Miniaturization of mechanical structures offers excellent performances of the device while has brought problems of fracture at nanoscale. However, whether the classical fracture theory is applicable at such a small scale and what is its low limit are still challenging problems. In this paper, by conducting atomistic simulation of graphene and compared with the reported in-situ experiments, the applicable range of distance from crack tip for crack-tip stress distribution models and the low limit of crack length for fracture criterion are investigated. It is found that all crack-tip stress models are invalid within fracture process zone whose dimension is 2.5 Å away from crack tip. The energy-based fracture criteria are not applicable when the crack length is less than 8 nm due to the nonlinear stress–strain relationship, while the modified Griffith criterion can be applied to low limit of crack length 5 Å. For the stress-based fracture criterion, the stress intensity factor criterion fails when the crack length is less than 8 nm due to the decreasing size of critical K-dominant zone ΛK, while the theory of critical distances and quantized fracture mechanics can accurately predict the critical fracture stress regardless of the crack length, which can be unified by a non-local stress criterion. This work will provide a mechanical basis for the reliable application of the microelectronic devices at nanoscale.
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