Crustal Protoliths Research Articles

Geochemistry of fine-grained sedimentary rocks: Implications for source area, paleoweathering, paleoclimate, and provenance of the Santa Maria Formation (Triassic, Paraná Basin, Brazil)

The integration of ICP-OES, XRD, chemical analysis, and scanning electron microscopy was used to investigate the source area, weathering, paleoclimate conditions, and provenance of the siltstones of the Santa Maria Formation (Middle to Upper Triassic, Southern Brazil). This unit is regionally subdivided, from base to top, into the Passo das Tropas Member (Late Anisian–Middle Ladinian) and the Alemoa Member (Middle Ladinian–Carnian). The Chemical Index of Alteration (CIA) was calculated for both members to highlight the weathering processes of primary minerals. The CIA results indicate moderate to extreme weathering of the source rocks for the siltstones. The extreme chemical alteration observed in the Passo das Tropas siltstones (CIA = 76.97–90.83) and in the mid-section of the Alemoa Member (CIA = 87.96–89.63) suggests weathering under more humid conditions, related to an increase in paleorainfall. Paleoclimate was interpreted as semi-arid to arid, with alternating wet and dry seasons. These results align with the geochemical behavior of uranium and thorium. Samples with higher CIA values show higher Th/U ratios, indicating a shift toward a more humid climate. X-ray diffraction analysis of the fine fraction (FF < 2 μm) of the samples identified mixed-layered illite-smectite (I/S) clay minerals with minor amounts of quartz. Regarding provenance, Th/U ratios coupled with Th vs. Sc and La-Th-Sc plots, suggest an upper crustal protolith for the southern Santa Maria siltstones, consisting of uplifted rocks from the crystalline basement of the Sul-Rio-Grandense shield and sedimentary rocks of the Camaquã Basin. The Th/Sc, Sc/Th, Co/Th, and La/Sc ratios, along with the contents of Al₂O₃, SiO₂, TiO₂, Co, V, Ni, and Sc, indicate a more felsic composition for the Passo das Tropas Member. Meanwhile, the source rocks of the Alemoa Member sediments demonstrate a more mafic composition in the mid-section, transitioning to a felsic composition in the uppermost succession.

Detrital K-feldspar as a novel archive of continental crustal evolution using coupled in situ Rb[sbnd]Sr dating and Pb isotope analysis

Here we present in situ RbSr and Pb isotopic analysis of K-feldspar from the Shap Granite, (Cumbria, UK) and detrital K-feldspar from the associated Shap Wells Conglomerate Formation, to investigate the potential of the detrital K-feldspar record as an archive of crustal composition. We use a unique, collision cell – multi collector inductively coupled plasma tandem mass spectrometer to make the in situ isotope measurements, using ‘chemical resolution’ of 87Rb+ and 204Hg+ isobaric interferences on 87Sr+ and 204Pb+, achieved with SF6 and NH3 reaction gases, respectively. Using this technique, we successfully demonstrate that the majority of detrital K-feldspar RbSr ages, as well as initial Sr and Pb isotope ratios, from the Shap Wells Conglomerate are within uncertainty of those for parental Shap Granite K-feldspar (398 ± 1 Ma, n = 6). Some detrital K-feldspar grains record perturbed RbSr ages, reflecting post depositional alteration events. The majority of samples with disturbed RbSr ages carry distinct petrographic features evident in SEM imaging, prior to in situ dating, which indicates a means to help screen for reliable ages.We further illustrate the potential value of combined RbSr and Pb isotopic information preserved in K-feldspar to estimate the timing and chemical composition of juvenile continental crust formed in the past. Where UPb has been fractionated during juvenile crust formation, the initial Pb isotope ratio provided by the K-feldspar yields model crustal U/Pb (diagnostic of tectonic setting) and extraction age. The contrast in the U/Pb composition of juvenile crust formed in intraplate or subduction settings allows the model U/Pb ratios of the detrital K-feldspars to be used to constrain the style of juvenile crust formation. Additionally, the initial 87Sr/86Sr isotope ratio measured in detrital K-feldspar can be combined with the calculated crustal extraction age and RbSr K-feldspar age to model the Rb/Sr of the juvenile crustal protolith.

Anatomy of a Lunar Silicic Construct—The Wolf Crater Complex, Mare Nubium and Implications for Early Silicic Magmatism on the Moon

AbstractSilicic lithologies on planetary surfaces indicate magmatic evolutionary processes in their interiors. The Wolf crater complex within Mare Nubium on the Moon is one such silicic construct associated with a high thorium anomaly. This study integrates morphological, compositional, chronological and gravity anomaly analyses of high‐resolution data from various lunar missions to establish this construct as a silicic volcanic caldera. Lobate flows with steeply sloping fronts indicate that the crater rims comprise high‐viscosity silicic lavas, while the structurally controlled inner crater walls suggest caldera collapse triggered by magma depletion. In the crater rims, low Christiansen Feature position values reaffirm the presence of silicic lithologies, consistent with the low gravity anomaly signature beneath the complex, while spectroscopic data reveal low mafic mineral abundances and negligible hydration features. Chronological analyses yield silicic volcanism ages coeval with surrounding mare basalts (3.8–3.6 Ga), while intra‐caldera basalts have 2.36–2.02 Ga ages, indicating prolonged magmatism in this region. Melting of suitable crustal protoliths like alkali gabbronorite/monzogabbro/troctolite by basaltic underplating is inferred to have generated silicic magmas that formed the Wolf volcanic complex, instead of basaltic magma fractionation or silicate‐liquid immiscibility processes. Large impacts during the Late Heavy Bombardment may have enhanced partial melting of the mantle and created crustal fractures that facilitated the ascent of viscous silicic melts through the lunar crust. Contemporaneous existence of suitable protoliths and adequate crustal pathways for magma ascent may have controlled silicic volcanism on the Moon, and can explain the sporadic occurrence and overlapping ages of the lunar silicic constructs.

