Cross-polarized Optical Microscopy Research Articles

Phase Behavior and Rheological Properties of Size-Fractionated MXene (Ti3C2Tx) Dispersions.

Understanding the dispersion behavior of MXenes is interesting from a fundamental colloid science perspective and critical to enabling the fluid-phase manufacturing of MXene devices with controlled microstructures and properties. However, the polydispersity, irregular shape, and charged surfaces of MXenes result in a complex phase behavior that is difficult to predict through theoretical calculations. As two-dimensional (2D) nanomaterials, MXenes can form lyotropic liquid crystal phases, gels, and aggregates. This work aims to elucidate the effects of MXene (Ti3C2Tx) sheet size on their phase behavior and associated rheological properties. Aqueous dispersions of large sheets with an average lateral dimension of 3.0 μm, small sheets with an average lateral dimension of 0.3 μm, and a bimodal mixture of the two sizes were investigated by using cross-polarized optical microscopy and rheology. At low concentrations, the large MXene dispersions exhibited lyotropic liquid crystal behavior and extended aligned textures, but increasing concentration resulted in the formation of dense flocs. Dispersions of small sheets formed small birefringent domains with increasing concentration but lacked long-range ordering. A bimodal mixture of these sizes enabled the formation of liquid crystalline phases with extended aligned textures with less floc formation. These results provide insights into using polydispersity to tune dispersion microstructure and rheological properties that can be applied to designing dispersions for fluid-phase manufacturing methods, such as direct ink writing.

Lyotropic liquid crystal phases of monoolein in protic ionic liquids.

Monoolein-based liquid crystal phases are established media that are researched for various biological applications, including drug delivery. While water is the most common solvent for self-assembly, some ionic liquids (ILs) can support lipidic self-assembly. However, currently, there is limited knowledge of IL-lipid phase behavior in ILs. In this study, the lyotropic liquid crystal phase behavior of monoolein was investigated in six protic ILs known to support amphiphile self-assembly, namely ethylammonium nitrate, ethanolammonium nitrate, ethylammonium formate, ethanolammonium formate, ethylammonium acetate, and ethanolammonium acetate. These ILs were selected to identify specific ion effects on monoolein self-assembly, specifically increasing the alkyl chain length of the cation or anion, the presence of a hydroxyl group in the cation, and varying the anion. The lyotropic liquid crystal phases with 20-80 wt. % of monoolein were characterized over a temperature range from 25 to 65 °C using synchrotron small angle x-ray scattering and cross-polarized optical microscopy. These results were used to construct partial phase diagrams of monoolein in each of the six protic ILs, with inverse hexagonal, bicontinuous cubic, and lamellar phases observed. Protic ILs containing the ethylammonium cation led to monoolein forming lamellar and bicontinuous cubic phases, while those containing the ethanolammonium cation formed inverse hexagonal and bicontinuous cubic phases. Protic ILs containing formate and acetate anions favored bicontinuous cubic phases across a broader range of protic IL concentrations than those containing the nitrate anion.

High [formula omitted]-phase PVDF films formed by uniaxial compression

Polyvinylidene fluoride (PVDF) is a semicrystalline polymer with excellent ferroelectric properties. The β crystal form has the best piezoelectric properties among its five crystal forms. Conventionally, PVDF films with a high β-phase are produced by uniaxial stretching of α-phase PVDF films. Uniaxial compression of α-PVDF samples of thickness 3.2 mm was done to obtain β-PVDF films of thickness about 100μm, with biaxial orientation. The effects of temperature and compression ratio on the compressed PVDF films were studied using Raman spectroscopy, FTIR spectroscopy and cross-polarized optical microscopy. Uniaxial compression of the α-phase PVDF sample resulted in transformation to the β-phase, accompanied by distortion of the originally present Maltese cross structures in the optical micrographs. The compressed samples exhibited β-phase fraction anisotropy along the radial and thickness directions of the sample at lower compression ratios. PVDF samples with about 80% β-phase were obtained for compression ratios more than 12 at temperatures of 60 and 90 °C.

