Crustal Conditions Research Articles

U-Pb ages of Gongga Shan granite, western Sichuan and its implication to the tectonic evolutions of eastern Tibet

The eastern margin of the Tibetan Plateau has given rise to much debate about mechanisms of plateau uplift and evolution and, in particular, the role of the lower crust in crustal thickening. Knowledge of the middle to lower crust conditions is critical for evaluating various models of crustal deformation, but data on crustal evolution through time are lacking. Here, we turn to the Gongga Shan granite, an intrusion along the Xianshuihe fault in easternmost Tibet that directly records local Cenozoic crustal conditions. We present 124 U-Pb samples from the Gongga Shan granite (GSG) that prove that the crust has been stepwise producing partial melt from 56 Ma to 4 Ma. According to the age distribution, the GSG can be separated into four major groups with ages of 4–10 Ma, 12–20 Ma, 25–40 Ma, and 43–56 Ma. Combining the timing information with geophysics and low-temperature thermochronology data, we suggest that events younger than 10 Ma may indicate the onset of recent crustal channel flow in the middle to lower crust. In contrast, the youngest 4 Ma ages indicate the ongoing partial melting of the middle crust. The 12–20 Ma events could be related to an earlier stage of crustal channel flow, consistent with the regional large-scale crustal channel flow in central Tibet.

Laboratory Thermal Conductivities Applied to Crustal Conditions

Using a divided bar apparatus, the thermal conductivity of some sedimentary and some common crystalline rock samples has been investigated. The divided bar can be heated by a guard heating system up to 600°C, and a contact pressure of about 50 MPa can be applied. The sandstones (Upper Carboniferous) exhibit a remarkable nonlinear increase of the thermal conductivity with pressure up to about 10 MPa. Siltstones and the crystalline rocks demonstrate a linear pressure dependence of the conductivity within the applied pressure range. The dependence of the conductivity upon temperature is high for sandstones and quartz-bearing rocks. The most fine grained siltstone and some crystalline rocks show a weak temperature sensitivity of the conductivity. If the thermal conductivity of sedimentary rocks is applied for heat flow determination, a difference of up to 20% may arise when the variation of conductivity with pressure and temperature is applied or neglected. Applying the measured thermal conductivity of crystalline rocks, the thermal conductivity vs. depth is estimated for Precambrian and Phanerozoic areas. Utilizando-se de um dispositivo de barra dividida, estudou-se a condutividade térmica de amostras de algumas rochas sedimentares e de algumas rochas cristalinas comuns. A barra dividida pode ser aquecida por uma manta de aquecimento até 600°C, e uma pressão de contato da ordem de 50 MPa pode ser aplicada. Os arenitos (Carbonífero Superior) apresentam um notável crescimento não-linear da condutividade térmica como função da pressão até aproximadamente 10 MPa. Siltitos e rochas cristalinas apresentam uma dependência linear da condutividade com a pressão dentro do intervalo de pressões aplicadas. A dependência da condutividade térmica com a temperatura é alta para os arenitos e para as rochas contendo quartzo. A maioria dos siltitos e algumas rochas cristalinas mostram que a condutividade é pouco sensível à temperatura. Quando a condutividade térmica de rochas sedimentares é utilizada em determinação de fluxo térmico, diferenças de até 20% podem ocorrer se a variação da condutividade térmica com a pressão for considerada ou desprezada. Utilizando-se das medidas de condutividade térmica em rochas cristalinas, a variação da condutividade térmica com a função de profundidade é estimada para áreas Pré-cambrianas e Fanerozóicas.

Transition from carbonatitic magmas to hydrothermal brines: Continuous dilution or fluid exsolution?

Carbonatites are the most important primary sources for the rare earth elements (REEs). While fractional crystallization of carbonate minerals results in the enrichment of volatiles, alkalis, and REEs in the remaining melts, the transition from carbonatitic magmas to hydrothermal brines remains unclear. Here, we investigated the pressure-temperature-composition (P-T-X) properties of the Na2CO3-H2O system up to 700°C and 11.0 kbar using a hydrothermal diamond anvil cell and a Raman spectrometer. Our results show that Na2CO3 becomes increasingly soluble under high P-T conditions, leading to the disappearance of melt-fluid immiscibility and the continuous transition from Na2CO3 melts to hydrothermal brines under deep crustal conditions. Given the abundance of Na2CO3 in highly evolved carbonatitic systems, we suggest that the continuous melt-fluid transition in deep-seated carbonatites results in REEs being sufficiently concentrated in the brine-melts to form economic ore bodies, whereas in shallow systems, REEs preferentially partition into carbonatitic magmas over synmagmatic brines and disperse in carbonatite rocks that underwent limited fractionation.