Late Paleozoic potassic igneous rocks of the Kensu and Dzholkolot plutons in the eastern Kyrgyz Tien Shan: Petrology, geochemistry, U-Pb zircon geochronology, and related skarn-porphyry W-Mo-Cu-Au mineralization

The Kensu and Dzholkolot multiphase intrusions are situated in the eastern part of the “Main Structural Line of Tien Shan”, or the “Nikolaev Line”. The plutons comprise mafic to intermediate (monzogabbro, monzonite, syenite, quartz syenite) and silicic (quartz monzonite, monzogranite, and leucogranite-alaskite) members, together with the interim (camptonite) and final monzodiorite-porphyry dikes. Geochemical signatures of the igneous rocks correspond to high-K calc-alkaline to shoshonitic series intrusions, with a strong A-type affinity, emplaced in post-collisional setting. Magmatic evolution included a generation of shoshonitic magma by a low-degree partial melting of the metasomatically-enriched upper mantle, followed by amphibole fractionation in a deep (lower crustal?) magma chamber. This was followed by a generation of mantle-induced granitic magmas in a crustal protolith, with possible mixing/mingling of various magmas. The rocks crystallized at shallow levels, in an oxidized environment, under decreasing pressure and temperature toward the younger (granitic) intrusion phases.Isotopic U-Pb (LA-ICP-MS) zircon dating of the igneous rocks indicates their Late Carboniferous age (ca. 325–302 Ma). The magma emplacement included a number of intrusion phases from monzogabbro (321 ± 4 Ma), monzonite (319 ± 4 Ma), and camptonite (306 ± 4 Ma), to quartz syenite (305.5 ± 2 Ma to 302 ± 3.7 Ma), quartz monzonite (305 ± 3 Ma) and subsequent granitic phases. Although the ages identified correspond to those of the subduction-related magmatism in the western part of the Middle Tien Shan, geochemical characteristics of the rocks supporting rather post-collisional setting of the plutons are in agreement with a “scissor-like” closure of the Turkestan paleoocean, starting from the east. Zircon xenocrysts dated at ca. 1.9 Ga suggest the presence of an underlying old continental crust.The skarn-porphyry W-Mo(−Cu-Au) mineralization complements the group of similar deposits associated with high-K calc-alkaline to shoshonitic series intrusions in the Middle Tien Shan and globally. The high endowment in W and Mo can be related to the fertilization of subduction-modified subcontinental lithospheric mantle in these metals, together with more common fertilization in Cu and Au, with its subsequent involvement in the magma generation in post-collisional setting. The endowment in W and Mo can also reflect a greater involvement of an ancient continental crust as the magma source(s). The oxidized paragenesis of hydrothermal alteration assemblages and mineralization corresponds to the respective affinities of the igneous rocks.

Petrogenesis and zircon U-Pb ages of the Late Paleozoic high-potassic Sonkul and Kokturpak plutons in Kyrgyz Tien Shan, with implications for related skarn-porphyry W-Au(-Cu-Mo) mineralization

ABSTRACT The Sonkul and adjacent Kokturpak multiphase plutons are situated along the ‘Major Structural Line of Tien Shan’ (known also as the ‘Nikolaev Line’) that extends for over 500 km and divides the terranes of the Middle and Northern Tien Shan. The plutons comprise a broad variety of high-potassic igneous rocks including the early olivine gabbro, intermediate monzonite to quartz monzonite, and later granodiorite, monzogranite, and leucogranite-alaskite, in turn followed by the late mafic dikes. U-Pb dating of zircon grains yields ages of 299 ± 2 Ma (olivine gabbro), 300 ± 3 Ma to 298 ± 3 Ma (monzonite to quartz monzonite), 299 ± 3 Ma to 298 ± 4 Ma to 297 ± 4 Ma (granodiorite), and 289 ± 4 Ma to 285 ± 2 Ma (monzogranite). These consecutive intrusive phases appear to have been produced by partial re-melting of a partially crystallized (mush) magma batch at deeper levels, which is evident by the presence of zircon antecrysts dated at some 306–311 Ma (up to 323 Ma?). Geochemical signatures of the igneous rocks correspond to high-K calc-alkaline to shoshonitic series intrusions emplaced in a transitional subduction-related to post-collisional setting. A low-degree partial melting of the metasomatically enriched upper mantle can be envisioned as the leading process of shoshonitic magma generation; this was followed by amphibole fractionation in a deep (lower crustal ?) magma chamber and possibly a mantle-induced generation of granitic magmas in the crustal protolith. Further mixing/mingling of the mafic magma and crustal granitic magma was followed by the magma fractionation and emplacement at shallow crustal levels. Assimilation of the old continental crust is consistent with the presence of ancient xenocrystic zircons (dated at ca. 1.5 to 2.5 Ga) in the studied rocks. The Late Carboniferous to Early Permian age and high-K calc-alkaline to shoshonitic composition are similar to those of highly mineralized intrusions of the other segments of the Middle Tien Shan. In this regard, several magmatic pulses of high-potassic intrusions and corresponding metallogenic pulses can be suggested in this region. Whereas the early (ca. 337 to 315 Ma) igneous suites accompanied by dominantly porphyry Cu-Au-Mo mineralization, the later (ca. 305 to 285 Ma) suites including the Sonkul and Kokturpak plutons are accompanied by W- and/or Au-dominant mineralization. This mineralization appears to pre-date more substantial intrusion-related to orogenic-type Au mineralization.

