Composition Of Crust Research Articles

The Composition of the Lower Oceanic Crust in the Wadi Khafifah Section of the Southern Samail (Oman) Ophiolite

AbstractThe composition of the intrusive gabbroic lower oceanic crust remains poorly characterized in comparison to the extrusive portion of the oceanic crust, especially for intermediate‐fast spreading mid‐ocean ridges. This is a consequence of limited exposures of extant lower oceanic crust or ophiolites similar to mid‐ocean ridge crust. One of the best analogues for mid‐ocean ridge crust is the southern Samail ophiolite that formed during a period of rapid seafloor spreading above a nascent subduction zone. Here, we focus on the geochemical stratigraphy (whole rock and mineral major and trace element compositions) of the 5,200 m‐thick, lower crustal, Wadi Khafifah section of the Wadin Tayin massif in the southern Samail (Oman) ophiolite. Gabbros from the lowermost 3,700 m of this section (the “lower gabbros”) show no systematic changes in composition with height above the Mantle Transition Zone. In contrast, gabbros from the uppermost 1,500 m (the “upper gabbros”) display marked increases in incompatible trace element concentration with increasing height. Liquids in equilibrium with the lower gabbros have major and trace element compositions that overlap with those measured in the upper gabbros and sheeted dikes. Upper gabbros preserve mineral cores with primitive major element compositions that overlap with the range of lower gabbros; however, upper gabbro whole rock compositions are significantly more enriched in incompatible trace elements relative to the lower gabbros. Our data reveal that the upper gabbros are a composite of accumulated minerals derived from primitive melts and a large fraction of evolved melts derived from the fractionation of the lower gabbros. We propose a new “Full Sheeted Sills” model for the lower oceanic crust in which primitive magmas from the mantle are emplaced throughout the lower crust and crystallized in situ. After diking events, evolved magmas leave the lower gabbros and replenish the upper gabbros, thereby contributing to the higher incompatible trace element budget in the upper gabbros relative to the lower gabbros. Our reconstructed bulk compositions of the lower plutonic crust and the bulk oceanic crust from the Wadi Khafifah section yield a plausible primary mantle‐derived magma composition in equilibrium with depleted mid‐ocean ridge basalts mantle.

Decoupling of dissolved and particulate Li isotopes during estuarine processes

Lithium isotopes in marine authigenic or detrital sedimentary archives have been recently used to trace continental weathering over geologic timescales. However, interpretations are predominantly based on the assumption that riverine Li isotopic signals can be propagated through estuaries without modification. Here, we verify this hypothesis by investigating the behaviour of Li isotopes in the Changjiang (Yangtze) River estuary. We observe a conservative mixing of dissolved Li and its isotopes between the Changjiang River water and seawater. The dissolved δ 7 Li yields a non-linear increase with salinity, and a significant increase occurs during the initial water mixing. Through the studied transect, estuarine flocculation and resuspension processes cause the homogenisation of offshore particulate δ 7 Li values, which are close to the average composition of upper continental crust. This study provides clear and direct evidence that the riverine dissolved Li isotopic signal is not modified during estuarine processes in large rivers, but caution should be exercised when using detrital δ 7 Li in marginal seas to investigate past continental weathering.

From machine learning to transfer learning in laser-induced breakdown spectroscopy analysis of rocks for Mars exploration

With the ChemCam instrument, laser-induced breakdown spectroscopy (LIBS) has successively contributed to Mars exploration by determining the elemental compositions of soils, crusts, and rocks. The American Perseverance rover and the Chinese Zhurong rover respectively landed on Mars on February 18 and May 15, 2021, further increase the number of LIBS instruments on Mars. Such an unprecedented situation requires a reinforced research effort on the methods of LIBS spectral data analysis. Although the matrix effects correspond to a general issue in LIBS, they become accentuated in the case of rock analysis for Mars exploration, because of the large variation of rock compositions leading to the chemical matrix effect, and the difference in surface physical properties between laboratory standards (in pressed powder pellet, glass or ceramic) used to establish calibration models and natural rocks encountered on Mars, leading to the physical matrix effect. The chemical matrix effect has been tackled in the ChemCam project with large sets of laboratory standards offering a good representation of various compositions of Mars rocks. The present work more specifically deals with the physical matrix effect which is still lacking a satisfactory solution. The approach consists in introducing transfer learning in LIBS data treatment. For the specific application of total alkali-silica (TAS) classification of rocks (either with a polished surface or in the raw state), the results show a significant improvement in the ability to predict of pellet-based models when trained together with suitable information from rocks in a procedure of transfer learning. The correct TAS classification rate increases from 25% for polished rocks and 33.3% for raw rocks with a machine learning model, to 83.3% with a transfer learning model for both types of rock samples.

