (⁓5 km deep). The pluton is metaluminous to slightly peraluminous and of a high-K calc-alkaline character. The 87Sr/86Sr(i) and εNd values of the studied samples range from 0.70684 to 0.70772 and from −6.1 to −2.3, respectively. Pb isotopic compositions are 18.74–19.29 for 206Pb/204Pb, 15.69–15.78 for 207Pb/204Pb, and 38.89–39.39 for 208Pb/204Pb. Geochemical modelling shows that a large amount of metasomatised lithospheric mantle-derived melt component (up to 70%) and a minor crustal component (<50%) contributed to the source region of the magma. The combination of isotopic data and thermodynamic modelling suggests that the compositional variations within the pluton were primarily the result of open system processes, predominantly the assimilation of crustal rocks with a dominance of fractional crystallisation. The Sr-Nd-Pb isotopic signatures and trace element characteristics of I-type pluton, as well as their comparisons with those of S-type leucogranites within the Çataldağ core complex, indicate heterogeneous magma sources, evolving from crust-dominated to mantle-dominated magma from Eo-Oligocene to the early Miocene, reflecting mantle upwelling beneath NW Anatolia. We infer that the long-lived, mantle-driven Eocene plutonic activity that preceded the development of core complexes may have led to thermal weakening, melting, and crustal flow in the lower-middle crust beneath NW Anatolia, facilitating the formation of the granite-gneiss-migmatite complex during the incipient phase of extension in the Eo-Oligocene. Coinciding with the rapid exhumation of the S-type granite and migmatite complex, the formation and emplacement of I-type synkinematic pluton along the detachment fault zone of the Çataldağ core complex were developed as a result of asthenospheric upwelling driven by lithospheric removal processes. This inferred lithospheric removal was triggered by Hellenic slab rollback affecting the entire western Anatolia since the Oligocene. The transition from S- to I-type granites observed in the Çataldağ core complex and other Aegean massifs may indeed be a manifestation of the intensity or accumulation of this crustal extension.

Determining subsurface temperature & lithospheric structure from joint geophysical-petrological inversion: A case study from Ireland

High quality maps of the geothermal gradient and temperature are essential when assessing geothermal potential for a region. However, determining geothermal potential is a challenge as direct measurements of in situ temperature are sparse and individual geophysical methods are sensitive to a range of parameters, not solely temperature. Here, we develop a novel approach to determine the geothermal gradient using a new joint geophysical-petrological inversion where seismic velocities and density in the mantle are related to temperature and bulk composition within a thermodynamic framework. Large datasets of phase velocities of seismic surface-waves are now incorporated into the inversion, and provide essential constraints on the lithospheric thickness and temperature, which shape the crustal geotherms to a significant extent. We also include all available measurements of the surface heat flow, radiogenic heat production (RHP) and thermal conductivity within the crust, to further constrain the temperature and geothermal gradient, in particular in the top few kilometres of the crust. We use Ireland as a case study and show how our new methodology can reproduce the results of previous work but also improve on them, thanks to the complementary sensitivities of the full range of data. Lithospheric and crustal thicknesses have primary controls on the temperature gradient, with areas of thinner lithosphere showing higher geothermal gradients. In some locations, anomalously warm geotherms result from high RHP within crustal granitic rocks, mudstone and shales. RHP is above continental averages across all Ireland, likely due to a crust with mostly felsic lithology. The new methodology provides a robust workflow for determining the geothermal potential in areas with limited direct temperature measurements, facilitating knowledge creation for the transition to sustainable energy sources and energy self-sufficiency.