Geodynamic Settings of Late Paleozoic–Early Mesozoic Granitoid Magmatism at the Arctic Continental Margins: Insights from New Geochronological and Geochemical Data from the Taimyr Peninsula

Despite significant progress in Arctic geological studies, a number of principal questions concerning the Paleozoic collisional events remain unanswered. Therefore, the Taimyr Peninsula, representing the only outcropped high Arctic region where magmatic complexes, formed by Hercynian collision between the Siberian Craton and the Kara Block, are well exposed, is crucially important. In this paper we report new geochemical and geochronological data for intrusions in the poorly studied northeastern part of the Taimyr Peninsula. The obtained results in combination with published data show that supra-subduction magmatism at the southern active margin of the Kara Block continued from ca. 345 to 285 Ma (Early Carboniferous to Early Permian), and was followed by a post-collisional magmatic pulse that affected the whole Taimyr across terrane boundaries at ca. 280 Ma in the Early Permian. After cessation of the post-collisional magmatism at ca. 265 Ma, the Taimyr experienced extension, and voluminous magmatic series associated with a Siberian mantle plume were formed between 251 and 228 Ma during the Triassic. The studied post-collisional and plume-related intrusions of the Northeastern Taimyr are generally classified as evolved high-K I-type granites with adakitic affinity. The latter is a regional feature because the majority of the analyzed plume-related granitoids are geochemically similar to high potassium continental adakites. It is suggested that the adakitic geochemical characteristics of the plume-related granitoids resulted from melting of hydrated mafic lower crustal protoliths and were controlled by the source lithology. Comparison of the new results with data available for adjacent areas allows for correlation of terranes on a regional scale and sheds light on the evolution of the Arctic continental margins in general. In the Early–Middle Paleozoic, the Kara Block was part of a continental terrane that formed at the northern edge of Baltica as a result of Neoproterozoic Timanian orogeny. In the Early Carboniferous, the southern margin of Kara turned into an active margin, while its inferred continuation in the eastern Uralian margin of Baltica remained a passive margin until the Early Permian. This discrepancy can be explained by dextral displacement of Kara relative to Baltica that took place in the Early Carboniferous and was later accommodated by the formation of the Taimyr collisional belt in the course of the Early Permian collision between Kara and Siberia. After collision, the Taimyr was incorporated into the northern Eurasian margin as an uplifted block that experienced surface erosion and supplied clastic material in surrounding basins.

Stratigraphy, geochronology, geochemistry and Nd isotopes of the Ouarzazate Group, Anti-Atlas, Morocco: Evidence of a Late Neoproterozoic LIP in the northwestern part of the West African Craton

In the eastern and central Anti-Atlas of Morocco, the Late Neoproterozoic Ouarzazate Group (OG) forms a ∼ 2 km-thick section of volcano-sedimentary rocks deposited during intermittent magmatic activity, spanning a time period between 590 and 540 Ma. In the eastern Anti-Atlas, the stratigraphy of the OG, termed IMS (Imiter Mine succession), includes four units that reflect a gradual change from fluvial to lacustrine depositional sedimentary environments. In the central Anti-Atlas, the deposition of the OG occurs within a caldera environment, consisting of five units referred to as BMS (Bou Azzer Mine succession). UPb dating on zircon from the rhyolite lava flow at the top of the IMS constrains the latest lava flow of the IMS to 570.7 ± 2.1 Ma. In the Bou Azzer inlier, the stratigraphically correlated basal andesite and top dacite lava flows were emplaced at 590.6 ± 4.2 Ma and 555.9 ± 20.4 Ma, respectively, suggesting that the OG was constructed through successive pulses within a long-lived magmatic episode. The magmatic rocks display geochemical signatures typical of continental arc magmas, including high-K calc-alkaline to shoshonite composition, enrichment in LILE, and negative Nb, Sr, Ti and P anomalies. Nd isotopes indicate that magmas supplying the plumbing systems of the IMS and BMS constitute transitional products resulting from a combination of orogenic and intraplate volcanism, involving deep crustal recycling. The compositions of these magmas evolved through processes of crustal contamination, bulk assimilation, and minor fractional crystallization of the parent melt. High εNd values of the BMS rocks argue for a juvenile origin, whereas lower εNdt recorded in the IMS likely reflect old crustal protoliths and an overall less contribution of juvenile material in their source. The magmatic rocks of the OG are interpreted as products of a large igneous province (LIP) developed by a post-collisional delamination model that initiated tens of millions of years after the subduction-collision process stage of the Pan-African orogeny in the northwestern part of the West African Craton (WAC).

Late Paleozoic potassic igneous rocks of the Adyrtor intrusions in the eastern Kyrgyz Tien Shan: geochemistry, isotope U-Pb zircon geochronology, and related W-Mo(-Cu-Au) mineralization