Crustal thickness andVp/Vsvariation beneath continental China revealed by receiver function analysis

SUMMARYUsing data from 3837 seismic stations deployed in or around continental China, we construct high-resolution models of crustal thickness (H) and seismic compressional and shear velocity ratio (Vp/Vs or κ) in continental China by analysis of 150 543 receiver functions. We group the receiver functions in cells with a spatial resolution of 0.25° × 0.25° in the North–South China Seismic Belt and parts of the North China Craton, and of 0.5° × 0.5° in other regions, classify the receiver functions based on their characteristics, and develop a modified H–κ stacking method to construct models in the regions where the receiver functions are significantly affected by sedimentary basins and by Moho architecture. The inferred crustal thickness model displays an eastward thinning trend from the thickest crust (>80 km) beneath the Qiangtang Block to the thinnest crust (<26 km) beneath the southern part of the Cathaysia Block. Crustal thickness is 26–50 km in several major basins and 26–55 km in the Precambrian cratonic blocks. The inferred Vp/Vs model in the crystalline crust displays moderate-to-high values (1.75–1.85) in the southeastern margin of the Tibetan Plateau, the Tengchong volcanic field, the Emeishan large igneous province, the north-central areas of the Bohaiwan and Songliao basins, the western margin of the Taikang Hefei Basin and the southeastern margin of the Cathaysia Block. Lower values (≤1.72) characterize the major regions of the Cathaysia Block and the Jiangnan Orogenic Belt, and the hinterlands of the Ordos Block and Sichuan Basin. We discuss possible tectonic processes, secular crustal evolution and crustal compositions that are consistent with our inferred crustal thickness and Vp/Vs structure in continental China. This study establishes a framework of seismic data sharing for future studies in the seismological community in one of the first steps of developing a China Seismological Reference Model.

Seismic structure and composition of the southern central Iberian crust: The ALCUDIA wide angle seismic reflection transect

The nature of the crust beneath central Iberia was estimated by a wide-angle seismic reflection/refraction transect, ALCUDIA-WA, which sampled the southern half of the Variscan Central Iberian Zone, covered in the north by the Cenozoic Tajo Basin. The shot gathers recorded by vertical component sensors revealed well defined P- and S-wave phases. These arrivals were modeled by an iterative forward approach providing 2D crustal models showing variations in the velocity distribution with upper crustal P- and S-wave velocities increasing northwards. The lower crust P-wave velocities are homogeneous along the profile while the S-wave velocities slightly increase northwards. The Moho is placed at 32 km depth in the southern edge of the profile, deepening northward down to 35 km beneath the Tajo Basin. The Poisson's ratio, calculated from P- and S-wave velocities, varies along the profile at upper crustal depths. The highest values are located below the Mora and Pedroches batholiths. These resulting physical properties can serve to constrain the crustal composition by comparing them with laboratory measurements on rock samples. Our results suggest that the upper crust in the southern and central segments of the ALCUDIA profile is made up of low-grade metasedimentary rocks, while the northern segment is dominated by igneous rocks, in agreement with the surface geology. Separated by a sharp boundary located between 12 km (south) and 18 km (north) depth, the lower crust is more homogeneous and shows low Poisson’ ratios compatible with a rather felsic composition. However, outstanding lamination described in coincident vertical incidence data indicates some degree of intercalation with mafic components.

The Mesozoic magmatic, metamorphic, and tectonic evolution of the eastern Gangdese magmatic arc, southern Tibet

ABSTRACTMagmatic arcs are natural laboratories for studying the growth of continental crusts. The Gangdese arc, southern Tibet, is an archetypal continental magmatic arc that formed due to Mesozoic subduction of the Neo-Tethyan oceanic lithosphere; however, its formation and evolution remain controversial. In this contribution, we combine newly reported and previously published geochemical and geochronological data for Mesozoic magmatic rocks in the eastern Gangdese arc to reveal its magmatic and metamorphic histories and review its growth, thickening, and fractionation and mineralization processes. Our results show that: (1) the Gangdese arc consists of multiple Mesozoic arc-type magmatic rocks and records voluminous juvenile crustal growth. (2) The Mesozoic magmatic rocks experienced Late Cretaceous granulite-facies metamorphism and partial melting, thus producing hydrous and metallogenic element-rich migmatites that form a major component of the lower arc crust and are a potential source for the Miocene ore-hosting porphyries. (3) The Gangdese arc witnessed crustal thickening and reworking during the Middle to Late Jurassic and Late Cretaceous. (4) Crystallization-fractionation of mantle-derived magmas and partial melting of thickened juvenile lower crust induced intracrustal chemical differentiation during subduction. We suggest that the Gangdese arc underwent the following main tectonic, magmatic, and metamorphic evolution processes: normal subduction and associated mantle-derived magmatism during the Late Triassic to Jurassic; shallow subduction during the Early Cretaceous and an associated magmatic lull; and mid-oceanic ridge subduction, high-temperature metamorphism and an associated magmatic flare-up during the early Late Cretaceous, and flat subduction, high-temperature and high-pressure metamorphism, partial melting, and associated crust-derived magmatism during the late Late Cretaceous. Key issues for further research include the temporal and spatial distributions of Mesozoic magmatic rocks, the evolution of the components and compositions of arc crust over time, and the metallogenic processes that occur in such environments during subduction.

