Cr Values Research Articles

Source apportionment and risk assessment of soil heavy metals in the Huangshui River Basin using a hybrid model

Source apportionment and risk assessment of soil heavy metals (HMs) are essential for pollution control. However, inherent limitations in receptor models hinder accurate source apportionment, impacting outcomes of source-oriented risk assessment. A hybrid model was employed by combining two receptor models, absolute principal component score/multiple linear regression (APCS/MLR) and positive matrix factorization (PMF) models. Four primary pollution sources were identified, followed by an assessment of source-oriented environmental and human health risks in the Huangshui River Basin. Results revealed that Cr, Cd, and Ni average concentrations surpassed their background by 3.1, 2.1, and 1.9 times, respectively. Additionally, 54.29%, 13.34%, and 18.09% of Igeo values for Cr, Cd, and Ni were classified as “moderately contamination” or higher. Natural sources significantly influence Cu (90.2%) and As (71.4%). Cr (63.4%) and Ni (77.9%) mainly originated from agriculture and industry, respectively. Transportation sources emerged as the primary contributors to Pb (59.6%), Zn (48.6%), and Cd (47.2%). The environmental risk level in this study area remained acceptable. Ecological risk was mainly attributed to industrial activities (46.6%) and transportation (37.6%), with Cd being the predominant metal responsible for this risk. Although the noncarcinogenic risk was negligible for all populations, the carcinogenic risk demands attention, particularly concerning children. Industrial sources (67.0%) and Ni were identified as the main contributors to the carcinogenic risk. This study represents an attempt to develop a hybrid model, providing an effective approach to combine models for the accurate apportionment of pollution sources and the reduction of risks.

Evaluation of clinical and laboratory parameters of patients with the diagnosis of upper gastrointestinal system bleeding

Aims: In this study, it was purposed to evaluate demographic, clinical, laboratory characteristics, bleeding etiologies, risk factors, comorbidity and mortality of the patients who were interned with the diagnosis of upper gastrointestinal system bleeding. Methods: In this study, 157 patients those hospitalized to Ministry of Health Beyoğlu Public Hospitals Association Gaziosmanpaşa Taksim Training and Research Hospital Internal Medicine Clinic with the diagnosis of upper gastrointestinal bleeding between 1 April 2014 and 1 April 2015 were evaluated retrospectively. Age, gender, duration of hospitalization, comorbidity, prescription story, need and amount of transfusion, endoscopic findings, hemoglobin (Hgb), blood urea nitrogen (BUN), urea, creatinine (Cr) values on admission, complication and mortality data were recorded. IBM SPSS (Statistical Package for Social Sciences) for MAC 21.0 program was used for statistical analysis in order to evaluate the data. Results: Patient were aged between 17 and 94 .The mean age was 59.04±20.55. 95 (68.35%) of patients were male and 44 (31.65%) were female with the male/female ratio of 2.15/1. While 64.75% of the patients in our study had at least one additional disease, no additional disease was detected in 35.25%. Endoscopic procedure was peformed 89.93% of patients for both diagnosis and treatment. Exitus was seen in 7 patients and mortality was detected as 5.04%. Median age of deceased patients was 75.28±15.39. Median age of surviving patients was 58.18±20.47. Conclusion: Our study revealed that upper GI bleeding is an important cause of mortality and morbidity despite advanced treatment options and intensive care conditions. The most important risk factors responsible for mortality are advanced age and the presence of comorbidities, as seen in our study.