ABSTRACT The Adyrtor multiphase pluton is situated in the easternmost part of the ‘Main Structural Line of Tien Shan’, or the ‘Nikolaev Line’, and intrudes the Paleoproterozoic metamorphic sequence representing the oldest (1.8–2.5 Ga) continental basement fragment in the Tien Shan orogenic belt. The intrusions comprise mafic to intermediate (monzodiorite, monzonite, quartz syenite) and silicic (quartz monzonite, monzogranite, and leucogranite-alaskite) rocks. Geochemical signatures of the igneous rocks correspond to high-K calc-alkaline to shoshonitic series intrusions, with a strong A-type granite affinity, emplaced in post-collisional setting. Based on the isotopic U-Pb data, quartz syenite from the Adyrtor intrusions crystallized at 330.7 ± 4.3 Ma, and quartz monzonite – at 329.5 ± 5.8 Ma. Although the ages identified correspond to those of the subduction-related magmatism in the western part of the Middle Tien Shan, geochemical characteristics of the rocks support rather post-collisional setting of the plutons, principally due to a ‘scissor-like’ closure of the Turkestan paleoocean, starting from the east. Magmatic evolution included a generation of shoshonitic magma by low-degree partial melting of the metasomatically-enriched upper mantle, followed by amphibole fractionation in a deep (lower crustal ?) magma chamber. Then, under the influence of mantle-supplied fluids and heat, granitic magmas in the crustal protolith could have been generated, with further mixing/mingling of the mantle-derived mafic (shoshonitic) magma and mantle-induced crustal granitic magma, followed by the magma fractionation and emplacement at shallower crustal levels. Assimilation of an old continental crust is also envisioned, consistent with the presence of the xenocrystic zircons dated at ca. 1.6 Ga to 2.5 Ga and the A-type granitoid affinity of the igneous rocks. The associated skarn-porphyry W-Mo(-Cu-Au) mineralization is consistent with post-collisional setting of the productive intrusions. This mineralization complements the group of similar deposits and occurrences associated with high-K calc-alkaline to shoshonitic series intrusions in the Middle Tien Shan and globally. The high endowment in W and Mo can be explained by the fertilization of subduction-modified subcontinental lithospheric mantle in these metals, with its further involvement in the magma generation in post-collisional setting. Also, a stronger W-Mo mineralization can reflect a greater role of a crustal protolith in the magma generation, as revealed by the distinct A-type affinity of the igneous rocks.

Late Ediacaran post–collisional granite in Babouri–Figuil (Northwest Cameroon): Implication for crustal–mantle contributions in an extensional setting

The Babouri–Figuil Magmatic Complex (BFMC, adjacent to the central-south Chad domain) is located on the southern flank of the Saharan Metacraton. It is amongst the least geologically studied regions in Cameroon; only a few key research papers on geochronology and isotopes have been completed. The emplacement of granitic bodies is poorly constrained between the early and late–Neoproterozoic with inherited zircons of older Paleoproterozoic–Neoproterozoic ages. In this study, undeformed biotite granite massifs (Lombel and Badesi) were studied, and their geochronologic, geochemical and mineral chemical data, including Nd–Sr–Hf isotopes, are presented. The massifs are enriched in pink K-feldspar (orthoclase and microcline; 60–65 wt%) and plagioclase (8–10 wt%) anastomosing to intergranular quartz (18–20 wt%) and biotite (3–5 wt%) crystals. The Lombel massif yielded a Concordia age of 566 ± 2.5 Ma (MSWD = 1.6, zircon U–Pb), slightly older than the Concordia age of 556 ± 2.7 Ma (MSWD = 2.1, zircon U–Pb) obtained for the Badesi massif. These are interpreted as emplacement ages, which post–date arc magmatism by ∼ 45 Ma. The geochemistry of the massifs showed sub- to mid–alkaline, high–K alkali–calcic, and weakly peraluminous compositional characteristics. The calculated biotite temperatures ranged from 613 to 647 °C, pressures from 100 to 300 MPa, and H2O from 3.0 to 3.5 wt%. Whole–rock composition geothermobarometry revealed low pressure of 100–500 MPa, depths of 3.5–18 km and low oxygen fugacity (ΔQFM = −0.6), indicating reducing crystallization conditions. The estimated radiogenic isotopic values are similar for both massifs, falling in the range from initial εHf(t) = +2.6 to +8.4 and initial εNd(t) = +1.3 to +2.1, with a corresponding average initial Sr of 0.70212–0.70458. These radiogenic isotope values suggest a mantle–derived origin for this granite or the melting of a juvenile mafic crustal protolith, as confirmed by the two–stage model age obtained (TDM2 = ∼ 1.2 Ga). Given that biotite is interstitial in alkali feldspar and plagioclase in both massifs, this suggests that biotite chemistry records conditions of magma evolution. Overall, these results confirm that the studied massifs are post–collisional products emplaced at shallow crustal levels under evolved magmatic conditions. They are coeval with a few post–magmatic intrusions in the central–south Chad and emplaced after the Sao–Francisco Congo Craton collided with the Saharan Metacraton. The ages obtained enabled a possible correlation with several Neoproterozoic post–collisional granites in Cameroon, south-central Chad, Central African Republic and Borborema Province of Brazil. The ages also revealed that continental assembly coupled with regional late–magmatism occurred during the Proterozoic.

Whole-rock geochemical and zircon U-Pb-Hf isotopic compositions of the Yunlougang and Wucun granitic plutons in the Hetai area of South China: Implications for petrogenesis and geodynamic setting

In the Nanling tectono-magmatic belt of South China, the geodynamic settings and tectonic style of Indosinian and Yanshanian magmatism remain debatable. Hereby, an integrated study of zircon U-Pb ages and Lu-Hf isotopes as well as whole-rock elemental and Sr-Nd isotopic compositions was carried out on the Yunlougang (Late Permian) and the Wucun (Late Jurassic) granitic plutons in the Hetai area, located to southwest of the Nanling region. Zircon U-Pb dating yielded emplacement ages of 255 Ma for the Yunlougang biotite monzogranite, 240 Ma for the Yunlougang granodiorite as dyke crosscutting the former, and 155 Ma for the Wucun two-mica granite. The biotite monzogranite and the two-mica granite are strongly peraluminous S-type granites (A/CNK ratios of 1.06–1.21) with a relatively low zircon saturation temperature (631–741 °C). The high initial 87Sr/86Sr ratios (0.71733 to 0.73383) and low εNd(t) values (−14.6 to −8.69) suggest a crustal protolith. However, the Wucun biotite granite is highly fractionated I-type one (most samples are metaluminous with A/CNK < 1.1) with a relatively high zircon saturation temperature (762–770 °C). Additionally, they exhibit less radiogenic 87Sr/86Sri ratios (0.70724–0.70786) and higher εNd(t) values (−5.34 to −4.94) as well as zircon εHf(t) values of −5.67 to −2.44, suggesting an origin of a crustal source with extra input from mantle. Based on the tectonic history of South China, we infer that the Yunlougang granite occurred in a compressive setting and might be produced by partial melting of a thickened ancient crust during the collision between the South China and the Indochina blocks, while the Wucun complex granites generated in an extensional environment that was influenced by the paleo-Pacific tectonic regime. Combined with previous studies, a NE-oriented I-type granite belt probably existed along the juncture belt of the Yangtze and Cathaysia blocks, which was respond to the foundering rather than rollback of the paleo-Pacific plate that led to the rapid change of the temperature of granite precursor and the involvement of mantle components into the Hetai region.