Mechanisms for generating elevated zircon δ18O in Archean crust: Insights from the Saglek-Hebron Complex, Canada

The Saglek-Hebron Complex (northern Labrador, Canada) is a polymetamorphic terrane preserving felsic crustal rocks as old as 3.87 Ga. Crustal rocks of this age are rare and offer opportunities to interrogate how Earth's earliest continent forming processes may have differed from the modern plate tectonic regime. Oxygen isotope ratios (δ18O) in primary crystalline zircon are strongly affected by the incorporation of supracrustal materials during magmatism and can provide useful information about the character of early crustal reworking events. While zircon δ18O signatures >+6.4 ‰ indicate the incorporation of supracrustal material into the source of crustal anatexis, questions remain regarding the volumetric scale, sources, and processes by which supracrustal and magmatic mixing occurred during the Archean. Here, we present 271 zircon in-situ oxygen isotope analyses for a suite of seven Saglek-Hebron granitoids emplaced between 3.87 and 2.79 Ga in age, significantly expanding the temporal and lithologic diversity of the magmatic SHC zircon δ18O record. Collected from carefully characterized grain domains, primary zircon δ18O values range from 5.0 to 8.4 ‰ and include some of the highest igneous Archean zircon oxygen isotope ratios recorded to date. Leveraging an integrated workflow for identifying preserved zircon geochemistry, and correlating our new data with previous information from zircon Hf and whole-rock 142Nd/144Nd isotopes, we identify three periods of contribution from high-δ18O supracrustal material to crustal melts during reworking events in the SHC at 3.63, 3.33, and 2.79 Ga. Our work points towards repeated episodes of interaction between a maturing surface environment and magmatism from 3.6 Ga onwards at this locality.

Late Mesozoic tectonic affinity of the Tengchong Block and southward extension of the Bangong-Nujiang Suture: constraints from Early Cretaceous granitic rocks in western Yunnan, SW China

ABSTRACT The southward extension of the Bangong-Nujiang Suture and the late Mesozoic tectonic affinity of the Tengchong Block have been subject to debate, and the Early Cretaceous magmatism in the eastern Tengchong Block provides a crucial window to address these issues. This paper reports comprehensive petrographic, geochemical, geochronological, and isotopic data of Early Cretaceous granitic rocks from the eastern Tengchong Block. Results show that these granitic rocks consist of monzogranites and granodiorites, with zircon U-Pb ages of 120.4–113.9 Ma. These granitic rocks are characterized by enrichments in large ion lithophile elements (e.g. Rb, U, K) and light rare earth elements, but depleted in high field strength elements (e.g. Nb, Ta, P, Ti), and have negative apatite εNd(t) values (−10.4 to −6.7) and negative zircon εHf(t) values (−11.7 to −1.2). The molar [Al2O3/(CaO + K2O + Na2O)] (A/CNK) values and whole-rock zircon saturated temperatures of the studied monzogranites of 1.04–1.09 and 714–799°C, respectively, indicate that they have I-type granite affinity. The presence of biotite indicative of I-type granite and the observation that P2O5 decrease with increasing SiO2 further indicated that the monzogranites have affinities of I-type granites. The petrography, geochemical and isotopic signatures of the studied monzogranites indicate that they originated from partial melting of mafic lower crustal rocks. The Na-rich granodiorites have elevated Na2O/K2O ratios and Na2O contents of 1.19–2.04 and 3.12–3.47 wt.%, respectively. These granodiorites also have relatively high Mg# values and the transition metal element Cr of 53.3–54.5 and up to 100 ppm, respectively. According to these isotopic and geochemical features and the occurrence of magnesiohornblende, we propose that the Na-rich granodiorites were derived from partial melting of ancient basaltic lower crust, with certain inputs of mantle materials in the magma source. Considering these results as well as published data, we finally propose that the Tengchong Block was likely the southeastern extension of the Lhasa Block and that these Early Cretaceous granitic rocks were formed in the setting of the volcanic arc due to westward subduction of the Bangong-Nujiang Tethys oceanic lithosphere beneath the Tengchong Block.