Intelligent visually lossless compression of dental images

Background: Tendencies to increase the mean size of dental images and the number of images acquired daily makes necessary their compression for efficient storage and transferring via communication lines in telemedicine and other applications. To be a proper solution, lossy compression techniques have to provide a visually lossless option (mode) where a desired quality (invisibility of introduced distortions for preserving diagnostically valuable information) is ensured quickly and reliably simultaneously with a rather large compression ratio.Objective: Within such an approach, our goal is to give answers to several practical questions such as what encoder to use, how to set its parameter that controls compression, how to verify that we have reached our ultimate goal, what are additional advantages and drawbacks of a given coder, and so on.Methods: We analyze the performance characteristics of several encoders mainly based on discrete cosine transform for a set of 512 × 512 pixel fragments of larger size dental images produced by Morita and Dentsply Sirona imaging systems. To control the visual quality of compressed images and the invisibility of introduced distortions, we have used modern visual quality metrics and distortion invisibility thresholds established for them in previous experiments. Besides, we have also studied the so-called just noticeable distortions (JND) concept, namely, the approach based on the first JND point when the difference between an image subject to compression and its compressed version starts to appear.Results: The rate-distortion dependences and coder setting parameters obtained for the considered approaches are compared. The values of the parameters that control compression (PCC) have been determined. The ranges of the provided values of compression ratio have been estimated and compared. It is shown that the provided CR values vary from about 20 to almost 70 for modern coders and almost noise-free images that is significantly better than for JPEG. For images with visible noise, the minimal and maximal values of produced CR are smaller than for the almost noise-free images. We also present the results of the verification of compressed image quality by specialists (professional dentists).Conclusion: It is shown that it is possible and easy to carry out visually lossless compression of dental images using the proposed approaches with providing quite high compression ratios without loss of data diagnostic value.

Ecological and human health hazards of soil heavy metals after wildfire: A case study of Liangshan Yi autonomous prefecture, China

Soil samples were collected in at different depths from the conflagration area in Liangshan Yi Autonomous Region, China, to investigate the distribution characteristics and ecological and human health risks of heavy metals after a wildfire. The samples collected comprise wildfire ash (WA) above the soil surface, ash soil (AS) 0–5 cm, and plain soil (PS) 5–15 cm below the soil surface. Additionally, reference soil (RS) was collected from a nearby unburned area at the same latitude as the conflagration area. The results showed that the concentrations of zinc (Zn), copper (Cu), lead (Pb), and cadmium (Cd) in the WA and AS were significantly higher than in reference soil (RS) (p < 0.05). Concentrations of Pb in the PS were 2.52 times higher than that in RS (17.9 mg kg−1) (p < 0.05). The AS and WA had the highest Index of potential ecological risks (RI > 600). In addition, The Cd in AS and WA contributed the most to the highest Improved nemerow index (INI) and RI with a contribution of more than 80%. The concentration of heavy metals was used to establish non-carcinogenic effects and cancer risks in humans via three exposure pathways: accident ingestion of soil, dermal contact with soil, and inhalation of soil particles. Hazard index (HI) values of each sample were all less than 1, indicating the non-carcinogenic risk was within the acceptable range and would not adversely affect the local population's health. The Cancer risk (CR) values of Cr, As, Cd, and Ni were all below 1 × 10−6, indicating that heavy metal pollution from this wildfire did not pose a cancer risk to residents.

Stock Performance Analysis of PT. Kalbe Farma TBK (KLBF) in 2016-2020

When the World Health Organization (WHO) announced that COVID-19 was upgraded to pandemic status, investors began to reconsider their portfolio structure from risky assets such as stocks to gold. This study aims to determine the stock performance of PT. Kalbe Farma Tbk during the COVID-19 pandemic. A quantitative descriptive approach by linking company financial statement data with the phenomenon of the COVID-19 pandemic is the method used in this study. Based on the results of the research that has been done, it can be concluded that the performance of PT. Kalbe Farma Tbk before and during the COVID-19 pandemic on the dependent variable (stock return), namely the Current ratio, had a significant effect on Stock Return. However, based on the results of hypothesis testing regarding the effect of Earnings Per Share and Net profit margin on Stock Return partially, it can be concluded that these variables do not have a significant effect on Stock Return. Based on the conclusions above, the researcher recommends that the first company is expected to make the value of CR better in order to attract investors in investing their funds. Because if the company has a high CR value then the company can be said to have no constraints to pay its debts, thus many investors will be interested in investing in pharmaceutical sector companies and that can be very profitable for the company. Next is advice for those who want to invest in pharmaceutical companies, it is recommended to look at the CR owned by the company if investors want to make long-term investments.