Barometers Behaving Badly II: a Critical Evaluation of Cpx-Only and Cpx-Liq Thermobarometry in Variably-Hydrous Arc Magmas

ABSTRACT The chemistry of erupted clinopyroxene crystals (±equilibrium liquids) have been widely used to deduce the pressures and temperatures of magma storage in volcanic arcs. However, the large number of different equations parameterizing the relationship between mineral and melt compositions and intensive variables such as pressure and temperature yield vastly different results, with implications for our interpretation of magma storage conditions. We use a new test dataset composed of the average Clinopyroxene-Liquid (Cpx-Liq) compositions from N = 543 variably hydrous experiments at crustal conditions (1 bar to 17 kbar) to assess the performance of different thermobarometers and identify the most accurate and precise expressions for application to subduction zone magmas. First, we assess different equilibrium tests, finding that comparing the measured and predicted Enstatite-Ferrosillite and KD (using Fet in both phases) are the most useful tests in arc magmas, whereas CaTs, CaTi and Jd tests have limited utility. We then apply further quality filters based on cation sums (3.95–4.05), number of analyses (N > 5) and the presence of reported H2O data in the quenched experimental glass (hereafter ‘liquid’) to obtain a filtered dataset (N = 214). We use this filtered dataset to compare calculated versus experimental pressures and temperatures for different combinations of thermobarometers. A number of Cpx-Liq thermometers perform very well when liquid H2O contents are known, although the Cpx composition contributes little to the calculated temperature relative to the liquid composition. Most Cpx-only thermometers perform very badly, greatly overestimating temperatures for hydrous experiments. These two findings demonstrate that the Cpx chemistry alone holds very little temperature information in hydrous systems. Most Cpx-Liq and Cpx-only barometers show similar performance to one another (mostly yielding root mean square errors [RMSEs] of 2–3.5 kbar), although the best Cpx-only barometers currently outperform the best Cpx-Liq barometers. We also assess the sensitivity of different equations to melt H2O contents, which are poorly constrained in many natural systems. Overall, this work demonstrates that Cpx-based barometry on individual Cpx only provides sufficient resolution to distinguish broad storage regions in continental arcs (e.g. upper, mid, lower crust). Significant averaging of Cpx compositions from experiments reported at similar pressures can reduce RMSEs to ~1.3–1.9 kbar. We hope our findings motivate the substantial amount of experimental and analytical work that is required to obtain precise and accurate estimates of magma storage depths from Cpx ± Liq equilibrium in volcanic arcs.

Strain hardening induced by crystal plasticity: A new mechanism for brittle failure in garnets

Garnet is a high-strength mineral stable across a wide range of pressure and temperature conditions and preserves structures that can consequently be used to understand the evolution of stress within the lower crust. Yet, the deformation mechanisms in the brittle-ductile regime of garnet remain ambiguous. Here, we study garnet porphyroclasts from an eclogite facies mylonite (central Australia) to investigate the mechanisms by which garnet is deformed under relatively dry, lower crustal conditions. Electron backscatter diffraction analysis reveals bands of small, relatively strain-free garnet with scattered orientations, outlined by polygonal to lobate high-angle grain boundaries separating the garnet porphyroclasts. Atom probe tomography of a high-angle grain boundary shows Fe enrichment in the form of planar and equally spaced arrays of nanoclusters. Our data demonstrate Fe segregation along grain boundaries of garnet, resulting in the nucleation of Fe-rich nanoclusters that act as barriers for migrating dislocations which could lead to strain-hardening and eventually facilitate mechanical failure.

Boron and Molybdenum Isotope Evidence for Source‐Controlled Compositional Diversity of Cenozoic Granites in the Eastern Tethyan Himalaya