Origin of Silurian granite in the Baiganhu field, Eastern Kulun Terrane, NW China: Implications for the tectonic setting of Sn-W mineralization

The Baiganhu area in the Eastern Kunlun Terrane on the northern margin of the Tibetan Plateau contains world-class Sn-W deposits in close association with monzogranite. However, the origin of granite and the tectonic setting for the Sn-W mineralization have not been well constrained. Here we present the petrological and geochemical data of the granite (431 Ma) associated with the Sn-W mineralization to evaluate the geological-tectonic setting for the mineralization. The monzogranite has high SiO2 contents, ranging from 65.8 to 73.5 wt%, and shows a geochemical affinity with A2-type granites. Relatively high zircon saturation temperatures, ranging between 750 °C and 921 °C, suggest that the parental magmas were hot. The whole-rock εNd (t = 431 Ma) values range from –2.7 to –3.1 with TDM ages between 1810 and 1040 Ma, and zircon εHf (t = 431 Ma) values range from + 0.7 to + 4.1 with TDM ages between 1040 and 900 Ma. The data suggest that the magmas had significant contributions of old rocks. The granitic rocks intruded into quartz-muscovite schist of the Proterozoic Xiaomiao Complex, which underlies the vast area. Zircon grains in the schist are magmatic in origin based on sharp oscillatory zoning and high Th/U ratios (>0.2). The 207Pb-206Pb zircon ages (n = 25) of the schist range from 1898 ± 2 to 1700 ± 6 Ma, suggesting that the zircon grains originate from a Paleoproterozoic magmatic belt. Such ancient rocks, either as lower crustal component or subcontinental lithospheric mantle, contributed ∼ 30 % to the parental magmas. We conclude that post-collisional extension within the Eastern Kunlun Terrane was accompanied by upwelling and adiabatic melting of the asthenospheric mantle which induced partial melting of subcontinental lithospheric mantle and lower crustal rocks and formed granitic magmas. Aqueous fluids separated from the granitic magma which preferentially incorporate W and Sn contributed to the mineralization in and around the granites.

Petrogenesis of magnesian troctolitic granulite clasts from Chang'e -5 drilling sample: Implications for the origin of ejecta material from lunar highlands

The lunar soil collected by the Chang'e-5 (CE-5) mission contains both local materials and components of various sources. The latter could have derived from the excavation of impact craters in the highlands away from the landing site, providing valuable information on the composition of the lunar crust beyond the mare basalts sampled by the CE-5 mission. In this study, we examined the mineralogy and petrology of magnesian troctolitic granulites (or troctolites) recovered in the CE-5 soil. The troctolites exhibit a granoblastic texture but have a finer grain size compared to Apollo granulites, and almost all plagioclase remains unaltered and not converted to maskelynite. The major element composition shows a SiO2 content of 45.4 wt%, CaO of 12 wt%, TiO2 of 0.2 wt%, Th of 0.1 ppm, and an Mg# of 76, lower than those of the Mg troctolitic lunar meteorites NWA 5744 and NWA 10401. The trace element budget indicates that the magnesian troctolites are KREEP-poor, which distinguishes them from the Mg-suite rocks in Apollo samples but is similar to some troctolitic lunar meteorites (NWA 10401). Furthermore, we predict –by using MELTS modeling– a plausible genetic connection between the Mg-suite rocks, and our troctolites, suggesting that the latter may be pristine and formed during a later stage along a fractional crystallization path. This scenario challenges the hybridization model and strengthens the evidence in favour of the fractional crystallization modeling. To ascertain the potential origin crater for the magnesian granulites, a comparative analysis was conducted with NWA 10401. Based on our findings, we propose that the Pythagoras crater, situated north of the CE-5 landing site, is the most probable source of the aforementioned magnesian troctolitic granulites. The ejecta from this crater may have been deposited between the Eratosthenian-aged mare basalts and the Imbrian-aged mare basalts beneath the CE-5 landing site. The KREEP-poor troctolitic granulite in the Chang'e-5 soil could represent paleo-ejecta from Pythagoras crater, excavated by subsequent impacts on the Eratosthenian-aged basalts and delivered them to the CE-5 site. The original location of the Mg troctolitic granulites is inferred to be near-surface, buried by the uppermost crustal rocks (<10 km), which is consistent with its contact with feldspathic impact glass.