Developing a psychological care competences framework for nurses in China: a mixed methods study

BackgroundWith social transformation, rapid economic development and deepening awareness of psychological health in China, people’s demand for psychological health services is becoming increasingly urgent. A key challenge for Chinese medical organizations is to train enough qualified psychological care nurses. A greater understanding of psychological care competences (PCC) can help in clinical nurse selection, training, and assessment.ObjectiveTo develop a PCC framework for Chinese nurses and obtain a consensus on the framework among experts.MethodsA descriptive mixed methods study was designed consisting of a literature review and semi-structured interviews followed by three Delphi rounds. The experts (n = 16) involved were nurses, nursing managers and educators from nine Chinese provinces with a specific interest in psychological care. Descriptive statistics assisted in data analysis.ResultsUsing the Iceberg Model as a theoretical foundation, five main dimensions and associated subdomains were integrated from 39 chosen articles. The semi-structured interviews with 24 nursing managers and nurses confirmed all of the themes from the literature review while generating new themes, both of which were incorporated into the initial PCC framework. After three Delphi rounds, the experts reached consensus on the PCC framework, including five domains (knowledge, skills, professional ethics, personal traits, internal motivations) and 22 subdomains with connotations. The response rate (RR) values for the three rounds of consultation were 80.00%, 87.50% and 92.86%, the composite reliability (Cr) values were 0.89–0.90, and the Kendall coordination coefficients were 0.155-0.200 (P < 0.05).ConclusionsOn the basis of the Iceberg Model, literature review and qualitative research methods along with Delphi technique were used to develop a scientific and systematic PCC framework. The research methods were feasible and the results were reliable, thereby providing a basis for adopting this framework into nursing education. A formal assessment tool should be developed to test the PCC of nurses in clinical practice.

Similarities and differences among selected gemmological varieties of chalcedony: chemistry, mineralogy and microstructure

AbstractThis study describes a new variety of chalcedony with a unique inhomogeneous bluish green hue, named aquaprase. It was discovered in Africa and is considered to be a valuable addition to the gem trade. A multi-methodological approach was used to examine its chemistry, mineralogy and microstructure, which were then compared to those of chrysoprase and agate, two of the most popular varieties of chalcedony. Optical microscopy revealed a complex microstructural heterogeneity in the different colour intensity areas/bands of aquaprase and agate, whereas chrysoprase exhibited a more homogeneous coexistence of micro- and cryptocrystalline quartz. High-resolution synchrotron XRD was essential for highlighting the complex assemblage of various types of α-quartz in aquaprase and agate (which differ in terms of crystal size and/or cell parameters). Micro-Raman spectroscopy revealed α-quartz and moganite in all three varieties of chalcedony and the presence of the nickel-bearing layered silicate mineral, willemseite, in chrysoprase, which is responsible for its green colouration. The chemical analysis displayed a homogeneous composition of agate, as well as high levels of nickel content in the chrysoprase variety. Aquaprase showed significant amounts (ppm by weight) of trace elements (Al, Mg, Na, K, Ca, Ti, U and Fe) characteristic of its formation environment, as well as high values of Cr, which are thought to be the cause of its bluish green colouration.

Fear of COVID-19 as a mediator within the impact of presenteeism on social loafing1.

The coronavirus disease 2019 (COVID-19) pandemic caused employees to be mentally absent at work and decreased their motivation and effort when they work collaboratively rather than individually due to the fear of transmission. The study aims to test the effect of fear caused by COVID-19 on levels of presenteeism and social loafing from job tasks of employees. Data were collected from 522 white-collar and blue-collar workers in Turkey by the snowball sampling method. Before testing the hypotheses, CFA was performed. Reliability analysis was assessed via Cronbach Alpha (FCV-19S = 0.941; PS = 0.713; SLS = 0.974), AVE (FCV-19S = 0.686; PS = 0.524; SLS = 0.725), and CR (FCV-19S = 0.734; PS = 0.722; SLS = 0.856) values. The mediating effect of fear of COVID-19 within the impact on presenteeism on social loafing was evaluated through Process Macro for SPSS. The coefficients for both direct and indirect effects were calculated in the 95% confidence interval using 5,000 bootstrap replicates. The results show that presenteeism has a significant positive impact on social loafing. Fear of COVID-19 has a statistically significant impact on presenteeism and social loafing. Also, fear of COVID-19 partially mediates within the impact of presenteeism on social loafing in the study. Organizations should consider employees' views to increase the level of well-being and productivity. A high level of inventiveness from organizations is compulsory to explore which organizational roles and workflow are at least remotely operated during this period.