Aptian Li-F Granites of the Northern Verkhoyansk–Kolyma Orogenic Belt, Eastern Russia: Composition, Genesis, and Ore Potential

This paper reports the results from an investigation on the geochemistry and petrogenesis of the Aptian Li-F granites from the Omchikandya, Burgali, and Arga Ynnakh Khaya ore fields in the northern Verkhoyansk–Kolyma orogenic belt in eastern Russia. Li-F microcline–albite granites intrude the Late Jurassic to Early Cretaceous syn-collisional granitoids. According to their geochemical composition, they are close to A-type granites and can be subdivided into low-P and high-P varieties, differing in their geochemistry and genesis. The low-P microcline–albite granites (Omchikandya massif) intrude syn-collisional biotite granites. It is assumed that the formation of their parent melt occurred at deep levels in the same magma chamber that produced biotite granites. The high-P granites (Verkhne–Burgali ethmolith and Kester harpolith) are supposed to have been derived from melts originated from a high-grade metamorphosed lower crustal protolith under the influence of deep-seated fluid flows related to diapirs of alkaline-ultrabasic or alkaline-basic composition. It is supposed that their formation was related to post-collisional extension during the early stages of the evolution of the Aptian–Late Cretaceous Indigirka belt of crust extension. All studied Li-F granites are enriched with rare metals and have associated Li deposits with accompanying Sn, W, Ta, and Nb mineralization. In the low-P Li-F Omchikandya massif, mineralization tends to occur within greisenized granites and greisens in their apical parts. In the high-P granite massifs, mineralization is found throughout their volume, and, therefore, the Verkhne–Burgali ethmolith and Kester harpolith can be considered as large ore bodies. There is a direct dependence of the content and reserves of Li2O on the content of P2O5. Minimum Li2O reserves are established in low-P Li-F microcline–albite granites of the Polyarnoe deposit of the Omchikandya ore field, whereas in the high-P granites of the Verkhne–Burgali and Kester deposits, the Li2O reserves are significantly higher.

Water in Omphacite and Garnet From Pristine Xenolithic Eclogite: T‐X‐fO2 Controls, Retentivity, and Implications for Electrical Conductivity and Deep H2O Recycling

AbstractKimberlite‐borne eclogite xenoliths having Precambrian oceanic crustal protoliths and entrained from ≥100 km depth can retain pristine geochemical features despite extended residence in the cratonic lithospheric mantle, making them valuable archives of deep chemical cycling including that of water. We determined, by Fourier Transform Infrared Spectroscopy, structural OH contents in clinopyroxene and garnet from 15 unmetasomatized eclogite xenoliths. Calculated total c(H2O) is 100–510 wt.ppm for clinopyroxene and below detection (∼2 wt.ppm) to 200 wt.ppm for garnet, while garnet δ18O, determined by Secondary Ion Mass Spectrometry, ranges from +5.0‰ to +7.3‰, (similar to high‐ and low‐temperature seawater‐altered oceanic crust). Estimated electrical conductivity in pristine eclogites increases with temperature (i.e., depth for conductive geotherms), while clinopyroxene‐garnet H2O partition coefficients decrease with increasing temperature and garnet grossular component (i.e., Ca#), similar to other incompatible components. Various considerations suggest the retention of primary H2O in the samples, likely occurring in km‐sized pods of coarse‐grained eclogite. High Al2O3 in clinopyroxene as omphacite component, stabilized during high‐pressure metamorphism, facilitates H2O uptake. Therefore, the high bulk c(H2O) estimated for samples with plagioclase‐rich, deep crustal protoliths (median 290 wt.ppm) may indicate an interaction with fluids expelled at depth from serpentinites. The c(H2O) of ancient and modern subducted bulk oceanic crust (∼220–240 wt.ppm) are similar, suggesting constant mantle ingassing since at least 3 Ga ago. This places constraints on factors, such as mantle temperatures, that determine the efficiency of deep water cycling.

Diamond potential of the marginal parts of ancient platforms and associated folded areas

In recent years, more and more information has become available on the subsidence of the oceanic lithosphere into the horizons of the transition zone and the lower mantle of the Earth. Highly metamorphosed rocks are often found in ophiolite complexes of folded areas, which, according to some researchers, can also have significant diamond content. A comprehensive study of all possible sources of information about the formation conditions and evolution of contrasting crustal protoliths opens up new prospects for determining such complex geological processes. These studies are also important in the context of identification of new mineralogical and geochemical markers of diamond-forming processes and, on their basis, determination of the possibility of their practical use in improving methods for predicting, prospecting and evaluating diamond deposits. The current issue of our Journal is devoted to these relevant problems.

