A comprehensive 3D imaging analysis was conducted to investigate the corrosion process in reinforced concrete (RC) samples at various stages of the accelerated galvanostatic corrosion process. A state-of-the-art X-ray computed tomography (CT) scan technology was utilized to collect high-resolution 3D images of the specimen. The CT imaging was complemented and validated using a multi-faceted approach utilizing Scanning electron microscopy (SEM) and Raman spectrometry techniques. The distribution and evolution of voids, corrosion products, and cracks were investigated. A localized corrosion was observed that has some similarity to pitted corrosion but not as wide spread along the bar. The micro-scale imaging investigations revealed a gradual increase in the diameter of voids as the time of corrosion increased, especially after 8 days of accelerated corrosion process at which a significant decrease in small-sized voids (≤0.11 mm) accompanied by an increase in other void sizes was observed. At 10 and 12 days of accelerated corrosion process, the volume of larger-sized voids (≥0.35 mm) continued to increase, indicating a rapid corrosion progress and the formation of corrosion-induced cracks. In addition, a thorough X-ray CT analysis allowed us to differentiate between various categories of corrosion products. Notably, iron oxides and iron hydroxides were found to dominate the corrosion products. Understanding the composition and distribution of these corrosion products is essential as they play a significant role in the degradation and deterioration of the concrete structure. The coexistence of iron oxides and iron hydroxides in the region of corrosion products were confirmed using Raman spectroscopy analysis. The CT scan images captured the evolution of cracks at different time intervals, revealing a strong correlation between the initiation of cracks and the presence of corrosion products. Subsequently, during the cracking in the matrix, while the propagation of corrosion products within the matrix contributed to the expansion of cracks. SEM images and elemental analysis confirmed that these cracks were filled with corrosion products.