Abstract Qiongdongnan Basin (QDNB), located at the northwestern corner of the South China Sea (SCS), is a key juncture between the extensional tectonic regime in the northern continental margin and the shear tectonic regime in the western continental margin. Analyzing the crustal density structure and tracking the thermodynamic controlling factors are effective approaches to reveal the nonuniform breakup process of the northwestern SCS. Herein, focusing on the obvious tectonic deformation with distinct eastern and western parts in the QDNB, we present the crustal density structures of five profiles and identify the high-density anomaly related to the synrifting mantle underplating and postrifting magmatic intrusions. The crustal density model was constructed from the Bouguer gravity anomaly, ocean bottom seismic profiles, and multichannel seismic reflection profiles. The northern part of QDNB, with normal crustal density, lower surface heat flow of <55 mW/m2, and limited extension factor of 1.25–1.70, is recognized as the initial nonuniform extension continental crust. The mantle underplating beneath the QDNB is identified as a high mantle density of 3.30–3.40 g/cm3 and a high lower crustal density of 2.92–2.96 g/cm3, which is usually recognized by the high-velocity layers in the northeastern margin of SCS. The magmatic intrusions are identified as the high-density bodies ranging from 3.26 g/cm3 at the base to 2.64 g/cm3 at the top, which become stronger from the west to east. The central part of Xisha Trough is featured by the cooling of the heavily thinned lower crust in the final continental rifting stage, which is close to the cold and rigid oceanic crust. Lateral variations in the deep magmatic anomaly should be the crucial factor for the nonuniform breakup process in the northwestern margin of SCS.
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