New evidence for the presence of the Inner Tauride Ocean: Lithological, geochronological and P-T correlations with the Tavşanlı and Afyon zones of Central Anatolia (Türkiye)

The Tavşanlı and Afyon zones, which are well defined in western Türkiye, represent high pressure-low temperature (HP-LT) metamorphic rocks formed in a subduction zone. The Korumaz and Hınzır mountains (northeast of Kayseri) between the Central Anatolian Crystalline Complex and the Eastern Tauride Belt are represented by a HP-LT metamorphic sequence, which is thought to have formed between the Carboniferous and the Cretaceous. Here we present 40Ar/39Ar data from white micas within the Lower-Middle Triassic calc-phyllites from Korumaz Mountain, which yielded an age of 87 ± 2 Ma. Therefore, based on new mineralogical and geochronological data we suggest that this low-grade (HP-LT) metasedimentary sequence correlates with the Afyon Zone. Tectonically emplaced on-top of the HP-LT metasedimentary units of the Korumaz and Hınzır mountains is a meta-accretionary complex consisting of serpentinite, listvenite, marble, phyllite, calc-phyllite, metabasite, and meta-plagiogranite. Petrographic and mineral chemical studies show that the meta-accretionary complex was subjected to metamorphism under the HP-LT conditions that are similar to those of the Tavşanlı Zone in western Türkiye. Zircon Hf isotopic compositions from the meta-plagiogranite in the Korumaz and Hınzır mountains exhibit a depleted mantle signature with positive epsilon Hf(t) values of +5.6 to +13.1, and yielded a U-Pb crystallization age of 101.14 ± 0.84 Ma, which is the oldest age determined in oceanic crustal rocks of the ophiolites from the Tauride Belt. Geochemically, the metabasites and meta-plagiogranites from the meta-accretionary complex show subduction-related characteristics. White micas from phyllites and listvenite, which dominate the matrix of the meta-accretionary complex, yielded 40Ar/39Ar metamorphic ages ranging from 78 to 60 Ma. Our new geological and geochronological data suggest that metamorphic units of the Korumaz and Hınzır mountains are the eastern continuation of the Afyon and Tavşanlı zones. This indicates that the Inner Tauride Ocean, the existence of which has been controversial in the literature, was indeed present between the Central Anatolian Crystalline Complex and the Eastern Tauride Belt.

The origin of calcite in calc‐silicate rocks from the Kokchetav ultrahigh‐pressure metamorphic complex

AbstractUnderstanding calcite genesis in ultrahigh‐pressure crustal rocks is a key to the reconstruction of the evolution of ultrahigh‐pressure metacarbonate rocks. Here, we present new data and a new model on the genesis and the P–T conditions of the formation of calcite found in the ultrahigh‐pressure calc‐silicate rocks from the Kokchetav massif. In the studied sample aragonite inclusions coexist with Type A calcite inclusions (previously interpreted as mineral inclusions) and the inclusions of Type B calcite (previously interpreted as derived from the crystallization of carbonatitic melt) in cores of garnet porphyroblasts. The most Mg‐rich calcite from Type A inclusions coexisting with aragonite inclusions in one garnet growth zone shows XCa = 0.935 implying their crystallization during a retrograde metamorphic stage at P ~ 2.3 GPa and T ~ 870°C along the P–T path. Type A calcite and aragonite inclusions were also found coexisting in one growth zone with K‐bearing clinopyroxene inclusion (ω[K2O] = 0.5 wt.%). Such a high K2O‐content in clinopyroxene testify that the pressure of inclusion capture exceeded 3.5 GPa, which contradicts the P–T conditions estimated by XCa in magnesian calcite. Thus, Type A calcite inclusions were initially captured as an aggregate of aragonite+ magnesian calcite at ultrahigh pressure metamorphic stage (P ≥ 3.5 GPa, T = 900–1,000°C) and then re‐equilibrated at lower conditions (P ≤ 2.3 GPa and T ≤ 870°C). The trace element composition of aragonite and Type A and Type B calcite from inclusions was also studied to clarify calcite genesis in these inclusions. Aragonite shows high LREE (5–57 ppm) and Sr‐content (600–800 ppm). Calcite from Type A inclusions shows low LREE (2.9–19.8 ppm) and Sr‐content (490–670 ppm). Calcite from Type B inclusions forms two groups according to the LREE and Sr content distribution (Type B1 and Type B2). Trace element distribution in Type B1 calcite is identical to that of Type A calcite, while Type B2 calcite shows high LREE (6.8–64.9 ppm) concentrations along with low Sr‐content (180–340 ppm). Type A and Type B1 calcite is interpreted to have been re‐equilibrated. Type B2 calcite inclusions crystallized from the hydrous carbonatitic melt.