Titanium transport and isotopic fractionation in the Critical Zone

Stable Ti isotopes have been applied in the detrital sediment record to reconstruct the bulk composition of Earth’s continental crust due to the relationship between magmatic differentiation and Ti isotopic compositions. However, no study has systematically evaluated the influence of provenance, physical, and chemical weathering on the composition of sediments relative to the protolith they originated from. To test the influence of these processes on Ti isotopic compositions we investigate the Ti isotope composition of 82 surface samples including loess, volcaniclastic rocks, river sediment, and two separate weathering profiles through igneous rocks, collected from a broad geographical area and a range of environmental conditions. Limited but significant Ti isotope fractionation exists in samples subjected to extreme chemical weathering processes, potentially as a result of elemental mobilization. For example, the δ49Ti isotopic composition of bauxites developed on Columbia River basalt varies by up to 0.1‰, becoming isotopically heavier with increasing weathering intensity. However, negligible variation in δ49Ti was found in a second profile of saprolites developed on weathered diabase. Titanium isotope variations in loess do not correlate with chemical weathering intensity or size sorting, but may instead be related to the provenance of the sediment. We find that the δ49Ti of Amazon River sediments is correlated with the Al/Zr ratio, indicating that δ49Ti is impacted by sediment sorting. At our study sites, the river averaged offset between the isotopic composition of the bedload and the suspended sediment fraction is 0.051‰, with the largest offset being + 0.116‰. Our data suggest that during chemical weathering, heavy Ti isotopes are preferentially incorporated into secondary minerals producing higher δ49Ti in intensely weathered soils. During fluvial transport, the Ti isotopic composition of fine-grained sediment is heavier than that of its coarser counterpart. Crustal protolith composition and sorting during transport and sedimentation have a stronger effect on the Ti isotopic composition than chemical weathering. Our results have implications for studies that utilize the Ti elemental concentration to calculate relative enrichment or depletion during chemical weathering and physical transport processes in the Critical Zone and for studies using Ti isotopes in terrigenous sediments to infer the composition of their provenance.

Petrogenesis of potassic granite suites along the southern margin of the Zimbabwe Craton

AbstractAn integrated approach embracing field studies, petrographic and geochemical investigations together with zircon U-Pb-Hf data was used to investigate the petrogenesis of potassic granite suites along the southern margin of the Zimbabwe Craton. Zircon U-Pb geochronology identifies age relationships, revealing coeval magmatism of the ca. 2 635 ± 5 to 2 625 ± 3 Ma Chilimanzi Suite, and the ca. 2 627 ± 7 Ma Razi Suite. Both suites represent syn- to late-tectonic, high-K, calc-alkaline, and metaluminous to weakly peraluminous granites and granodiorites with I-type affinity. The granite suites contain xenocrystic zircons, with the Chikwanda Pluton of the Chilimanzi Suite yielding a grain of up to 3 206 Ma old. Both granite suites exhibit eHf values of between -5.6 ± 1.3 and -7.3 ± 1.6 and TDM model ages of ca. 3.4 to 3.5 Ga which suggests a similar crustal source. The unradiogenic zircon Hf isotopic compositions are consistent with formation of the granite suites through partial melting of pre-existing crustal protoliths, including Palaeoarchaean tonalite-trondhjemite-granodiorites (TTGs) of the Zimbabwe proto-craton. Partial melting of lower crust gave rise to granitic melts that became emplaced over a relatively short time interval from 2 635 to 2 625 Ma and heralded the stabilisation of the Zimbabwe Craton.In addition to virtually identical ages, the Razi and Chilimanzi suites have similar geochemistry. Small geochemical differences between the Chilimanzi and the Razi suites are attributed to the crustal level at which they are preserved, the modal mineralogy and the extent to which the melts are evolved. The Razi Suite melts were generated from lower crust partial melting of thickened charnockite-enderbite source rocks rich in heat producing elements. The partial melting occurred under fluid-absent conditions and magmas were emplaced at lower to mid crustal levels. The Chilimanzi Suite magmas were similarly derived by the partial melting of TTG lower crust and were emplaced at upper crustal levels. Accordingly, the Chilimanzi Suite exhibits more evolved magmatic fractionation indices indicated by high Rb/Sr, as well as low K/Rb ratios relative to the Razi Suite. Both suites reveal varying degrees of enrichment in incompatible elements including Rb, Th, and U, as well simultaneous depletions in Ba, Sr, and Hf which underscores the role of fractional crystallisation in the evolution of the granitic magmas.

Geological evolution of the Proterozoic Betul belt (∼2.16–0.95 Ga) of the Central Indian tectonic Zone: Its linkage to the assembly and dispersal of Columbia and Rodinia supercontinents

The Proterozoic Betul Belt is an important supracrustal unit that records the protracted history of crustal accretion and growth in the Central Indian Tectonic Zone (CITZ). Here, we present results from systematic geological mapping, petrological, geochemical (including Sm-Nd isotope) studies, and U-Th-Pb geochronology on rocks from the Betul belt, with the objective of reconstructing its Proterozoic evolution and its link with past supercontinents. The Betul belt comprises ca. 2167 ± 11 Ma granite gneisses, ca. 2051 ± 80 Ma mafic volcanics (pillowed lava), 1715 ± 10 Ma rhyolite, and older granitoids (1671 ± 29 Ma) that have undergone multi-stage deformation and amphibolite-facies regional metamorphism. The bulk rock geochemistry of gneisses, pillow lava, and mafic intrusions are characterized by arc-like signatures, whereas the rhyolite and granites are anorogenic and back-arc related. The whole-rock geochemical and Sr-Nd isotopic compositions of pillow lavas and mafic intrusions suggest the involvement of recycled crustal material in their source, possibly in the form of associated sediments. The Betul granite gneisses were emplaced at 2167 Ma in a collisional setting by melting crustal protoliths having an affinity with the Bundelkhand craton and may constitute the basement for the supracrustal sequence. The supracrustal units, i.e., mafic volcanics and rhyolites, occur as a bimodal suite formed in the arc and back-arc environment with penecontemporaneous sedimentation. Bulk rock geochemistry and age data indicate two phases of A-type granite magmatism at 1674 Ma and 1079 Ma, with post-collisional geochemical traits forming within an anorogenic and back-arc setting, respectively. Younger post-orogenic granites (Navegaon) were emplaced in a back-arc setting at ca 1079–954 Ma, synchronous with a collisional event in the Sausar belt. Spot ages from monazite in Hbl gabbro yield a weighted mean of 1026 ± 97 Ma (MSWD = 0.15), reflecting Grenville-age regional metamorphism in the CITZ. The geological events recorded in the rocks of the Betul belt between ca 2167 Ga and 954 Ma correlate well with events that affected Laurentia, Baltica, Australia, and East Antarctica within the frameworks of the Columbia (ca. 2.1–1.7 Ga) and Rodinia (ca.1.2–0.9 Ga) supercontinents.