AbstractThe origins of Cenozoic granites in the Himalaya are key to understanding the evolution of the Himalayan orogen. However, it is unclear whether these granites represent primary melts, and the nature of their magma source is controversial. Here, we present a systematic element and Sr–Nd–B–Mo isotope study of Cenozoic granites from the Yardoi area in the eastern Tethyan Himalaya, China. These granites can be divided into two groups: mid‐Eocene porphyritic two‐mica granites with low SiO2 contents (65.9−69.6 wt.%) and adakitic geochemical signatures, and mid‐Eocene to Miocene equigranular granites with high SiO2 contents (71.6−75.5 wt.%). The high‐SiO2 granites (HSG) have similar Sr−Nd isotope compositions to the low‐SiO2 granites (LSG), but they have distinct δ11B values of −19.4‰ to −11.4‰ and −10.6‰ to −6.89‰. This indicates that the two groups have different sources, with the LSG derived by partial melting dominantly of metamafic rocks at thickened lower crustal conditions, and the HSG generated by partial melting of the mid‐crust metasedimentary rocks with less enriched Nd isotope compositions. The δ98/95Mo of the LSG and HSG are highly variable with values of −0.68‰ to 0.12‰ and −1.13‰ to 0.46‰, respectively. δ11B values of the HSG correlate positively with δ98/95Mo and Sr/Y values and correlate negatively with K2O, Rb, Zr, and Rb/Sr, reflecting the addition of external metamorphic fluids during anatexis of the metapelites. The B–Mo isotope data robustly suggest source‐controlled compositional diversity of the Himalayan granites, which could provide clues to the physical and geochemical responses during the evolution of a large orogen.

The origin of olivine basalts from Medvezhya Mount (Avachinsky group of volcanoes, Kamchatka): The evidence of assimilation of sulfide-bearing cumulates

The role and conditions of liquid immiscibility and crystallization of sulfide phase during evolution of subduction related magmas remains to be a debated topic, which bears relevance to mechanisms of porphyry copper deposit formation and evolution of the continental crust. We studied rare volcanic rocks with inclusions of magmatic sulfides in olivine – the basalts of Medvezhya Mount in the Avachinsky group of volcanoes. The rocks belong to primitive (Mg# = 66 mol. %) middle-K island arc olivine basalts. Olivine with normal zoning predominate (~98%) among phenocrysts. The olivine compositions are typical for Kamchatka basalts, except for an unusual trend of increase of MnO content from 0.20 to 0.55 wt. % and decrease of Fe/Mn from 60 to 35 with change of olivine composition from Fo87.8 to Fo78.2. Olivines of this group contain numerous inclusions of minerals of the spinel group varying in composition from chromium spinel to magnesian magnetite. Olivine phenocrysts with sulfide inclusions are characterized by the absence or weak reverse zoning and reduced contents of Ca, Ni, Mn, Cr, and Al. The estimated crystallization temperatures for olivines of the prevailing type are 1036–1241°C, for sulfide-bearing olivines – 1010–1062°C. The data suggest that crystallization of the main olivine population occurred under relatively shallow conditions and was accompanied by strong oxidation of the magmas. On the contrary, the zoning and composition features of sulfide-bearing olivine suggest its xenogenic origin and probable crystallization at conditions of deep crust from low temperature water-rich and/or low-Ca magmas. The results obtained confirm the possibility of saturation of oxidized island-arc magmas with sulfide phase at lower crustal conditions, but show that this process is rare and not typical for low-pressure crystallization stage.

Origin of the Paleoproterozoic basaltic dikes from the central and eastern Dharwar Craton and sills and volcanics from the adjoining Cuddapah Basin, southern India

Reverse fractionation modeling considering energy-constrained assimilation-fractional crystallization is performed to estimate primary magma compositions, degree of crustal contamination, pressure–temperature of equilibrium with mantle, and potential temperatures for the origin of the Paleoproterozoic (~ 2.37–1.88 Ga) basaltic dikes in central and eastern Dharwar Craton and sills and volcanics in the adjoining Cuddapah Basin, southern India. Mineral thermobarometry indicates that the dikes crystallized at upper crustal conditions (~ 1–6 kbar/ ~ 1120–1210 °C). Hence, the reverse fractionation calculations are performed at low pressures by adding olivine + plagioclase + clinopyroxene, olivine + plagioclase and only olivine in equilibrium with melt, and simultaneously subtracting an upper crustal partial melt in small steps until the melt is multiply saturated with lherzolite at a high pressure. The results indicate that the basalts are 5–30% contaminated, and their enriched light rare earth element (REE) patterns can be attributed to upper crustal assimilation. The upper crust was pre-heated to 665–808 °C during dike emplacement. The primary magmas of all basalts were last equilibrated with spinel lherzolite at 10–16.5 kbar/1291–1366 °C, and they resemble pooled polybaric incremental melts generated along a ~ 1450 °C adiabat. The estimated mantle potential temperatures (1293–1515 °C) are similar to Paleoproterozoic ambient mantle temperatures. All basalts and their primary magmas show lower chondrite-normalized DyN/YbN ratios than the plume-derived mid-Proterozoic Mackenzie dikes of Canadian Shield, and the primary magmas show flat REE patterns indicating spinel lherzolite melting. The low estimated potential temperatures, low DyN/YbN ratios, and a spinel-bearing mantle source are at odds with an origin of the basalts from mantle plumes.