Potential toxic heavy metals in village rainwater runoff of antimony mining area, China: Distribution, pollution sources, and risk assessment

The potential toxic heavy metal runoff from antimony mining areas poses a serious threat to the water environment and the health of residents in the village. The study found that the average concentrations of As, Sb, Cr, Pb, and Cd in the runoff were 0.1237, 0.1148, 0.0332, 0.0140, and 0.0013 mg/L, which were higher than the normal average concentrations in the water environment of 0.018, 0.0009, 0.05, 0.012, and 0.000013 mg/L, respectively.Sb and As are severely polluted, while Cd, Pb, and Cr have lower pollution levels. The coefficients of variation for As, Sb, Cr, Pb, and Cd range from 0.079 to 1.051, with Sb showing exceptionally high variability. Heavy metal elements Pb, Cd, and Sb accumulate in the southeastern area of the village, with Sb concentrations decreasing from the southeast to the northwest. As is mainly distributed in the northeastern part of the village, while Cr is primarily found in the central-western region. Source analysis indicates that As and Sb originate from mining and industrial activities, dust deposition, and domestic sewage. Cr comes from the natural geological background and metal product industry, Pb from lead-acid batteries, industrial activities, and gasoline additives, and Cd from fertilization in residential green areas and pesticide use. Health risk analysis reveals that the hazard index (HI) values for As and As in the water environment are 1.49 and 2.31, respectively, both exceeding 1, posing a serious threat to the health of village residents. The HI values for Pb, Cr, and Cd elements are all below 1, indicating lower risks. This study identified that Sb in the antimony ore area and its associated metal element As are the main elements leading to potential heavy metal pollution in the runoff of village residential areas, providing direction for subsequent water environment restoration work.

First report of saffron latent virus in Crocus sativus from Hungary.

In early April of 2018 we sampled asymptomatic autumn flowering Crocus plants (Fig. S1.) in a private collection in Hajdú-Bihar county, Hungary. From each species (Cr. kotschyanus subsp. kotschyanus, Cr. sativus, Cr. speciosus) 200 mg leaf sample was collected from 5 neighboring shoot, which were treated as one sample. ELISA tests were carried out in duplicates using potyvirus-specific MAb PTY1 antibodies (Jordan and Hammond 1991) on the samples (Agdia, Elkhart, IN, USA). A sample was considered positive if the absorbance was at least three times greater than that of the negative control. Only one sample tested positive; the absorbance values of Cr. sativus leaves were 0.013 and 0.014, while the negative controls were 0.002 and 0.003, respectively. The samples were further tested by RT-PCR for potyviruses (Salamon and Palkovics 2005), tomato spotted wilt virus (TSWV) (Nemes and Salánki 2020) and nepovirus subgroup A (Digiaro et al. 2007). Total nucleic acid was extracted with the phenol-chloroform method of White and Kaper (1989), and reverse transcription was carried out with Maxima H Minus First Strand cDNA Synthesis Kit (Thermo Fisher Scientific Baltics UAB, Vilnius, Lithuania) using random hexamer primer. The samples were negative for TSWV and nepovirus subgroup A, but a single PCR product of ~ 1700 nucleotide (nt) was amplified with potyvirus specific primers and cloned into pGEM®-T Easy vector (Promega, Madison, WI, USA). The 1726 nt long insert sequence, including the complete coat protein region was determined and deposited in the NCBI GenBank database (Accession No: OR425160). Digestion of the original PCR products with restriction enzyme SacI yielded only the predicted restriction fragments (364 / 1362 bp), indicating the presence of only a single potyvirus in the infected sample. BLASTn analysis of the CP cistron revealed the highest nt identities to saffron latent virus (SaLV) Iranian isolates (GenBank AccNo.: MN990394 - 85.44%, MN990415 - 85.39% and RefSeq: NC_036802 - 84.05%). For phylogenetic analyses MEGA11 (Tamura et al. 2021) was used. The resulting Maximum Likelihood tree (Fig. S2) showed that all Iranian SaLV isolates grouped together, while the Hungarian isolate is on an adjacent branch, separate from other virus species, and supported with 100% bootstrap values. From these results, it appears that the Hungarian isolate has been separated from the Iranian clade, and has evolved separately as a distinct lineage. We were unable to fulfill Koch's postulates as all available Crocus sativus plants were infected with SaLV. Latent potyvirus infection of Crocus species, by bean yellow mosaic virus (BYMV), iris mild mosaic virus (IMMV), iris severe mosaic virus (ISMV) and turnip mosaic virus (TuMV) has been reported by Grilli Caiola and Faoro (2011). SaLV was first reported from Iran (Parizad et al. 2017), but to our knowledge has never been reported from Europe or from any current EPPO member state. Since Crocus species can be asymptomatic virus reservoirs, it is important that any certification scheme for production should require laboratory tests to prove the health of the plants; or advise growers to keep possible high value susceptible crops such as breeding material and nuclear stocks at a distance from crocuses to mitigate virus transmission between stocks. It is also advisable to grow infected lots far from healthy stocks and protected wild hosts. To our knowledge, this is the first report of SaLV from Hungary and from Europe.