Arc-like magmatism in syn- to post-collisional setting: The Ediacaran Angra Fria Magmatic Complex (NW Namibia) and its cross-Atlantic correlatives in the south Brazilian Florianópolis Batholith

Ediacaran syn-tectonic plutonic rocks (amphibole gabbros, quartz diorites/tonalites to biotite- and muscovite-bearing granites) of the Angra Fria Magmatic Complex (Kaoko Belt, north-western Namibia) belong to two compositionally similar, magnesian, transitional tholeiitic–calc-alkaline suites, the Older (∼625–620 Ma) and the Younger (∼585–575 Ma). Both have counterparts in the broadly contemporaneous Florianópolis Batholith (southern Brazil), from which they were separated during the Cretaceous opening of the southern Atlantic. In the Angra Fria Magmatic Complex, the only unequivocal mantle contributions are identified in mingling zones of the Younger Suite and hybrid mafic–intermediate dykes of uncertain age. Previously published Hf-in-zircon isotopic data, together with new whole-rock geochemical and Sr–Nd isotopic signatures, underline an important role of crustal anatexis of a material with late Palaeoproterozoic to early Mesoproterozoic mean crustal residence (1.9–1.5 Ga). This interval resembles some of the published Nd model ages for Tonian ‘Adamastor Rift’-related felsic magmatic rocks in the Namibian Coastal and Uruguayan Punta del Este terranes. In detail, the Older Suite probably originated mainly by fluid-present melting of metabasalts and metatonalites, followed by (near) closed-system fractional crystallization (with or without accumulation) of amphibole ± plagioclase. For the Younger Suite, the principal process was the dehydration melting of relatively felsic lower crustal protoliths (metagreywackes or intermediate–acid orthogneisses >> metapelites), leaving garnet in the residue. Based on the geological context, the conspicuous enrichment of hydrous-fluid-mobile large ion lithophile over the conservative high field strength elements is not interpreted through a classic model of oceanic plate subduction, devolatilization, and fluxed-melting of the overriding mantle wedge. Instead, it is thought to reflect high-grade metamorphism of deeply buried continental crust and attendant water-fluxed melting of the overlying crustal lithologies, connected with inversion of the Tonian ‘Adamastor Rift’.

Lithospheric thinning and ignition of a Cordilleran magmatic flare-up: Geochemical and O-Hf isotopic constraints from Cretaceous plutons in southern Korea

Northeast Asian continental margins contain the products of magma emplacement driven by prolonged subduction of the (paleo-)Pacific plate. As observed in many Cordilleran arcs, magmatic evolution in this area was punctuated by high-volume pulses amid background periods. The present study investigates the early evolution of the Cretaceous magmatic flare-up using new and published geochronological, geochemical, and O-Hf isotope data from plutonic rocks in the southern Korean Peninsula. After a long (∼50 m.y.) magmatic hiatus and the development of the Honam Shear Zone through flat-slab subduction, the Cretaceous flare-up began with the intrusion of monzonites, granodiorites, and granites in the inboard Gyeonggi Massif and the intervening Okcheon Belt. Compared to Jurassic granitoids formed during the former flare-up, Albian (∼111 Ma) monzonites found in the Eopyeong area of the Okcheon Belt have distinctly higher zircon εHf(t) (−7.5 ± 1.3) and δ18O (7.78‰ ± 0.25‰) values and lower whole-rock La/Yb and Sr/Y ratios. The voluminous coeval granodiorite and granite plutons in the Gyeonggi Massif are further reduced in Sr/Y and to a lesser extent, in La/Yb, and have higher zircon εHf(t) values (−13 to −19) than the Precambrian basement (ca. −30). These chemical and isotopic features indicate that Early Cretaceous lithospheric thinning, most likely resulting from delamination of tectonically and magmatically overthickened lithospheric keel that was metasomatized during prior subduction episodes, and consequent asthenospheric upwelling played vital roles in igniting the magmatic flare-up. The O-Hf isotopic ranges of synmagmatic zircons from the Albian plutons and their Paleoproterozoic and Jurassic inheritance attest to the involvement of lithospheric mantle and crustal basement in magma generation during this decratonization event. Arc magmatism then migrated trenchward and culminated in the Late Cretaceous, yielding widespread granitoid rocks emplaced at shallow crustal levels. The early Late Cretaceous (94–85 Ma) granites now prevalent in Seoraksan-Woraksan-Sokrisan National Parks are highly silicic and display flat chondrite-normalized rare earth element patterns with deep Eu anomalies. Synmagmatic zircons in these granites mimic their host rock’s chemistry. Delamination-related rejuvenation of crustal protoliths is indicated by zircon εHf(t) values of granites (−6 to −20) that are consistently higher than the Precambrian basement value. Concomitant core-to-rim variation in zircon O-Hf isotopic compositions reflects a typical sequence of crustal assimilation and fresh input into the magma chamber.

