Crude Production Research Articles

Impurities in Arylboronic Esters Induce Persistent Afterglow.

Several recent reports suggest that arylboronic esters can exhibit room temperature phosphorescence (RTP), an optical property that is desirable for applications in security printing, oxygen sensing, and bioimaging. These findings challenged the fundamental notion that heavy elements or changes in orbital symmetry were required for intersystem crossing to occur in organic compounds. As we had not observed long afterglow in the many arylboronic esters we had synthesized over many years, we suspected that the RTP observed in these systems had a simpler explanation: the materials reported were impure. Herein, we synthesized 12 arylboronic esters that were previously reported to show RTP, and carefully purified them by column chromatography, recrystallization, and sublimation. We re-examined their photophysical properties alongside single-crystal X-ray diffraction analysis and detailed theoretical studies. While 4 of the 12 compounds showed long afterglows as crude products, none of them showed persistent RTP after careful purification. We also successfully isolated the impurity 4-amino-3,5-bis(pinacolatoboryl)benzonitrile (2), identifying it as the impurity responsible for inducing delayed fluorescence in 3,5-bis(pinacolatoboryl)benzonitrile (1). Doping 1 with 1.0 mol % 2 led to a persistent afterglow with a lifetime of 67 ms, which is mediated by a dimer charge transfer state. Our findings call for a re-examination of previous studies reporting RTP from arylboronic esters, highlight the importance of careful purification in photophysical research, and provide a practical strategy for designing organic materials with a long afterglow.

Friedman Test Technique for Optimizing a Seasonal Box-Jenkins ARIMA Model Building

This study employs the Box-Jenkins methodology for time series modelling to analyze Nigerian crude oil production data. To enhance the model-building process, the Friedman rank test for seasonality was utilized. Data were sourced from the Nigerian Petroleum Corporation’s Annual Statistical Bulletin, covering the period from January 1997 to September 2014. The findings indicate that the yearly and monthly mean distributions exhibit non-constant behavior over time, implying that both natural and governmental factors significantly impact crude oil production (COP) dynamics. Consequently, a seasonal ARIMA(0,1,1) (0,1,1)12 model was fitted and deemed appropriate for the data.

Culture-Dependent Characterization of Hydrocarbon Utilizing Bacteria and Fungi from an Artisanal Crude Oil Refining Site

Crude oil refining is a global insert responsible for the production of a wide array of petroleum based products crucial for various sectors including energy, transportation, and manufacturing. However, the artisanal form of crude oil refining, often characterized by its small scale and limited technological infrastructure, has emerged as a major environmental concern in several regions around the world. Illegal refining of crude oil has led to oil spillages which in turn lead to a disruption of the microbial population of the soil. Hence, the aim of this study was to isolate and characterize the heterotrophic and hydrocarbon utilizing bacteria and fungi from an artisanal crude oil refining site. A total of thirty six (36) soil samples were collected from three (3) artisanal crude oil refining sites at iwofe, ogbogoro and ibaa community all in Rivers State, Nigeria. The samples were collected using soil auger and subjected to standard microbiological procedures such as culturing, isolation and identification. The results revealed significantly elevated levels of heterotrophic and hydrocarbon utilizing bacteria and fungi in the soil samples, with notable variations (p≤0.05) across the different artisanal crude oil refining sites. Total Heterotrophic Bacteria (THB) counts ranged from 3.75x105CFU/g in Iwofe to 2.70x105CFU/g in Ibaa, Total heterotrophic Fungal (THF) counts ranged from 2.80x104CFU/g recorded in Ogbogoro to 1.45x104CFU/g recorded in Iwofe, Hydrocarbon Utilizing Bacteria (HUB) counts ranged from 2.25x103CFU/g in Ibaa to 1.30x103CFU/g in Iwofe and Hydrocarbon Utilizing Fungi (HUF) counts ranged from 2.50x102CFU/g recorded in Ogbogoro to 1.40x102CFU/g recorded in Ibaa community with significant differences (p≤0.05). Bacteria isolated and characterized from the soil include Enterobacter, Pseudomonas putida, Serratia and Bacillus amyloliquefaciens while fungi include Fusarium, Aspergillus, Penicillium and Mucor. The microorganisms identified in this study have been reported to play key roles in the utilization of crude oil. Pseudomonas and Bacillus were the most dominant bacterial isolates and their dominance could imply that the soil could support the growth of crops. Thus, while they utilize the hydrocarbons, they also serve as plant-growth promoting microorganisms. Although some of the microorganisms in the present study have been reported to promote the growth of plant, the dumping of crude oil products legal or illegal should be minimized to avoid the extinction of plant-promoting microorganisms.