Geothermal potential and genetic mechanisms of the geothermal system in the mountainous area on the northern margin of north china

Geothermal resources as clean and renewable energy can be utilized for agriculture, tourism, and industry. The assessment of geothermal potential and the study of genetic mechanism of the geothermal system is an essential part of geothermal resource development. In this study, 16 steady-state temperature logs are obtained in the mountainous area on the northern margin of North China. Thermal conductivity and heat production rates are tested or collected from more than 200 rock samples of these wells and outcrops around the study area. Based on these data, for the first time, the detailed delineations of temperature distributions, genetic mechanisms of geothermal systems, and resource potential of Hot Dry Rock in the study area are achieved. The heat flow map indicates a low heat flow state with an average value of 53.1 mW/m2 in the study area, which is lower than the average value of 62.5 mW/m2 in mainland China. The distribution of hot springs in the area is mainly controlled by fault systems. Heat flow only exhibits a minor effect on the temperature of hot springs and geothermal wells. On this basis, the deep temperature distribution within 3–10 km depths of the study area is calculated using the one-dimensional steady-state heat conduction equation. With it, the reservoir depths of hot springs are estimated to be 3–5 km with temperatures ranging from 70°C to 110°C. Furthermore, a conceptual model for the geothermal system in the study area is derived. According to the results, Northeastern Chengde and northern Beijing exhibit the highest temperatures at all depths. Similar patterns are observed in the temperature distribution maps and the heat flow map, which suggest that the deep temperature distribution is mainly controlled by regional heat flow. With the depth increases, the temperature shows larger variation at each depth level, which is possibly caused by the heterogeneity of crustal composition. According to our resource assessment by volumetric method, the exploitable potential of Hot Dry Rock within the depth of 7–10 km of the study area is equivalent to about 3.1 × 1011 tons of standard coal, but the barrier is still existing for development under the current technical and economic conditions.

Effects of climate change and land use intensification on regional biological soil crust cover and composition in southern Africa

Biological soil crusts (biocrusts) form a regular and relevant feature in drylands, as they stabilize the soil, fix nutrients, and influence water cycling. However, biocrust forming organisms have been shown to be dramatically vulnerable to climate and land use change occurring in these regions.In this study, we used Normalized Difference Vegetation Index (NDVI) data of biocrust-dominated pixels (NDVIbiocrust) obtained from hyperspectral and LANDSAT-7 data to analyse biocrust development over time and to forecast future NDVIbiocrust development under different climate change and livestock density scenarios in southern Africa. We validated these results by analysing the occurrence and composition of biocrusts along a mesoclimatic gradient within the study region.Our results show that NDVIbiocrust, which reached maximum values of 0.2 and 0.4 in drier and wetter years, respectively, mainly depended on water availability. A predicted decrease in rainfall events according to all future climate scenarios combined with increased temperatures suggested a pronounced decrease in NDVIbiocrust by the end of the 21st century caused by reduced biocrust coverage. Livestock trampling had similar effects and exacerbated the negative impacts of climate change on biocrust coverage and composition. Data assessed in the field concurred with these results, as reduced biocrust cover and a shift from well-developed to early stages of biocrust development were observed along a gradient of decreasing precipitation and increasing temperatures and livestock density.Our study demonstrates the suitability of multi-temporal series of historical satellite images combined with high-resolution mapping data and Earth system models to identify climate change patterns and their effects on biocrust and vegetation patterns at regional scales.