Rupture and Afterslip Controlled by Spontaneous Local Fluid Flow in Crustal Rock

AbstractShear rupture and fault slip in crystalline rocks like granite produce large dilation, impacting the spatiotemporal evolution of fluid pressure in the crust during the seismic cycle. To explore how fluid pressure variations are coupled to rock deformation and fault slip, we conducted laboratory experiments under upper crustal conditions while monitoring acoustic emissions and in situ fluid pressure. Our results show two separate faulting stages: initial rupture propagation, associated with large dilatancy and stabilized by local fluid pressure drops, followed by sliding on the newly formed fault, promoted by local fluid pressure recharge from the fault walls. This latter stage had not been previously recognised and can be understood as fluid‐induced afterslip, co‐located with the main rupture patch. Upscaling our laboratory results to the natural scale, we expect that spontaneous fault zone recharge could be responsible for early afterslip in locally dilating regions of major crustal faults, independently from large‐scale fluid flow patterns.

Low–Ti Continental Tholeiite Origin of Magmas With Calc‐Alkaline Signature in Transcurrent Settings: The Mississippian Matachel Volcanic Field (SW Iberian Massif)

AbstractIn the Mississippian Matachel small volcanic field of the Ossa‐Morena Zone (southern Iberian Massif) outpoured basic‐intermediate lavas exhibit geochemical characteristics of Low‐Ti continental tholeiites and calc‐alkaline lavas. Low‐Ti continental tholeiites integrate two contrasting groups of rocks: basalts (Mg#: 54 to 70; Ti/Zr: 61–79; LaN/LuN: 1.6–2.9; εNdi: +4.0–+6.6; “Group #1”), and basalts and basaltic andesites (Mg#: 43 to 66; Ti/Zr: 36–58; LaN/LuN: 2.5–5.9; εNdi: −0.2–+3.5; “Group #2”). Primitive Group #1 tholeiitic magmas were generated by partial melting of a garnet‐free lherzolite from an enriched lithospheric mantle, near the lithosphere‐asthenosphere thermal boundary layer (with a very limited asthenosphere melting input). Progressive interaction of these magmas with crustal alkali igneous rocks resulted in the formation of the petrological evolutionary trends observed, to a larger extent in the case of Group #2 Low‐Ti tholeiites. Further assimilation of amphibole‐rich calc‐alkaline metaigneous rocks might have originated the basalts and basaltic andesites with calc‐alkaline signature (Mg#: 33 to 56; Ti/Zr: 25–78; LaN/LuN: 2.0–5.6; εNdi: +2.8–+4.8). These exhibit a “Cordilleran‐type” evolutionary trend, though are unrelated to plate convergence. The magmas with calc‐alkaline signature attest to a closed‐system differentiation process controlled by the fractionation of plagioclase, clinopyroxene, magnetite and ilmenite. It is proposed that Mississippian lithospheric‐scale intra‐continental wrenching, unrelated to coeval mantle plume upwelling, reworked complexly docked mantle domains and triggered mantle melting. Enduring mid‐upper crustal processes (magma storage in mid‐crustal chambers and crustal assimilation) likely shaped the latest petrologic and geochemical aspects of the Matachel Low‐Ti tholeiites and related rocks with calc‐alkaline signature.