Optimal allocation of production quotas using an inverse DEA integrated with lean production capacity and negative data

In the past decade, the petroleum industry has faced two significant oil price crashes. The first occurred in 2014, driven by increased U.S. production, geopolitical shifts, and changes in OPEC policies. The more recent crash in 2020 was a consequence of the COVID-19 pandemic. Despite these secondary factors, industry experts widely attribute both crashes to excessive crude oil production. Considering this and aiming to prevent recurrences of unexpected price crashes in the future, this paper proposes a novel application of inverse DEA for optimizing OPEC production quotas. In this study, two versions of the inverse DEA are proposed − unbounded and bounded. Essentially, the unbounded model computes theoretical estimates of production quotas, while the bounded model computes practical estimates. To illustrate the applicability of the proposed models, a numerical real-world example is presented in OPEC member nations. Based on a preliminary analysis, only Algeria, Libya, Nigeria, and Venezuela were eligible for production allocations. The application of the unbounded model revealed all four nations were capable of maxing out their production quotas. For practical reasons, and in order to ensure market stability, the bounded model found out that only Libya could potentially receive a maximum allocation of 7.71%. This translates to an increase of 93 thousand barrels of oil per day for Libya. The bounded model not only averted excessive crude oil production but also curtailed hazardous waste associated with increased oil production, resulting in significant positive effects in both Libya and Venezuela. According to our findings, the unbounded model is appropriate for theoretical analysis, while the bounded model is suitable for regulatory bodies such as OPEC.

Quantitative Characterization of Surfactant Displacement Efficiency by NMR—Take the Tight Oil of Chang 8 Member of Yanchang Formation in Fuxian Area, Ordos Basin, as an Example

Surfactant flooding is a pivotal technique for enhancing oil recovery efficiency. The Chang 8 member of the Yanchang Formation in the Ordos Basin exemplifies a quintessential tight oil reservoir. Specifically, 47.9% of wells yield less than 0.1 t/d, 27.0% produce between 0.1 and 0.2 t/d, and 18.8% generate outputs ranging from 0.2 to 0.3 t/d, while only a mere 6.3% exceed production rates of over 0.3 t/d, indicating minimal efficacy of water flooding development in this context. In this study, we conducted an extensive investigation into the geological characteristics of the Yanchang 8 reservoir within the Ordos Basin, leading to the identification and evaluation of three surfactants based on their interfacial tension properties. The optimal injection concentration was determined through on-line displacement nuclear magnetic resonance imaging analysis that refined surface activity conducive to developing the Chang 8 member, ultimately resulting in increased spread volume and enhanced crude oil production from individual wells. The results indicate the following: (1) The interfacial tension of NP-10, FSD-952, and GPHQ-1 at concentrations of 0.05%, 0.1%, 0.2%, 0.3%, 0.4%, and 0.5% exhibited a pattern of initial decrease followed by an increase. The mass concentration corresponding to the minimum interfacial tension for NP-10 is identified as 0.1%, which is also the case for GPHQ-1; however, for FSD-952, this occurs at a concentration of 0.4%. Among the surface-active agents NP-10, GPHQ-1, and FSD-952, GPHQ-1 demonstrated the lowest interfacial tension value at an impressive measurement of 0.0762 mN/m. (2) When the displacement of the 0.1% GPHQ-1 surfactant reaches 10 PV, the displacement efficiency improves from 69.69% to 76.36%, representing an increase of 6.67%. The minimum pore size observed during GPHQ-1 surfactant displacement is 0.01 μm. In contrast, when the displacement of the NP-10 surfactant at a concentration of 0.1% reaches 10 PV, the efficiency rises from 68.32% to 72.02%, indicating an enhancement of 3.7%. The corresponding minimum pore size for NP-10 surfactant displacement is recorded at 0.02 μm. Furthermore, when the displacement of the FSD-952 surfactant at a concentration of 0.4% achieves 10 PV, its efficiency increases from 69.93% to 74.77%, reflecting an improvement of 4.81%. The minimum pore size associated with the activated portion of FSD-952 is noted as being approximately 0.03 μm.