The Relationship between Deformation Localization and Catastrophic Failure in Fluid-Saturated Crystalline Rocks in Upper Crustal Conditions

The Relationship between Deformation Localization and Catastrophic Failure in Fluid-Saturated Crystalline Rocks in Upper Crustal Conditions

Barometers Behaving Badly I: Assessing the Influence of Analytical and Experimental Uncertainty on Clinopyroxene Thermobarometry Calculations at Crustal Conditions

Abstract The composition of clinopyroxene and clinopyroxene-liquid (Cpx-Liq) pairs are frequently used to calculate crystallization/equilibration pressures in igneous systems. While canonical uncertainties are often assigned to calculated pressures based on fits to calibration or test datasets, the sources of these uncertainties (and thus ways to reduce them) have not been rigorously assessed. We show that considerable uncertainties in calculated pressures arise from analytical error associated with Electron Probe Microanalyser (EPMA) measurements of Cpx. Specifically, low X-ray counts during analysis of elements with concentrations <1 wt% resulting from insufficient count times and/or low beam currents yield highly imprecise measurements (1σ errors of 10–40% for Na2O). Low analytical precision propagates into the calculation of pressure-sensitive mineral components such as jadeite. Using Monte Carlo approaches, we demonstrate that elemental variation resulting from analytical precision alone generates pressures spanning ~4 kbar (~15 km) for a single Cpx and ~6 kbar for a single Cpx-Liq pair using popular barometry expressions. In addition, analytical uncertainties in mineral compositions produce highly correlated arrays between pressure and temperature that have been previously attributed to transcrustal magma storage. Before invoking such geological interpretations, a more mundane origin from analytical imprecision must be ruled out. Most importantly, low analytical precision does not just affect the application of barometers to natural systems; it has also affected characterization of Cpx in experimental products used to calibrate and test barometers. The impact of poor precision on each individual measurement is often magnified by the small number of measurements made within experimental charges, meaning that low analytical precision and true variability in mineral compositions have not been sufficiently mediated by averaging multiple EPMA analyses. We compile the number of Cpx measurements performed in N = 307 experiments used to calibrate existing barometers, and N = 490 new experiments, finding ~45% of experiment charges were characterized by ≤5 individual Cpx analyses. Insufficient characterization of the true composition of experimental phases likely accounts for the fact that all Cpx-based barometers exhibit large errors (± 3 kbar) when tested using global experimental datasets. We suggest specific changes to analytical and experimental protocols, such as increased count times and/or higher beam currents when measuring low concentration elements in relatively beam resistant Cpx in experiments and natural samples. We also advocate for increasing the number of analyses per experimental charge, resolving interlaboratory analytical offsets and improving data reporting. Implementing these changes is essential to produce a more robust dataset to calibrate and test the next generation of more precise and accurate Cpx-based barometers. In turn, this will enable more rigorous investigation of magma storage geometries in a variety of tectonic settings (e.g. distinguishing true transcrustal storage vs. storage in discrete reservoirs).

Role of acidic fluids in Earth’s deep lithosphere: Insights from the Neoarchean magmatic roots of the Nilgiri Block, southern India

Fluids play a major role in facilitating igneous/metamorphic processes in the Earth’s crust and mantle. In this study, we investigate the nature and composition of fluids in Earth’s interior by studying the lower crustal rocks. We compare accessory minerals (e.g., apatite, monazite, allanite, and titanite), their texture, mineral reactions and composition among regionally distributed metamorphosed mafic and felsic rocks representing the roots of Neoarchean arc magmatism from the Nilgiri Block of the Southern Granulite Terrane in India. Regional trends in accessory minerals show the formation of monazite, allanite, and titanite in the felsic rocks. Apatite is depleted in REEs in all the rock types, irrespective of the difference in their whole-rock chemistry. Textural features and mineral reactions show that these accessory minerals were affected by fluids present in the lower crustal conditions. By comparing our results with those from previous experimental results, we further show that acidic CO2-H2O-HCl-HF fluids stable in lower crustal conditions could have resulted in these chemical and textural features. Dielectric constant of water is high (10–35 compared to lower crustal conditions) in high-pressure and low-temperature conditions of subduction zones and the upper mantle. Such conditions would enhance dissociation of HCl (compared to lower crust) and result in acidic fluids during dehydration reactions in subduction zones and in the upper mantle. Our results have important implications in understanding the nature and composition of fluids in Earth’s interior and would be helpful to model the tectonic and deep geochemical processes in both early and modern conditions in planetary interiors.