Ocean. History of water and the Earth’s crust

Views on the origin and evolution of water (the amount and mode of incorporation into crustal and mantle rocks) on Earth are quite diverse. To substantiate them, arguments from various sections of geography, geology, geochemistry, cosmochemistry, and cosmogony are used. A comprehensive analysis allows us to fairly confidently assume that the appearance of water is associated with the final stage of the formation of the planet, which began after the accumulation of 60—90 % of its volume. This period coincided with the entry of water-bearing carbonatites,among other chondrites,into the accretion zone. Having estimated their contribution to the formation of water from different sources, we can compare it with the geological and geophysical data on the Earth’s early history. For this purpose, the author’s idea of the global asthenosphereas a relic of an ancient magmatic ocean, was used. The framework made it possible to estimate the volume of matter from which the emergence of a magma ocean made it possible to extract water. The synthesis of these independent results allows us to state quite confidently that water to fill the ocean was available (in one form or another) throughout the entire studied geological history of the planet.&#x0D; The problem of the ocean itself (a deep-water reservoir with a crust different from the crust of the continents — less powerful and more basic) is considered mainly using the well-known results of B.A. Bluman and E.M. Rudich on the oceans and M.I. Budyko and co-authors on the continents. Their conclusions agree with the schemes of deep processes in the ocean tectonosphere considered by the author. These processes are controlled by a series of geological phenomena and anomalies in geophysical fields.The processes are reduced to heat and mass transfer in the eugeosyncline superimposed on the anomalously basic continental crust and subsequent activation.Thus, a fairly definite picture of the formation of the modern ocean due to the previous development of the Earth’s tectonosphere in the Mesozoic-Cenozoic is emerging.

High-pressure melting in metapelites of a 2 Ga old subducted oceanic crust (Usagaran belt, Tanzania): implications from melt inclusions, fluid inclusions and thermodynamic modelling

Investigation of polymineralic melt inclusions preserved in garnet of eclogite-facies metapelites of the Usagaran belt, Tanzania, is of particular importance as these metapelites, intercalated in oceanic metabasites, document the rare case of partial melting at high temperatures in a subducted oceanic crust. With an age of 2 Ga the rocks represent one of the oldest oceanic crusts and confirm a subduction process already at Paleoproterozoic times. Partial melting probably was initiated by dehydration melting under the presence of a CO2-rich fluid phase. The melt is preserved in siliceous polymineralic inclusions, while CO2 locally reacted with the garnet host to form dolomite-quartz-kyanite inclusions. During this reaction, the REE spectrum of garnet is adopted by the dolomite. Furthermore, graphite inclusions in garnet must have precipitated from the CO2 fluid by reduction. The highly ordered graphite structure indicates a formation temperature of at least 700 °C. Rehomogenization experiments of the siliceous polymineralic inclusions yield a homogeneous melt of rhyolitic, peraluminous composition. Thermodynamic modelling enables to deduce a P–T path in accordance with high P–T conditions (minimum 2.0 GPa, 900 °C) where a partial melt formed due to phengite breakdown leading to the preserved peak mineral assemblage garnet, alkali feldspar, kyanite, quartz and rutile. A very fast uplift of the oceanic crustal rocks can be deduced from the occurrence of very finely exsolved metastable ternary feldspar and from the preserved prograde zoning in garnet.

Probing the deep mantle wedge in an active subduction zone: Xenoliths from the Mercaderes Volcanic District, Southern Colombia