The environmental impact of heavy metals in sediments of main valleys in the eastern side of Mosul City, Iraq.

Analyzing the geochemical changes in stream sediments can reveal important surface processes on Earth, like weathering, transportation, and cation exchange. The study area is located on the eastern side of Mosul, where valleys named Al-Rashediya, Al-Kharrazi, Al-Khosar, Al-Danffilli, and Al-Shor flow towards the Tigris River. These valleys' sediments contain diverse components like clay minerals, organic matter, iron oxides, carbonates, and heavy metals (H.M.s), either as part of these substances or adsorbed onto them. In this study, 36 sediment samples were gathered from these valleys. They underwent chemical analysis through X-ray fluorescence to ascertain their chemical constituents of major oxides. To understand the distribution of H.M.s in these sediments, correlation coefficient analysis and factor analysis were utilized. The study employed the geoaccumulation index (Igeo) and enrichment factor (E.F.) to evaluate sediment contamination. The results of Igeo ranged from Cr = 0.24 to 1.83, Ni = -0.92 to 0.77, Cu = -2.41 to 0.05, Zn = -1.83 to 0.89, Pb = -1.54 to 0.36, and As = -2.84 to 0.80. These findings suggest that the valley sediments are generally in the range of deficiency to minimal enrichment and moderate enrichment. However, Al-Danffilli Valley shows strong contamination levels for Cu, Zn, and Pb. The E.F. values for Cr = 3.63-12.50, Ni = 1.95-4.19, Cu = 0.69-12.36, Zn = 1.08-16.19, Pb = 1.25-62.16, and As = 0.60-1.79 indicate levels ranging from deficiency to minimal and moderate enrichment. Al-Danffilli Valley, in particular, was identified as ranging from moderate to extremely high enrichment, attributed to its location near industrial areas and its tributaries.

Examining the Relationship Among Leisure Satisfaction, Emotional Intelligence, Hedonia and Eudaimonia

This study aims to examine and understand the relationships between leisure satisfaction, emotional intelligence, hedonia and eudaimonia. The research data were gathered from 222 academic and administrative staff of Bitlis Eren University in Turkey using a questionnaire technique through previous studies measurement scales. Firstly, SPSS 23 Program was used to make an explanatory factor analysis. In the following step, the data were analysed through SmartPLS statistical software to test the structural equation model of the study. In order to examine the measurement model of the study, Cronbach Alpha, CR and AVE values as well as discriminant validity findings were evaluated. Bootstrapping technique was used for the structural model analysis. As a result of the analysis, all three research hypotheses were accepted. Namely, analysis results prove that, from an in-depth perspective, leisure satisfaction affects emotional intelligence, and emotional intelligence affects hedonia and eudaimonia. On these results, promoting and spreading leisure activities throughout Bitlis by the university seems necessary for the staff to perform better. It is expected to increase the productivity of both academic and administrative staff and create a healthier working environment for Bitlis Eren University and other universities in Turkey. Therefore, it is crucial that various universities, especially Bitlis Eren University, encourage their staff to participate in some form of activities and take the initiative to organize these activities. Based on the results of this study, several theoretical and practical contributions are discussed.

Evaluation of essential and trace metals/metalloids distribution and probable human health risk implications from branded liquid and powder milks available in Dhaka City, Bangladesh.