Non-covalent planarizing interactions yield highly ordered and thermotropic liquid crystalline conjugated polymers.

Controlling the multi-level assembly and morphological properties of conjugated polymers through structural manipulation has contributed significantly to the advancement of organic electronics. In this work, a redox active conjugated polymer, TPT-TT, composed of alternating 1,4-(2-thienyl)-2,5-dialkoxyphenylene (TPT) and thienothiophene (TT) units is reported with non-covalent intramolecular S⋯O and S⋯H-C interactions that induce controlled main-chain planarity and solid-state order. As confirmed by density functional theory (DFT) calculations, these intramolecular interactions influence the main chain conformation, promoting backbone planarization, while still allowing dihedral rotations at higher kinetic energies (higher temperature), and give rise to temperature-dependent aggregation properties. Thermotropic liquid crystalline (LC) behavior is confirmed by cross-polarized optical microscopy (CPOM) and closely correlated with multiple thermal transitions observed by differential scanning calorimetry (DSC). This LC behavior allows us to develop and utilize a thermal annealing treatment that results in thin films with notable long-range order, as shown by grazing-incidence X-ray diffraction (GIXD). Specifically, we identified a first LC phase, ranging from 218 °C to 107 °C, as a nematic phase featuring preferential face-on π-π stacking and edge-on lamellar stacking exhibiting a large extent of disorder and broad orientation distribution. A second LC phase is observed from 107 °C to 48 °C, as a smectic A phase featuring sharp, highly ordered out-of-plane lamellar stacking features and sharp tilted backbone stacking peaks, while the structure of a third LC phase with a transition at 48 °C remains unclear, but resembles that of the solid state at ambient temperature. Furthermore, the significance of thermal annealing is evident in the ∼3-fold enhancement of the electrical conductivity of ferric tosylate-doped annealed films reaching 55 S cm-1. More importantly, thermally annealed TPT-TT films exhibit both a narrow distribution of charge-carrier mobilities (1.4 ± 0.1) × 10-2 cm2 V-1 s-1 along with a remarkable device yield of 100% in an organic field-effect transistor (OFET) configuration. This molecular design approach to obtain highly ordered conjugated polymers in the solid state affords a deeper understanding of how intramolecular interactions and repeat-unit symmetry impact liquid crystallinity, solution aggregation, solution to solid-state transformation, solid-state morphology, and ultimately device applications.

New optical microscopy method for determining the influence of feedstock composition on the morphology of microcarbon residue test petroleum cokes

Predicting the petroleum coke or petcoke morphology tendencies of Delayed Coking feeds is paramount to optimizing refinery operation and profitability. Herein, we report a new analytical methodology employing cross-polarized light optical microscopy (CPL-OM) of Microcarbon Residue Test (MCRT) cokes, followed by image segmentation and statistical analysis to determine several structural parameters, i.e., average area, average Feret maximum, and percentage of isochromatic domains with Feret maximum <8 μm (Feret is defined as the maximum distance between the two parallel planes of a given coke particle). Several advantages over previous CPL-OM methods include using more extensive data sets and machine-learning software to accurately segment images to yield better statistics, eliminating isochromatic domains on edge to reduce error, and stitching multiple images to account for larger domains. The new CPL-OM-image segmentation-statistical analysis procedure was effectively used to determine the influence and predict the morphology of MCRT cokes based on Delayed Coking feed properties (C7-asphaltenes percentage/MCRT percentage ratio and the asphaltene solubility parameter) and in blends of vacuum resids. The structural parameters Feret Max. Percentage <8 μm and average area showed excellent agreement within the errors of the technique. This technique represents a convenient analytical tool to qualitatively rank Delayed Coking feedstocks in terms of coke morphology tendencies.

