Valles Marineris is a unique vertical section through the uppermost kilometers of the martian crust. Its location, east of the Tharsis bulge, and its water-related history, fuel a great diversity of rock types in this area (Carr, M.H., Head, J.W. [2010]. Earth Planet. Sci. Lett. 294, 185–203). HiRISE and CRISM data available over the walls of the canyon were analyzed to infer the importance of magmatic and sedimentary processes through time. This contribution provides a complete morphologic and mineralogic characterization of the cross-section of rocks exposed in the canyon walls. Low-calcium pyroxene and olivine are detected in the lower portion of the walls, in association with morphologically distinct outcrops, leading to the idea that pristine Noachian crust might be exposed. Phyllosilicates are also present within the walls, but they appear to correspond to an alteration product. No proper sedimentary layers were observed within the walls of Valles Marineris at the resolution available today. All these detections are limited to the eastern portion of Valles Marineris, especially Juventae, Coprates, Capri, and Ganges chasmata. Preserved Noachian crustal material is rare on the martian surface and is rarely exposed in its pristine geologic context. Such detections lend precious information about early igneous processes. This survey also supports observations from the nearby impact crater central peaks (Quantin, C., Flahaut, J., Allemand, P. [2009]. Lunar Planet. Sci. 10; Quantin, C., Flahaut, J., Clenet, H., Allemand, P., Thomas, P. [2011]. Icarus, submitted for publication) and suggests that the western part of Valles Marineris may be cut into another material, consistent with lavas or volcanic sediments.
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