The processed forms of milk, branded liquid, and power milk available in Dhaka city, the capital of Bangladesh, were investigated for essential and trace metal/metalloids regarding nutritional and human health risk aspects. For this, the potential nutritional contribution, estimated daily intake (EDI) and non-carcinogenic risk for six different life stages with male and female categories, as well as the carcinogenic risk for children and adults of both genders, were addressed. In total, 46 branded liquid and powder milk samples were considered for this analysis employing atomic absorption spectroscopy. The concentration of essential elements showed the trends of K > Ca > Na > Mg > Fe > Zn > Mn > Cu and K > Ca > Na > Mg > Fe > Cu > Mn > Zn for liquid and powder milk samples, respectively, but the potentially hazardous one showed the same trends (Cr > Pb > Hg > As > Cd) for both items. Except for Cr, Hg, and Fe, the elemental compositions of both milk categories differed considerably (< 0.05). Compared to the threshold values for milk samples (liquid and powder), Fe (19% and 27%), Mn (100% and 63%), Cu (0% and 23%), Zn (94% and 0%), Pb (25% and 13%), and Cr (0% and 3%) showed above the permissible limits. The nutrient input was the highest for Ca (27.2% and 18.7%), followed by Mg, K, and Na. The EDI of studied elements was within the daily permissible limit in both the milk category (except age group (≤ 3) and the female category). The non-carcinogenic risk assessment showed that the age groups ≤ 3 for liquid milk and ≤ 3 and 3 < X ≤ 14 with female categories for powder milk exceeded the threshold level (> 1) in the case of Cr, Cd, As, Zn, and Mn. The probable carcinogenic risks indicated an unacceptable risk level (< 1.00E-04) for the ingestion of Cr through powder milk samples for children in male and female categories. Finally, it believes that green cow farming practices and green milk processing technology, as well as continuous monitoring of toxic metals, can limit the ultimate risk worldwide.

Application of AHP Method in Determining Priority Work Accident Areas at CV Pesona Mebelindo

&lt;span lang="EN"&gt;This research aims to determine the priority order of work accident areas in the furniture business at CV Pesona Mebelindo. One of the urgencies of this research is that the number of work accidents in Indonesia is still relatively high, so prevention efforts are needed to minimize the number of work accidents. The method used in this research is Analytical Hierarchy Process (AHP). In this method, there are three important parts, namely goals, criteria and alternatives. The aim of this research is to determine priority areas for work accidents&lt;/span&gt;&lt;span lang="EN-ID"&gt;. &lt;/span&gt;&lt;span lang="EN"&gt;The criteria in this research include workers, environment and equipment. Meanwhile, alternatives in this research include the raw goods room, material room, sanding room, finishing, packing and stuffing. The data collection process was obtained from questionnaires filled out by workers at CV Pesona Mebelindo which were processed into a pairwise comparison matrix, matrix normalization, determining importance weights, and calculating consistency ratios with the condition that the CR value had to be below 10%. By using the Analytical Hierarchy Process (AHP) method, the priority order of work accident areas at CV Pesona Mebelindo was obtained, namely the sanding, finishing, packing, stuffing, materials room and raw goods room&lt;/span&gt;

Cumulative effect of chronic dehydration and age on postoperative complications after total shoulder arthroplasty

Dehydration is a modifiable risk factor that should be optimized prior to all surgical procedures. The aim of this study was to determine the effects of dehydration on postoperative complications following total shoulder arthroplasty (TSA). The American College of Surgeons National Surgical Quality Improvement database was queried for all patients who underwent TSA between 2015 and 2019 and a total of 16,993 patients were included in this study. The study population was subsequently classified into 3 categories: 8498 (50.0%) nondehydrated patients with blood urea nitrogen/creatinine (BUN/Cr)<20, 4908 (28.9%) moderately dehydrated patients with 20≤BUN/Cr≤25, and 3587 (21.1%) severely dehydrated patients with 25<BUN/Cr. A subgroup analysis involving only elderly patients aged > 65 years and normalized gender-adjusted Cr values was also performed. Postoperative complications within 30 days of the TSA were collected. Multivariate logistic regression analysis was conducted to explore the correlation between dehydration and postoperative complications. Adjusted multivariate logistic regression analysis showed that the severely dehydrated cohort had a greater risk of postoperative transfusion, mortality, nonhome discharge, and increased length of stay (all P<.05). The moderately dehydrated cohort had a greater risk of wound dehiscence (P=.044). Among the elderly, severely dehydrated patients had a greater risk of cardiac complications, postoperative transfusion, mortality, nonhome discharge, and increased length of stay (all P<.05). Finally, the elderly moderately dehydrated cohort had a greater risk of postoperative transfusion and nonhome discharge (all P<.05). BUN/Cr ratio is an important preoperative diagnostic tool to identify at-risk dehydrated patients. Providers should optimize dehydration to prevent complications, decrease costs, and improve discharge planning.