Controlling the Structure and Morphology of Organic Nanofilaments Using External Stimuli.

In our continuing pursuit to generate, understand, and control the morphology of organic nanofilaments formed by molecules with a bent molecular shape, we here report on two bent-core molecules specifically designed to permit a phase or morphology change upon exposure to an applied electric field or irradiation with UV light. To trigger a response to an applied electric field, conformationally rigid chiral (S,S)-2,3-difluorooctyloxy side chains were introduced, and to cause a response to UV light, an azobenzene core was incorporated into one of the arms of the rigid bent core. The phase behavior as well as structure and morphology of the formed phases and nanofilaments were analyzed using differential scanning calorimetry, cross-polarized optical microscopy, circular dichroism spectropolarimetry, scanning and transmission electron microscopy, UV-vis spectrophotometry, as well as X-ray diffraction experiments. Both bent-core molecules were characterized by the coexistence of two nanoscale morphologies, specifically helical nanofilaments (HNFs) and layered nanocylinders, prior to exposure to an external stimulus and independent of the cooling rate from the isotropic liquid. The application of an electric field triggers the disappearance of crystalline nanofilaments and instead leads to the formation of a tilted smectic liquid crystal phase for the material featuring chiral difluorinated side chains, whereas irradiation with UV light results in the disappearance of the nanocylinders and the sole formation of HNFs for the azobenzene-containing material. Combined results of this experimental study reveal that in addition to controlling the rate of cooling, applied electric fields and UV irradiation can be used to expand the toolkit for structural and morphological control of suitably designed bent-core molecule-based structures at the nanoscale.

Chiral Liquid Crystal Microdroplets for Sensing Phospholipid Amphiphiles.

Designing simple, sensitive, fast, and inexpensive readout devices to detect biological molecules and biomarkers is crucial for early diagnosis and treatments. Here, we have studied the interaction of the chiral liquid crystal (CLC) and biomolecules at the liquid crystal (LC)-droplet interface. CLC droplets with high and low chirality were prepared using a microfluidic device. We explored the reconfiguration of the CLC molecules confined in droplets in the presence of 1,2-diauroyl-sn-glycero3-phosphatidylcholine (DLPC) phospholipid. Cross-polarized optical microscopy and spectrometry techniques were employed to monitor the effect of droplet size and DLPC concentration on the structural reorganization of the CLC molecules. Our results showed that in the presence of DLPC, the chiral LC droplets transition from planar to homeotropic ordering through a multistage molecular reorientation. However, this reconfiguration process in the low-chirality droplets happened three times faster than in high-chirality ones. Applying spectrometry and image analysis, we found that the change in the chiral droplets’ Bragg reflection can be correlated with the CLC–DLPC interactions.

Real-time liquid crystal-based creatinine sensor using a micro-patterned flexible substrate

ABSTRACT We propose a novel, simple, cost-effective sensor based on orientational transitions of nematic liquid crystals (LC) for real-time, quantitative, and sensitive detection of creatinine. A micro-well array structure on a polydimethylsiloxane (PDMS) substrate was fabricated to replace traditional copper grids stabilising a thin LC film, which contains 4-cyano-4ʹ-pentylbiphenyl (5CB) LC material and 4ʹ-hexylbiphenyl-4-carboxylic acid (HBA). The principle of the sensor is based on the ordering transition of LCs induced by enzymatic reactions of creatinine and creatinine deaminase (CD), resulting in an optical signal change. The orientational response of LCs was quantitatively monitored in the presence of different amounts of creatinine by cross-polarised optical microscopy and light transmittance measurement system in real time. Concentrations from 50 to 1100 μM of creatinine were successfully detected.

Mechanisms of Directional Polymer Crystallization.