Exploring the impact of financial development on energy intensity in a global study: Do levels of innovation and technology matter?

The present study aims to investigate the effect of financial development on energy intensity (EI) at different levels of innovation and technology. In addition, this study seeks to answer whether financial development affects EI and how such effect alters in the presence of varying levels of innovation and technology. To this aim, a panel smoothing transition regression (PSTR) method was used on a sample of OPEC + countries during 2000–20. Sectors of financial development affect EI at various levels of innovation and technology differently. Based on the results, the development of the banking sector and stock market increases EI to a certain level of the threshold variable (0.28 and 0.21 %, respectively), which is research and development (R&D) expenditure as a percentage of gross domestic production (GDP). Total financial development affects EI slightly differently. The above-mentioned process reduces EI up to a certain level of the threshold (0.25 %). Then, the process decreases EI more significantly. The present study aims to assess the specific effect of financial development on EI based on the level of innovation and technology. The results indicate that the behavior of the evaluated countries, which plays a significant role in proven oil reserves, crude oil production, and oil trade in the world, becomes similar to that of developed countries after reaching a certain threshold level of innovation and technology.

Penggunaan Slurry sebagai Pupuk Organik terhadap Kualitas dan Fermentabilitas Rumput Setaria (Setaria splendida Stapf) di Rumen

Biogas slurry is an organic product derived from livestock manure and produced through an aerobic fermentation process that can be used to improve soil fertility, forage production, and quality. This study aimed to investigate the effect of slurry organic fertilizer on crude protein content, crude fiber, and total fermentation gas production in the rumen in vitro . The study was conducted in a completely randomized design (CRD), consisting of five treatments of slurry levels as organic fertilizer and four replications consisting of two experimental units. The treatments consisted of S0 = without slurry, S1 = slurry 20 g/polybag, S2 = slurry 25 g/polybag, S3 = slurry 30 g/polybag, and S4 = slurry 35 g/polybag. The variables measured in this study were crude protein content, crude fiber, and total fermentation gas production. The data obtained were analyzed using a variance analysis (ANOVA). Duncan’s test was used to determine the effect of different levels of slurry on the measured parameters. The results showed that the use of slurry as an organic fertiliser increases crude protein content by an average of 16.06%, increases crude protein production from 1.47 g/poly bag to 96.38 g/poly bag and improves fermentability in the rumen by an average of 8.08% of setaria grass (Setaria splendida Stapf). The use of slurry at the level of 35 g/poly bag is recommended for the cultivation of setaria grass (Setaria splendida Stapf).

Oil biomarkers: main types, value and applications fields

Recent advances in modern chemistry provide environmental scientists with the ability to identify and track spilled oil residues in various environments. The compounds commonly used to identify the source of spilled oil are called biomarkers, they are universal in crude oil and petroleum products and are generally more stable to atmospheric environmental influences than most other oil constituents. The distribution of biomarker compounds is unique to each oil. Fingerprint indices calculated from oil fingerprints provide a stable and useful tool for determining the correspondence or non-correspondence of various oil residues present in some environmental samples. This paper highlights the main biomarkers of oil, their role in the study of oil and its deposits, and also shows the results of the authors’ own research.