Geostatistical appraisal of water quality, contamination, source distribution of potentially toxic elements (PTEs) in the lower stretches of Subarnarekha River (Odisha), India, and health risk assessment by Monte Carlo simulation approach.

In the present study, the status of water quality, environmental contamination in the lower stretch of Subarnarekha River with respect to potentially toxic elements (PTEs), its seasonal distribution, and ecotoxicological health impacts were investigated. For this purpose, a combination of indexing approaches and geospatial methods was used. The estimated water quality index (WQI) has shown that the river water falls under "moderate to very poor" category during the pre-monsoon and "moderate to poor" category in the post-monsoon season. The abundance of PTEs (Pb, Cu, Ni, Cd, Fe, and Cr) was on the higher side during the pre-monsoon in comparison with the post-monsoon season. The results of contamination index (Cd) and heavy metal evaluation index (HEI) explain that Subarnarekha River has low-to-moderate levels of contamination with PTEs in the majority of sampling sites. However, HPI indicated that the river water is moderate-to-highly contaminated with PTEs in both seasons. Principal component analysis (PCA) and cluster analysis (CA) reveal that anthropogenic sources are prime contributors to PTEs contamination in Subarnarekha River. The potential non-cancerous health concerns for child and adults due to Cr and Pb in some sampling stations along the river stretch have been observed. The carcinogenic risk (CR) has been established for Cr, Pb, and Cd in Subarnarekha River with Cr (> 10-4) as the most unsafe element. Monte Carlo simulation (MCS) indicates a high risk of cancer hazards due to Cr (values > 1E-04) in present as well as future for both child and adults.

Source identification and health risk assessment of PM2.5 in urban districts of Hanoi using PCA/APCS and UNMIX.

Comparing results obtained by different models with different physical assumptions and constraints for source apportionment is important for better understanding the sources of pollutants. Source apportionment of PM2.5 measured at three sites located in inner urban districts of Hanoi was performed using two receptor models, UNMIX and principal component analysis with absolute principle component score (PCA/APCS). A total of 78 daily samples were collected consecutively during the dry and wet seasons in 2019 and 2020. The average PM2.5 concentration (66.26µg/m3 ± 29.70µg/m3 with a range from 23.57 to 169.04µg/m3) observed in Hanoi metropolitan exceeded the National Ambient Air Quality standard QCVN 05:2013/BTNMT (50µg/m3). Both UNMIX and PCA/APCS expressed comparable ability to reproduce measured PM2.5 concentrations. Additionally, both models identified similar potential sources of PM2.5 including traffic-related emissions, scrap metal recycling villages, crustal mixed with construction sources, coal combustion mixed with industry, and biomass burning. Both UNMIX and PCA/APCS confirmed that traffic-related emission was the most influential PM2.5 with a high percentage contribution of 59% and 55.97%, respectively. All the HQ and Cr values for both children and adults of toxic elements apportioned by both UNMIX and PCA/APCS in every source were within the acceptable range.

New approach into human health risk assessment associated with heavy metals in surface water and groundwater using Monte Carlo Method

This study assessed the environmental and health risks associated with heavy metals in the water resources of Egypt's northwestern desert. The current approaches included the Spearman correlation matrix, principal component analysis, and cluster analysis to identify pollution sources and quality-controlling factors. Various indices (HPI, MI, HQ, HI, and CR) were applied to evaluate environmental and human health risks. Additionally, the Monte Carlo method was employed for probabilistic carcinogenic and non-carcinogenic risk assessment via oral and dermal exposure routes in adults and children. Notably, all water resources exhibited high pollution risks with HPI and MI values exceeding permissible limits (HPI > 100 and MI > 6), respectively. Furthermore, HI oral values indicated significant non-carcinogenic risks to both adults and children, while dermal contact posed a high risk to 19.4% of samples for adults and 77.6% of samples for children (HI > 1). Most water samples exhibited CR values exceeding 1 × 10–4 for Cd, Cr, and Pb, suggesting vulnerability to carcinogenic effects in both age groups. Monte Carlo simulations reinforced these findings, indicating a significant carcinogenic impact on children and adults. Consequently, comprehensive water treatment measures are urgently needed to mitigate carcinogenic and non-carcinogenic health risks in Siwa Oasis.