Zone annealing, a directional crystallization technique originally used for the purification of semiconductors, is applied here to crystalline polymers. Tight control over the final lamellar orientation and thickness of semicrystalline polymers can be obtained by directionally solidifying the material under optimal conditions. It has previously been postulated by Lovinger and Gryte that, at steady state, the crystal growth rate of a polymer undergoing zone annealing is equal to the velocity at which the sample is drawn through the temperature gradient. These researchers further implied that directional crystallization only occurs below a critical velocity, when crystal growth rate dominates over nucleation. Here, we perform an analysis of small-angle X-ray scattering, differential scanning calorimetry, and cross-polarized optical microscopy of zone-annealed poly(ethylene oxide) to examine these conjectures. Our long period data validate the steady-state ansatz, while an analysis of Herman’s orientation function confirms the existence of a transitional region around a critical velocity, vcrit, where there is a coexistence of oriented and isotropic domains. Below vcrit, directional crystallization is achieved, while above vcrit, the mechanism more closely resembles that of conventional isotropic isothermal crystallization.

Process-related Changes in Polyetherimide Joined by Friction-based Injection Clinching Joining (F-ICJ).

This work presents a comprehensive study on the effects of the Friction-based Injection Clinching Joining (F-ICJ) process on the microstructure and local properties of the stake head. The manuscript evaluates the consequences on the quasi-static mechanical performance of hybrid joints of amorphous polyetherimide (PEI) with aluminium AA6082. Through an overlay of microhardness map on a cross-polarized transmitted-light optical microscopy (CP-TLOM) image, two lower-strength microstructural zones in the PEI stake head were observed: a plastically-deformed zone (PDZ) and a thermo-mechanically-affected zone (PTMAZ). When compared to the base material, PDZ and PTMAZ have a reduction of 12%–16% and 8%–12%, respectively, in local mechanical properties. The reduced local strength was associated with distinct volumes of loosely packed PEI chains with unsteady chain conformation and thus larger free volume in the affected regions. The mechanical strength reduction is reversible through physical aging by thermal annealing the joints, which additionally shows that process-induced thermomechanical degradation of PEI by chain scission, as evidenced by size exclusion chromatography (SEC) analysis, does not appear to affect local mechanical strength. An evaluation of typical loading regimes of staked joints in lap shear (average ultimate force of 1419 ± 43 N) and cross tensile (average ultimate force of 430 ± 44 N) testing indicates that the process-induced changes of PEI do not compromise the global mechanical performance of such a structure. These findings provide a better understanding of the relationships between processing, microstructure, and properties for further F-ICJ process optimization.

Lyotropic liquid crystal phase behavior of a cationic amphiphile in aqueous and non-stoichiometric protic ionic liquid mixtures.

Protic ionic liquids (PILs) are the largest and most tailorable known class of non-aqueous solvents which possess the ability to support amphiphile self-assembly. However, little is known about the effect of solvent additives on this ability. In this study, the lyotropic liquid crystal phase (LLCP) behavior of the cationic surfactant cetyltrimethylammonium bromide (CTAB) was investigated in the model PILs of ethylammonium nitrate (EAN) and ethanolammonium nitrate (EtAN), and derived multi-component solvent systems containing them to determine phase formation and diversity with changing solvent composition. The solvent systems were composed of water, nitric acid and ethylamine (or ethanolamine), with 26 unique compositions for each PIL covering the apparent pH and ionicity ranges of 0-13.5 and 0-11 M, respectively. The LLCPs were studied using cross polarized optical microscopy (CPOM) and small and wide-angle X-ray scattering (SAXS/WAXS). Partial phase diagrams were constructed for CTAB concentrations of 50 wt% and 70 wt% in the temperature range of 25 °C to 75 °C to characterise the effect of surfactant concentration and temperature on the LLCPs in each solvent environment. Normal micellar (L1), hexagonal (H1) and bicontinuous cubic (V1) phases were identified at both surfactant concentrations, and from temperatures as low as 35 °C, with large variations dependent on the solvent composition. The thermal stability and diversity of phases were greater and broader in solvent compositions with excess precursor amines present compared to those in the neat PILs. In acid-rich solvent combinations, the same phase diversity was found, though with reduced onset temperatures of phase formation; however, some structural changes were observed which were attributed to oxidation/decomposition of CTAB in a nitric acid environment. This study showed that the ability of PIL solutions to support amphiphile self-assembly can readily be tuned, and that the ability of PILs to promote amphiphile self-assembly is robust, even with other solvent species present.

