In this paper, freezing and thawing resistance of CA mortar was investigated and some influential factors such as the ratio between asphalt emulsion and cement (A/C), cement types, various additives were also explored. Results indicated that a gain of mass was observed for every mixture after the test; mixtures with a higher A/C performed better in terms of higher relative elastic moduli. Mixtures proportioned by partially replacing ordinary Portland cement (OPC) with sulfoalumninate cement (SAC) underperformed in freezing and thawing property. Addition of crumb rubber powder (CRP), redispersible polymer powder (RPP) and organic fiber (FR) improved the resistance of CA mortar to freezing and thawing while that of silica fume (SF) undermined it.