Mixing of cognate magmas as a process for producing high-silica granites: Insights from Guanmenshan Complex in Liaodong Peninsula, China

Ascertaining how high-silica granites form is important for understanding why Earth has a high-silica continental crust and how the composition of the continental crust has evolved through time. This study presents a systematic dataset for the petrology, mineralogy, geochronology, and geochemistry of the granite porphyries and related microgranular enclaves and diabases from the Early Cretaceous Guanmenshan Complex (126–123 Ma) in Liaodong Peninsula, North China Craton, to reveal the complex, multi-stage, magmatic evolution in a shallow silicic magma system prior to and during emplacement of high-silica granites. Zircons from the granite porphyries and microgranular enclaves can be classified into two groups: those with dark-CL cores surrounded by light-CL rims, and those comprising entirely light-CL domains, without dark-CL cores. Our results indicate that dark-CL zircon domains with high Th (46–579 ppm), U (120–1274 ppm), and Hf (6709–12,493 ppm) contents and low Ti contents (1.52–7.85 ppm) and Ti-in-zircon temperatures (TTiZ = 622–751 °C) formed from highly evolved magmas, whereas light-CL zircon domains with low Th (14–157 ppm), U (24–236 ppm), and Hf (4749–10,474 ppm) contents and high Ti contents (7.59–29.36 ppm) and Ti-in-zircon temperatures (TTiZ = 748–885 °C) formed from low evolved magmas. These characteristics, combined with the similar UPb ages and Hf isotopic compositions of the dark-CL zircon cores and light-CL zircon domains and insignificant intra- or inter-grain (87Sr/86Sr)i variations of plagioclase from the granite porphyries and microgranular enclaves, reflect mixing between two cognate magma batches with contrasting evolved signatures. This study presents a model in which the highly evolved magmas were derived from initial interstitial melts that were extracted from a crystal mush leaving behind residual cumulates, whereas the less evolved magmas were the products of re-melting of the cognate cumulates. The diabases likely represent the mafic recharge magma that contributed necessary heat but limited mass to remobilize the cumulate mush, inducing the internal self-mixing and formation of the hybrid high-silica magmas. Feeder-dyke related emplacement of the hybrid magma generated more mafic rocks that became incorporated and dispersed into the high-silica granite porphyries as cognate microgranular enclaves. Our results lend new insights into the important role of cognate magma mixing induced by mafic recharge in generation of high-silica granites.

Crustal reworking and growth during India–Asia continental collision: Insights from early Cenozoic granitoids in the central Lhasa Terrane, Tibet

Studying granitoids can provide important knowledge on the composition of continental crust and the geodynamic processes of continental growth. Nevertheless, the mechanisms of granitoids formation during continental collision remain uncertain. In this paper, we present new zircon U–Pb–Hf isotope and whole‐rock Sr–Nd isotope compositions, and major‐ and trace‐element data for granitoids from the Chacangka area of the central Lhasa Terrane, southern Tibet. The Chacangka quartz monzonites crystallized at ca. 61 Ma, whereas the monzonites and granites were emplaced at ca. 51 Ma. The quartz monzonites are peraluminous and have high 87Sr/86Sri ratios (0.7129–0.7131), and their low εNd(t) (−7.65 to −7.10) and zircon εHf(t) (−9.3 to −7.5) values are more depleted than those of ancient crustal basement beneath the central Lhasa Terrane, which suggests that they originated from a mixed source of juvenile and ancient lower crust. Compared with the quartz monzonites, the monzonites have much higher contents of MgO (2.34–3.62 wt%) and values of Mg# (42.3–46.3) and zircon εHf(t) (−6.9 to 1.9) and show more depleted Sr–Nd isotopes, indicating that more juvenile materials were involved in their source. The granites have Sr–Nd isotope compositions that are similar to those of the coeval monzonites but have higher SiO2 contents, lower CaO and MgO contents, and lower values of Mg#, suggesting that they were differentiates of the monzonites. The elemental and isotopic compositions of the Chacangka granitoids exhibit a marked transformation from 61 to 51 Ma, probably indicating breakoff of the Neo‐Tethyan oceanic slab. The Neo‐Tethyan slab breakoff not only induced the upwelling of deep material and eruption of magma but also caused re‐melting and destruction of ancient crustal basement of the central Lhasa Terrane.

К СТРАТИГРАФИИ И ГЕОДИНАМИКЕ ЗИЛАИРСКИХ ОТЛОЖЕНИЙ НА ЮЖНОМ УРАЛЕ

It is known that the upper shell of our planet is the earth's crust, which is different in composition on the continents and in the oceans. The composition of the continental crust is predominantly sialic, and the oceanic one is simatic. The capacity of the first is within 35-70 km, the second is close to 5-12. The formation of any type of the earth's crust is determined by the participation of specific geological processes, causal relationships of matter and geodynamics, which is justified by researchers on the basis of well-proven facts and judgments. The concepts used must be specific, in accordance with well-known definitions, such as: stratigraphy is a branch of geology that studies «the formation of rocks in their primary spatial relationships», and geodynamics is «a branch of geology that studies the forces and processes in the crust, mantle and core of the Earth, deep and surface movements of masses in time and space» [1]. The use of the conceptual framework and the study of numerous facts allow us to confidently identify the sequence of connections and the reasons for the relationship.