Pore-scale modeling of wettability alteration coupled two-phase flow in carbonate porous media

The Middle East marine carbonate reservoirs are the primary targets for global crude oil exploration and production. In contrast to the clastic rock reservoirs, the marine carbonate reservoirs have undergone more complicated deposition, diagenesis and transformation, and the rock surface tends to be oil-wet or mixed-wet. One of the most effective methods for enhancing oil recovery in marine carbonate reservoirs is the use of an ion matched (IM)-surfactant (S) system to alter the wettability of rock surfaces. In this paper, we propose a microscale mathematical model of wettability alteration-coupled fluid flow by considering oil–water two-phase flow, wettability alteration, solute advection- diffusion and surfactant adsorption. The proposed microscale mathematical model is solved using the multi-component lattice Boltzmann model, and its accuracy is further verified. Finally, the effects of displacing fluid, ion-matched water concentration and surfactant concentration on oil mobilization at pore-scale are studied. Results show that, ion-matched water has a positive effect on wettability alteration, and typically shifts the cross-point of oil–water relative permeability curve to the right. The concentration of ion-matched water primarily affects fluid morphology of the wetting-phase and has little effect on phase permeability. After adding surfactant to the ion-matched water, the Euler coefficient of oil-phase gradually increases as the displacement continues, a large amount of remaining oil is gradually dispersed into scattered oil droplets and the oil-phase relative permeability is further improved.

Research and Application Progress of Crude Oil Demulsification Technology

The extraction and collection of crude oil will result in the formation of numerous complex emulsions, which will not only decrease crude oil production, raise the cost of extraction and storage, and worsen pipeline equipment loss, but also seriously pollute the environment because the oil in the emulsion can fill soil pores, lower the soil’s permeability to air and water, and create an oil film on the water’s surface to prevent air–water contact. At present, a variety of demulsification technologies have been developed, such as physical, chemical, biological and other new emulsion breaking techniques, but due to the large content of colloid and asphaltene in many crude oils, resulting in the increased stability of their emulsions and oil–water interfacial tension, interfacial film, interfacial charge, crude oil viscosity, dispersion, and natural surfactants have an impact on the stability of crude oil emulsions. Therefore, the development of efficient, widely applicable, and environmentally friendly demulsification technologies for crude oil emulsions remains an important research direction in the field of crude oil development and application. This paper will start from the formation, classification and hazards of crude oil emulsion, and comprehensively summarize the development and application of demulsification technologies of crude oil emulsion. The demulsification mechanism of crude oil emulsion is further analyzed, and the problems of crude oil demulsification are pointed out, so as to provide a theoretical basis and technical support for the development and application of crude oil demulsification technology in the future.

The Evaluation of Tifton 68 Production Under Irrigation and Early Nitrogenous Fertilization

Objective: To evaluate the effect of the anticipation of nitrogenous fertilization for the winter period, on dry matter production, crude protein content, handling height and productivity in the grasslands of irrigated Tifton 68 grass. Theoretical Framework: Tifton 68 use through years of thorough selection, extensive field testing and careful evaluations culminated in the development of the Tifton 68 cultivar with highly desirable characteristics such as: growth, pest resistance, abundant biomass production and important nutritional quality for the rural producer. Method: A test was conducted in the municipality of Uberlândia, Minas Gerais, for 2 years, with fertilizers carried out in weekly plots on June 21, June 28, July 05, July 12, July 19 and July 26 of the year 2021 to evaluate the performance of the cultivar Cynodon sp cv Tifton 68 with controlled release in vegetative development, as well as the impacts of this technology of sizing on its performance and productivity. Results and conclusion: Anticipation of nitrogenous fertilization in the Cynodon sp cv culture of Tifton 68 had a statistical difference for productivity (g/m²) in year 1 with the best fertilization 234 kg/ha, being the treatment that most closely approximates the result is T4. Anticipation of nitrogenous fertilization was not statistically significant for Height, dry matter content and crude protein. Implications of the research: With the results of the research, it was possible to identify the positive factors of the use of nitrogenous fertilizers in the controlled release for culture Cynodon sp cv of Tifton 68, so many in the aspects of strengthening biomass and added nutritional value in forage. Originality/value: a better understanding of the effects of the appropriate use of fertilization on the cultivar Cynodon sp cv Tifton 68, both in the biometric and productive generating economic and environmental performance in agribusiness.