Predicting coke morphology in Delayed Coking from feed characteristics

Currently, there is no well-established methodology to predict coke morphology in Delayed Coking from feed characteristics. We found that for a series of fourteen coking feeds from different parts of the world, coke morphology and shot-coke propensity can be predicted by determining the asphaltene solubility parameter using the asphaltene solubility profile method without further separation and in ~25 min runs. The results are attributed to asphaltenes with higher solubility parameters that favor phase separation from the hydrocarbon matrix and lead to shot coke formation. Similarly, asphaltene peptizability measured by flocculation onset, ΔPS stability parameter determined by asphaltene solubility profile, and surface area measurements of MCRT cokes showed good potential for predicting coke morphology and shot-coke tendency of coking feeds. Conversely, mean particle size measured by cross-polarized light optical microscopy of the MCRT cokes showed a relatively large dispersion of the data and a weak correlation with the shot-coke propensity. Finally, a general scheme for the formation of shot and sponge cokes during Delayed Coking was proposed.

Liquid crystal alignment properties on surface-reformed solution-derived lanthanum-doped zinc oxide films

ABSTRACTLiquid crystal (LC) alignment characteristics were investigated using a solution-derived lanthanum-doped zinc oxide (La:ZnO) film that was exposed to various intensities of ion-beam (IB) irradiation. At an IB intensity of 1700 eV, uniform and homogeneous LC alignment was achieved, as revealed by cross-polarized optical microscopy and pre-tilt angle measurement. Field-emission scanning electron microscopy (FE-SEM), atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS) were used to verify that the IB irradiation induced physical and chemical surface reformation of the La:ZnO film that relate to LC alignment. FE-SEM and AFM revealed that the IB irradiation reformed the existing surface structure into a new structure with an altered surface roughness. The XPS results showed that the van der Waals force with anchoring energy increased as the IB intensity increased, and this profoundly affected the state of LC alignment. The capacitance-voltage (C-V) hysteresis curve was measured as a function of IB intensity to characterize the accumulated charge as a residual DC. Nearly zero C-V hysteresis was achieved at an IB intensity of 1700 eV. Therefore, a solution-derived La:ZnO film with an IB intensity of 1700 eV has great potential for high-quality LC applications.

Transparent and Homogenous Cellulose Nanocrystal/Lignin UV-Protection Films.

In the context of valorization of lignin produced from the pulp and paper industries, biodegradable UV-protection films were prepared using lignin and cellulose nanocrystals (CNCs). Initially, CNC films were optimized for improving their transparency by studying the effect of various sodium hydroxide (NaOH) concentrations. Maximum (%) transmittance of CNC film was obtained for NaOH addition between 3 and 4 wt %. The optimized CNC suspensions were used for incorporating alkaline lignin (AL) and softwood kraft lignin (SKL) in various concentrations (1–10 wt %). Morphological characterization showed homogeneity of the lignin distribution in CNC/lignin films. Complete UV blocking was achieved at 10 wt % lignin (AL or SKL) in CNC films. Cross-polarized optical microscopy and scanning electron microscopic images of films showed some degrees of global alignment of CNC rods upon addition of NaOH, which remained unaffected by lignin addition. Lignin modification through acetylation reduced the lignin color and improved visible light transmission of films without significantly affecting the UV-absorption properties. Presence of lignin also enhanced the thermal and contact angle stability of the films. This work shows for the first time that CNC aqueous suspensions with and without containing lignin could be tuned through the addition of NaOH to produce transparent and homogenous films, providing a simple and green approach in engineering CNC/lignin UV-protection films.