Pervasive Neoarchean melting of subducted sediments generating sanukitoid and associated magmatism in the North China Craton, with implications for the operation of plate tectonics

Abstract The Mesoarchean to Neoarchean period (ca. 3.0–2.5 Ga) is the most important stage during the emergence and evolution of plate tectonics. However, plate subduction at this time may have been less stable and perhaps more susceptible to the lubrication effect of sediments than the modern counterpart. Such predictions have not yet been verified by field-based investigations. In this work, we identified two types of rock units (i.e., sanukitoids and associated adakitic suites, exposed in the Eastern Hebei Complex of the North China Craton) and illustrated their petrogenesis and tectonic context through field, geochronologic, geochemical, and isotopic investigations. Laser ablation–inductively coupled plasma–mass spectrometry zircon U-Pb analyses suggest that the two magmatic suites formed within a relatively short time span of ca. 2596–2544 Ma and ca. 2559–2533 Ma, respectively. The sanukitoids are composed of meta-andesites and diorite porphyrites and characterized by relatively high MgO (3.94–5.62 wt%), Mg# (50–61), Cr (73–343 ppm), and Ni (37–111 ppm) values. The adakitic rocks are composed of granodiorite-granite gneisses and have relatively high Sr (316–1001 ppm) and low Y (7–13 ppm) and Yb (0.83–1.37 ppm) contents, and relatively high Sr/Y (36–89) and La/Yb (16–45) ratios. Rocks from both suites exhibit depletions of Nb, Ta, and Ti and have similar Sr-Nd-Hf-Zn isotopes: variable (87Sr/86Sr)i (0.7002–0.7053), weakly positive εNd(t) (+0.3 to +1.7) and εHf(t) (+1.8 to +6.8), and slightly heavy δ66Zn (0.30‰–0.36‰). These geochemical characteristics indicate that the sanukitoids were derived from the melting of subducted sediments followed by melt-mantle interaction, whereas the adakitic rocks were produced by direct partial melting of subducted plate (including tonalite-trondjhemite-granodiorite melts) under a garnet stability field with minor sediments. Such distinct magmatic rock associations, together with the coeval charnockites and tholeiites with diverse compositions in the adjacent area, can be best explained by a slab breakoff model. Further, events associated with slab breakoff are likely to represent a transition of a quasi-plate tectonic regime, characterized by multiple, continuous, and stagnant attempts to start the modern-style subduction on Earth. In addition, the emergence of sanukitoids and associated magmas symbolized the onset of supracrustal recycling into the mantle. Combined with the Nd-Hf-Zn isotopes of diverse magmatic rocks in the North China Craton that are comparable to other Precambrian magmatic rock suites worldwide, we suggest that supracrustal recycling symbolized the onset of plate tectonics since ca. 3.0 Ga, and by inference played a key role in the development of subduction-driven plate tectonics in addition to Earth’s secular cooling.

Groundwater Environment and Health Risk Assessment in an In Situ Oil Shale Mining Area

To clarify the risk posed to groundwater in oil shale in situ mining areas, we examine five leached pollutants: Fe, Mn, Cr, sulfate, and ammonia nitrogen. Potential groundwater contents of these five pollutants were evaluated using an improved Nemero comprehensive index method and a health risk assessment method. The results show that, compared with the Class III groundwater quality standard (GB/T 14848-2017) used in the People’s Republic of China, average values of Fe, Mn, and sulfate in leaching solution from Fuyu oil shale exceed the standard, while Cr and ammonia nitrogen do not exceed the standard, and the leaching solution is within Class V groundwater quality. The average values of Fe and Mn in the leaching solution from Fushun oil shale exceed the Class III standard, while Cr, sulfate, and ammonia nitrogen values from this oil shale do not exceed the standard, and the leaching solution is Class IV in terms of groundwater quality. The weighting value used in the Nemero assessment method for the heavy metal Cr is the largest as its potential to cause harm to groundwater quality is the largest. The weight value for sulfate is the smallest as the harm degree is the smallest. The chemical carcinogen Cr has the greatest potential impact on human health. The health risk caused by the chemical non-carcinogen Mn is greater than that caused by Fe and ammonia nitrogen. When high pyrolysis temperatures are used, Mn will be released into groundwater in large quantities. Therefore, supervision and control should be strengthened. The results presented here can provide a reference for the comprehensive evaluation of groundwater risks caused by in situ oil shale mining.