Isotopic modelling of Archean crustal evolution from comagmatic zircon–apatite pairs

The composition of Earth's early crust is challenging to assess as only a fragmented record remains. As a consequence, deciphering the composition of early crust as a means to understand early processes on our planet often relies on the isotopic composition of resistive minerals. Here we present a new tool for investigating igneous petrogenesis and crustal evolution by combining 87Sr/86Sr measurements of apatite inclusions with U–Pb and Hf isotope analysis of their host zircon crystals. This approach takes advantage of the complementary inverse fractionation behaviour of Rb/Sr and Lu/Hf, and the cogenetic host/inclusion relationship, to link the three isotopic systems and construct an evolution model in triple isotope space. By applying this triple isotope system modelling to Mesoarchean igneous rocks from the Akia terrane in SW Greenland, we reconstruct a bulk SiO2 composition of 63-68 wt% for the precursor source crust and infer an average crustal residence time of 300–350 Ma. Our modelling implicates involvement of intermediate to felsic Paleo-Eoarchean crust in the genesis of voluminous 3.0 Ga magmatic rocks of the Akia terrane, one of the largest components of the Archean North Atlantic Craton. A further outcome of this approach is the ability to place more robust empirical constraints on the Lu/Hf ratio of the precursor crust by comparison of the modelling output to a global whole-rock dataset. The approach in this work provides a template for further application to ancient rocks in order to better understand the evolution of early Earth.

Gold in Ferromanganese Deposits from the NW Pacific

Ferromanganese crusts from four different areas of the North-West Pacific Ocean—the Detroit (northern part of the Imperial Ridge) guyot, the Zubov (Marshall Islands) guyot, the “Gummi Bear” seamount (an intraplate volcano near the Krusenstern FZ), and Belyaevsky volcano (the Sea of Japan)—were studied. Samples from the Detroit and Zubov guyots and the “Gummi Bear” seamount have similar chemical and mineral compositions of hydrogenetic cobalt-rich ferromanganese crusts. Crust from the Sea of Japan seems to reflect a hydrothermal influence. The gold content in most samples from the Detroit guyot was 68 ppb and from the Zubov guyot varied from 180 to 1390 ppb, which is higher than the average for the Pacific crusts (55 ppb). Gold content in two other samples was less than 10 ppb. Based on the electron microscopic studies, aggregation of gold particles with a size of 680 μm were identified in the Detroit guyot crust. The sizes of the Au particles are up to 10–15 μm, which has not been previously noted. Gold particles similar in morphology and size were also found in the Zubov guyot crust, which is located far from the Detroit guyot. The largest particle of gold (≈60 μm), represented by electrum, was found in the clay substrate from the “Gummi Bear” seamount. The lamellar, rudaceous morphology of the gold particles from the Detroit and Zubov guyots reflects their in situ formation, in contrast to the agglutinated, rounded with traces of dragging gold grain found in the substrate of the sample from the “Gummi Bear” seamount. Three-component (Ag-Au-Cu) gold particles were found in the hydrothermal crust from the Belyaevsky underwater volcano. Grains similar in composition were also found in Co-rich crust. The research results show that the gold was probably added to by hydrothermal fluid in the already-formed hydrogenetic ferromanganese crusts during rejuvenated volcanic stages. Biogeochemical processes may have played a major role in the formation of submicron solid-phase gold particles.

Products of an Early Cretaceous extensional mechanism in the central Great Xing'an Range: Felsic plutons in the Zhalantun area and their parental magma compositions and diagenetic processes