Liquid Crystalline Nanostructures as PEGylated Reservoirs of Omega-3 Polyunsaturated Fatty Acids: Structural Insights toward Delivery Formulations against Neurodegenerative Disorders.

Omega-3 polyunsaturated fatty acids (ω-3 PUFAs) are bioactive lipids with considerable impact in medicine and nutrition. These compounds exert structuring effects on the cellular membrane organization, regulate the gene expression, and modulate various signaling cascades and metabolic processes. The purpose of the present work is to demonstrate the structural features of ω-3 PUFA-containing three-dimensional supramolecular lipid assemblies suitable for pharmaceutical applications that require soft porous carriers. We investigate the liquid crystalline structures formed upon mixing of eicosapentaenoic acid (EPA, 20:5) with the lyotropic nonlamellar lipid monoolein and the formation of multicompartment assemblies. Starting with the monoolein-based lipid cubic phase, double membrane vesicles, cubosome precursors, sponge-type particles (spongosomes), mixed intermediate nonlamellar structures, and multicompartment assemblies are obtained through self-assembly at different amphiphilic compositions. The dispersions containing spongosomes as well as nanocarriers with oil and vesicular compartments are stabilized by PEGylation of the lipid/water interfaces using a phospholipid with a poly(ethylene glycol) chain. The microstructures of the bulk mixtures were examined by cross-polarized light optical microscopy. The dispersed liquid crystalline structures and intermediate states were studied by small-angle X-ray scattering, cryogenic transmission electron microscopy, and quasielastic light scattering techniques. They established that PUFA influences the phase type and the sizes of the aqueous compartments of the liquid crystalline carriers. The resulting multicompartment systems and stealth nanosponges may serve as mesoporous reservoirs for coencapsulation of ω-3 PUFA (e.g., EPA) with water-insoluble drugs and hydrophilic macromolecules toward development of combination treatment strategies of neurodegenerative and other diseases.

Tuning charge carrier transport and optical birefringence in liquid-crystalline thin films: A new design space for organic light-emitting diodes

Liquid-crystalline organic semiconductors exhibit unique properties that make them highly interesting for organic optoelectronic applications. Their optical and electrical anisotropies and the possibility to control the alignment of the liquid-crystalline semiconductor allow not only to optimize charge carrier transport, but to tune the optical property of organic thin-film devices as well. In this study, the molecular orientation in a liquid-crystalline semiconductor film is tuned by a novel blading process as well as by different annealing protocols. The altered alignment is verified by cross-polarized optical microscopy and spectroscopic ellipsometry. It is shown that a change in alignment of the liquid-crystalline semiconductor improves charge transport in single charge carrier devices profoundly. Comparing the current-voltage characteristics of single charge carrier devices with simulations shows an excellent agreement and from this an in-depth understanding of single charge carrier transport in two-terminal devices is obtained. Finally, p-i-n type organic light-emitting diodes (OLEDs) compatible with vacuum processing techniques used in state-of-the-art OLEDs are demonstrated employing liquid-crystalline host matrix in the emission layer.

How ionic species structure influences phase structure and transitions from protic ionic liquids to liquid crystals to crystals.