Sulfur dissolution capacity of highly hydrated and fluid-saturated dacitic magmas at the lower crust and implications for porphyry deposit formation

Arc basalts with high H2O content are expected to evolve into highly hydrated felsic melts saturated with aqueous fluids at lower crustal pressures, which are potentially important in providing sulfur (S) and metals for porphyry deposit formation. However, the role of such highly hydrated and fluid-saturated magmas in the transfer of S (and metals) remains rarely studied. To investigate the S dissolution capacity of highly hydrated felsic magmas saturated with fluids at the lower crustal conditions, this study performed experiments with dacite + 10 wt% FeS at H2O contents of 10, 15, and 20 wt%. All the experiments were performed in piston-cylinder apparatus at 1.0 GPa and 950 °C with fO2 conditions imposed by the following solid-state buffers: cobalt-cobalt oxide (CCO), nickel-nickel oxide (NNO), rhenium-rhenium oxide (RRO), MnO-Mn3O4 (MMO), and hematite-magnetite (HM), resulting in a fO2 range of FMQ−1.5 to FMQ+3.3 log units (FMQ = fayalite + magnetite + quartz oxgen buffer). The experimental results show that the H2O content in the felsic melt, in addition to fO2 and melt composition, has a strong effect on the concentration of S in the silicate melt at sulfide ± anhydrite saturation. At a given fO2, the S concentration in the melt increases with increasing H2O content (hydration), resulting in a S concentration of up to ∼8000 ppm in the highly hydrated dacitic melts at fO2 ∼ FMQ+2. We found that high melt hydration at an intermediate fO2 not only dramatically increases sulfide and anhydrite solubilities in the dacitic melts but also promotes the saturation of S-rich fluids. The S concentration in the fluid that corresponds to the highest measured S concentrations in the melt (∼8000 ppm) are ∼5 wt%. These results show that highly hydrated felsic magmas saturated with fluids have a high capacity for S dissolution. Therefore, injection of such fluid-saturated magmas from lower crustal to shallow magma reservoirs is a potential mechanism for the effective transport of S (and perhaps metals) to facilitate subsequent porphyry ore deposit formation.

Integrating Multidisciplinary Observations in Vent Environments (IMOVE): Decadal Progress in Deep-Sea Observatories at Hydrothermal Vents

The unique ecosystems and biodiversity associated with mid-ocean ridge (MOR) hydrothermal vent systems contrast sharply with surrounding deep-sea habitats, however both may be increasingly threatened by anthropogenic activity (e.g., mining activities at massive sulphide deposits). Climate change can alter the deep-sea through increased bottom temperatures, loss of oxygen, and modifications to deep water circulation. Despite the potential of these profound impacts, the mechanisms enabling these systems and their ecosystems to persist, function and respond to oceanic, crustal, and anthropogenic forces remain poorly understood. This is due primarily to technological challenges and difficulties in accessing, observing and monitoring the deep-sea. In this context, the development of deep-sea observatories in the 2000s focused on understanding the coupling between sub-surface flow and oceanic and crustal conditions, and how they influence biological processes. Deep-sea observatories provide long-term, multidisciplinary time-series data comprising repeated observations and sampling at temporal resolutions from seconds to decades, through a combination of cabled, wireless, remotely controlled, and autonomous measurement systems. The three existing vent observatories are located on the Juan de Fuca and Mid-Atlantic Ridges (Ocean Observing Initiative, Ocean Networks Canada and the European Multidisciplinary Seafloor and water column Observatory). These observatories promote stewardship by defining effective environmental monitoring including characterizing biological and environmental baseline states, discriminating changes from natural variations versus those from anthropogenic activities, and assessing degradation, resilience and recovery after disturbance. This highlights the potential of observatories as valuable tools for environmental impact assessment (EIA) in the context of climate change and other anthropogenic activities, primarily ocean mining. This paper provides a synthesis on scientific advancements enabled by the three observatories this last decade, and recommendations to support future studies through international collaboration and coordination. The proposed recommendations include: i) establishing common global scientific questions and identification of Essential Ocean Variables (EOVs) specific to MORs, ii) guidance towards the effective use of observatories to support and inform policies that can impact society, iii) strategies for observatory infrastructure development that will help standardize sensors, data formats and capabilities, and iv) future technology needs and common sampling approaches to answer today’s most urgent and timely questions.