Productive performance and milk composition of dairy ewes supplemented with corn silage (Zea mays L.), sunflower (Helianthus annuus) silage and their mixture.

The work reported in the Research Communication investigated in vitro rumen gas kinetics and fermentation profile as well as in vivo performance of lactating ewes fed corn silage (CS), sunflower silage (SFS) and their 50 : 50 mixture (CS-SFS). For the in vivo experiment, nine early-lactation Suffolk × Texel ewes were grouped in a replicated 3 × 3 Latin square design of three 21-d periods. Treatments were based on ad libitum CS, SFS, and CS-SFS supplemented with concentrate at 48 g/kg LW0.75. In vitro results showed that the CS had the highest dry matter degraded substrate and microbial crude protein production followed by CS-SFS. The in vivo data showed that animals fed on CS had higher digestibility of dry matter and organic matter than CS-SFS, while SFS were intermediate. Nitrogen (N) intake, fecal N excretion, and urine N excretion were similar between groups, however, milk N excretion was lower in SFS than CS. Milk yield was higher for CS and CS-SFS than SFS group, however, SFS-fed ewes had higher milk fat content than either CS or CS-SFS (all differences reported here were significant, P < 0.05 or better). Overall, CS-SFS could be used as dietary roughage for dairy ewes without deleterious effects on nutrient intake, N-balance and milk yield whilst potentially offering a more sustainable alternative to CS.

Mapping the Global Carbon Emissions of Marine Sectors.

The ocean serves as a vital ecosystem for sustaining life on earth and ensuring human well-being. Presently, there is a significant surge in global demand for various ocean-based economic activities, including fishing, shipping, offshore wind energy production, maritime tourism, and so on. However, this growth has also resulted in an increase in emissions from marine sectors, which have not been thoroughly evaluated or analyzed. It is therefore necessary to conduct comprehensive evaluations of the current emissions, covering marine sectors. To address this need, through this Perspective, we have globally analyzed and discussed carbon emissions linked to maritime transportation, marine capture fisheries, marine aquaculture, offshore wind, ocean renewables, and crude oil production. Additionally, we explored country-specific scales for these emissions and discussed points for future research to address the existing gaps. By gaining a better understanding of emissions over the oceans, policymakers could prioritize policy measures for achieving emission reduction goals and promote sustainable ocean development.

Preparation of novel nanoparticle demulsifier and its demulsification for surfactant-stabilized crude oil emulison

The application of nanoparticle (NP) demulsifiers in processing the emulsified crude oil production fluid is of great significance for improving production efficiency and reducing energy consumption in crude oil extraction. In this work, a novel NP demulsifier (PPA@KAO) was prepared by chemically modifying the mineral kaolinite (KAO) nanoparticles using γ-Methacryloyl propyltrimethoxysilane (MPS) and polyether-polyquaternium (PPA). The morphology and structure of the PPA@KAO demulsifiers were characterized by FT-IR, SEM, TG, XPS and Zeta potential. The contact angle measurements, interfacial tension (IFT) characterization, and the distribution of nanoparticles in the oil-water phase showed that PPA@KAO have good amphiphilicity and interfacial activity. The demulsification performance of PPA@KAO demulsifiers for a sodium dodecyl benzene sulfonate (SDBS) stabilized crude oil emulsion was studied with bottle method. It was found that the oil-water separation could be completed within 20 min, with a demulsification efficiency of 96.75 % at a dosage of 3 g L−1，pH of 6 and temperature of 30°C. Such a result indicates that the PPA@KAO NP demulsifier can achieve rapid and efficient demulsification for the surfactant-stabilized crude oil emulsion at room temperature. The demulsification mechanism of PPA@KAO for the SDBS-stabilized crude oil emulsion was well revealed, which provides an important synthetic strategy of how obtaining an effective NP demulsifiers by regulating the amphiphilicity and surface functional groups of the nanoparticles.