The phase behaviour of n-alkylammonium (C6 to C16) nitrates and formates has been characterised using synchrotron small angle and wide angle X-ray scattering (SAXS/WAXS), differential scanning calorimetry (DSC), cross polarised optical microscopy (CPOM) and Fourier transform infrared spectroscopy (FTIR). The protic salts may exist as crystalline, liquid crystalline or ionic liquid materials depending on the alkyl chain length and temperature. n-Alkylammonium nitrates with n ≥ 6 form thermotropic liquid crystalline (LC) lamellar phases, whereas n ≥ 8 was required for the formate series to form this LC phase. The protic ionic liquid phase showed an intermediate length scale nanostructure resulting from the segregation of the polar and nonpolar components of the ionic liquid. This segregation was enhanced for longer n-alkyl chains, with a corresponding increase in the correlation length scale. The crystalline and liquid crystalline phases were both lamellar. Phase transition temperatures, lamellar d-spacings, and liquid correlation lengths for the n-alkylammonium nitrates and formates were compared with those for n-alkylammonium chlorides and n-alkylamines. Plateau regions in the liquid crystalline to liquid phase transition temperatures as a function of n for the n-alkylammonium nitrates and formates are consistent with hydrogen-bonding and cation-anion interactions between the ionic species dominating alkyl chain-chain van der Waals interactions, with the exception of the mid chained hexyl- and heptylammonium formates. The d-spacings of the lamellar phases for both the n-alkylammonium nitrates and formates were consistent with an increase in chain-chain layer interdigitation within the bilayer-based lamellae with increasing alkyl chain length, and they were comparable to the n-alkylammonium chlorides.

Liquid crystal aligning capabilities on surface-reformed indium-doped zinc oxide films via ion-beam exposure

ABSTRACTWe investigated the characteristics of a solution-processed indium-doped zinc oxide (In:ZnO) film formed via ion-beam (IB) irradiation as a liquid crystal (LC) alignment layer. The In:ZnO film was deposited using solution processing and cured at various temperatures. Uniform LC alignment was observed at all curing temperatures in cross-polarised optical microscopy images. A regular pre-tilt angle supported these results and showed homogeneous LC alignment. Several surface analyses were conducted to evaluate the effect of IB irradiation on the In:ZnO film surface. X-ray diffraction analysis showed an amorphous structure both before and after IB irradiation, and physical surface reformation was observed using atomic force microscopy. Root mean square surface roughness was reduced and a smooth surface was achieved after IB irradiation. X-ray photoelectron spectroscopy was used to detect chemical surface reformation. It was found that the IB irradiation broke the metal-oxide bonds and increased the occurrence of oxygen vacancies, which affected the van der Waals forces between the LC molecules and the In:ZnO film surface. Electrical performance was observed to identify the possibility of using the In:ZnO film in LC applications. Enhanced electro-optical performance was measured and zero residual DC voltage which was verified using a capacitance-voltage curve was achieved.

Self-Assembled Microwires of Terephthalic Acid and Melamine

Self-assembled microwires of terephthalic acid (TPA) and melamine are prepared through the evaporation of water in a solution mixture of TPA and melamine. The microwires were characterized by using scanning electron microscope (SEM), attenuated total reflection infrared (ATR-IR) spectra, and cross-polarized optical microscopy (CPOM). The TPA•M microwires showed semi-conductive properties.

Free residual DC voltage for nematic liquid crystals on solution-derived lanthanum tin oxide film

ABSTRACTWe present the liquid crystal (LC) alignment properties of solution-derived lanthanum tin oxide (LaSnO) films cured at various temperatures and exposed to ion-beam (IB) irradiation. Using a solution process, LaSnO films were deposited on the indium-tin-oxide glass substrates and IB irradiation was used as an alignment method. Homogeneous and uniform LC alignment was achieved and observed by cross-polarised optical microscopy. Pre-tilt angle results with low standard deviation supported the notion of uniform LC alignment. The LaSnO film cured at 300°C showed nearly zero capacitance–voltage hysteresis. The change of the surface morphology of the LaSnO film due to IB irradiation was observed by atomic force microscopy. The effects of IB irradiation on the LC alignment layer were further demonstrated by X-ray photoelectron spectroscopy. The strong IB irradiation broke the metal–oxide bonds present, which in turn induced an increased number of oxygen vacancies on the whole surface. Uniform LC alignment was attributed to surface reformation and van der Waals forces.