Experimental determination of N2 solubility in silicate melts and implications for N2–Ar–CO2 fractionation in magmas

The solubility of nitrogen in magmatic melts is key for understanding the degassing of Earth’s interior and formation of Earth’s N-rich atmosphere. We performed high-pressure experiments to determine the solubility of nitrogen at N2-saturation in basaltic to granitic melts at pressures of 0.3–8 GPa, temperatures of 1200–1600 °C, and oxygen fugacities between the Fe–FeO and Ni–NiO oxygen buffers. The solubility and speciation of nitrogen in the quench silicate melts were quantified by Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR), electron probe microanalyzer (EPMA), and Nano-scale secondary ion mass spectrometry (NanoSIMS). The results show that the predominant N-species in our silicate melts is N2, which dissolves physically by filling the interstitial sites of the silicate melt network. The measured N-solubilities in silicate melts (SN2melt) by using different approaches agree with each other, and they vary from 200 to 17,000 ppm by weight. The SN2melt increases with increasing pressure and/or decreasing silicate melt NBO/T (the ratio of non-bridging oxygens to tetrahedrally coordinated cations), but it is temperature-independent. Using our newly obtained SN2melt and previous SN2melt and SArmelt data, we develop an empirical model that describes the physical dissolution of N2 and Ar in silicate melts as a function of gas partial pressure and silicate melt composition, and this model can be used to predict SN2melt and SArmelt in magmatic melts of Earth’s mantle and crust. The comparison of our SN2melt data with previous SArmelt and SCO2melt data shows that the solubility in granitic melts is in the order of SArmelt >SCO2melt >SN2melt, but in basaltic melts it is in the order of SCO2melt >SArmelt > SN2melt. The lower SN2melt than SArmelt at Earth’s mantle and crustal conditions suggests N2–Ar fractionation during degassing of mid-ocean ridge basalts and arc magmas. Therefore, the N2/Ar ratios in degassed magmas may not fully represent those in their mantle source regions. The solubility-controlled, preferential degassing of N2 relative to CO2 in Earth’s oxidized shallow magma ocean, in conjunction with collision-induced atmospheric loss, can explain the superchondritic C/N ratio in the bulk silicate Earth. However, the two orders of magnitude higher N2/36Ar ratio in Earth’s mantle than in atmosphere could have resulted from preferential retention of reduced N-species in Earth’s reduced silicate magma ocean or preferential deep subduction of nitrogen.

Time‐Lapse Record of an Earthquake in the Dry Felsic Lower Continental Crust Preserved in a Pseudotachylyte‐Bearing Fault

AbstractThe mechanisms of earthquake rupture in lower continental crust, below the usual frictional‐viscous transition, remain uncertain. In addressing this problem, the study of pseudotachylyte (quenched frictional melt produced during seismic fault slip) and related structures from deeply exhumed rocks can provide direct observational constraints. A felsic granulite from the Musgrave Ranges (central Australia) exceptionally preserves pristine microstructures spatially related to a pseudotachylyte. This sample remained dry, without introduction of hydrous fluids, during pseudotachylyte development and subsequent exhumation. It was therefore unaffected by alteration and metamorphic re‐equilibration. Fractures in the damage zone developed asymmetrically to either side of the pseudotachylyte and are marked by new, randomly oriented quartz, feldspar, and garnet grains. Pulverization of garnet occurred locally between intersecting fractures with powder injected into dilatant fractures in a quartz inclusion within the garnet host. Injection of pulverized material can explain the growth of new, compositionally different minerals (quartz, feldspar, kyanite, ilmenite, magnetite, and rutile) along dilatant fractures developed in a short‐lived seismic event. The pseudotachylyte contains only clasts of quartz, suggesting an unusually high melting temperature. The sequentially developed microstructures provide a time‐lapse record of thermomechanical processes during a single earthquake event, including initial rupture propagation with associated off‐fault damage and local pulverization during very dynamic fluctuations in the local stress field; frictional heating and eventual melting during fault slip; flow and injection of melt; and rapid solidification (quenching) and crystallization of new minerals. This occurred under lower continental crustal conditions of ca. 650°C and 1.2 GPa about 550 Myrs ago.