Fe3+ Distribution and Fe3+/ΣFe-Oxygen Fugacity Variations in Kimberlite-Borne Eclogite Xenoliths, with Comments on Clinopyroxene-Garnet Oxy-Thermobarometry

Abstract The valence state of iron in mantle-derived melts, such as mid-ocean ridge basalt, is a useful proxy for oxygen fugacity (ƒO2). On subduction, oceanic crust undergoes metamorphic reactions that alter its initial ƒO2, generating compositional and redox heterogeneity in the supra-subduction zone and in the convecting mantle source of oceanic basalts. Kimberlite-borne eclogite xenoliths with ancient oceanic crustal protoliths represent an important archive to trace these processes in deep time. We determined, by Mössbauer spectroscopy, Fe3+/ΣFe for garnet (0.03–0.15, average 0.08; n = 13) and clinopyroxene (0.05–0.37, average 0.23; n = 11) in bimineralic eclogite xenoliths from the Udachnaya kimberlite pipe (Siberian craton), combined the results with high-quality literature data to estimate bulk Fe3+/ΣFe and ƒO2, assessed associated uncertainties and discussed petrological implications. The incorporation of Fe3+ in, and distribution between, eclogite minerals is controlled by chemical composition (X), temperature (T), pressure (P) and ƒO2. Therefore, Fe3+/ΣFe in garnet alone is an imperfect proxy for bulk Fe3+/ΣFe. Values for the distribution of Fe3+/ΣFe between clinopyroxene and garnet (D(Fe3+/ΣFe)cpx-grt) range from 1.4 ± 0.1 to 20 ± 13 and correlate strongly with the abundance distribution of another polyvalent element, vanadium (r2 = 0.80, n = 28), probably because both vary as a function of X-T–P-ƒO2. This allows to estimate Fe3+/ΣFe in clinopyroxene and bulk rocks (0.01–0.32, average 0.06, n = 159) for the majority of literature data where only garnet Fe3+/ΣFe is known. Low Fe3+/ΣFe is retained in many high-Al2O3 eclogites with plagioclase-rich cumulate protoliths (Eu/Eu*&amp;gt; &amp;gt; 1), despite extended residence in the cratonic lithosphere. Bulk Fe3+/ΣFe increases during mantle metasomatism but is not particularly linked to enrichment in highly incompatible elements. Low grossular content in garnet ensuing from mantle metasomatism, especially at low temperature, limits uptake of Fe3+, which is accommodated in clinopyroxene instead, leading to very high D(Fe3+/ΣFe)cpx-grt. Eclogite oxybarometry requires that Fe3+/ΣFe of only garnet be known, whereby the input temperatures should be calculated with all Fe as Fe2+. For temperatures projected onto regional steady-state geothermal gradients, ƒO2 values relative to the fayalite-magnetite-quartz buffer (∆logƒO2(FMQ)) range from −5.9 to −0.2 (average − 3.1, n = 174), and are too low to stabilise oxidised sulphur in all and oxidised carbon in the vast majority of samples. Thus, ancient oceanic crust was a sink rather than a source of oxygen. In particular CaO-rich eclogite xenoliths occasionally are corundum-bearing and SiO2-undersaturated, typically with silica-deficient clinopyroxene with cations per formula unit &amp;lt;1.97 for 6 O anions, resulting in overestimated ƒO2. For the remaining samples, cryptic metasomatism, with enrichment in highly incompatible elements, is clearly focused in the ƒO2 interval of FMQ−4 to FMQ−3, indicating that mantle metasomatism can have both an oxidising and a reducing effect on eclogite. Unmetasomatised bimineralic eclogites have lower ƒO2 than coesite-bearing ones, reflecting reduction during metamorphism and silica-consuming partial melting of ancient subducted oceanic crust.

Petrogenesis and tectonic implication of Neoproterozoic I-Type Granitoids and orthogneisses in the Goa-Mandja area, Central African Fold Belt (Cameroon)

The geological evolution of the Central African Fold Belt (CAFB) remains debated. The granitoids, orthogneisses and granitic veins from the Goa-Mandja area (Adamawa-Yade domain) are considered to constrain this belt. These rocks are consistent with late-D2 regional emplacement and synchronous with the magmatism at ~600 Ma within the CAFB in Cameroon and its extension into northeastern Brazil, as the zircon UPb dating points to 603–598 Ma crystallization ages. Analytical data reveal slightly elevated δ18Ozrn (6.45–7.17‰) and δ18OWR (8.20–8.61‰), moderate to high SiO2 (59.70–77.23 wt%), low MgO (0.07–2.77 wt%), Cr (0.29–55.12 ppm), Ni (0.45–33.6 ppm), V (1.52–116.62 ppm) and Mg# (0.02–0.36) contents, indicating crustal origin. The low to medium 87Sr/86Sri (0.703328–0.722670) and positive to negative εNd(t) (+5.7 to −9.9), coupled with the diversity of Nd model ages (TDM2) support the heterogeneity of crustal protoliths. The high positive εNd(t) (+5.7) of the granitic vein indicates derivation from juvenile Neoproterozoic (Nd-TDM2 at 854 Ma) crustal protolith. TDM2(Nd) and TDM2(Hf) ages of 1188–2120 Ma and 2173–2480 Ma also suggest the involvement of Mesoproterozoic to Paleoproterozoic crustal protoliths.Samples show metaluminous to weakly peraluminous, high-K calc-alkaline to shoshonitic and I-type granitoid features and are similar with crustal rocks in regard to LILE (Rb, K) and LREE enrichments and HFSE (Nb, Ta, Ti) depletions. These combined features indicate slab subduction related setting for the magma generation. Slab subduction may have generated the heat necessary to provoke partial melting at the lower crustal level. Considering their position close to the Tchollire-Banyo Fault corridor, at the transition between the Adamawa-Yade and northern domains, the subduction derived features shown by the Goa-Mandja I-type granitoids could be related to the subduction of an old plate boundary during amalgamation of Gondwana. Therefore, the Goa-Mandja area records dominant magmatic accretion along the northern margin of the Congo craton (active margin) associated with a possible northwestern subduction.