The aim of this research is to investigate the influence of nickel alloy type from the same group, the parameters of flame spraying, as well as the preparation of the substrate and the heat treatments of the substrate on the microstructure of the coating/substrate system. Due to the possibility of applying nickel alloys in corrective maintenance of tools used on elevated working temperatures, hot work tool steel X38CrMoV5-1 was selected as a substrate material. The investigation of the microstructure of the coating/substrate system was carried out according to the factorial design of experiment, where the input factors were varied on two levels. The factors that were varied are: Ni based self-fluxing alloys - NiCrBSi and NiBSi; distance of the burner from the workpiece - small (6 mm) and large (20 mm); preparation of the substrate - roughened and non roughened and the heat treatments of the substrate - soft annealed and tempered condition. Ni-based self-fluxing alloys were applied on samples (12,5 × 25 × 25 mm) by flame spraying with simultaneous fusing process. Analysis of the microstructures of the coating/substrate system was carried out on the Leica DM 2500M light microscope. After the conducted analysis the paper concluded that by spraying the selected coatings onto the X38CrMoV5-1 tool steel base, poor quality coatings are obtained, due to the appearance of cracks (NiCrBSi) or separation of the coating from the substrate (NiBSi). This is attributed to the formation of martensitic structure of the substrate after spraying and the presence of residual stresses.
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