Electrical Conductivity of KCl‐H2O Fluids in the Crust and Lithospheric Mantle

AbstractEvidence from diamond inclusions suggests that KCl‐bearing fluids may be abundant in the subcratonic mantle and these fluids may also cause local anomalies of high electrical conductivity. We therefore measured the electrical conductivity of aqueous fluids containing 6.96, 0.74 and 0.075 wt% KCl using a hydrothermal diamond anvil cell to 2.5 GPa and 675°C, and with a piston‐cylinder apparatus to 5 GPa and 900°C. We found that below 550°C, increasing pressure generally decreases solution conductivity, while at higher temperatures the effect is opposite. However, at high pressures, the conductivity of KCl in H2O is smaller than for NaCl, possibly due to a hydration shell collapse. The experimental data are described by two numerical models. The first model (R2 = 0.999), is preferable for crustal conditions: log σ = −2.03 + 25.0 × T−1 + 0.923 × log c + 0.990 × log ρ + log Λ0, where σ is the conductivity in S/m, T is temperature in K, c is KCl concentration in wt%, ρ is the density of pure water (in g/cm3) at given pressure and temperature. Λ0 is the limiting molar conductivity of KCl (in S·cm2·mol−1): Λ0 = 1,377 – 1,082 × ρ + 6,883 × 102 × T−1 – 2,471 × 105 × T−2. The second model (R2 = 0.986), is applicable to the lithospheric mantle: log σ = −1.52 – 357 × T−1 + 0.865 × log c + 1.72 × log ρ + log Λ0, with the same equation for Λ0. The latter model shows that already traces of KCl‐bearing aqueous fluid may account for high conductivity anomalies in the subcratonic mantle.

Middle Pleistocene fluid infiltration with 10–15 ka recurrence within the seismic cycle of the active Monte Morrone Fault System (central Apennines, Italy)

This study integrates field, geochronological and geochemical data to constrain fluid circulation in the damage and core zone of the seismogenic Monte Morrone Fault System (MMFS), central Apennines (Italy). Faulting along the MMFS evolved from a diffuse deformation at the damage zone towards progressive localisation of a narrower fault core and, finally, to (re)activation of discrete slip surfaces at shallower crustal conditions. Multiple generations of carbonate mineralisations, including veins and slickfibers, occur along the main fault surfaces. Carbonate mineralisations are locally fractured and incorporated in the surrounding cataclasites, documenting repetitive structurally-controlled fluid infiltration during transient episodes of permeability creation and destruction. Stable carbon and oxygen isotopes of the carbonate mineralisations document a dominant meteoric water source probably mixed with deeper circulating waters having longer residence time. Clumped-isotope yield formation temperatures of vein and slickenfibers in the range between 23 and 40 °C. U-Th dating of carbonate mineralisations yield Middle Pleistocene ages (from 268 to 189 ka BP), with a 10–15-ka cyclicity that we link to the coseismic rejuvenation of the structural permeability in the fault zone. We propose that fault-related mineralisations recorded the interactions among tectonic deformation and climate during the Quaternary. Our study is the first documentation of fault-controlled recurrence intervals in fluid infiltration in a seismically active fault of central Apennines.

Spatio–temporal evolution of Mesoproterozoic magmatism in NE Australia: A hybrid tectonic model for final Nuna assembly

The tectonic regimes that drove the 1560–1490 Ma granitic magmatism c. 50 m.yr. after the final assembly of the Proterozoic supercontinent Nuna in NE Australia remain elusive. Collision between NE Australia (Mount Isa Inlier—MTI) and NW Laurentia (Georgetown Inlier—GTI) occurred at c. 1600 Ma and was associated with a west-dipping subduction zone, with the MTI as the upper plate and the GTI as the lower plate.Structural studies in the GTI showed that the collisional event involved 1600 Ma WNW-ESE shortening, followed by 1550 Ma WNW-ESE directed extension. During this later stage, a crustal-scale, west-dipping detachment fault-system juxtaposed middle- to lower-crustal levels, associated with voluminous, 1550 Ma S-type granites against greenschist facies upper crustal rocks. Regionally, post-collisional magmatism defines a westward, chemical, and temporal trend from 1560 to 1550 Ma, dominantly S-type confined to the lower plate (GTI) through c. 1545–1540 Ma I-/A-type (below the Carpenteria Basin) to 1540–1490 Ma A-type granites that intruded further west the Australian upper plate (eastern MTI). This transition from hydrous (S-type) granites in the east to drier (A-type) granites in the west is also supported by increasing zircon saturation temperatures and geochemical discriminators. Recent zircon Lu–Hf and new in-situ monazite Sm–Nd analyses in granites show increasingly radiogenic initial (at the time of crystallization) isotopic ratios from the GTI to the MTI, reflecting a concomitant westward increase in mantle input. Combined, these features suggest a spatio–temporal evolution of hotter and drier crustal conditions westward associated with progressive lithospheric extension. Classical Phanerozoic upper-plate delamination, slab break-off, and slab rollback and/or tearing tectonic models do not account for all the features of this post-collisional magmatic record. Alternatively, a hybrid tectonic scenario between fast–hard Indian and slow–soft Aegean collision better explains the attributes of Mesoproterozoic NE Australia during Nuna assembly.