Late Mesozoic extensional mechanisms in the Great Xing'an Range (GXR) and relevant crust–mantle interactions are complicated, which result in widespread magmatisms with diverse parental origins and petrogenesises. In this paper, we present the lithology, whole‐rock geochemistry, and zircon U–Pb–Lu–Hf isotopes for granodiorite‐monzogranite rocks (GM) and their enclaves of quartz monzodiorites in the Zhalantun area, east of central GXR. Zircon U–Pb dating results reveal that both GM rocks and their enclaves of quartz monzodiorites yield a nearly identical crystallization age of ~125 Ma. The GM rocks exhibit weak peraluminous and high‐K calc‐alkaline compositions with high SiO2, Na2O + K2O, and Al2O3 contents, and low MgO, Mg#, Fe2O3T, and TiO2 contents, which are characterized by fractionated REE patterns, relatively strong negative Eu anomalies, enrichments of LILEs (e.g., Rb, Ba, and K), and depletions of Nb, Ta, P, and Ti. The parental origins for GM samples were juvenile crustal materials, with positive zircon εHf(t) values of +2.5 to +12.9. The whole‐rock and zircon geochemical simulations limit slightly lower GM magma crystallization temperatures (TTi‐Zrn) of 683–824°C and relatively more oxidizing conditions (log(fO2) = FMQ+7.6–FMQ‐6.8), and further confine that they were probably formed by ~10–35% degrees of fluid‐present partial melting of lower to middle crustal materials, with fractional crystallization and/or residual mineral phases of plagioclase, amphibole, clinopyroxene, and garnet. By contrast, the enclaves of quartz monzodiorites possess lower SiO2 and Na2O + K2O compositions, but higher MgO, Mg#, Fe2O3T, and TiO2 values, which are consistent with metaluminous–weak peraluminous and high‐K calc‐alkaline series. All quartz monzodiorites exhibit sub‐parallel right‐declined REE patterns, negligible to none Eu anomalies, enrichments of LILEs, and depletions of Nb, Ta, and Ti. Combined with mineral morphology and disequilibrium structures, the whole‐rock geochemical and Hf isotopic simulations imply that parental magmas for quartz monzodiorites were hybrid mixtures between ~50% host GM acid magmas and ~50% ancient crust compositions, with a wide range of zircon εHf(t) of +14.0 to −7.7, slightly higher TTi‐Zrn of 710–835°C, and lower log(fO2) of FMQ+8.2–FMQ‐10.5. Taken together, felsic plutons in the Zhalantun area correspond to an episode of extensional mechanism‐related crust–mantle interactions, which might be induced by either the Mongol‐Okhotsk domain or Palaeo‐Pacific tectonic domain, or both of them.

Constraints on the Cycling of Iron Isotopes From a Global Ocean Model.

Although iron (Fe) is a key regulator of primary production over much of the ocean, many components of the marine iron cycle are poorly constrained, which undermines our understanding of climate change impacts. In recent years, a growing number of studies (often part of GEOTRACES) have used Fe isotopic signatures (δ56Fe) to disentangle different aspects of the marine Fe cycle. Characteristic δ56Fe endmembers of external sources and assumed isotopic fractionation during biological Fe uptake or recycling have been used to estimate relative source contributions and investigate internal transformations, respectively. However, different external sources and fractionation processes often overlap and act simultaneously, complicating the interpretation of oceanic Fe isotope observations. Here we investigate the driving forces behind the marine dissolved Fe isotopic signature (δ56Fediss) distribution by incorporating Fe isotopes into the global ocean biogeochemical model PISCES. We find that distinct external source endmembers acting alongside fractionation during organic complexation and phytoplankton uptake are required to reproduce δ56Fediss observations along GEOTRACES transects. δ56Fediss distributions through the water column result from regional imbalances of remineralization and abiotic removal processes. They modify δ56Fediss directly and transfer surface ocean signals to the interior with opposing effects. Although attributing crustal compositions to sedimentary Fe sources in regions with low organic carbon fluxes improves our isotope model, δ56Fediss signals from hydrothermal or sediment sources cannot be reproduced accurately by simply adjusting δ56Fe endmember values. This highlights that additional processes must govern the exchange and/or speciation of Fe supplied by these sources to the ocean.

Prior Probability Distributions of Neutron Star Crust Models

Abstract To make best use of multifaceted astronomical and nuclear data sets, probability distributions of neutron star models that can be used to propagate errors consistently from one domain to another are required. We take steps toward a consistent model for this purpose, highlight where model inconsistencies occur, and assess the resulting model uncertainty. Using two distributions of nuclear symmetry energy parameters—one uniform, the other based on pure neutron matter theory—we prepare two ensembles of neutron star inner crust models. We use an extended Skyrme energy density functional within a compressible liquid drop model (CLDM). We fit the surface parameters of the CLDM to quantum 3D Hartree–Fock calculations of crustal nuclei. All models predict that more than 50% of the crust by mass and 15% of the crust by thickness comprises pasta with medians of around 62% and 30%, respectively. We also present 68% and 95% ranges for the crust composition as a function of density. We examine the relationships between crust–core boundary and pasta transition properties, the thickness of the pasta layers, the symmetry energy at saturation and subsaturation densities, and the neutron skins of 208Pb and 48Ca. We quantify the correlations using the maximal information coefficient, which can effectively characterize nonlinear relationships. Future measurements of neutron skins, information from nuclear masses and giant resonances, and theoretical constraints on PNM will be able to place constraints on the location of the pasta and crust–core boundaries and the amount of pasta in the crust.