Synthesis of Hetaryl Substituted Pyrazolo[3,4-b]Quinolinone Systems by Multicomponent Cyclocondensation Reaction

In this study, the synthesis of pyrazolo[3,4-b]quinolinone compounds was carried out via one-pot three-component reactions. These reactions proceed as domino processes, making them easier to occur than the conventional multistep organic reactions. By employing this method, new organic molecules can be synthesized in a single step, using minimal time and number of trials. In the first phase of this two-step study, heteroaromatic carbaldehydes (quinoline-8-carboxaldehyde and quinoline-4-carboxaldehyde) were prepared to be used as substrates in subsequent reactions by oxidation of 8-methylquinoline and 4-methylquinoline with selenium dioxide, a mild oxidant. In the second step, heteroaromatic carbaldehyde reacted with aminopyrazole and dimedone in anhydrous ethanol by one-pot multicomponent condensation method to synthesize six new compounds with heteryl-substituted pyrazolo[3,4-b]quinolinone ring system. The crude products were obtained in excellent yields and further purified by crystallization. The structures of the compounds, which were found to be completely pure as a result of chromatographic studies, were elucidated by spectroscopic methods and elemental analysis.

MINERAL PRODUCTION AND ENVIRONMENTAL POLLUTION IN NIGERIA

This study empirically determined the effect of mineral production on environmental pollution in Nigeria from 1985 to 2022. The research utilised time series data obtained from the Central Bank of Nigeria (CBN) data bulletin and the World Development Indicators (WDI) of the World Bank. The data analysis methodologies utilised include descriptive statistical analysis, ADF Unit Root test, ARDL Bound Co-integration test, and ARDL methodology. The result of the ADF unit root test indicated the presence of a combination of stationary and non-stationary elements. That is a mixture of I(0) and I(1). Furthermore, the ARDL limits co-integration test has shown the presence of a long-term link between the variables. Finally, the ARDL estimation revealed that crude petroleum and natural gas production, likewise mining and quarrying had significant and positive implication on emission of CO2 in both long and short runs. Coal production had positively significant impact on CO2 emission in the long run but positively insignificant impact in the short run. In addition, metal ores positively and insignificantly impacted on CO2 emission in both the long and short runs. The study's results indicated that mineral mining in Nigeria resulted in a rise in environmental contamination. The report proposed that the Nigerian government should thoroughly evaluate and revise current environmental laws and regulations in order to effectively address the environmental consequences of mineral development. This should include establishing clear standards, guidelines, and permits for mining operations, waste management, pollution control, and rehabilitation of mining sites. KEYWORDS: Mineral Production, Environmental Pollution, CO2 Emission

A green and efficient synthesis of alkyl 2-((5-hydroxy-1H-pyrazole-4-carbonothioyl)thio)acetates via a one-pot, solvent-free reaction

A green and efficient synthesis of alkyl 2-((5-hydroxy-1H-pyrazole-4-carbonothioyl)thio)acetates is described. The method involves a one-pot, solvent-free reaction of pyrazolone derivatives, carbon disulfide, and alkyl bromoacetates in the presence of triethylamine. The crude products were readily purified by simple water washing followed by recrystallization from diethyl ether. The structures of the synthesized pyrazole-4-carbonothioyl-thio-acetate derivatives were confirmed by IR, 1H NMR, 13C NMR, and mass spectrometry.