Platinum-group elements in Late Quaternary high-Mg basalts of eastern Kamchatka: Evidence for minor cryptic sulfide fractionation in primitive arc magmas

The geochemical variations of magmas across and along supra-subduction zones (SSZ) have been commonly attributed to profound changes in the phase and chemical compositions of the mantle source and subduction-derived melt and fluid fluxes, as well as the physical parameters (e.g. depth, temperature, oxygen fugacity etc) of slab dehydration, mineral breakdown and melting. Here we test the variability of the Late Quaternary primitive magmas in the southern and northern parts of the meridionally oriented Eastern Volcanic Belt (EVB) of Kamchatka, with a slab depth varying from 60 to 160 km. Eight high-Mg (Mg# > 60 mol%) basalts were characterized for major, trace and platinum-group element (PGE) abundances, as well as the compositions of olivine phenocrysts and olivine-hosted spinel inclusions. The basalts in our study are geochemically typical of SSZ magmas and contain similar liquidus assemblages of forsteritic olivine (Mg# 78–92 mol%), low-Ti Cr-spinel and clinopyroxene. Although the absolute abundances of major and trace elements, and their ratios, in the basalts fluctuate to some extent, the observed variability cannot be correlated with any of considered parameters in the geometry of the Kamchatka SSZ and conditions of melting. This unexpected result led to the evaluation of the platinum-group element (PGE) systematics against the lithophile and chalcophile trace element geochemistry and the compositions of phenocrysts. Total whole-rock PGE content varies from 2.3 to 11.7 ppb, whereas the normalized PGE concentration patterns are typical for supra-subduction zones magmas and broadly similar in all studied samples. They are enriched in Rh, Pd and Pt relative to mid-ocean ridge basalts (MORB) and have nearly identical concentrations of Ir-group PGE. The only parameter that correlates well with PGE contents is the average Mg# of olivine phenocrysts from 84 to 90.3 mol%. This is interpreted to result from minor cryptic fractionation of sulfide melt, together with primitive olivine, in low-to-mid crustal conditions. Negative Ru anomalies on chondrite-normalized diagrams correspond to the Fe2+/Fe3+ ratios in spinel (a proxy for magma redox conditions), which reflects a replacement of monosulfide solid solution by laurite in the mantle wedge during oxidation.

Diffusion anisotropy of Ti in zircon and implications for Ti-in-zircon thermometry

Ti-in-zircon thermometry has become a widely used tool to determine zircon crystallization temperatures, in part due to reports of extremely sluggish Ti diffusion perpendicular to the crystallographic c-axis in this mineral. We have conducted Ti-in-zircon diffusion experiments, focusing on diffusion parallel to the c-axis, at 1 atm pressure between 1100 and 1540°C, with oxygen fugacities equivalent to air and the Ni-NiO buffer. There is no resolvable dependence of Ti diffusion in zircon upon silica or zirconia activity, or upon oxygen fugacity. The diffusion coefficient of Ti in zircon is found to be a weak function of its own concentration, spanning less than 0.5 log units across any profile induced below 1300°C. Ti diffusion in zircon, parallel to the c-axis at 1 atm pressure, is well described using:log10⁡DTi=[1.34(±1.44)−555425(±44820)Jmol−12.303RT(K)]m2s−1 where R is the gas constant in J/(mol⋅K). In conjunction with diffusion coefficients for Ti in zircon perpendicular to the c-axis reported by Cherniak and Watson (2007), strong diffusion anisotropy for Ti in zircon is observed. Diffusion parallel to the c-axis is ∼4-5 orders of magnitude faster than diffusion perpendicular to the c-axis within the experimentally constrained temperature range shared between these two studies (1540-1350°C). This difference increases if the data are extrapolated to lower temperatures and reaches ∼7.5-11 orders of magnitude between 950-600 °C, a typical range for zircon crystallization. Diffusion of Ti in natural zircons will predominantly occur parallel to the c-axis, and the Ti-in-zircon thermometer appears susceptible to diffusive modification under some crustal conditions. Temperatures calculated using this system should therefore be evaluated on a case-by-case basis, particularly when considering high-T, slowly cooled, reheated and/or small zircons.