ゴジラメガムリオン掘削から明らかにする背弧海盆海洋下部地殻と上部マントルの組成と構造

A significant fraction of the ocean floor is created in back-arc basins, where water plays a major role in generating back-arc basin basalts, contrasting strikingly with magmatic processes at mid-oceanic ridges. Furthermore, much of our understanding of all of the oceanic crust comes from ophiolites, which are largely attributed to supra-subduction zone environments. Therefore, studying the back-arc basin lower crust and uppermost mantle is arguably important, contributing to the overall geology of the oceanic crust. The Godzilla Megamullion, located in the extinct Parece Vela Basin in the Philippine Sea, is the largest known oceanic core complex. It is an elongated massif with a distinct corrugated surface consisting of several individual domal highs. It records the secular evolution of the mantle melting beneath a dying back-arc spreading ridge along the length of the megamullion surface. Furthermore, strong heterogeneity in the P-wave velocity structure is observed along the length of the megamullion, with a normal oceanic crust-like structure in the distal (i.e., near breakaway) to medial parts, and a shallow high-velocity body in the proximal (i.e., near termination) part. The Godzilla Megamullion should arguably be the best place in the world to study the architecture of the back-arc basin lower crust and uppermost mantle, and the actual crust/mantle boundary through the International Ocean Discovery Program (IODP). By locating three 400- to 800 m-deep drill holes along its length, key data are obtained to better understand and constrain the composition of the back-arc basin oceanic crust and uppermost mantle, as well as the architecture of oceanic core complexes. The extinct back-arc basin environment at the Godzilla Megamullion provides a further unique opportunity to explore life in an oceanic crust after extinction of its hydrothermal activity.

Nitrogen loss and isotopic fractionation during granulite-facies metamorphism in the lower crust (Ivrea Zone, NW Italy)

The Ivrea Zone, exposed in the Southern Alps, affords an examination of nitrogen mobilization and storage in deep continental crust, in rocks spanning the amphibolite to granulite facies transition and that experienced multiple devolatilization reactions and partial melting. Such information is important for considerations of whole-Earth N cycling, as continental crust is thought to contain up to ~15% of global N, much of it organic in origin and thus tied to ancient-Earth biogeochemical processes.In these rocks, N is redistributed among silicate phases during devolatilization and both H2O-saturated and dehydration melting, showing particular affinity for potassic phases such as biotite, muscovite and alkali feldspar. In metasedimentary rocks, N concentrations decrease strongly with increasing grade, from the Kinzigite Zone (amphibolite facies) with 29 to 181 μg/g to the Stronalite Zone (granulite facies) containing only 10 to 15 μg/g. The decrease in N is intermediate in magnitude to that of Cs, showing somewhat greater loss, and that of Rb that shows smaller degrees of loss. The loss of N with increasing grade is due to breakdown of biotite, which is the main mineral host of N. It also reflects a strong preference of N for the fluid during dehydration and a moderate preference of N for the melt during partial melting. Accompanying this loss of N is a shift by up to 9‰ in δ15N towards lower values. The direction of this shift contrasts with what would be expected for loss of N into fluids speciated as either N2 or NH3 and likely reflects complex isotope fractionation effects during equilibration between melt, fluid, and rock, perhaps during evolving redox conditions. The lowest δ15N values for metabasaltic rocks in this suite are near that of the mantle (−5‰) and the array of values across the traverse could represent initial protolith heterogeneities and superimposed effects of magmatic degassing of the protolith. The leucosomes broadly overlap in N concentrations and δ15N values with their host rocks and lack any systematic relationships with metamorphic grade or type of host lithology.As has been noted in previous work, estimation of the size and isotopic composition of the N reservoir in continental crust is complicated its great lithologic heterogeneity and by the paucity of data for metamorphic rocks representing greater depths. Superimposed on the lithologic heterogeneity associated with varying protoliths is the ability of highly devolatilized and partially melted deep crustal rocks to store N over long time periods. We used our new data of deep crustal rocks from the Ivrea Zone, combined with published N data and based on lithological proportions in the crust, to provide a first estimate for the N content in the middle continental crust of 56 ± 4 μg/g. For the lower continental crust, we estimate a N content of 26 ± 4 μg/g N but note that the data base of granulite-facies samples is still small. Calculation of the total continental crust N content yields 74 ± 4 μg/g, which is in between previous estimates of 56, 60 and 88 μg/g N. Finally, we estimate the N isotopic composition of the bulk continental crust as δ15N = 4.3 ± 0.5.