In subduction zones, the mantle wedge is the domain where liquid phases released by the oceanic subducting plates cause mantle hydration, metasomatism, and partial melting, producting the arc crust. However, direct petrologic information on mantle wedges overlying active subduction zones remains scarce. Here we constrain key aspects of the petrological evolution of the supra-subduction mantle underneath the active volcanic district of Southern Colombia (Mercaderes) by studying a unique suite of peridotite and pyroxenite xenoliths hosted by andesites and lamprophyres. These garnet-bearing peridotite, websterite, clino- and orthopyroxenite xenoliths equilibrated between 2.5 and 4 GPa and 1100–1200 °C. The studied rocks display considerable heterogeneity in terms of lithotypes, textures, mineral abundance and extent of metasomatic overprint. Most samples display fine-grained mylonitic textures overprinting coarse-grained peridotite and garnet pyroxenite precursors; the EBSD study of undeformed garnet websterite samples suggests crystallization from melts and/or melt-rock reaction processes. Modal enrichment in clinopyroxene as well as in the alkalis and LREE contents in some garnet peridotite implies interaction with alkaline basaltic melts, whereas enrichment in silica, Pb and Sr in the garnet-bearing orthopyroxenites records interaction with metasomatic, slab-derived liquids. Some garnet clinopyroxenite xenoliths display marked positive Sr anomalies and minor Eu anomalies, indicating derivation of these rocks from Mg-rich, plagioclase-bearing (and garnet-absent) low-pressure cumulates. Their equilibration in the garnet field implies that after crystallization these clinopyroxenites were transported to deeper levels in the mantle, as the result of foundering into the mantle of the dense arc roots, as already documented in Mercaderes and elsewhere in the Andes. In conclusion, the Mercaderes xenoliths probe a heterogeneous and chemically active domain of the Colombian mantle wedge, where deep sinking lower crustal rocks, melt metasomatism by distinct venues of chemically different melts, and deformation predate fast exhumation by volatile-rich melts.

Triassic felsic magmatism in SE Peninsular Malaysia: Petrogenesis and geodynamic implications for the Eastern Paleotethyan tectonic transition

Middle–Late Triassic volcanism and contemporary granitoids in East Malaya provide significant insights into the magmatic evolution and geodynamic processes of the Paleotethyan Ocean in SE Asia. This paper presents new zircon ages and whole-rock geochemical data including Sr-Nd-Pb-Hf isotopic analyses for newly identified felsic volcanic rocks and granites in SE Peninsular Malaysia. Zircon geochronological data constrain their formation time at 238–235 Ma. All samples have relatively high SiO2 contents with enrichment in light rare earth elements but have negative anomalies at Nb, Ta, Ti, and Eu on spidergrams. Calculated zircon saturation temperatures are between 840 °C and 957 °C. Samples have (87Sr/86Sr)i ratios between 0.70501 and 0.71014 and εNd (t) values ranging from −6.6 to −5.9, with (206Pb/204Pb)i = 18.45–18.77, (207Pb/204Pb)i = 15.68–15.71, and (208Pb/204Pb)i = 38.88–38.97. The zircon in-situ εHf (t) values and TDM2 ages range from −5.6 to +4.5 and 1.62 Ga to 0.98 Ga, respectively. The primary melting source which produced these felsic volcanic rocks and granites was Proterozoic crustal rocks with a juvenile middle-lower crustal component. Triassic volcanism in SE Peninsular Malaysia northerly correlates with synchronous volcanic rocks in the Lancangjiang and Chiang Khong-Lampang-Tak volcanic zones. Our data, along with regional observations, indicate that these volcanic rocks and granites formed in a localized extensional setting in response to the Paleotethyan slab breakoff. While the initial collision of Sibumasu with East Malaya may have occurred at ∼237 Ma.

Tectonic setting and provenance analysis of the Yaojia Formation in the northeastern Songliao Basin, NE China: constraints from sandstone geochemistry, Hf isotopes, and zircon U–Pb chronology

The Songliao Basin is rich in uranium ores, and the Yaojia Formation, which is dominated by gray fine-grained sandstones, contains the main ore-bearing stratum. Rocks in the formation contain high SiO2, Al2O3, and total alkali, with enrichment in Rb, Th, U, K, and light rare earth elements but are depleted in high field strength elements, similar to upper crustal rocks. U–Pb dating of zircon grains from sandstones in the formation yielded four groups of ages, including 99–182, 202–245, 284–365, and 1800–1900 Ma. These ages combined with the Hf isotope composition, geochemical characteristics, and regional history suggest that the Yaojia Formation rocks are associated with passive and active continental margin settings. These clastic rocks originate principally from felsic rocks in the Zhangguangcailing–Xiao Xing'anling area, and these were deposited in oxic freshwater environments.