FOAM ASSISTED GAS LIFT (FAGL) TECHNIQUE: LABORATORY TESTS, FIELD APPLICATION, AND EVENTUAL EFFECTS ON CRUDE OIL PROCESSING

Even though the foam assisted gas-lift (FAGL) technology is not exactly a technical innovation, curiously, it has attracted the attention of the crude oil industry in recent years. Broadly speaking, the FAGL consists in either boosting the well’s crude oil flow rate while maintaining the same gas injection rate, or, conversely, it refers to maintaining the well´s crude oil production at a reduced gas injection rate. The application of the FAGL technology to a crude oil well is simple, just demanding the dosage of a tailored crude oil foamer surfactant (“crude oil foamer”) to the Gas Lift (GL) stream. Preliminary lab tests and the data recovered from the specialized literature together with the ones derived from the still sparse FAGL field applications have shown promising results. The FAGL´s underlying philosophy, its eventual interference on the topside crude oil processing, and some other pivotal FAGL-related questions are also addressed in this technical contribution.

Mobility and Method of Enhanced Oil Recovery for Yingxiongling Shale Oil

Abstract There are abundant shale oil resources in Yingxiong Ling, Qaidam Basin, but the oil recovery rate is low due to complex lithofacies types, large physical property differences, diverse pore types and structures, and strong heterogeneity. In order to improve the oil recovery efficiency of Yingxiong Ling shale oil, based on the analysis of the factors affecting the micro-mobility of Yingxiong Ling shale oil, through spontaneous imbibition and nuclear magnetic test, the oil mobility evaluation of different lithology reservoirs and different pore structures and the feasibility of surfactant to improve oil recovery were carried out. The research results show that: (1) Yingxiong Ling shale oil has considerable mobile hydrocarbon base, effective seepage channels, high viscosity reduction conditions and elastic properties, and has the potential for efficient development. (2) In the spontaneous imbibition state, the utilization efficiency of laminar limestone and laminar limestone are 10% and 12.5%, respectively, and that of small pores, large pores and texture cracks are 6.7%, 5.2% and 1.8%, respectively. The overall utilization efficiency is low. (3) The solution containing surfactant components can effectively improve the crude oil production degree of Gan Chaigou shale oil reservoir. The variable-viscosity fracturing fluid can increase the oil production efficiency to 21.46%, and the nano-emulsion can increase the oil production efficiency to 33.43%. The surfactant has a significant effect on the EOR of Yingxiong Ling shale oil. Based on the analysis of micromobility, the characteristics of crude oil mobility and the experimental results of enhanced oil recovery by surfactants, it is concluded that the oil recovery of Yingxiong Ling shale oil can be greatly improved by combining high efficiency surfactants with large-scale volumetric fracturing.

Analytical prediction model for edge water invasion flow rate in SAGD heavy oil reservoirs

SAGD (Steam Assisted Gravity Drainage) technology is a highly developed method for the extracting heavy oil. In the Liaohe Oilfield in China, there are 72 SAGD well groups within a massive heavy oil reservoir containing edge water and the risk associated with edge water invasion is substantial. Currently, the injected steam is less than 50 m away from the edge water, which increases the urgency to address the potential invasion of edge water. If the edge water flows into the reservoir, it will impact nearly 8.0 × 105 tons of crude oil production. Recognizing the importance of mitigating the edge water invasion, this paper proposes a prediction model for the edge water invasion flow rate in SAGD reservoirs. The model integrates mass and heat transfer dynamics between the steam chamber and edge water, the relative permeabilities of oil and water phases, and the viscosity-temperature relationship of water. The model is validated through numerical simulations and field data. The findings indicate that for SAGD reservoirs with a permeability greater than 1 D, maintaining a minimum distance of 25 m between the edge water and the steam chamber is advisable, especially when the pressure differential is 0.5 MPa. Furthermore, the prediction model is used to forecast the edge water breakthrough time and evaluate water invasion risk. A prediction chart for the edge water invasion flow rate is developed, providing a practical tool for estimating invasion flow rate curves. Also, a method of edge water invasion warning is established, with a corresponding chart that offers a quick assessment of water invasion risks in heavy oil reservoirs. Overall, this research lays a foundational framework for understanding and managing the edge water invasion in SAGD operations, offering critical insights for the future study aimed at addressing the challenge posed by edge water in heavy oil reservoirs.