Zirconium isotopic composition of the upper continental crust through time

The stable isotopic composition of insoluble, refractory elements such as titanium (Ti) or zirconium (Zr), which are modified by magmatic differentiation but, a priori, are poorly affected by weathering or diagenesis, serve as powerful potential proxies to reconstruct the compositional evolution of the continental crust. Here we present the evolution of the Zr stable isotopic compositions (δ94/90ZrIPGP-Zr, per mille deviation of 94Zr/90Zr from IPGP-Zr standard) of the continental crust through time, using 38 sedimentary samples from the upper continental crust (UCC), including 12 Holocene loesses from the Chinese Loess Plateau and Xinjiang, three oceanic sediments from the sea floor outboard of the Lesser Antilles island arc and 23 glacial diamictite composites with depositional ages ranging from ∼ 2.9 Ga to 0.3 Ga from South Africa, South America, Canada, USA and China. The samples show limited Zr isotopic variations with δ94/90ZrIPGP-Zr values of 0.043‰ - 0.109‰ for loess; 0.069‰ - 0.083‰ for oceanic sediments and 0.031‰ - 0.118‰ for glacial diamictites; their Zr-weighted average values are, 0.081 ± 0.044‰ (2SD, n = 12), 0.073 ± 0.015‰ (2SD, n = 3) and 0.078 ± 0.047‰ (2SD, n = 23), respectively. The isotopic similarity among loess, oceanic sediments and glacial diamictites, suggests that zircon enrichment effects previously documented in some sedimentary samples have not biased the Zr isotope compositions of these sedimentary rocks from their source rocks. Two groups with or without Zr enrichment have similar average δ94/90ZrIPGP-Zr values (0.075 ± 0.040‰ and 0.080 ± 0.046‰). There is no correlation between Zr isotope compositions and any proxy of chemical weathering (e.g., Al2O3/SiO2, Fe2O3/SiO2, CIA, K2O/Al2O3 and δ7Li). The δ94/90ZrIPGP-Zr values are quite constant for these sedimentary samples regardless of their depositional ages and locations. Therefore, the UCC appears to have had a constant Zr isotopic composition between 3 Ga and present, and is homogeneous at a large scale. Combining data for sedimentary reference materials from the literature and the sedimentary rocks in this study, we suggest a Zr-weighted δ94/90ZrIPGP-Zr value of 0.077 ± 0.058‰ (2SD, n = 44) for the UCC, which is statistically distinct (t test, p value = 2.88 × 10−10) and higher than that of the mantle (0.040 ± 0.044‰, n = 72). Combining the δ94/90ZrIPGP-Zr values of different terrestrial reservoirs, the δ94/90ZrIPGP-Zr of the BSE and bulk Earth is constrained to be 0.041 ± 0.041‰.

Potassium isotopic composition of low-temperature altered oceanic crust and its impact on the global K cycle

To constrain the behavior of K isotopes during the low-temperature alteration of oceanic crust and reveal its impact on the global K cycle, we measured the K isotopic compositions of 49 fresh and altered basalts recovered from the Integrated Ocean Drilling Program (IODP) Sites U1365 (~100 Ma) and U1368 (~13.5 Ma) in the South Pacific Ocean. The measured basalts representing the uppermost oceanic crust have been subjected to low-temperature (<150 °C) alteration of different types and intensities as reflected by different secondary mineral modal abundances and element mobility. Both Sites have remarkably low sedimentation rates (0.71 and 1.1 m/Myr, respectively). The altered basalts from both Sites show higher K2O contents and K/Nb ratios than fresh basalts, suggesting the addition of K during low-temperature alteration. The measured δ41K values of the altered basalts vary over a large range (−0.76‰ to −0.17‰) compared to unaltered basalts, indicating significant K isotopic fractionation during low-temperature alteration of the oceanic crust. We propose that the K isotopic characteristics of the altered basalts were caused by the combined effects of equilibrium and kinetic isotopic fractionations between seawater and alteration minerals during the incorporation and adsorption of K into alteration minerals. A weighted average δ41K value of −0.40 ± 0.33‰ (2sd) is given for the low-temperature altered oceanic crust (AOC) at Sites U1365 and U1368, which is indistinguishable from the fresh N-MORB value (−0.44 ± 0.17‰), but significantly lower than its K source, i.e., seawater (δ41K = +0.12 ± 0.07‰, 2sd). Therefore, low-temperature AOC serves as an important sink for K and is a cause for the heavy K isotopic composition of seawater. In addition, the heterogeneous K isotopic compositions of the low-temperature AOC, together with large scale fractionation during various crustal processes, further highlights the utility of the K isotope system to trace subducted crustal materials.